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1.发明申请Method of Producing a Substrate Which is Coated With a Mesoporous Layer and Use Thereof in Ophthalmic Optics 有权产生介孔层的基板的制造方法及其在眼科用途中的应用公开(公告)号：US20080079894A1
公开(公告)日：2008-04-03
申请号：US11573137
申请日：2005-05-03
CPC分类号： C09D183/04 , C09D183/02
摘要： The invention relates to a method of producing a substrate which is coated with a mesoporous layer and to the use thereof in ophthalmic optics. The inventive method comprises the following steps consisting in: preparing a precursor sol containing (i) a precursor agent that is selected from compounds having formula M(X)4 (I), in which X is a hydrolysable group and M represents silicon or a tetravalent metal and mixtures thereof, (ii) at least one organic solvent, (iii) at least one pore-forming agent and (iv) water; depositing a film of the precursor sol on a main surface of the substrate; optionally consolidating the mesoporous structure of the deposited film; eliminating the pore-forming agent; and recovering the substrate coated with the mesoporous layer. The method is characterized in that: (i) the pore-forming agent is eliminated at a temperature of less than or equal to 150° C.; and (ii) the method comprises a step involving the introduction of at least one reactive agent bearing at least one hydrophobic group, before the deposition step (b) and/or after said step.
摘要翻译： 本发明涉及一种制造涂覆有介孔层的基材的方法及其在眼科光学中的用途。 本发明的方法包括以下步骤：制备前体溶胶，所述前体溶胶含有（i）选自具有式M（X）4（I）的化合物的前体试剂，其中X是可水解基团，M代表硅或 四价金属及其混合物，（ii）至少一种有机溶剂，（iii）至少一种成孔剂和（iv）水; 在所述基板的主表面上沉积所述前体溶胶的膜; 可选地固结沉积膜的介孔结构; 消除造孔剂; 并回收涂有介孔层的基材。 该方法的特征在于：（i）在小于或等于150℃的温度下除去成孔剂; 和（ii）该方法包括在沉积步骤（b）和/或所述步骤之后引入至少一种带有至少一个疏水基团的反应剂的步骤。
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2.发明授权Method of producing a substrate which is coated with a mesoporous layer and use thereof in ophthalmic optics 有权制备涂覆有介孔层的基材的方法及其在眼科光学中的用途公开(公告)号：US08182866B2
公开(公告)日：2012-05-22
申请号：US11573137
申请日：2005-05-03
IPC分类号： B05D5/06 , C09D183/02 , C09D183/04 , G02B1/04
CPC分类号： C09D183/04 , C09D183/02
摘要： The invention relates to a method of producing a substrate which is coated with a mesoporous layer and to the use thereof in ophthalmic optics. The inventive method comprises the following steps comprising: preparing a precursor sol containing (i) a precursor agent that is selected from compounds having formula M(X)4 (I), in which X is a hydrolysable group and M represents silicon or a tetravalent metal and mixtures thereof, (ii) at least one organic solvent, (iii) at least one pore-forming agent and (iv) water; depositing a film of the precursor sol on a main surface of the substrate; optionally consolidating the mesoporous structure of the deposited film; eliminating the pore-forming agent; and recovering the substrate coated with the mesoporous layer. The method is characterized in that: (i) the pore-forming agent is eliminated at a temperature of less than or equal to 150° C.; and (ii) the method comprises a step involving the introduction of at least one reactive agent bearing at least one hydrophobic group, before the deposition step and/or after said step.
