公开(公告)号：US4069274A

公开(公告)日：1978-01-17

申请号：US598946

申请日：1975-07-25

申请人： Minoru Shibata ,  Naozumi Iwasawa ,  Tadashi Watanabe ,  Ichiro Yoshihara

发明人： Minoru Shibata ,  Naozumi Iwasawa ,  Tadashi Watanabe ,  Ichiro Yoshihara

IPC分类号： C09D5/03 ,  C08G81/00 ,  C08G81/02 ,  C08J3/20 ,  C09D5/46 ,  C08L63/00

CPC分类号： C08G81/027

摘要： A thermosetting powder coating composition comprising:A. a functional glycidyl group-containing graft copolymer ofI. 10 to 40 percent of a linear polyester having a number average molecular weight of 600 to 3,000 and containing one terminal carboxyl group andIi. 60 to 90 percent of acrylic copolymer of ii-a) 6.5 to 60 percent of at least one of glycidyl esters having the formula ##STR1## wherein R.sub.1 is hydrogen or methyl, ii-b) 10 to 93.5 percent of at least one of acrylic monomers having the formula CH.sub.2 .dbd.C(R.sub.2)COOR.sub.3 wherein R.sub.2 is hydrogen or methyl and R.sub.3 is alkyl having 1 to 14 carbon atoms, cyclohexyl or hydroxyalkyl having 1 to 4 carbon atoms, and ii-c) 0 to 65 percent of additional monomers selected from the group consisting of acrylonitrile, methacrylonitrile and styrenes having the formula ##STR2## wherein R.sub.4 is hydrogen or alkyl having 1 to 4 carbon atoms, said graft copolymer having a softening point of 70.degree. to 110.degree. C and a number average molecular weight of 2,000 to 30,000 and containing glycidyl group in an amount of 0.35 to 2.35 moles per kilogram of the graft copolymer; andB. at least one of polycarboxylic acids and anhydrides thereof in an amount of 0.6 to 1.2 moles in terms of carboxyl group per mole of the glycidyl group contained in the graft copolymer.

摘要翻译： 一种热固性粉末涂料组合物，其包含：

公开(公告)号：US4089910A

公开(公告)日：1978-05-16

申请号：US588709

申请日：1975-06-20

申请人： Minoru Shibata ,  Naozumi Iwasawa ,  Tadashi Watanabe ,  Ichiro Yoshihara

发明人： Minoru Shibata ,  Naozumi Iwasawa ,  Tadashi Watanabe ,  Ichiro Yoshihara

IPC分类号： B05D7/14 ,  B05D1/38 ,  C08F299/04 ,  C08G59/32 ,  C08G59/42 ,  C08L63/00

CPC分类号： C08G59/42 ,  C08F299/0478 ,  C08G59/3209 ,  Y10S524/904 ,  Y10T428/31529

摘要： A thermosetting powder coating composition comprising:(A) a graft copolymer ofA. 10 to 40 percent of a linear polyester having a number average molecular weight of 600 to 3,000 and containing one ethylenically unsaturated double bond only at one end of the molecule,B. 5 to 30 percent of at least one of glycidyl esters having the formula ##STR1## wherein R.sub.1 is hydrogen or methyl, and C. 10 TO 85 PERCENT OF AT LEAST ONE OF ACRYLIC COMPOUNDS HAVING THE FORMULA OF CH.sub.2 .dbd.C(R.sub.2)COOR.sub.3, wherein R.sub.2 is hydrogen or methyl and R.sub.3 is alkyl having 1 to 14 carbon atoms, cyclohexyl or hydroxyalkyl represented by ##STR2## wherein R.sub.4 is hydrogen, methyl or ethyl, said graft copolymer having a softening point of 70.degree. to 110.degree. C and a number average molecular weight of 2,000 to 30,000; and(B) at least one of polycarboxylic acids and anhydrides thereof in an amount of 0.6 to 1.2 moles in terms of carboxyl group per mole of the glycidyl group contained in the graft copolymer.

摘要翻译： 一种热固性粉末涂料组合物，

公开(公告)号：US4011381A

公开(公告)日：1977-03-08

申请号：US581430

申请日：1975-05-28

申请人： Naozumi Iwasawa ,  Nobuo Sugiyama ,  Ichiro Yoshihara ,  Tadashi Watanabe ,  Taizo Kondo

发明人： Naozumi Iwasawa ,  Nobuo Sugiyama ,  Ichiro Yoshihara ,  Tadashi Watanabe ,  Taizo Kondo

