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公开(公告)号：US4302396A
公开(公告)日：1981-11-24
申请号：US886563
申请日：1978-04-24
IPC分类号： C07D307/89 , C07C51/00 , C07C51/363 , C07C63/68 , C07C63/72 , C07C67/00 , C07C63/16
CPC分类号： C07C63/68
摘要： Novel chlorinated 4-methylphthalic acids or anhydrides of the general formula ##STR1## wherein n is an integer of 1, 2 or 3, with the proviso that when n is 1, the chlorine atom is positioned at 3- or 5-position and when n is 2, the chlorine atoms are positioned at 3- and 5-positions. The new compounds are produced by dissolving 4-methylphthalic anhydride in concentrated sulfuric acid or fuming sulfuric acid to form a solution, and reacting the solution with chlorine at room temperature preferably in the presence of a catalytic amount of iodine, thereby to yield a crude product containing a mixture of chlorinated 4-methylphthalic acids. By subjecting the mixture to a thermal dehydration treatment in an inactive organic solvent, each of the chlorinated compounds may be isolated as its corresponding anhydride in the form of crystals.These chlorinated 4-methylphthalic anhydrides are valuable as intermediates for the preparation of dyestuffs or pigments.
摘要翻译： 新型氯代4-甲基邻苯二甲酸或通式为“IMAGE”的酸酐，其中n为1,2或3的整数，条件是当n为1时，氯原子位于3-或5-位，当 n为2，氯原子位于3-和5-位。 新化合物通过将4-甲基邻苯二甲酸酐溶解在浓硫酸或发烟硫酸中而形成溶液，并在室温下优选在催化量的碘存在下使溶液与氯反应，从而得到粗产物 含有氯代4-甲基邻苯二甲酸的混合物。 通过在惰性有机溶剂中对混合物进行热脱水处理，可以将各氯化化合物作为其相应的酸酐以晶体的形式分离。 这些氯代4-甲基邻苯二甲酸酐作为制备染料或颜料的中间体是有价值的。
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2.发明授权
公开(公告)号：US4735744A
公开(公告)日：1988-04-05
申请号：US738348
申请日：1985-05-28
IPC分类号： B41M5/00 , B41M5/155 , C07C50/04 , C07C317/00
CPC分类号： B41M5/155 , C07C317/00
摘要： Disclosed herein is a novel benzoquinone derivative represented by the following general formula (I): ##STR1## wherein R.sub.1 means an alkyl or cycloalkyl group, R.sub.2 denotes an alkyl or cycloalkyl group, a phenyl group which may optionally contain one or more halogen atoms and/or alkyl, cycloalkyl, alkoxy, alkylene, phenoxy, phenyl and/or biphenylyl groups, or a benzyl or naphthyl group which may optionally contain one or more methyl groups. This compound is useful as an oxidative color-developing agent for recording materials.
摘要翻译： 本文公开了由以下通式（I）表示的新型苯醌衍生物：其中R 1表示烷基或环烷基，R 2表示烷基或环烷基，可任选地含有一个或多个 卤素原子和/或烷基，环烷基，烷氧基，亚烷基，苯氧基，苯基和/或联苯基，或可任意含有一个或多个甲基的苄基或萘基。 该化合物可用作记录材料的氧化显色剂。
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3.发明授权
公开(公告)号：US4384871A
公开(公告)日：1983-05-24
申请号：US347415
申请日：1982-02-10
CPC分类号： B41M5/136 , B41M5/132 , B41M5/1366
摘要： A dyestuff-containing microscopic capsule dispersion for record materials, which comprises at least one methine dyestuff represented by the general formula (I): ##STR1## wherein X means a phenyl, naphthyl, indolyl, .beta.-styryl, pyridyl, pyrimidyl or pyrazinyl group which may optionally be substituted, R.sub.1 -R.sub.6 are individually an amino, substituted amino, lower alkyl, cycloalkyl, lower alkoxy or lower haloalkyl group or a halogen or hydrogen atom, R.sub.7 and R.sub.8 are each a hydrogen or halogen atom or a lower alkoxy group and may be coupled together to form a ring, and said methine dyestuff contains at least one substituted amino group at a position para to the central methine group in the molecule thereof, said methine dyestuff being contained in microscopic capsules; and alkanolamine represented by the general formula (II): ##STR2## wherein R denotes a lower alkylene, hydroxyalkylene or poly(oxyalkylene) group, R' and R" mean individually a hydrogen atom, an alkyl, hydroxyalkyl, aryl, aralkyl, acyl, or .omega.-hydroxyalkyl-polyoxyalkylene group or a lower alkyl ether of an .omega.-hydroxyalkyl-polyoxyalkylene group, and R' and R" may be coupled together to form a ring, and/or a metal ion sequestering agent, said alkanolamine and/or metal ion sequestering agent being contained in said microscopic capsules and/or a liquid medium wherein said microscopic capsules are dispersed.