摘要翻译： 本发明涉及一种制造涂覆有介孔层的基材的方法及其在眼科光学中的用途。 本发明的方法包括以下步骤：制备前体溶胶，该前体溶胶含有（i）选自具有式M（X）4（I）的化合物的前体试剂，其中X是可水解基团，M代表硅或四价 金属及其混合物，（ii）至少一种有机溶剂，（iii）至少一种造孔剂和（iv）水; 在所述基板的主表面上沉积所述前体溶胶的膜; 可选地固结沉积膜的介孔结构; 消除造孔剂; 并回收涂有介孔层的基材。 该方法的特征在于：（i）在小于或等于150℃的温度下除去成孔剂; 和（ii）该方法包括在沉积步骤之前和/或在所述步骤之后引入至少一种带有至少一个疏水基团的活性剂的步骤。
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3.发明申请Methods for Making an Article Coated with a Photochromic Film and Use Thereof in Ophthalmological Optics 审中-公开制造涂有光致变色膜的物品的方法及其在眼科学中的应用公开(公告)号：US20130108858A1
公开(公告)日：2013-05-02
申请号：US12278130
申请日：2007-01-31
CPC分类号： G02B5/23 , C03C1/008 , C03C17/007 , C03C2217/425 , C03C2218/113 , C08J7/047 , C08J2483/00 , C09K9/02 , C09K2211/1029 , C09K2211/1033 , C09K2211/1088 , G03C1/73 , Y10T428/249953
摘要： The present invention relates to a method for making a substrate coated with a mesoporous photochromic film, comprising: a) preparing a precursor sol of a mesoporous film comprising an inorganic precursor agent, at least one organic solvent, water, at least one pore-forming agent and one hydrophobic precursor agent bearing at least one hydrophobic group; b) depositing a film of the precursor sol onto a main surface of a substrate; c) removing the pore-forming agent from the film resulting from the previous step at a temperature ≦150° C.; d) impregnating the mesoporous film resulting from step c) with a solution comprising at least one photochromic agent. In an alternative embodiment, the photochromic agent is directly introduced into the precursor sol. In an alternative embodiment of the previous alternative embodiment, the precursor sol does not comprise any hydrophobic precursor agent but the photochromic film is made hydrophobic by a treatment subsequent to its preparation.
摘要翻译： 本发明涉及一种制备涂覆有介孔光致变色膜的基材的方法，包括：a）制备介孔膜的前体溶胶，所述介孔膜包含无机前体试剂，至少一种有机溶剂，水，至少一个成孔 剂和一种具有至少一个疏水基团的疏水性前体剂; b）将前体溶胶的膜沉积到基底的主表面上; c）在150℃的温度下从上一步骤得到的膜中除去造孔剂; d）用包含至少一种光致变色剂的溶液浸渍由步骤c）得到的介孔膜。 在替代实施方案中，将光致变色剂直接引入前体溶胶中。 在先前替代实施方案的替代实施方案中，前体溶胶不包含任何疏水性前体试剂，但是通过在其制备之后的处理使光致变色膜成为疏水性的。
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4.发明申请Article Comprising a Mesoporous Coating Having a Refractive Index Profile and Methods for Making Same 审中-公开包含具有折射率分布的介孔涂层的文章及其制造方法公开(公告)号：US20090169859A1
公开(公告)日：2009-07-02
申请号：US12278133
申请日：2007-02-02
申请人： John Biteau , Jean-Pierre Boilot , Mamonjy Cadet , Hervé Cado , Thierry Gacoin , Muriel Matheron , Philippe Roisin , Laurianne Vagharchakian
发明人： John Biteau , Jean-Pierre Boilot , Mamonjy Cadet , Hervé Cado , Thierry Gacoin , Muriel Matheron , Philippe Roisin , Laurianne Vagharchakian
CPC分类号： G02B3/0087 , G02B1/11 , G02B6/02033 , G02B6/4432 , Y10T428/249953
摘要： The present invention relates to an article comprising a substrate having a main surface coated with a coating, part of which at least is mesoporous and has a refractive index profile with optical function, whose variation is imposed by the mesopore content and/or the filling ratio of the mesopores.The profile may be such that the refractive index varies depending on the distance to a given axis, or such that the refractive index variation is monotone, decreasing along any axis which is perpendicular to the surface of the substrate underlying the mesoporous part of said coating and oriented away from the substrate.The present invention also relates to methods for making said article, which differ depending on the technique from which the refractive index profile is created.The invention is applicable to ophthalmic optics.