IPC分类号： C09D5/03 ,  C08G59/32 ,  C08G59/42 ,  C08J3/20 ,  C09D5/46 ,  C09D157/04 ,  C08F220/14

CPC分类号： C08G59/42 ,  C08G59/3209 ,  C08K3/0033 ,  C08K5/0041 ,  C08K5/09 ,  C09D157/04 ,  Y10T428/31855

摘要： A process for preparing a thermosetting powder coating composition comprising the steps of copolymerizing 5 to 25 wt.% of at least one of glycidyl acrylate and glycidyl methacrylate with 95 to 75 wt.% of an ethylenically unsaturated compound in a solvent having a boiling point of up to 170.degree. C to obtain a solution of copolymer, the copolymer having a number average molecular weight of 2,000 to 30,000 and a melt viscosity of 100 to 500 poises at 160.degree. C, uniformly dispersing a pigment into the copolymer solution, removing the solvent from the resulting mixture at a temperature of 170.degree. to 220.degree. C and reduced pressure, thereafter admixing a di- or tri-carboxylic acid cross-linking agent with the mixture with heating at a temperature of up to 120.degree. C, and pulverizing the solid mixture obtained.

公开(公告)号：US5102775A

公开(公告)日：1992-04-07

申请号：US413677

申请日：1989-09-28

申请人： Motoko Okuhara ,  Ichiro Yoshihara ,  Yasuo Doi ,  Takao Yamamoto ,  Kenji Seko ,  Yutaka Yoshikawa ,  Naozumi Iwasawa

发明人： Motoko Okuhara ,  Ichiro Yoshihara ,  Yasuo Doi ,  Takao Yamamoto ,  Kenji Seko ,  Yutaka Yoshikawa ,  Naozumi Iwasawa

IPC分类号： C08F2/50 ,  G03F7/004 ,  G03F7/038 ,  G03F7/16

CPC分类号： G03F7/004 ,  G03F7/038 ,  G03F7/164 ,  Y10S430/12 ,  Y10S430/121 ,  Y10S430/123 ,  Y10S430/127 ,  Y10S430/136 ,  Y10S430/146

摘要： A composition for visible light sensitive electrodeposition coating which comprises (A) a photocurable resin having light sensitive groups capable of being crosslinked or polymerized by light irradiation and ionic groups, (B) a sensitizer which is excited by absorption of visible light and has a property to interact with the resin (A), (C) a water-insoluble polymerization initiator, and optionally, (D) at least one specific nitrogen-containing compound; and an image-forming method which comprises (i) coating the surface of a conductor by electrodeposition with the aforesaid composition, (ii) exposing the resulting film by electrodeposition by partially irradiating the film with visible light, and then (iii) contacting the resulting film with a developing solution to remove the unexposed areas.

摘要翻译： 一种用于可见光敏电沉积涂料的组合物，其包含（A）具有能够通过光照射和离子基团交联或聚合的光敏基团的光固化树脂，（B）通过吸收可见光而被激发并具有 与树脂（A），（C）水不溶性聚合引发剂和任选的（D）至少一种特定的含氮化合物相互作用; 以及图像形成方法，其包括：（i）通过用上述组合物电沉积涂覆导体的表面，（ii）通过用可见光部分地照射该膜而通过电沉积曝光所得到的膜，然后（iii）使所得到的膜 用显影液除去未曝光的区域。

公开(公告)号：US5045434A

公开(公告)日：1991-09-03

申请号：US629484

申请日：1990-12-18

申请人： Ichiro Yoshihara ,  Motoko Okuhara ,  Takao Yamamoto ,  Naozumi Iwasawa ,  Yasuo Doi ,  Tsukasa Ohyama ,  Kazuhiko Murayama ,  Yoriaki Matsuzaki ,  Susumu Kasamatsu ,  Keisuke Takuma ,  Kimitoshi Kato

发明人： Ichiro Yoshihara ,  Motoko Okuhara ,  Takao Yamamoto ,  Naozumi Iwasawa ,  Yasuo Doi ,  Tsukasa Ohyama ,  Kazuhiko Murayama ,  Yoriaki Matsuzaki ,  Susumu Kasamatsu ,  Keisuke Takuma ,  Kimitoshi Kato

IPC分类号： C08F2/50 ,  G03F7/031 ,  G03F7/038

CPC分类号： G03F7/031 ,  C08F2/50 ,  G03F7/0388 ,  Y10S430/115 ,  Y10S430/116 ,  Y10S430/127 ,  Y10S430/136 ,  Y10S430/148

摘要： A visible radiation sensitive composition comprising:(A) a photosetting resin containing a photosensitive group capable of crosslinking or polymerizing by photoirradiation,(B) a sensitizer represented by the formula (i): ##STR1## wherein R.sub.1 and R.sub.2 are the same or different lower alkyl, and R.sub.3 is a hydrogen atom, lower alkyl group, alkoxyalkyl group, hydroxyalkoxyalkyl group or alkoxycarbonylalkyl group, and(C) a polymerization initiator.

