Resinous composition and antifouling paint
    1.
    发明授权
    Resinous composition and antifouling paint 失效
    树脂组合物和防污漆

    公开(公告)号:US4485197A

    公开(公告)日:1984-11-27

    申请号:US456289

    申请日:1983-01-06

    摘要: Resinous compositions comprising an acrylic resin containing, as polymer constituting units, 20 to 55% by weight of tri-organic tin .alpha.,.beta.-unsaturated carboxylate, 0.1 to 25% by weight of hydroxy bearing (meth)acrylate and the remainder of another polymerizable unsaturated monomer are provided. The compositions are useful as resinous vehicles for antifouling paints, capable of being gradually hydrolyzed in sea water, thereby resulting in a smooth coating surface and liberating an antifouling agent by themselves.

    摘要翻译: 含有作为聚合物构成单元的丙烯酸树脂的树脂组合物含有20〜55重量%的三有机锡α,β-不饱和羧酸酯,0.1〜25重量%的含羟基的(甲基)丙烯酸酯,其余的可聚合的 不饱和单体。 该组合物可用作防污涂料的树脂载体,能够在海水中逐渐水解,从而形成光滑的涂布表面并自身释放防污剂。

    Resin for use in an antifouling coating and antifouling coating
    5.
    发明授权
    Resin for use in an antifouling coating and antifouling coating 失效
    用于防污涂料和防污涂料的树脂

    公开(公告)号:US06462102B1

    公开(公告)日:2002-10-08

    申请号:US09401854

    申请日:1999-09-22

    IPC分类号: C09D516

    CPC分类号: C08F8/42 C09D5/1668

    摘要: The present invention is related to a resin for use in an antifouling coating which is a polymer obtained by polymerizing a polymerizable unsaturated monomer(s) and having, at side chain terminals thereof, a trisubstituted borane-amine complex and an azomethine group, or a group represented by the following general formula (1): (wherein M represents a metal selected from the group consisting of copper, zinc, nickel and cobalt, - - - means a chemically bound state, W represents —N(R1)R2— (in which R1 and R2 may be the same or different and each represents a hydrogen atom or an alkyl group containing 1 to 4 carbon atoms), —OCO—, —OSO2— or L represents an alkylene group containing 1 to 4 carbon atoms, and m represents an integer of 0 to 4).

    摘要翻译: 本发明涉及一种用于防污涂料的树脂,其是通过聚合可聚合不饱和单体而获得的聚合物,并且在侧链末端具有三取代的硼烷 - 胺络合物和偶氮甲碱基,或 由以下通式(1)表示的基团:(其中M表示选自铜,锌,镍和钴的金属, - 表示化学键合状态,W表示-N(R1)R2-( 其中R 1和R 2可以相同或不同,并且各自表示氢原子或含有1至4个碳原子的烷基),-OCO-,-OSO 2 - 或L表示含有1至4个碳原子的亚烷基,m 表示0〜4的整数)。

    Antifouling paint compositions
    6.
    发明授权
    Antifouling paint compositions 失效
    防油漆组合物

    公开(公告)号:US5199977A

    公开(公告)日:1993-04-06

    申请号:US732882

    申请日:1991-07-19

    IPC分类号: C09D5/16

    CPC分类号: C09D5/1668

    摘要: An antifouling paint containing a copolymer including a recurring unit of the formula: ##STR1## wherein R.sup.1 is hydrogen atom, methyl or an alkoxycarbonyl, R.sup.2 is hydrogen atom or an alkoxycarbonyl, A is an acid ion-terminated pendant group, M is a transitional metal ion, L is a monobasic organic acid ion, and m is the valency of the transitional metal M; and an amount of an organic ligand capable of coordinating to the transitional metal. The ion-association and reactivity of the metal in the copolymer may be retarded by complexing with the organic ligand in situ.

    COATING COMPOSITION AND METHOD FOR PRODUCING THE SAME, COATING FILM AND UNDERWATER STRUCTURES
    10.
    发明申请
    COATING COMPOSITION AND METHOD FOR PRODUCING THE SAME, COATING FILM AND UNDERWATER STRUCTURES 有权
    涂料组合物及其制造方法,涂膜和水下结构

    公开(公告)号:US20110178204A1

    公开(公告)日:2011-07-21

    申请号:US13120608

    申请日:2009-09-28

    IPC分类号: C09D5/16

    摘要: Provided are coating composition containing an organic polymer particle (A) composed of an organic polymer having a hydroxyl group and a cationic group in a molecule, the weight average particle size of which being 10 to 35 μm, and a base resin (B), wherein the content of the organic polymer particle (A) is 0.5 to 5.0% by weight in the solid content of the coating composition, and a method of producing the same, and a coating film and underwater structure using the coating composition. The base resin (B) has a group represented by the following general formula (1): —COO-M-OCO-A  (1) (wherein, M represents a divalent or higher valent metal, and A represents an organic acid residue of monobasic acid) or a group represented by the following general formula (2): —COO—Si(R1R2R3)  (2) (wherein, R1, R2 and R3, which may be the same or different, represent an isopropyl group or an n-butyl group) in a side chain, or has a cross-linking structure represented by the following general formula (3): —COO-M-OCO—  (3) (wherein, M represents the same meaning as described above).

    摘要翻译: 本发明提供含有由分子内具有羟基和阳离子性基团的有机聚合物构成的有机聚合物粒子(A)的重均粒径为10〜35μm的涂料组合物和基础树脂(B), 其中,所述有机聚合物粒子(A)的含量为所述涂料组合物的固体成分中的0.5〜5.0重量%,其制造方法,以及使用所述涂料组合物的涂膜和水下结构体。 基础树脂(B)具有以下通式(1)表示的基团:-COO-M-OCO-A(1)(其中,M表示二价以上的金属,A表示有机酸残基 一元酸)或由以下通式(2)表示的基团:-COO-Si(R 1 R 2 R 3)(2)(其中,R 1,R 2和R 3可以相同或不同,表示异丙基或n (3)表示的交联结构:-COO-M-OCO-(3)(其中,M表示与上述相同的含义)。