摘要翻译： 本发明涉及一种包括基材的制品，该基材具有涂覆有涂层的主表面，其一部分至少是介孔的并且具有光学功能的折射率分布，其变化由中孔含量和/或填充率 的中孔。 轮廓可以使得折射率根据到给定轴的距离而变化，或者使得折射率变化是单调的，沿着垂直于衬底的介孔部分的所述涂层的表面的任何轴减小，以及 远离基板。 本发明还涉及制造所述制品的方法，其根据产生折射率分布的技术而不同。 本发明适用于眼科光学。
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5.发明申请Methods of Using a Non-Photocatalytic Porous Coating as an Antisoiling Coating 审中-公开使用非光催化多孔涂层作为反异涂层的方法公开(公告)号：US20110305827A1
公开(公告)日：2011-12-15
申请号：US13002299
申请日：2009-07-01
申请人： Jean-Pierre Boilot , Mamonjy Cadet , Thierry Gacoin , Muriel Matheron , Lorraine Raboin , Laurianne Vagharchakian
发明人： Jean-Pierre Boilot , Mamonjy Cadet , Thierry Gacoin , Muriel Matheron , Lorraine Raboin , Laurianne Vagharchakian
CPC分类号： G02B1/18 , C03C17/006 , C03C2217/425 , C09D5/1675 , C09D5/1693 , C09D183/04 , G02B1/105 , G02B1/115 , G02B1/14 , G02B27/0006
摘要： The present invention relates to the use as an antisoiling coating of a porous coating comprising a polysiloxane matrix and a porous volume such that the potential filling ratio of the total volume of said coating by oleic acid is at least 25% by volume, having a porosity rate ranging from 25 to 70% by volume and having no photocatalytic properties. The antisoiling porous coating is self-cleaning, easy to clean and can be regenerated by simple washing. It is mainly intended for use in ophthalmic optics, and proves to be very effective against sebum. In the preferred embodiment of the invention, this coating has a mesoporous structure.
摘要翻译： 本发明涉及作为包含聚硅氧烷基质和多孔体积的多孔涂层的防污涂层的用途，使得所述油酸涂料的总体积的潜在填充率为至少25体积％，具有孔隙率 率为25〜70体积％，无光催化性能。 防污多孔涂层是自清洁的，易于清洁，可以通过简单的洗涤再生。 它主要用于眼科光学，并证明对皮脂非常有效。 在本发明的优选实施方案中，该涂层具有介孔结构。
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公开(公告)号：US20090324968A1
公开(公告)日：2009-12-31
申请号：US12307927
申请日：2007-07-10
CPC分类号： C07F7/0836 , C07F7/0838 , Y10T428/31612 , Y10T428/31663
摘要： Hydrophobic treatment composition comprising one or more compounds, as a mixture, corresponding to the formula in which at least one R is a CaF2a+1 group, a being an integer, it being possible for another R to be an SiX3-bRCb1 group, b being 0, 1 or 2X being a hydrolysable group, such as alkoxy, hydroxyl or halo R1 being a hydrocarbon group, such as lower alkyl S is a hydrogen atom, an OH group, an alkyl group, in particular a lower alkyl group, such as CH3, or an OSiR2R3R4 group, R2, R3 and R4 being identical or different and consisting in particular of one of the abovementioned groups carried by an Si atom, such as (CH2)2—R, a hydrogen atom, an alkyl group or OSIR2R3R4, n is an integer≧1, the total number of Si atoms not exceeding 20. Process for treatment by this composition.Hydrophobic glass substrate thus obtained and its application, in particular as glazing.