公开(公告)号：US4185045A

公开(公告)日：1980-01-22

申请号：US880797

申请日：1978-02-24

申请人： Ichiro Yoshihara ,  Tadashi Watanabe ,  Osamu Iwase

发明人： Ichiro Yoshihara ,  Tadashi Watanabe ,  Osamu Iwase

IPC分类号： C09D5/03 ,  C08L33/06 ,  C08L61/32 ,  C09D5/46 ,  C09D133/06 ,  C09D167/00 ,  C08L25/08 ,  C08L61/26 ,  C08L61/28 ,  C08L67/00

CPC分类号： C09D133/066 ,  C09D167/00 ,  C08L2205/02 ,  C08L33/066 ,  C08L61/32

摘要： A powdery coating composition comprising (1) 10 to 40% by weight of a solid cross-linking agent having a softening point of 50.degree. to 120.degree. C. and prepared by heating 40 to 75% by weight of an acrylic resin having free hydroxyl groups and 60 to 25% by weight of an alkoxyaminotriazine at 50.degree. to 120.degree. C., and (2) 90 to 60% by weight of a base resin having a softening point of 60.degree. to 130.degree. C. and an acid value of up to 30 and containing 0.4 to 2.0 moles of free hydroxyl groups per kilogram of the resin, the alkoxyaminotriazine having 0 to 1 non-methylolated NH bond per triazine ring, at least 80% of the methylol groups of the alkoxyaminotriazine having been etherified with an aliphatic or alicyclic alcohol or ethylene glycol monoalkyl ether.

摘要翻译： 一种粉末涂料组合物，其包含（1）10至40重量％的软化点为50至120℃的固体交联剂，并通过加热40至75重量％的具有游离羟基的丙烯酸树脂 基团和60〜25重量％的烷氧基氨基三嗪在50〜120℃，（2）90〜60重量％的软化点为60〜130℃的基础树脂，酸值 至多30，并且每千克树脂含有0.4至2.0摩尔游离羟基，烷氧基氨基三嗪每三嗪环具有0至1个非羟甲基化NH键，至少80％的烷氧基氨基三嗪的羟甲基已被醚化 脂肪族或脂环族醇或乙二醇单烷基醚。

公开(公告)号：US4230829A

公开(公告)日：1980-10-28

申请号：US969195

申请日：1978-12-13

申请人： Ichiro Yoshihara ,  Tadashi Watanabe ,  Osamu Iwase

发明人： Ichiro Yoshihara ,  Tadashi Watanabe ,  Osamu Iwase

IPC分类号： C09D5/03 ,  C08G63/20 ,  C08L67/00 ,  C09D5/46 ,  C09D133/00 ,  C09D161/32 ,  C08L61/28

CPC分类号： C09D161/32 ,  C08G63/20 ,  C08L67/00 ,  C09D133/00 ,  Y10S525/934

摘要： The powdery coating composition of the present invention comprises:(i) 10 to 40% by weight of a solid cross-linking agent prepared by heating polyester and alkoxyaminotriazine, and(ii) 90 to 60% by weight of a base resin.An object of the present invention is to provide a powdery coating composition which will not pose any environmental pollution and has an outstanding property against bubbling.The above object can be fulfilled by using the solid cross-linking agent in combination with a base resin.

摘要翻译： 本发明的粉末涂料组合物包括：（i）10-40重量％的通过加热聚酯和烷氧基氨基三嗪制备的固体交联剂，和（ii）90-60重量％的基础树脂。 本发明的目的是提供一种不会对环境造成污染且具有突出的起泡性的粉末状涂料组合物。 上述目的可以通过使用固体交联剂与基础树脂组合来实现。

公开(公告)号：US09004152B2

公开(公告)日：2015-04-14

申请号：US13126921

申请日：2009-10-22

申请人： Ichiro Yoshihara

发明人： Ichiro Yoshihara

IPC分类号： B01F15/06 ,  F28D11/02 ,  F26B11/16 ,  F26B17/20 ,  F26B17/28 ,  F28F5/04 ,  F28D21/00

CPC分类号： F28D11/02 ,  F26B11/16 ,  F26B17/20 ,  F26B17/28 ,  F28D2021/0045 ,  F28F5/04 ,  Y10T29/4935

摘要： A heat exchange device for powdery and granular materials configured to reduce adherence and accumulation of the materials and manufacturing time. The heat exchange device includes at least one substantially hollow disk-shaped heat exchanger among a plurality of heat exchangers that is disposed on the shaft about which the heat exchanger rotates. The hollow disc-shape heat exchanger includes a cutout recess part, plate surfaces extending from one side edge of the cutout recess part and forming a wedge-shaped plate surface, and a smoothly bulging projection formed at a central part of the heat exchanger. In addition, an opening is provided in the hollow disk-shaped heat exchanger at a tip end of the projection, and a shaft is inserted into the opening and joined to the hollow disc-shaped heat exchanger.

