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    Procedure for the thermal treatment of powdered and granulated catalysts and the like
    1.
    发明授权
    Procedure for the thermal treatment of powdered and granulated catalysts and the like 失效
    粉末和粒状催化剂等的热处理步骤

    公开(公告)号：US4399350A

    公开(公告)日：1983-08-16

    申请号：US273197

    申请日：1981-08-21

    申请人： Michael Schneider ,  Karl Kochloefl ,  Gerhard Diez ,  Franz Maier ,  Josef E. Rauch ,  Wolfgang Liebelt

    发明人： Michael Schneider ,  Karl Kochloefl ,  Gerhard Diez ,  Franz Maier ,  Josef E. Rauch ,  Wolfgang Liebelt

    IPC分类号： B01J8/16 ,  B01J37/08 ,  F27B9/06

    CPC分类号： B01J8/16 ,  B01J37/08

    摘要： Process for the thermal treatment of powdered and granulated catalysts, catalyst intermediate products, and inorganic substances, which are usable as constituents of catalysts or as auxiliary agents for the production of catalysts. The known process material is placed on a heated vibrating conveyor and there, in the form of a thin layer, in which the particles of the process material are moved with a larger horizontal and a smaller vertical component, heated and allowed to cool either outside the vibrating conveyor or in a separate vibrating conveyor or in the outlet portion of the first vibrating conveyor.

    摘要翻译： 用于粉末和颗粒化催化剂，催化剂中间产物和无机物质的热处理方法，其可用作催化剂的成分或作为催化剂生产的辅助剂。 将已知的处理材料放置在加热的振动输送机上，并且其中以薄层的形式，处理材料的颗粒以较大的水平和较小的垂直分量移动，加热并允许其在 振动输送机或在单独的振动输送机中或在第一振动输送机的出口部分中。

    SiO.sub.2 -containing cooper oxide-chromium oxide catalyst for the hydrogenation of fatty acids and fatty esters
    2.
    发明授权
    SiO.sub.2 -containing cooper oxide-chromium oxide catalyst for the hydrogenation of fatty acids and fatty esters 失效
    含氧化合物氧化铬氧化物催化剂用于加氢脂肪酸和脂肪酸

    公开(公告)号：US5217937A

    公开(公告)日：1993-06-08

    申请号：US795493

    申请日：1991-11-21

    申请人： Michael Schneider ,  Gerd Maletz ,  Karl Kochloefl

    发明人： Michael Schneider ,  Gerd Maletz ,  Karl Kochloefl

    IPC分类号： B01J23/86 ,  C07B61/00 ,  C07C29/149 ,  C07C31/125

    CPC分类号： B01J23/868 ,  C07C29/149 ,  Y10S502/524

    摘要： An SiO.sub.2 -containing copper oxide-chromium oxide catalyst is obtained through heat treatment of copper oxide and chromium oxide, or of a precursor compound convertible into copper oxide or chromium oxide in the presence of an SiO.sub.2 component; it is characterized by the fact that, after the heat treatment,(a) the intensity ratio between the X-ray diffraction lines (XRD reflexes) of the copper oxide with d=0.232 nm and of the CuCr.sub.2 O.sub.4 spinel with d=0.240 nm formed through heat treatment, determined as the ratio of the reflex amplitudes, is 0.7 to 4.0:1, and(b) the copper mass, which is dissolved by stirring 10 g of the catalyst in 100 ml of 10 weight percent acetic acid at 20.degree. C. for 2 minutes, amounts to a maximum of 200 mg.

    摘要翻译： 通过氧化铜和氧化铬的热处理，或在SiO2组分存在下可转化为氧化铜或氧化铬的前体化合物，得到含SiO 2的氧化铜 - 氧化铬催化剂; 其特征在于，在热处理后，（a）形成d = 0.232nm的氧化铜的X射线衍射线（XRD反射）与d = 0.240nm的CuCr 2 O 4尖晶石之间的强度比 通过作为反射幅度的比率确定的热处理为0.7〜4.0:1，（b）通过在10g 20重量％乙酸中在20℃下搅拌10g催化剂而溶解的铜质量 2分钟，最多达200毫克。

    Catalyst for decreasing the content of nitrogen oxides in flue gases
    3.
    发明授权
    Catalyst for decreasing the content of nitrogen oxides in flue gases 失效
    用于降低烟道气中氮氧化物含量的催化剂

