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    SILANE COUPLING AGENTS FOR FILLED RUBBERS
    2.
    发明申请
    SILANE COUPLING AGENTS FOR FILLED RUBBERS 有权
    用于填充橡胶的硅烷偶联剂

    公开(公告)号：US20100261826A1

    公开(公告)日：2010-10-14

    申请号：US12678165

    申请日：2008-09-05

    申请人： Michele Gerster ,  Manuel Mihalic

    发明人： Michele Gerster ,  Manuel Mihalic

    IPC分类号： C08K3/36 ,  C08L9/00 ,  C08K3/22 ,  C07F7/18

    CPC分类号： C08K5/548 ,  C08L21/00

    摘要： The invention describes a composition comprising a) a naturally occurring or synthetic rubber susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula I wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula I.

    摘要翻译： 本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成橡胶，b）白色增强填料，和c）作为偶联剂，至少一种 式I化合物，其中通式如权利要求1所定义，或式I化合物的低聚水解产物。

    PERFLUOROALKYL SUBSTITUTED PHENOL DERIVATIVES AS SURFACE MODIFIERS
    3.
    发明申请
    PERFLUOROALKYL SUBSTITUTED PHENOL DERIVATIVES AS SURFACE MODIFIERS 失效
    全氟烷基取代的苯酚衍生物作为表面改性剂

    公开(公告)号：US20090242822A1

    公开(公告)日：2009-10-01

    申请号：US12310259

    申请日：2007-08-29

    申请人： Michele Gerster ,  Manuel Mihalic

    发明人： Michele Gerster ,  Manuel Mihalic

    IPC分类号： D06M15/687 ,  C08K5/136 ,  C08K5/375 ,  C07C321/20 ,  C07C271/58

    CPC分类号： C07C69/82 ,  C07C43/225 ,  C07C43/23 ,  C07C43/315 ,  C07C69/63 ,  C07C69/65 ,  C07C69/712 ,  C07C235/20 ,  C07C271/44 ,  C07C271/58 ,  C07C323/16 ,  C08K5/06 ,  C08K5/10 ,  C08K5/136 ,  C08K5/205 ,  C08K5/375

    摘要： The instant invention relates to a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least one compound of the formula (I) wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH2—CH(CH3)—S(O)p—R12, —CH2—CH2—CH2—S(O)p—R12, —CH2—CH(R11)—CH2—R12 or —CH2—CH═CH—R12, R11 is hydrogen or halogen, R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms; or —CH2CH2(CF2)mCF3, m is 3 to 12, and p is 0, 1 or 2. The compounds of the formula I are useful as reducers of surface energy for organic materials, for example synthetic polymer. Polymers with such a reduced surface energy possess an “easy-to-clean”, “self-cleaning” “antisoiling”, “soil-release” “antigraffiti”, “oil resistance”, “solvent resistance”, “chemical resistance”, “self lubricating”, “scratch resistance”, “low moisture absorption”, “dirt pickup resistance”, “slip properties” and “hydrophobic surface”; and anti-adhesion properties against proteins and against microorganism such as for example bacteria, fungi and algae.

    摘要翻译： 本发明涉及一种组合物，其包含a）对氧化，热或光诱导降解敏感的有机材料，和b）至少一种式（I）化合物，其中一般符号如权利要求1所定义; 特别是其中基团R 2，R 3或R 4中的至少一个为-CH 2 -CH（CH 3）-S（O）p -R 12，-CH 2 -CH 2 -CH 2 -S（O）p -R 12，-CH 2 -CH（ R11）-CH2-R12或-CH2-CH-CH-R12，R11是氢或卤素，R12是具有四至二十个完全氟化的碳原子的一价全氟化烷基或烯基，直链或支链有机基团; 或-CH 2 CH 2（CF 2）m CF 3，m为3至12，p为0,1或2.式I化合物可用作有机材料例如合成聚合物的表面能的还原剂。 具有这种表面能降低的聚合物具有“易清洁”，“自清洁”“防污”，“释放”“防刮涂”，“耐油性”，“耐溶剂性”，“耐化学性” “自润滑”，“耐划伤性”，“低吸湿性”，“抗污性”，“滑爽性”和“疏水性表面”; 和抗蛋白质和抗微生物（例如细菌，真菌和藻类）的抗粘附性。

