摘要:
The instant invention relates to a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least one compound of the formula (I) wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH2—CH(CH3)—S(O)p—R12, —CH2—CH2—CH2—S(O)p—R12, —CH2—CH(R11)—CH2—R12 or —CH2—CH═CH—R12, R11 is hydrogen or halogen, R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms; or —CH2CH2(CF2)mCF3, m is 3 to 12, and p is 0, 1 or 2. The compounds of the formula I are useful as reducers of surface energy for organic materials, for example synthetic polymer. Polymers with such a reduced surface energy possess an “easy-to-clean”, “self-cleaning” “antisoiling”, “soil-release” “antigraffiti”, “oil resistance”, “solvent resistance”, “chemical resistance”, “self lubricating”, “scratch resistance”, “low moisture absorption”, “dirt pickup resistance”, “slip properties” and “hydrophobic surface”; and anti-adhesion properties against proteins and against microorganism such as for example bacteria, fungi and algae.
摘要:
Organic materials which possess outstanding stability to oxidative, thermal or light-induced degradation comprise as stabilizers at least one compound of the formula (I) wherein the general symbols are as defined in claim 1. The compounds of formula I are especially useful as stabilizers for protecting polymers and lubricants against oxidative, thermal or light-induced degradation and as scavengers for oxidized developer in color photographic material.
摘要:
The invention describes a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least one melt additive of a compound of the formula I R1 (I) R3 X R2 wherein the general symbols are as defined in claim 1. The compounds of the formula I are useful as reducers of surface energy for organic materials, for example, for increasing the oil and water repellency of organic materials.
摘要翻译:本发明描述了一种组合物,其包含a)对氧化,热或光诱导降解敏感的有机材料,和b)式I R1(I)R3 X R2化合物的至少一种熔融添加剂,其中通用符号 如权利要求1中所定义。 式I的化合物可用作有机材料的表面能的还原剂,例如用于增加有机材料的防油和拒水性。
摘要:
A composition containing (I) a natural or synthetic organic polymer having a melt flow index of 15 to 1000 g/10 min at 230° C. and 2.16 kg and (II) an additive mixture containing components (A1) and (A2), wherein (A1) is at least one organic cyclic phosphoric acid ester of the formula (I) (I) wherein Ro is a direct bond, —S—, C3-C12cycloalkylidene or a group —C(Xi)(X2)— with X1 and X2 independently of one another being hydrogen, C1-C18salkyl or C3-C12cycloalkyl; and the radicals R1 are identical and are C1-C4alkyl or C3-C12cycloalkyl unsubstituted or substituted by one, two or three C1-C4alkyl; and (A2) is at least one alkali or alkaline earth metal salt of a saturated or unsaturated aliphatic mono or dicarboxylic acid unsubstituted or substituted by —OH; with the proviso that the composition is essentially free of an inorganic or organic pigment.
摘要:
The invention describes a composition comprising a) a naturally occurring or synthetic rubber susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula I wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula I.
摘要:
The invention describes a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least a compound of the formula (I) wherein Q is a direct bond (II), R1 is C1-C100alkyl, C2-C100alkenyl, C3-C12cycloalkyl or C3-C12cycloalkyl substituted by 1 to 5 C1-C4alkyl; R2 is a fluorine containing group, and R3 and R4 independently of each other are hydrogen or C1-C4alkyl. The compounds of the formula (I) are useful as reducers of surface energy for organic materials, for example, for increasing the oil and water repellency of organic materials.
摘要:
The instant invention relates to new compounds of the formula I R1 and R2 are each independently of the other a fluorine containing group, R3 and R4 are each independently of the other hydrogen, a fluorine containing group, C1-C12alkyl, phenyl or R4, together with the carbon atom to which they are bonded, form a C5-C8-cycloalkylidene ring that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl groups; R5, R6, R7 and R8 are each independently of the other hydrogen, C1-C12alkyl or C3-C12alkenyl, X1 and X2 are each independently of the other a direct bond or C1-C12alkylene, m is 1 to 10,000, and n is 0 to 10,000. These new compounds of the formula I are useful as reducers of surface energy for organic materials such as polycarbonates, polyesters or polyketones or their mixtures, blends or alloys. Polymers with such a reduced surface energy possess an “easy to clean”, “self-cleaning”“antisoiling”, “soil-release” “antigraffiti”, “oil resistance”, “solvent resistance”, “chemical resistance”, “self lubricating”, “scratch resistance”, “low moisture absorption” and “hydrophobic” surface.
摘要翻译:本发明涉及式IR 1和R 2的新化合物各自独立地为含氟基团R 3 3和 R 4各自独立地为另一个氢,含氟基团,C 1 -C 12 - 烷基,苯基或R 4 与它们所键合的碳原子一起形成未被取代或被1至3个取代的C 5 -C 8 - 亚烷基亚环 C 1 -C 4烷基; C 1 -C 4烷基; R 5,R 6,R 7和R 8各自独立地为另一个氢,C
摘要:
The invention describes a composition comprising comprising a) a natural, semi-synthetic or synthetic polymer which is susceptible to oxidative, thermal or light-induced degradation, and b) a compound of the formula (I) wherein RF, R, Q and q are as defined herein, and are prepared from diallylamine, a perfluoroalkyl iodide and an amino-reactive compound selected from the group of carboxylic acids, anhydrides, acid chlorides, oxiranes, haloalkanes, isocyanates and ureas. The compounds of the formula I are useful as reducers of surface energy for natural, semi-synthetic or synthetic polymers, for example, for increasing the oil and water repellency and stain release of natural, semi-synthetic or synthetic polymers.
摘要:
The invention describes a composition comprising a) a naturally occurring or synthetic elastomer susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula (I) wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula (I).
摘要:
Polymers grafted with a compound of formula I, wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.