Stripping ammonia from liquid effluent of a hydrodenitrification process
    1.
    发明授权
    Stripping ammonia from liquid effluent of a hydrodenitrification process 失效
    从加氢脱氮过程的液体流出物中除去氨

    公开(公告)号:US4059503A

    公开(公告)日:1977-11-22

    申请号:US712088

    申请日:1976-08-05

    CPC分类号: C10G65/04

    摘要: A nitrogen containing feedstock is hydrodenitrified by passing the feed through at least two hydrodenitrification zones, with ammonia produced in the hydrodenitrification being purged from the system prior to the last hydrodenitrification zone to maintain a low ammonia partial pressure in the last hydrodenitrification zone. The ammonia is preferably purged by stripping ammonia from the liquid portion of the effluent withdrawn from the next to last hydrodenitrification zone. Improved denitrification is obtained by maintaining a low ammonia partial pressure in the last hydrodenitrification zone.

    摘要翻译: 通过使进料通过至少两个加氢脱氮区,含氮原料被加氢脱硝,在最后一个加氢脱氮区之前,在加氢脱氮中产生的氨被从系统中清除,以在最后的加氢脱氮区保持低的氨分压。 优选通过从从下一个最后一个加氢脱氮区抽出的废液的液体部分中汽提氨来净化氨。 通过在最后一个加氢脱氮区保持低的氨分压来获得改进的反硝化作用。

    Demetallization of hydrocarbon feedstock
    2.
    发明授权
    Demetallization of hydrocarbon feedstock 失效
    烃原料脱金属

    公开(公告)号:US4227995A

    公开(公告)日:1980-10-14

    申请号:US966901

    申请日:1978-12-06

    摘要: A metal containing hydrocarbon feedstock, such as a heavy residue, is contacted with hydrogen and a material characterized by low porosity, less than 0.3 cc/gram; low surface area, less than 5 m.sup.2 /g; high average pore diameter, greater than 1,000 Angstroms; and a high distribution of large pores, at least 40%, and preferably 50 to 80% of pores greater than 10,000 Angstroms. A preferred material is coke.

    摘要翻译: 含有碳氢化合物原料(例如重残余物)的金属与氢气和特征为低孔隙率小于0.3cc / g的材料接触; 低表面积,小于5m2 / g; 高平均孔径,大于1000埃; 以及大孔的高分布,至少40%,优选50-80%的孔大于10,000埃。 优选的材料是焦炭。

    Coupling process
    3.
    发明授权
    Coupling process 失效
    耦合过程

    公开(公告)号:US4045504A

    公开(公告)日:1977-08-30

    申请号:US671388

    申请日:1976-03-29

    摘要: Process for coupling an alkane to either an alkane, alkene, aliphatic carboxylic acid, or aromatic hydrocarbon by effecting contacting thereof and a melt containing a multivalent metal halide in both its higher and lower valance state. In accordance with a preferred embodiment, the contacting is effected in the presence of an oxygen containing gas or the melt is previously contacted with an oxygen containing gas to produce the corresponding oxyhalide of the metal, whereby the reaction may be effected on a continuous basis.

    摘要翻译: 通过使烷烃与烯烃,烯烃,脂肪族羧酸或芳香族烃的接触和含有多价金属卤化物的熔体在其较高和较低价态下进行偶合来进行。 根据优选实施方案,接触在含氧气体的存在下进行,或者熔体预先与含氧气体接触以产生相应的金属卤氧化物,由此可以连续进行反应。

    Removal of arsenic impurity from hydrocarbons
    4.
    发明授权
    Removal of arsenic impurity from hydrocarbons 失效
    从碳氢化合物中去除砷杂质

    公开(公告)号:US4439313A

    公开(公告)日:1984-03-27

    申请号:US332662

    申请日:1981-12-21

    CPC分类号: C10G25/003

    摘要: Arsenic is removed from a hydrocarbon containing arsenic as an impurity; e.g., shale oil, by contact with hydrogen in the presence of a contact material, such as coke, to deposit the arsenic on the contact material. The arsenic deposited on the contact material is subsequently reacted with an iron compound to produce an iron-arsenic compound suitable for disposal.