摘要翻译： 一种用于记录材料的含染料的显微镜胶囊分散体，其包含至少一种由通式（I）表示的次甲基染料：其中X表示苯基，萘基，吲哚基，β-苯乙烯基，吡啶基，嘧啶基 或可任选被取代的吡嗪基，R 1 -R 6各自为氨基，取代的氨基，低级烷基，环烷基，低级烷氧基或低级卤代烷基或卤素或氢原子，R 7和R 8各自为氢或卤素原子或 低级烷氧基并且可以连接在一起形成环，并且所述次甲基染料在其分子中的中央次甲基的对位位置含有至少一个取代的氨基，所述次甲基染料包含在微观胶囊中; 和由通式（II）表示的链烷醇胺：其中R表示低级亚烷基，羟基亚烷基或聚（氧化烯）基，R'和R“表示氢原子，烷基，羟基烷基，芳基 ，芳烷基，酰基或ω-羟烷基 - 聚氧化烯基或ω-羟烷基 - 聚氧化烯基的低级烷基醚，并且R'和R“可以连接在一起形成环，和/或金属离子螯合剂 所述的所述显微胶囊中含有的所述链烷醇胺和/或金属离子螯合剂和/或其中分散有所述显微胶囊的液体介质。
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公开(公告)号：US4632987A
公开(公告)日：1986-12-30
申请号：US562587
申请日：1983-12-02
IPC分类号： C07B61/00 , B01J27/00 , C07C67/00 , C07C209/00 , C07C209/68 , C07C209/78 , C07C211/44 , C07C211/50 , C07C213/00 , C07C217/80 , C09B11/14 , C09B11/10 , C07D209/04 , C07D209/18 , C07D265/30
CPC分类号： C09B11/14
摘要： A process for the preparation of triarylmethane compounds which comprises reacting a benzene or naphthalene compound with a formylating agent for such compounds in the presence of an acid catalyst to form an aromatic aldehyde compound; adding water to the reaction mixture and thereby hydrolyzing the acid catalyst without isolating the aromatic aldehyde compound from the reaction mixture; and uninterruptedly condensing the aromatic aldehyde compound with an aromatic compound in the resulting mixture.
摘要翻译： PCT No.PCT / JP83 / 00133 Sec。 371日期：1983年12月2日 102（e）1983年12月2日日期PCT提交1983年4月28日PCT公布。 出版物WO83 / 03840 日本1983年11月10日。一种制备三芳基甲烷化合物的方法，其包括在酸催化剂存在下使苯或萘化合物与甲酰化剂反应形成芳族醛化合物; 向反应混合物中加入水，从而水解酸催化剂，而不从反应混合物中分离出芳族醛化合物; 并在所得混合物中不间断地将芳族醛化合物与芳族化合物缩合。
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公开(公告)号：US4480002A
公开(公告)日：1984-10-30
申请号：US326005
申请日：1981-11-30
CPC分类号： B41M5/132 , B41M5/145 , B41M5/1455 , Y10T428/2984
摘要： Dyestuff-containing microscopic capsule suspension for record materials, containing in microscopic capsules a lactone family dyestuff represented by the general formula (I): ##STR1## wherein a, b, c and d are each a carbon atom or either one or two atoms of said a, b, c and d are nitrogen atoms and the remaining atoms are carbon atoms, said a, b, c and d may have one or two substituent groups, adjacent a-b, b-c or c-d bond may form another ring, X and Y represent individually a benzene, naphthalene or aromatic heterocyclic ring which may include one or more substituent groups, and X and Y may be the same or different and may be coupled together to form a ring; and a metal ion sequestering agent in the capsules or a liquid medium in which the capsules are suspended.
