Polysiloxane modified resol resin, moulded bodies and composites obtained therefrom and methods for producing the resin, the moulded bodies and the composites
    1.
    发明授权
    Polysiloxane modified resol resin, moulded bodies and composites obtained therefrom and methods for producing the resin, the moulded bodies and the composites 有权
    聚硅氧烷改性甲阶酚醛树脂,成型体和由其获得的复合材料和制备树脂,成型体和复合材料的方法

    公开(公告)号:US09328236B2

    公开(公告)日:2016-05-03

    申请号:US14131773

    申请日:2012-07-05

    摘要: The present invention relates to a resol resin consisting of at least one aromatic component with a phenolic OH group and at least one aldehyde component, wherein areas embedded in the resol resin matrix consisting of organically-modified polysiloxane, with said polysiloxane containing hydrocarbon groups that are at least partially bonded to said silicon in the form of non-substituted or substituted alkyl, alkenyl, aryl, arylalkyl or alkyl-aryl groups and that are not linked by covalent bonds to reactive groups of said resol resin. The invention additionally relates to molded articles manufactured from said resin, composites from a sheet material impregnated with said resin, which was subsequently hardened, as well as methods for manufacturing said resin, said molded articles, and said composites.

    摘要翻译: 本发明涉及由至少一种芳族组分与酚OH基团和至少一种醛组分组成的甲阶酚醛树脂,其中包含在由有机改性聚硅氧烷组成的甲阶酚醛树脂基质中的区域,所述聚硅氧烷含有烃基, 至少部分地以未取代或取代的烷基,烯基,芳基,芳基烷基或烷基 - 芳基的形式键合到所述硅上,并且不与所述甲阶酚醛树脂的反应性基团共价键连接。 本发明还涉及由所述树脂制成的模制品,从浸渍有所述树脂的片材的复合材料,随后硬化​​,以及制造所述树脂,所述模制品和所述复合材料的方法。

    POLYSILOXANE MODIFIED RESOL RESIN, MOULDED BODIES AND COMPOSITES OBTAINED THEREFROM AND METHODS FOR PRODUCING THE RESIN, THE MOULDED BODIES AND THE COMPOSITES
    2.
    发明申请
    POLYSILOXANE MODIFIED RESOL RESIN, MOULDED BODIES AND COMPOSITES OBTAINED THEREFROM AND METHODS FOR PRODUCING THE RESIN, THE MOULDED BODIES AND THE COMPOSITES 有权
    多晶硅改性酚醛树脂,成型体和由其获得的复合材料以及用于生产树脂,模塑体和复合材料的方法

    公开(公告)号:US20140275373A1

    公开(公告)日:2014-09-18

    申请号:US14131773

    申请日:2012-07-05

    IPC分类号: C08L61/06

    摘要: The present invention relates to a resol resin consisting of at least one aromatic component with a phenolic OH group and at least one aldehyde component, wherein areas embedded in the resol resin matrix consisting of organically-modified polysiloxane, with said polysiloxane containing hydrocarbon groups that are at least partially bonded to said silicon in the form of non-substituted or substituted alkyl, alkenyl, aryl, arylalkyl or alkyl-aryl groups and that are not linked by covalent bonds to reactive groups of said resol resin. The invention additionally relates to moulded articles manufactured from said resin, composites from a sheet material impregnated with said resin, which was subsequently hardened, as well as methods for manufacturing said resin, said moulded articles, and said composites.

    摘要翻译: 本发明涉及由至少一种芳族组分与酚OH基团和至少一种醛组分组成的甲阶酚醛树脂,其中包含在由有机改性聚硅氧烷组成的甲阶酚醛树脂基质中的区域,所述聚硅氧烷含有烃基, 至少部分地以未取代或取代的烷基,烯基,芳基,芳基烷基或烷基 - 芳基的形式键合到所述硅上,并且不与所述甲阶酚醛树脂的反应性基团共价键连接。 本发明还涉及由所述树脂制成的模制品,从浸渍有所述树脂的片材的复合材料,随后硬化​​,以及制造所述树脂,所述模制品和所述复合材料的方法。

    RESINS FROM UNSATURATED POLYESTERS AND POLYSILAZANES AND DUROPLASTIC REACTION RESIN MOULDING MATERIALS PRODUCED THEREFROM
    3.
    发明申请
    RESINS FROM UNSATURATED POLYESTERS AND POLYSILAZANES AND DUROPLASTIC REACTION RESIN MOULDING MATERIALS PRODUCED THEREFROM 审中-公开
    来自不饱和聚酯和多晶硅的树脂和生产的酚醛树脂模塑材料