摘要翻译： 用于粉末和颗粒材料的热交换装置，其被配置为减少材料的粘附和积累以及制造时间。 热交换装置包括多个热交换器中的至少一个基本中空的盘状热交换器，热交换器设置在热交换器所围绕的轴上。 中空盘形热交换器包括切口凹部，从切口凹部的一个侧边缘延伸并形成楔形板表面的板表面，以及形成在热交换器的中心部的平滑的凸出突起。 此外，在中空盘形热交换器的突起部的前端设有开口部，将轴插入开口并与中空圆盘状的热交换器接合。

公开(公告)号：US20110203784A1

公开(公告)日：2011-08-25

申请号：US13126921

申请日：2009-10-22

申请人： Ichiro Yoshihara

发明人： Ichiro Yoshihara

IPC分类号： F28F7/00 ,  B21D53/02

CPC分类号： F28D11/02 ,  F26B11/16 ,  F26B17/20 ,  F26B17/28 ,  F28D2021/0045 ,  F28F5/04 ,  Y10T29/4935

摘要： An object of the present invention is to provide a heat exchange device for a powder and granular material, which is capable of suppressing an object to be processed from adhering/accumulating, and reducing the number of manufacturing processes (time), while keeping high heat efficiency, piston flowability and other advantages of a conventional device that uses wedge-shaped hollow rotating bodies. In order to achieve this object, a heat exchange device for a powder and granular material according to the present invention is configured such that at least one of a plurality of heat exchangers 30 to be disposed on a shaft 13 is formed as a substantially hollow disk-shaped heat exchanger in which a cutout recess part 31 directed from a circumferential edge of the heat exchanger toward a center of the same is provided; plate surfaces extending from one side edge 31a of the cutout recess part to another side edge 31b of a following cutout recess part are formed into a wedge-shaped plate surface 32 by gradually increasing a distance between the plate surfaces; a projection 33 that smoothly bulges in a horizontal direction as viewed from the side is formed at a central part of the heat exchanger; and an opening 34 is formed at a tip end of the projection, and the heat exchanger is disposed on the shaft by inserting the shaft into the opening.

摘要翻译： 本发明的目的是提供一种粉末和颗粒材料的热交换装置，其能够抑制被加工物的粘附/积聚，并且减少制造工艺（时间），同时保持高的热量 效率，活塞流动性和使用楔形中空旋转体的常规装置的其它优点。 为了达到上述目的，本发明的粉末和颗粒状材料用热交换装置构成为：设置在轴13上的多个热交换器30中的至少一个形成为大致中空的圆盘 其中设置有从热交换器的周缘引导到其中心的切口凹部31; 通过逐渐增加板表面之间的距离，将从切口凹部的一个侧边缘31a延伸到随后的切口凹部的另一侧边缘31b的板表面形成为楔形板表面32; 在热交换器的中心部形成有从侧面观察而在水平方向上平滑地隆起的突起33; 并且在突起的前端形成开口34，并且通过将轴插入开口而将热交换器设置在轴上。

公开(公告)号：US06652917B2

公开(公告)日：2003-11-25

申请号：US10127767

申请日：2002-04-23

申请人： Takato Adachi ,  Ichiro Yoshihara ,  Yugen Kawamoto

发明人： Takato Adachi ,  Ichiro Yoshihara ,  Yugen Kawamoto

IPC分类号： B05D136

CPC分类号： C08G59/3209 ,  C08G59/4207 ,  C09D163/00

摘要： The present invention provides a method for forming a topcoat according to a 2-coat 1-bake system comprising the steps of applying to a substrate a thermosetting aqueous colored base coating composition, applying to the uncured surface of the base coat a clear coating composition, and curing the two coats by heating, wherein the clear coating composition is a thermosetting powder coating composition comprising: (A) an epoxy-containing resin; and (B) a curing agent containing acid anhydride (a) represented by formula X—COO—[CO—(CH2)m—COO]n—CO—X  (1) and at least one species selected from the group consisting of acid anhydride (b) represented by the formula HO—[CO—(CH2)p—COO]q—H  (2) and dibasic acid (c).

摘要翻译： 本发明提供了一种根据2-涂层1-烘烤系统形成面漆的方法，包括以下步骤：向基底施加热固性水性着色底漆涂料组合物，向底涂层的未固化表面施加透明涂料组合物， 并且通过加热固化所述两个涂层，其中所述透明涂料组合物是热固性粉末涂料组合物，其包含：（A）含环氧树脂; 和（B）含有由式表示的酸酐（a）和选自由式和二元酸（c）表示的酸酐（b））中的至少一种的固化剂。