摘要:
The present invention relates to a resol resin consisting of at least one aromatic component with a phenolic OH group and at least one aldehyde component, wherein areas embedded in the resol resin matrix consisting of organically-modified polysiloxane, with said polysiloxane containing hydrocarbon groups that are at least partially bonded to said silicon in the form of non-substituted or substituted alkyl, alkenyl, aryl, arylalkyl or alkyl-aryl groups and that are not linked by covalent bonds to reactive groups of said resol resin. The invention additionally relates to molded articles manufactured from said resin, composites from a sheet material impregnated with said resin, which was subsequently hardened, as well as methods for manufacturing said resin, said molded articles, and said composites.
摘要:
The present invention relates to a resol resin consisting of at least one aromatic component with a phenolic OH group and at least one aldehyde component, wherein areas embedded in the resol resin matrix consisting of organically-modified polysiloxane, with said polysiloxane containing hydrocarbon groups that are at least partially bonded to said silicon in the form of non-substituted or substituted alkyl, alkenyl, aryl, arylalkyl or alkyl-aryl groups and that are not linked by covalent bonds to reactive groups of said resol resin. The invention additionally relates to moulded articles manufactured from said resin, composites from a sheet material impregnated with said resin, which was subsequently hardened, as well as methods for manufacturing said resin, said moulded articles, and said composites.
摘要:
The invention relates to an unsaturated polyester resin containing a polyester or a polyester mixture, produced from at least one unsaturated dicarboxylic acid and at least one diol; and at least one silazane which is accessible for copolymerization with a C═C double bond of the dicarboxylic acid. The invention also relates to an unsaturated polyester resin moulding material which can be obtained or is obtained by cross-linking an unsaturated polyester resin as defined above. Said moulding material can optionally contain reinforcing materials. Said unsaturated polyester resin can be produced using the following steps: (a) a polyester from at least one diol and at least one unsaturated dicarboxylic acid is provided; (b) at least one silazane which is accessible for copolymerization which a C═C double bond of the dicarboxylic acid is provided; (c) the components are mixed according to (a) and (b). The unsaturated polyester resin moulding material can be produced from the above-mentioned polyester resin by hardening thereof by means of a radical initiator.
摘要:
The present invention pertains to a copolymer obtained by reacting a mixture of acrylonitrile or of a mixture of acrylonitrile and an organic molecule that can be copolymerized with acrylonitrile, with which a monomeric, oligomeric and/or polymeric silazane can be obtained, said silazane containing at least one vinylic double bond. The copolymer can be brought into fiber form and/or made infusible. The production of ceramic fibers by pyrolysis is possible with fiber-like copolymers.
摘要:
The present invention pertains to a copolymer obtained by reacting a mixture of acrylonitrile or of a mixture of acrylonitrile and an organic molecule that can be copolymerized with acrylonitrile, with which a monomeric, oligomeric and/or polymeric silazane can be obtained, said silazane containing at least one vinylic double bond. The copolymer can be brought into fiber form and/or made infusible. The production of ceramic fibers by pyrolysis is possible with fiber-like copolymers.
摘要:
This invention refers to hybrid pre-polymers and polymers, produced through conversion from difunctional, oligofunctional and/or polyfunctional cyanates and/or from their pre-polymers with monomeric, oligomeric and/or polymeric silazanes. The polymers are duromers with high glass transition temperature and fracture toughness, compared to duromers from the respective cyanate source material. In their pre-polymerized state, they can be dissolved in solvents and are therefore suitable as impregnating resins for prepregs. In addition, they can be processed to become moldings. Their burning properties are described as particularly outstanding.
摘要:
An apparatus and method are disclosed for retaining an attachment, such as an awning, to the wall of a recreational vehicle. The apparatus includes a flexible strap assembled from a plurality of strap segments. Male and female portions of adjacent strap segments are joined together to form a flexible interconnection between adjacent strap segments. The apparatus also includes an upper mounting portion for fixedly connecting a first end of the strap to the wall, and a lower mounting portion for detachably connecting a second end of the strap to the wall. Also disclosed are methods of installing and using an apparatus for retaining a recreational vehicle attachment.
摘要:
Method of hydrodechlorinating nuclear-chlorinated o-xylenes and recovering o-xylene, forming hydrogen chloride, the nuclear-chlorinated o-xylenes being hydrogenated in the gas phase at a noble-metal-containing catalyst at a temperature in the range from 220 to 360° C. The catalyst preferably comprises palladium or platinum, in particular supported palladium or platinum. The nuclear-chlorinated o-xylenes can be used individually or as mixtures.
摘要:
A method for the nuclear chlorination of ortho-xylene using a chlorinating agent in the presence of at least one Friedel-Crafts catalyst and chloro-substituted 2,8-dimethylphenoxathiin as co-catalyst. The co-catalyst used is preferably tetrachlorinated 2,8-dimethylphenoxathiin, in particular 1,3,7,9-tetrachloro-2,8-dimethylphenoxathiin of the formula
摘要:
A process for preparing amines of the general formula (I) R1R2CHNR3R4 (I) in which R1, R2, R3 and R4 are each independently hydrogen, straight-chain or branched, halogenated or halogen-free C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, by catalytic, hydrogenating amination of carbonyl compounds of the general formula (II) R1—C(═O)—R2 (II)with nitrogen compounds of the general formula (III) HNR3R4 (III)in the presence of bifunctional catalyst systems comprising a.) a hydrogenation-active catalyst component comprising one or more metals of transition group 8 of the Periodic Table and b.) one or more solid, acidic cocatalysts, wherein the hydrogenating amination is carried out in the presence of aqueous ammonia or aqueous amine of the formula (III) and at least one organic solvent miscible with ammonia or the aqueous amine of the formula (III).