    Silane coupling agents for filled rubbers
    4.
    发明授权
    Silane coupling agents for filled rubbers 有权
    用于填充橡胶的硅烷偶联剂

    公开(公告)号：US08252862B2

    公开(公告)日：2012-08-28

    申请号：US12678165

    申请日：2008-09-05

    申请人： Michele Gerster ,  Manuel Mihalic

    发明人： Michele Gerster ,  Manuel Mihalic

    IPC分类号： C08K3/34 ,  C08K3/22

    CPC分类号： C08K5/548 ,  C08L21/00

    摘要： The invention describes a composition comprising a) a naturally occurring or synthetic rubber susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula I wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula I.

    摘要翻译： 本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成橡胶，b）白色增强填料，和c）作为偶联剂，至少一种 式I化合物，其中通式如权利要求1所定义，或式I化合物的低聚水解产物。

    S-perfluoroalkyl substituted hydroxybenzylthioethers and derivatives as surface modifiers
    6.
    发明授权
    S-perfluoroalkyl substituted hydroxybenzylthioethers and derivatives as surface modifiers 失效
    S-全氟烷基取代的羟基苄基硫醚及其衍生物作为表面改性剂

    公开(公告)号：US08246859B2

    公开(公告)日：2012-08-21

    申请号：US12308036

    申请日：2007-06-04

    申请人： Michèle Gerster ,  Manuel Mihalic

    发明人： Michèle Gerster ,  Manuel Mihalic

    IPC分类号： C09K15/10 ,  C09K15/12 ,  C07C317/00 ,  C07C319/00

    CPC分类号： C08K5/42

    摘要： The invention describes a process for reducing the surface energy of organic materials such as for example increasing the oil and water repellency and stain release of organic materials, which comprises treating the organic material with at least a compound of the formula I wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH(R11)—S(O)p—R12; R11 is hydrogen, C1-C8alkyl, unsubstituted or with C1-C4alkyl substituted phenyl; R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms, and p is 0, 1 or 2.

    摘要翻译： 本发明描述了一种减少有机材料的表面能的方法，例如增加有机材料的防水和防水性和污迹释放，其包括用至少一种式I化合物处理有机材料，其中通式为 如权利要求1所定义; 特别是其中基团R 2，R 3或R 4中的至少一个为-CH（R 11）-S（O）p -R 12; R11是氢，未被取代的C 1 -C 8烷基或与C 1 -C 4烷基取代的苯基; R12是具有四至二十个完全氟化的碳原子的一价全氟化烷基或烯基，直链或支链有机基团，p是0,1或2。

    Perfluoroalkyl substituted phenol derivatives as surface modifiers
    8.
    发明授权
    Perfluoroalkyl substituted phenol derivatives as surface modifiers 失效
    全氟烷基取代酚衍生物作为表面改性剂

    公开(公告)号：US08258217B2

    公开(公告)日：2012-09-04

    申请号：US12310259

    申请日：2007-08-29

    申请人： Michèle Gerster ,  Manuel Mihalic

    发明人： Michèle Gerster ,  Manuel Mihalic

    IPC分类号： C08K5/136 ,  C08K5/375

    CPC分类号： C07C69/82 ,  C07C43/225 ,  C07C43/23 ,  C07C43/315 ,  C07C69/63 ,  C07C69/65 ,  C07C69/712 ,  C07C235/20 ,  C07C271/44 ,  C07C271/58 ,  C07C323/16 ,  C08K5/06 ,  C08K5/10 ,  C08K5/136 ,  C08K5/205 ,  C08K5/375