摘要翻译： 疏水性处理组合物，其包含一种或多种化合物，作为混合物，其中至少一个R为CaF 2 a + 1基团，a为整数，另外R为SiX 3-bRC b 1基团的式 0或1或2个X为可水解基团，例如烷氧基，羟基或卤素R 1为烃基，例如低级烷基S为氢原子，OH基团，烷基，特别是低级烷基， 例如CH 3或OSiR 2 R 3 R 4基团，R 2，R 3和R 4相同或不同，特别由上述基团之一由Si原子例如（CH 2）2 -R，氢原子，烷基 或OSIR2R3R4，n为整数> = 1，Si原子总数不超过20.用该组合物处理的方法。 这样得到的疏水玻璃基板及其应用，特别是玻璃。
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7.发明申请RARE-EARTH PHOSPHATE COLLOIDAL DISPERSION, METHOD FOR THE PRODUCTION THEREOF AND A TRANSPARENT LUMINESCENT MATERIAL OBTAINABLE FROM SAID DISPERSION 审中-公开稀土磷酸盐胶体分散剂，其生产方法和可从固体分散体获得的透明发光材料公开(公告)号：US20110114886A1
公开(公告)日：2011-05-19
申请号：US13010986
申请日：2011-01-21
申请人： Jean-Pierre Boilot , Valérie Buissette , Jean-Yves Chane-Ching , Thierry Gacoin , Thierry Le-Mercier
发明人： Jean-Pierre Boilot , Valérie Buissette , Jean-Yves Chane-Ching , Thierry Gacoin , Thierry Le-Mercier
IPC分类号： C09K11/81
CPC分类号： C01B25/45 , B01J13/0013 , B01J13/0039 , C01B25/37 , C09K11/02 , C09K11/7777 , C09K11/7794 , Y02B20/181
摘要： The invention relates to a colloidal dispersion comprising rhabdophane-structured rare-earth phosphate particles (Ln) and a polyphosphate. Said dispersion is prepared by a method consisting in forming a medium comprising at least one type of rare-earth salt and a poly phosphate in such quantities that the P/Ln ratio is equal to or higher than 3, in heating the thus obtained medium and in removing residual salts, thereby obtaining said dispersion. Said invention also relates to a transparent luminescent material which is obtainable from said dispersion and based on the rare-earth phosphate particles and a polyphosphate and whose P/Ln ratio is higher than 1, to a luminescent system comprising said material and to an excitation source.
摘要翻译： 本发明涉及一种包含rhabdophane结构的稀土磷酸盐颗粒（Ln）和多磷酸盐的胶态分散体。 所述分散体是通过以下方法制备的：在加热由此获得的介质和包含至少一种类型的稀土盐和聚磷酸盐的P / Ln比等于或高于3的量的介质中， 除去残留的盐，从而获得所述分散体。 本发明还涉及从所述分散体和基于稀土磷酸盐颗粒和多磷酸盐并且其P / Ln比高于1的透明发光材料，涉及包含所述材料的发光体系和激发源 。
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公开(公告)号：US08415016B2
公开(公告)日：2013-04-09
申请号：US12307927
申请日：2007-07-10
IPC分类号： B32B9/04
CPC分类号： C07F7/0836 , C07F7/0838 , Y10T428/31612 , Y10T428/31663
摘要： Hydrophobic treatment composition comprising one or more compounds, as a mixture, corresponding to the formula in which at least one R is a CaF2a+1 group, a being an integer, it being possible for another R to be an SiX3-bRC1b group, b being 0, 1 or 2 X being a hydrolysable group, such as alkoxy, hydroxyl or halo R1 being a hydrocarbon group, such as lower alkyl S is a hydrogen atom, an OH group, an alkyl group, in particular a lower alkyl group, such as CH3, or an OSiR2R3R4 group, R2, R3 and R4 being identical or different and consisting in particular of one of the abovementioned groups carried by an Si atom, such as (CH2)2—R, a hydrogen atom, an alkyl group or OSIR2R3R4, n is an integer≧1, the total number of Si atoms not exceeding 20. Process for treatment by this composition. Hydrophobic glass substrate thus obtained and its application, in particular as glazing.