    公开(公告)号:US20130338309A1

    公开(公告)日:2013-12-19

    申请号:US13825929

    申请日:2011-09-13

    IPC分类号: C08G63/91 C08K7/06

    CPC分类号: C08G63/918 C08K7/06 C08L67/06

    摘要: The invention relates to an unsaturated polyester resin containing a polyester or a polyester mixture, produced from at least one unsaturated dicarboxylic acid and at least one diol; and at least one silazane which is accessible for copolymerization with a C═C double bond of the dicarboxylic acid. The invention also relates to an unsaturated polyester resin moulding material which can be obtained or is obtained by cross-linking an unsaturated polyester resin as defined above. Said moulding material can optionally contain reinforcing materials. Said unsaturated polyester resin can be produced using the following steps: (a) a polyester from at least one diol and at least one unsaturated dicarboxylic acid is provided; (b) at least one silazane which is accessible for copolymerization which a C═C double bond of the dicarboxylic acid is provided; (c) the components are mixed according to (a) and (b). The unsaturated polyester resin moulding material can be produced from the above-mentioned polyester resin by hardening thereof by means of a radical initiator.

    摘要翻译: 本发明涉及含有由至少一种不饱和二羧酸和至少一种二醇制成的聚酯或聚酯混合物的不饱和聚酯树脂; 和至少一个可与二羧酸的C = C双键共聚的硅氮烷。 本发明还涉及一种不饱和聚酯树脂成型材料,其可以通过交联如上所述的不饱和聚酯树脂获得或获得。 所述模制材料可任选地包含增强材料。 所述不饱和聚酯树脂可以使用以下步骤制备:(a)提供至少一种二醇和至少一种不饱和二羧酸的聚酯; (b)提供二羧酸的C = C双键的至少一种可用于共聚的硅氮烷; (c)根据(a)和(b)将组分混合。 不饱和聚酯树脂成型材料可以通过使用自由基引发剂进行硬化而由上述聚酯树脂制造。

    Hybrid Polymers from Cyanates and Silazanes, Process for Their Production and Use
    6.
    发明申请
    Hybrid Polymers from Cyanates and Silazanes, Process for Their Production and Use 审中-公开
    氰化物和硅氮烷的混合聚合物,其生产和使用过程

    公开(公告)号:US20120135217A1

    公开(公告)日:2012-05-31

    申请号:US13257085

    申请日:2010-03-16

    IPC分类号: C08L83/16 B32B17/02 C08G77/62

    摘要: This invention refers to hybrid pre-polymers and polymers, produced through conversion from difunctional, oligofunctional and/or polyfunctional cyanates and/or from their pre-polymers with monomeric, oligomeric and/or polymeric silazanes. The polymers are duromers with high glass transition temperature and fracture toughness, compared to duromers from the respective cyanate source material. In their pre-polymerized state, they can be dissolved in solvents and are therefore suitable as impregnating resins for prepregs. In addition, they can be processed to become moldings. Their burning properties are described as particularly outstanding.

    摘要翻译: 本发明涉及通过从双官能,低官能和/或多官能的氰酸酯和/或其预聚物与单体,低聚和/或聚合的硅氮烷的转化而产生的混合预聚物和聚合物。 与来自各个氰酸酯源材料的十二指肠相比,聚合物是具有高玻璃化转变温度和断裂韧性的十二指肠。 在其预聚合状态下,它们可以溶解在溶剂中,因此适合作为浸渍树脂用于预浸料。 此外,它们可以加工成成型。 它们的燃烧性能被描述为特别突出。

    Apparatus and method for retaining a recreational vehicle attachment
    7.
    发明授权
    Apparatus and method for retaining a recreational vehicle attachment 失效
    用于保持娱乐车辆附件的装置和方法

    公开(公告)号:US07461823B2

    公开(公告)日:2008-12-09

    申请号:US11556955

    申请日:2006-11-06

    IPC分类号: E06B9/17

    摘要: An apparatus and method are disclosed for retaining an attachment, such as an awning, to the wall of a recreational vehicle. The apparatus includes a flexible strap assembled from a plurality of strap segments. Male and female portions of adjacent strap segments are joined together to form a flexible interconnection between adjacent strap segments. The apparatus also includes an upper mounting portion for fixedly connecting a first end of the strap to the wall, and a lower mounting portion for detachably connecting a second end of the strap to the wall. Also disclosed are methods of installing and using an apparatus for retaining a recreational vehicle attachment.