    摘要： The instant invention relates to a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least one compound of the formula (I) wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH2—CH(CH3)—S(O)p—R12, —CH2—CH2—CH2—S(O)p—R12, —CH2—CH(R11)—CH2—R12 or —CH2—CH═CH—R12, R11 is hydrogen or halogen, R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms; or —CH2CH2(CF2)mCF3, m is 3 to 12, and p is 0, 1 or 2. The compounds of the formula I are useful as reducers of surface energy for organic materials, for example synthetic polymer. Polymers with such a reduced surface energy possess an “easy-to-clean”, “self-cleaning” “antisoiling”, “soil-release” “antigraffiti”, “oil resistance”, “solvent resistance”, “chemical resistance”, “self lubricating”, “scratch resistance”, “low moisture absorption”, “dirt pickup resistance”, “slip properties” and “hydrophobic surface”; and anti-adhesion properties against proteins and against microorganism such as for example bacteria, fungi and algae.

    摘要翻译： 本发明涉及一种组合物，其包含a）对氧化，热或光诱导降解敏感的有机材料，和b）至少一种式（I）化合物，其中一般符号如权利要求1所定义; 特别是其中基团R 2，R 3或R 4中的至少一个为-CH 2 -CH（CH 3）-S（O）p -R 12，-CH 2 -CH 2 -CH 2 -S（O）p -R 12，-CH 2 -CH（ R 11）-CH 2 -R 12或-CH 2 -CH = CH-R 12，R 11是氢或卤素，R 12是具有四至二十个完全氟化的碳原子的一价全氟化烷基或链烯基的直链或支链有机基团; 或-CH 2 CH 2（CF 2）m CF 3，m为3至12，p为0,1或2.式I化合物可用作有机材料例如合成聚合物的表面能的还原剂。 具有这种表面能降低的聚合物具有“易清洁”，“自清洁”“防污”，“释放”“防刮涂”，“耐油性”，“耐溶剂性”，“耐化学性” “自润滑”，“耐划伤性”，“低吸湿性”，“抗污性”，“滑爽性”和“疏水性表面”; 和抗蛋白质和抗微生物（例如细菌，真菌和藻类）的抗粘附性。

    S-perfluoroalkyl substituted hydroxybenzylthioethers and derivatives as surface modifiers
    9.
    发明申请
    S-perfluoroalkyl substituted hydroxybenzylthioethers and derivatives as surface modifiers 失效
    S-全氟烷基取代的羟基苄基硫醚及其衍生物作为表面改性剂

    公开(公告)号：US20090326145A1

    公开(公告)日：2009-12-31

    申请号：US12308036

    申请日：2007-06-04

    申请人： Michèle Gerster ,  Manuel Mihalic

    发明人： Michèle Gerster ,  Manuel Mihalic

    IPC分类号： C08G63/48 ,  C07C321/10 ,  C08F8/34

    CPC分类号： C08K5/42

    摘要： The invention describes a process for reducing the surface energy of organic materials such as for example increasing the oil and water repellency and stain release of organic materials, which comprises treating the organic material with at least a compound of the formula I wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH(R11)—S(O)p—R12; R11 is hydrogen, C1-C8alkyl, unsubstituted or with C1-C4alkyl substituted phenyl; R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms, and p is 0, 1 or 2.

    摘要翻译： 本发明描述了一种减少有机材料的表面能的方法，例如增加有机材料的防水和防水性和污迹释放，其包括用至少一种式I化合物处理有机材料，其中通式为 如权利要求1所定义; 特别是其中基团R 2，R 3或R 4中的至少一个为-CH（R 11）-S（O）p -R 12; R11是氢，未被取代的C 1 -C 8烷基或与C 1 -C 4烷基取代的苯基; R12是具有四至二十个完全氟化的碳原子的一价全氟化烷基或烯基，直链或支链有机基团，p是0,1或2。