    公开(公告)号：US4722918A

    公开(公告)日：1988-02-02

    申请号：US895406

    申请日：1986-08-11

    申请人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

    发明人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

    IPC分类号： B01J21/16 ,  B01D53/56 ,  B01D53/86 ,  B01D53/94 ,  B01J8/00 ,  B01J20/12 ,  B01J21/12 ,  B01J23/10 ,  B01J23/16 ,  B01J23/22 ,  B01J23/24 ,  B01J37/00 ,  C01B21/20

    CPC分类号： B01J21/16 ,  B01D53/8628 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/1066

    摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate). The three-layer silicate is acid-activated while essentially retaining its crystalline layer structure. The three-layer silicate has a cation-exchange capacity of 30 mvals/100 g or more before acid activation. The acid activation lowers the concentration of interlayer cations and increases the BET surface at least 15% and preferably at least 50% in terms of the BET surface of the three-layer silicate before acid activation. The atomic ratio of the silicon in the acid-activated three-layer silicate to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.

    摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 该催化剂含有一种或多种氧化物与具有三层结构的硅酸盐（三层硅酸盐）结合的钛，锆，钒，钨，钼或铈中的至少一种。 三层硅酸盐是酸活化的，同时基本保持其结晶层结构。 三层硅酸盐在酸活化之前的阳离子交换容量为30mΩ/ 100g以上。 酸活化降低了层间阳离子的浓度，并且在酸活化之前，三层硅酸盐的BET表面以BET表示增加至少15％，优选至少为50％。 酸活化三层硅酸盐中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。

    Acid-resistant copper oxide-chromium oxide catalyst for the hydrogenation of fatty acids and fatty esters
    5.
    发明授权
    Acid-resistant copper oxide-chromium oxide catalyst for the hydrogenation of fatty acids and fatty esters 失效
    用于加氢脂肪酸和脂肪酸的耐酸铜氧化物氧化物催化剂

    公开(公告)号：US5206203A

    公开(公告)日：1993-04-27

    申请号：US795491

    申请日：1991-11-21

    申请人： Michael Schneider ,  Gerd Maletz ,  Karl Kochloefl

    发明人： Michael Schneider ,  Gerd Maletz ,  Karl Kochloefl

    IPC分类号： B01J23/86 ,  C07B61/00 ,  C07C29/149 ,  C07C31/02 ,  C07C31/125

    CPC分类号： B01J23/868 ,  C07C29/149

    摘要： Acid-resistant copper oxide-chromium oxide catalysts for hydrogenation of fatty acids or fatty acid mixtures and/or the esters thereof are obtained through heat treatment of copper oxide and chromium oxide or of precursor compounds that are convertible into copper oxide or chromium oxide and which contain aluminum zirconium, cerium and/or lanthanum oxide as an additional metal component. The acid resistance is defined by the fact that the amount of copper which is dissolved by stirring 10 g of the catalyst for 2 minutes in 100 ml of 10 weight percent acetic acid at 20.degree. C., is a maximum of 200 mg.

    摘要翻译： 通过热处理氧化铜和氧化铬或可转化为氧化铜或氧化铬的前体化合物，可获得用于脂肪酸或脂肪酸混合物和/或其酯氢化的耐酸氧化铜 - 氧化铬催化剂，其中 含有锆锆，铈和/或氧化镧作为附加金属组分。 耐酸性由以下事实定义：通过在20℃下在100ml 10重量％乙酸中搅拌10g催化剂2分钟而溶解的铜的量最多为200mg。

    Catalyst for decreasing the content of nitrogen oxides in flue gases
    6.
    发明授权
    Catalyst for decreasing the content of nitrogen oxides in flue gases 失效
    用于降低烟道气中氮氧化物含量的催化剂

    公开(公告)号：US4734391A

    公开(公告)日：1988-03-29

    申请号：US895559

    申请日：1986-08-11

    申请人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

    发明人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

    IPC分类号： B01D53/86 ,  B01J21/16 ,  B01J20/16

    CPC分类号： B01J21/16 ,  B01D53/8628

    摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate) selected from the group consisting of illite and mica. The atomic ratio of the silicon in the three-layer silicate to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.

    摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 催化剂含有至少一种金属钛，锆，钒，钨，钼或铈，其中一种或多种氧化物与具有三层结构（三层硅酸盐）的硅酸盐形式组合，所述三层结构（三层硅酸盐）选自 由伊利石和云母组成的组。 三层硅酸盐中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。

    Chromium-free catalyst based on iron oxide for conversion of carbon monoxide
    7.
    发明授权
    Chromium-free catalyst based on iron oxide for conversion of carbon monoxide 失效
    基于氧化铁的无铬催化剂用于转化一氧化碳

    公开(公告)号：US5830425A

    公开(公告)日：1998-11-03

    申请号：US766391

    申请日：1996-12-12

    申请人： Michael Schneider ,  Karl Kochloefl ,  Gerd J. Maletz ,  Jurgen Ladebeck ,  Christoph Heinisch

    发明人： Michael Schneider ,  Karl Kochloefl ,  Gerd J. Maletz ,  Jurgen Ladebeck ,  Christoph Heinisch

    IPC分类号： B01J23/745 ,  B01J23/83 ,  B01J23/89 ,  C01B3/16 ,  C01B31/20

    CPC分类号： B01J23/8946 ,  B01J23/745 ,  B01J23/83 ,  B01J23/8926 ,  C01B3/16 ,  Y02P20/52

    摘要： The invention relates to a catalyst for conversion of carbon monoxide with steam into hydrogen, carbon dioxide and hydrogen-rich synthesis gases. The conversion can be done at temperatures above roughly 300.degree. C. In addition, a chromium-free catalyst for the aforementioned purpose is described which contains the following in "application form:" (a) 30-98% by weight iron oxide, computed as Fe.sub.2 O.sub.3 ; (b) 0.1-20% by weight copper oxide, computed as CuO; (c) 0.1-20% by weight of an oxide of the rare earth levels computed as Me.sub.2 O.sub.3 (in which Me is a rare earth metal) and/or zirconium oxide, computed as ZrO.sub.2 ; (d) 0.1-30% by weight of at least one oxide of one or several other base metals with an ionic radius from 50 to 72 pm (other than chromium) (e) 0-0.1% by weight of at least one oxide of one or several precious metals from the platinum group; (f) 0-30% by weight barium oxide.

    摘要翻译： 本发明涉及一氧化碳与蒸汽转化为氢气，二氧化碳和富氢合成气体的催化剂。 该转化可以在高于约300℃的温度下进行。此外，描述了用于上述目的的无铬催化剂，其在“申请形式”中包含以下内容：（a）30-98重量％的氧化铁，计算 作为Fe2O3; （b）0.1-20重量％的氧化铜，以CuO计算; （c）以ZrO 2计算的作为Me 2 O 3（其中Me是稀土金属）和/或氧化锆计算的稀土含量的0.1-20重量％ （d）0.1-30重量％的至少一种氧化物，其一种或多种其它贱金属的氧化物，其离子半径为50至72μm（不同于铬）（e）0-0.1重量％的至少一种氧化物 来自铂族的一种或几种贵金属; （f）0-30重量％的氧化钡。

    Catalyst for decreasing the content of nitrogen oxides in flue gases
    10.
    发明授权
    Catalyst for decreasing the content of nitrogen oxides in flue gases 失效
    用于降低烟道气中氮氧化物含量的催化剂

    公开(公告)号：US4719192A

    公开(公告)日：1988-01-12

    申请号：US895558

    申请日：1986-08-11

    申请人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

    发明人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

    IPC分类号： B01J21/16 ,  B01D53/56 ,  B01D53/86 ,  B01D53/94 ,  B01J8/00 ,  B01J20/12 ,  B01J21/12 ,  B01J23/10 ,  B01J23/16 ,  B01J23/22 ,  B01J23/24 ,  B01J37/00 ,  C01B21/20

    CPC分类号： B01J21/16 ,  B01D53/8628 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/1066

    摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate) which is or comprises talc. The three-layer silicate is preferably acid-activated while essentially retaining its crystalline layer structure and being not yet X-ray amorphous. The acid activation increases the BET surface area at least 15% and preferably at least 50% in terms of the BET surface area of the talc before acid activation. The atomic ratio of the silicon in the talc to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.

    摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 催化剂含有至少一种金属钛，锆，钒，钨，钼或铈，其中一种或多种氧化物与具有三层结构的硅酸盐（三层硅酸盐）结合的形式，其是或 包括滑石。 三层硅酸盐优选是酸活化的，同时基本保持其结晶层结构并且还不是X射线无定形的。 在酸活化之前，酸活化使得BET表面积以滑石粉的BET表面积计增加至少15％，优选至少50％。 滑石中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。