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    Molecularly-imprinted material made by template-directed synthesis
    1.
    发明授权
    Molecularly-imprinted material made by template-directed synthesis 失效
    通过模板指导合成制备的分子印迹材料

    公开(公告)号：US06713416B2

    公开(公告)日：2004-03-30

    申请号：US10337723

    申请日：2003-01-08

    申请人： Michael A. Markowitz ,  Paul E. Schoen ,  Bruce P. Gaber ,  Banahalli R. Ratna ,  Paul R. Kust ,  David C. Turner ,  Douglas S. Clark ,  Jonathan S. Dordick

    发明人： Michael A. Markowitz ,  Paul E. Schoen ,  Bruce P. Gaber ,  Banahalli R. Ratna ,  Paul R. Kust ,  David C. Turner ,  Douglas S. Clark ,  Jonathan S. Dordick

    IPC分类号： C03C100

    CPC分类号： B82Y30/00 ,  B01J37/00 ,  C01B37/02 ,  C01P2004/52 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/16 ,  C09C1/3081 ,  Y10T436/10

    摘要： A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase. When reactive monomers are allowed to polymerize in the water phase to form particles, the surface of the particles have cavities that are the mirror image of the imprint group.

    摘要翻译： 制作分子印迹多孔结构的方法利用具有印迹分子部分作为表面活性剂头基的要印迹的分子的表面活性剂类似物。 允许表面活性剂类似物在混合物中自组装以产生具有暴露的印迹基团的至少一个超分子结构。 通过将反应性单体加入到混合物中并使单体以超分子结构作为模板聚合而形成印迹多孔结构。 所得到的固体结构具有与超分子结构的形状互补的形状，并且具有作为印迹组的镜像的空腔。 类似地，分子印迹的颗粒可以通过使用表面活性剂来制备油包水微乳液，其中印迹组暴露于水相。 当使反应性单体在水相中聚合以形成颗粒时，颗粒的表面具有作为印迹组的镜像的空腔。

    Molecularly-imprinted material made by template-directed synthesis
    2.
    发明授权
    Molecularly-imprinted material made by template-directed synthesis 失效
    通过模板指导合成制备的分子印迹材料

    公开(公告)号：US06310110B1

    公开(公告)日：2001-10-30

    申请号：US09363819

    申请日：1999-07-30

    申请人： Michael A. Markowitz ,  Paul E. Schoen ,  Bruce P. Gaber ,  Banahalli R. Ratna ,  Paul R. Kust ,  David C. Turner ,  Douglas S. Clark ,  Jonathan S. Dordick

    发明人： Michael A. Markowitz ,  Paul E. Schoen ,  Bruce P. Gaber ,  Banahalli R. Ratna ,  Paul R. Kust ,  David C. Turner ,  Douglas S. Clark ,  Jonathan S. Dordick

    IPC分类号： C01B3312

    CPC分类号： B82Y30/00 ,  B01J37/00 ,  C01B37/02 ,  C01P2004/52 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/16 ,  C09C1/3081 ,  Y10T436/10

    摘要： A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase. When reactive monomers are allowed to polymerize in the water phase to form particles, the surface of the particles have cavities that are the mirror image of the imprint group.

    摘要翻译： 制作分子印迹多孔结构的方法利用具有印迹分子部分作为表面活性剂头基的要印迹的分子的表面活性剂类似物。 允许表面活性剂类似物在混合物中自组装以产生具有暴露的印迹基团的至少一个超分子结构。 通过将反应性单体加入到混合物中并使单体以超分子结构作为模板聚合而形成印迹多孔结构。 所得到的固体结构具有与超分子结构的形状互补的形状，并且具有作为印迹组的镜像的空腔。 类似地，分子印迹的颗粒可以通过使用表面活性剂来制备油包水微乳液，其中印迹组暴露于水相。 当使反应性单体在水相中聚合以形成颗粒时，颗粒的表面具有作为印迹组的镜像的空腔。