摘要翻译： 含有染料的显微胶囊悬浮液用于记录材料，在微观胶囊中含有由通式（I）表示的内酯家族染料：其中a，b，c和d各自为碳原子，或者一个或多个 所述a，b，c和d的两个原子是氮原子，剩余的原子是碳原子，所述a，b，c和d可以具有一个或两个取代基，相邻的ab，bc或cd键可以形成另一个环， X和Y分别表示可以包含一个或多个取代基的苯，萘或芳族杂环，并且X和Y可以相同或不同并且可以连接在一起形成环; 和胶囊中的金属离子螯合剂或其中悬浮胶囊的液体介质。
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公开(公告)号：US4561000A
公开(公告)日：1985-12-24
申请号：US557181
申请日：1983-12-01
CPC分类号： B41M5/3375
摘要： A heat-sensitive recording unit formed by supporting a methine-type chromogenic reactant and oxidizing organic compound on a base. A color production sensitivity regulator may further be supported on the base. It is also feasible to add a quaternary ammonium salt, tertiary alkanol amine or water-soluble ion sequestering agent for avoiding undesirable color production of the methine-type chromogenic reactant. The ammonium salt, amine or ion sequestering agent may be added upon forming the methine-type chromogenic reactant into an aqueous suspension in order support the methine-type chromogenic reactant on the base.
摘要翻译： PCT No.PCT / JP83 / 00250 Sec。 371日期：1983年12月1日 102（e）1983年12月1日授权PCT 1983年8月2日提交。一种热敏记录单元，其通过在基底上负载次甲基型显色反应物和氧化有机化合物而形成。 彩色生产灵敏度调节器可进一步支撑在基座上。 添加季铵盐，叔链烷醇胺或水溶性离子螯合剂也可以避免次甲基型显色反应物的不期望的颜色产生。 在形成次甲基型显色反应物时，可以将铵盐，胺或离子螯合剂加入到水性悬浮液中，以便在基底上支持次甲基型显色反应物。
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公开(公告)号：US4398753A
公开(公告)日：1983-08-16
申请号：US330325
申请日：1981-12-14
CPC分类号： B41M5/136 , B41M5/1366 , Y10S428/914
摘要： Disclosed is a pressure sensitive recording unit which comprises a single base web sheet and a methine-type dyestuff and an organic oxidizing compound both supported on the single base web sheet, or a combination of first and second base web sheets and the methine-type dyestuff and organic oxidizing compound supported individually on the first and second base web sheets. Such a recording unit includes for example a pressure sensitive recording unit formed in combination of (a) a back-coated topsheet (CB-sheet) making use of microscopic capsules containing a solution obtained by dissolving a methine-type dyestuff in a solvent having a high boiling point and (b) a front-coated undersheet (CF-sheet) carrying an organic oxidizing compound coated thereon. Also disclosed is a pressure sensitive recording unit which includes a base web sheet carrying thereon such a methine-type dyestuff together with a metal ion sequestering agent and/or alkanol amine.