    摘要翻译: 公开了用于将诸如遮篷的附件保持在休闲车辆的墙壁上的装置和方法。 该装置包括从多个带段组装的柔性带。 相邻带段的阳和女部分连接在一起以在相邻带段之间形成柔性互连。 该装置还包括用于将带的第一端固定地连接到壁的上部安装部分和用于将带的第二端可拆卸地连接到壁的下部安装部分。 还公开了安装和使用用于保持娱乐车辆附件的装置的方法。

    Method of hydrodechlorinating nuclear-chlorinated ortho-xylenes
    8.
    发明授权
    Method of hydrodechlorinating nuclear-chlorinated ortho-xylenes 失效
    加氢脱氯氯代邻二甲苯的方法

    公开(公告)号:US07098371B2

    公开(公告)日:2006-08-29

    申请号:US10659600

    申请日:2003-09-10

    IPC分类号: C07C1/26

    摘要: Method of hydrodechlorinating nuclear-chlorinated o-xylenes and recovering o-xylene, forming hydrogen chloride, the nuclear-chlorinated o-xylenes being hydrogenated in the gas phase at a noble-metal-containing catalyst at a temperature in the range from 220 to 360° C. The catalyst preferably comprises palladium or platinum, in particular supported palladium or platinum. The nuclear-chlorinated o-xylenes can be used individually or as mixtures.

    摘要翻译: 加氢脱氯核氯代邻二甲苯并回收邻二甲苯形成氯化氢的方法,在含贵金属的催化剂的气相中核氯化邻二甲苯在220至360℃的温度范围内 催化剂优选包含钯或铂,特别是负载的钯或铂。 核氯化的邻二甲苯可以单独使用或作为混合物使用。

    Method for the nuclear chlorination of ortho-xylene
    9.
    发明授权
    Method for the nuclear chlorination of ortho-xylene 有权
    邻二甲苯核氯化方法

    公开(公告)号:US06930216B2

    公开(公告)日:2005-08-16

    申请号:US10659590

    申请日:2003-09-10

    CPC分类号: C07C17/12 C07C25/125

    摘要: A method for the nuclear chlorination of ortho-xylene using a chlorinating agent in the presence of at least one Friedel-Crafts catalyst and chloro-substituted 2,8-dimethylphenoxathiin as co-catalyst. The co-catalyst used is preferably tetrachlorinated 2,8-dimethylphenoxathiin, in particular 1,3,7,9-tetrachloro-2,8-dimethylphenoxathiin of the formula

    摘要翻译: 在至少一种Friedel-Crafts催化剂和氯取代的2,8-二甲基苯氧硫蛋白作为助催化剂的存在下,使用氯化剂对邻二甲苯进行核氯化的方法。 所用的助催化剂优选为四氯化的2,8-二甲基苯氧硫蛋白,特别是1,3,7,9-四氯-2,8-二甲基苯氧硫蛋白

    Process for reductively aminating ketones and aldehydes with aqueous amines and catalysts suitable therefor
    10.
    发明申请
    Process for reductively aminating ketones and aldehydes with aqueous amines and catalysts suitable therefor 失效
    用含胺胺和合适的催化剂还原胺化酮和醛的方法

    公开(公告)号:US20070078282A1

    公开(公告)日:2007-04-05

    申请号:US11526337

    申请日:2006-09-25

    IPC分类号: C07C209/26

    摘要: A process for preparing amines of the general formula (I) R1R2CHNR3R4  (I) in which R1, R2, R3 and R4 are each independently hydrogen, straight-chain or branched, halogenated or halogen-free C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, by catalytic, hydrogenating amination of carbonyl compounds of the general formula (II) R1—C(═O)—R2  (II)with nitrogen compounds of the general formula (III) HNR3R4  (III)in the presence of bifunctional catalyst systems comprising a.) a hydrogenation-active catalyst component comprising one or more metals of transition group 8 of the Periodic Table and b.) one or more solid, acidic cocatalysts, wherein the hydrogenating amination is carried out in the presence of aqueous ammonia or aqueous amine of the formula (III) and at least one organic solvent miscible with ammonia or the aqueous amine of the formula (III).

    摘要翻译: 制备通式(I)的胺的方法<?in-line-formula description =“In-line Formulas”end =“lead”?> R&lt; 2&lt; 2&gt; (I)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中R R 1 -C(-O)-R 与通式(III)的氮化合物< 公式描述=“内联公式”end =“lead”?> HNR <3> 4(III)<?in-line-formula description =“In- 在包含a)包含一种或多种元素周期表第8族金属的氢化活性催化剂组分和b)一种或多种固体,酸性的双官能催化剂体系的存在下,式“末端=”尾“ 助催化剂,其中所述氢化胺化在式(III)的氨水或胺水溶液的存在下进行,和至少一种可与氨或式(III)的胺水溶液混合的至少一种有机溶剂。