    摘要翻译: 将砷作为杂质从含有砷的烃中除去; 例如页岩油,通过在诸如焦炭的接触材料的存在下与氢接触,以将砷沉积在接触材料上。 随后将沉积在接触材料上的砷与铁化合物反应以产生适于处置的铁砷化合物。

    Oxychlorination of methane
    5.
    发明授权
    Oxychlorination of methane 失效
    甲烷的氧氯化

    公开(公告)号:US4207268A

    公开(公告)日:1980-06-10

    申请号:US891411

    申请日:1978-03-30

    IPC分类号: C07C17/154 C07C17/00

    CPC分类号: C07C17/154

    摘要: Methane is oxychlorinated to one or more chlorinated methanes, without net production of carbon tetrachloride, by contacting methane and chlorine and/or hydrogen chloride with a molten mixture of cuprous chloride, cupric chloride, and copper oxychloride, in the presence of an amount of carbon tetrachloride which inhibits net production thereof.

    摘要翻译: 通过在一定量的碳存在下,将甲烷和氯和/或氯化氢与氯化亚铜,氯化铜和氯氧化铜的熔融混合物接触,将甲烷氧氯化成一种或多种氯化甲烷,而不产生四氯化碳。 四氯化碳抑制其净产量。

    Hydroliquefaction of coal
    8.
    发明授权
    Hydroliquefaction of coal 失效
    煤的水化

    公开(公告)号:US4316792A

    公开(公告)日:1982-02-23

    申请号:US106275

    申请日:1979-12-21

    CPC分类号: C10G1/083

    摘要: Coal is catalytically hydroliquefied by passing coal dispersed in a liquefaction solvent and hydrogen upwardly through a plurality of parallel expanded catalyst beds, in a single reactor, in separate streams, each having a cross-sectional flow area of no greater than 255 inches square, with each of the streams through each of the catalyst beds having a length and a liquid and gas superficial velocity to maintain an expanded catalyst bed and provide a Peclet Number of at least 3. If recycle is employed, the ratio of recycle to total feed (coal and liquefaction solvent) is no greater than 2:1, based on volume. Such conditions provide for improved selectivity to liquid product to thereby reduce hydrogen consumption. The plurality of beds are formed by partitions in the reactor.

    摘要翻译: 通过在单独的反应器中将分散在液化溶剂中的煤和氢向上通过多个平行的膨胀催化剂床,在分开的流中将煤分解成氢气,每个流具有不大于255英寸平方的横截面流动面积, 通过每个催化剂床的每个流具有长度和液体和气体空塔速度,以保持膨胀的催化剂床,并提供至少为3的佩佩克数。如果使用再循环,则循环与总进料的比例(煤 和液化溶剂)基于体积不大于2:1。 这样的条件提供了对液体产物的改进的选择性,从而降低了氢消耗。 多个床由反应器中的隔板形成。

    Coke production
    10.
    发明授权
    Coke production 失效
    可口可乐生产

    公开(公告)号:US4547284A

    公开(公告)日:1985-10-15

    申请号:US640228

    申请日:1984-08-13

    IPC分类号: C10B55/00 C10G9/14

    CPC分类号: C10B55/00

    摘要: In the delayed coking of a coking feedstock wherein the feedstock is continuously heated in a coking heater and introduced into a coke drum, the heater is operated to provide a coke drum temperature of from 415.degree. to 455.degree. C., and, after filling of the drum to the desired level, feedstock introduction is discontinued and the coke drum contents are heated at a temperature of 450.degree. C. to 500.degree. C., and which heating temperature is at least 10.degree. C. greater than the coking temperature, by passing a non-coking vapor through the contents of the drum to reduce the volatile combustible matter content to a value of 4% to 10% by weight and thereby reduce the CTE of the formed coke. The process is applicable to the production of needle coke from various kinds of feedstocks, in particular from a petroleum feedstock wherein the feedstock is initially treated by thermal soaking in the presence of sulfur, followed by thermal cracking to increase the aromaticity. Noncrystalline substances may be removed prior to coking to further improve the process.

    摘要翻译: 在焦化原料的延迟焦化中,其中原料在焦化加热器中连续加热并引入焦炭鼓中,操作加热器以提供415℃至455℃的焦炭鼓温度,并且在填充 将鼓转到所需水平,原料引入停止,并将焦碳鼓内容物在450℃至500℃的温度下加热,并且该加热温度比焦化温度高至少10℃,由 使非焦化蒸气通过鼓的内容物,以将易挥发的可燃物含量减少到4重量%至10重量%,从而降低形成的焦炭的CTE。 该方法适用于从各种原料,特别是石油原料生产针状焦,其中原料最初通过在硫的存在下进行热浸,然后进行热裂解以增加芳香性。 在结焦之前可以除去非结晶物质以进一步改善该方法。