摘要翻译： 公开了一种压敏记录单元，其包括单个基网网片和次甲基型染料和有机氧化剂，两者均支撑在单个基网幅材上，或第一和第二基网幅片与次甲基型染料 和在第一和第二基底幅片上分别支撑的有机氧化剂。 这样的记录单元包括例如压敏记录单元，其组合使用（a）使用含有通过将次甲基型染料溶解在溶剂中而得到的溶液的微观胶囊的背面涂布的顶片（CB片） 高沸点和（b）在其上涂覆有有机氧化剂的前涂底片（CF-片）。 还公开了一种压敏记录单元，其包括其上承载有次甲基型染料的基础网片与金属离子螯合剂和/或链烷醇胺。
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公开(公告)号：US5559247A
公开(公告)日：1996-09-24
申请号：US422033
申请日：1995-04-14
IPC分类号： B41M5/28 , B41M5/323 , B41M5/333 , C07D209/44 , C07D209/50 , C07D491/10
CPC分类号： B41M5/323 , B41M5/286 , B41M5/3335 , C07D209/44 , C07D209/50 , C07D491/10
摘要： A carboxylate is herein disclosed which is represented by the formula (1) or (2) ##STR1## wherein a ring X is an aromatic residue which may have a substituent; the other substitutents are as defined herein. A heat-sensitive recording material comprising this carboxylate is excellent in the stability of the color image and can provide an optically character-readable sharp color image.
摘要翻译： 本文公开的羧酸酯，其由式（1）或（2）表示：其中环X为可具有取代基的芳族残基; 其他取代基如本文所定义。 包含这种羧酸盐的热敏记录材料在彩色图像的稳定性方面是优异的，并且可以提供光学性质可读的清晰图像。
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9.发明授权Crystals of fluoran compound, crystalline solvates thereof, process for their preparation and recording material comprising said crystal or said solvate 失效氟化合物的晶体，其结晶溶剂合物，其制备方法和包含所述晶体或所述溶剂合物的记录材料
公开(公告)号：US5302571A
公开(公告)日：1994-04-12
申请号：US075935
申请日：1993-06-14
CPC分类号： C09B11/24 , B41M5/1455 , B41M5/3275
摘要： Disclosed are a crystal and crystalline solvate of a fluoran compound represented by the formula ##STR1## wherein R.sub.1 is ##STR2## and which are useful as chromogenic compounds in recording materials such as pressure-sensitive and heat-sensitive recording materials, a process for preparation of said crystal and said crystalline solvate, and recording materials comprising said crystal or said crystalline solvate.
摘要翻译： 公开了由下式表示的荧烷化合物的晶体和结晶溶剂化物，其中R1是
，其可用作记录材料如压敏和热敏记录材料中的显色化合物， 所述晶体和所述结晶溶剂化物的制备方法，以及包含所述晶体或所述结晶溶剂合物的记录材料。 -
公开(公告)号：US5300473A
公开(公告)日：1994-04-05
申请号：US28911
申请日：1993-03-08
CPC分类号： C09B67/0025 , B41M5/1455 , B41M5/3275 , C09B11/24
摘要： Disclosed are a crystal of a fluoran compound having the formula comprising exhibiting high peaks at diffraction angles (2.theta.) of 7.5.degree. and 17.0.degree. and relatively high peaks at diffraction angles (2.theta.) of 15.1.degree., 19.1.degree., 21.5.degree. and 25.3.degree. in an X-ray diffraction diagram by the CU-K.alpha. beam and a crystal of a fluoran compound having the formula (II) comprising exhibiting high peaks at diffraction angles (2.theta.) of 5.5.degree. and 19.2.degree. in an X-ray diffraction diagram by the CU-K.alpha. beam, which is useful as a color forming compound in recording materials. ##STR1##
摘要翻译： 公开了具有以下通式的荧烷化合物的晶体，其包括在7.5度和17.0度的衍射角（2（θ））处呈现高峰，并且在15.1度，19.1度的衍射角（2（θ））处具有相对高的峰， 通过CU-K（α）光束在X射线衍射图中为21.5度和25.3度，并且具有式（II）的荧烷化合物的晶体包括在5.5度的衍射角（2（θ））处表现出高峰 在通过CU-K（α）光束的X射线衍射图中为19.2度，其可用作记录材料中的成色化合物。 （*化学结构*）（I）（*化学结构*）（II）
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