摘要翻译： 疏水性处理组合物，其包含一种或多种化合物，作为其中至少一个R为CaF 2 a + 1基团的化合物的混合物，a为整数，另外R可为SiX 3-bRC 1 b基团，b 0或1或2个X为可水解基团，例如烷氧基，羟基或卤素R 1为烃基，例如低级烷基S为氢原子，OH基团，烷基，特别是低级烷基， 例如CH 3或OSiR 2 R 3 R 4基团，R 2，R 3和R 4相同或不同，特别由上述基团之一由Si原子例如（CH 2）2 -R，氢原子，烷基 或OSIR2R3R4，n为1以上的整数，Si原子数不超过20个。 这样得到的疏水玻璃基板及其应用，特别是玻璃。
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9.发明申请公开(公告)号：US20130078458A1
公开(公告)日：2013-03-28
申请号：US13702043
申请日：2011-05-26
申请人： Claudine Biver , Sandrine Duluard , Joëlle Corde , Jean-Pierre Boilot , Thierry Gacoin , Sandrine Perruchas
发明人： Claudine Biver , Sandrine Duluard , Joëlle Corde , Jean-Pierre Boilot , Thierry Gacoin , Sandrine Perruchas
IPC分类号： B05D3/06
CPC分类号： B05D3/065 , C23C18/1225 , C23C18/1254 , C23C18/1295 , C23C18/14 , C23C18/1603 , C23C18/165 , C23C18/1667 , C23C18/42 , Y10T428/265
摘要： The present invention relates to a method for manufacturing mesostructural coatings comprising electrically conductive structures formed of metal nanoparticles. Said method includes the steps that involve: a) depositing on a substrate, a first layer consisting of a silica material, mesostructured by a structuring agent, and a photocatalytic material: b) depositing on the first layer, a second layer of a mesostructural silica material, said second layer being free of photocatalytic material: c) consolidating the first and second layers at at temperature between 50° C. and 250° C.; and d) placing the consolidating coating in contact with a solution that contains and irradiatting coating with a radiation that enables the photocatalytic material to be activated. Said method is characterized in that it includes no heat treatment at a temperature greater than 250° C.
摘要翻译： 本发明涉及包含由金属纳米颗粒形成的导电结构的介观涂层的制造方法。 所述方法包括以下步骤：a）沉积在基材上，由由结构化剂介孔结构的二氧化硅材料和光催化材料组成的第一层，和b）在第一层上沉积第二层中等结构二氧化硅 所述第二层不含光催化材料：c）在50℃和250℃之间的温度下固化第一层和第二层; 以及d）将固结涂层与含有能够使光催化材料活化的辐射的包含和照射涂层的溶液接触。 所述方法的特征在于它不包括在大于250℃的温度下的热处理
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公开(公告)号：US07510763B2
公开(公告)日：2009-03-31
申请号：US10510714
申请日：2003-04-16
申请人： Lethicia Gueneau , Mauricette Rondet , Sophie Besson , Jean-Pierre Boilot , Thierry Gacoin , Clarisse Durand
发明人： Lethicia Gueneau , Mauricette Rondet , Sophie Besson , Jean-Pierre Boilot , Thierry Gacoin , Clarisse Durand
CPC分类号： B01J21/063 , B01J35/0013 , B01J35/004 , B01J37/0018 , B01J37/036 , C03C17/006 , C03C17/256 , C03C17/3417 , C03C17/3423 , C03C17/3435 , C03C17/3441 , C03C25/42 , C03C25/52 , C03C2217/212 , C03C2217/425 , C03C2217/477 , C03C2217/71 , C03C2218/113 , C04B41/5041 , C04B41/52 , C04B2111/2061 , Y10T428/24364 , Y10T428/2438 , Y10T428/249957 , Y10T428/31 , Y10T428/315 , C04B41/4525 , C04B41/4549 , C04B41/4582 , C04B41/5035 , C04B41/4531 , C04B41/5059
摘要： The invention relates to a transparent substrate based on glass or one or more polymers, or a ceramic or glass substrate, or a substrate made of architectural material of the type comprising a wall render, a concrete slab or block, architectural concrete, roof tile, material of cementitious composition, terracotta, slate, stone, metal surface or a fibrous substrate, based on glass of the mineral insulation wool type, or glass reinforcement yarns. This substrate is distinguished in that it is provided, on at least part of its surface, with a coating whose mesoporous structure exhibits photocatalytic properties and comprises at least partially crystallized titanium oxide. Process for manufacturing this substrate, its application in glazing, as architectural material or as mineral insulation wool is also described.
摘要翻译： 本发明涉及一种基于玻璃或一种或多种聚合物或陶瓷或玻璃基材或由建筑材料制成的基材的透明基材，所述建筑材料包括壁涂，混凝土板或块，建筑混凝土，屋顶瓦， 基于矿物绝缘羊毛类型的玻璃或玻璃增强纱线的水泥组合物，陶土，石板，石材，金属表面或纤维基材的材料。 该基材的特征在于，在其表面的至少一部分上提供其介孔结构表现出光催化性能并且包含至少部分结晶的二氧化钛的涂层。 还描述了用于制造该基材的方法，其在玻璃中的应用，作为建筑材料或矿物绝缘羊毛。
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