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公开(公告)号：US06783749B2
公开(公告)日：2004-08-31
申请号：US10144489
申请日：2002-05-13
IPC分类号： C01B300
CPC分类号： C01B3/382 , B01D53/047 , B01D53/86 , B01D2253/102 , B01D2253/108 , B01D2256/16 , B01D2257/504 , B01D2257/7025 , B01D2259/40001 , C01B3/386 , C01B3/48 , C01B3/56 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/043 , C01B2203/0435 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0877 , C01B2203/1023 , C01B2203/1064 , C01B2203/1082 , C01B2203/1205 , C01B2203/1241 , C01B2203/142 , C01B2203/146 , C01B2203/147 , C01B2203/148 , Y02C10/08 , Y02C20/20 , Y02P20/123 , Y02P20/152 , Y02P20/156 , Y02P20/52 , Y02P20/57
摘要： Improved method for recovering hydrogen and carbon monoxide from hydrocarbon conversion processes are disclosed. A monolith catalyst reactor means is utilized in treating the waste gas stream from the hydrocarbon conversion process to assist in recovering hydrogen and carbon monoxide from the waste gas stream. The present invention also provides a method for improving the yield of hydrogen and carbon monoxide from a hydrocarbon conversion process utilizing a monolith catalyst reactor means.
摘要翻译： 公开了用于从烃转化方法回收氢和一氧化碳的改进方法。 整体催化剂反应器装置用于处理来自烃转化过程的废气流，以帮助从废气流中回收氢气和一氧化碳。 本发明还提供了一种利用整体催化剂反应器装置从烃转化方法提高氢和一氧化碳的产率的方法。
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2.发明授权Monolith based catalytic partial oxidation process for syngas production 失效用于合成气生产的基于Monolith的催化部分氧化方法公开(公告)号：US07090826B2
公开(公告)日：2006-08-15
申请号：US10657610
申请日：2003-09-08
申请人： Weibin Jiang , Seungdoo Park , Mark S. Tomczak , Divyanshu R. Acharya , Satish S. Tamhankar , Ramakrishnan Ramachandran
发明人： Weibin Jiang , Seungdoo Park , Mark S. Tomczak , Divyanshu R. Acharya , Satish S. Tamhankar , Ramakrishnan Ramachandran
CPC分类号： C01B3/386 , C01B2203/0261 , C01B2203/043 , C01B2203/046 , C01B2203/047 , C01B2203/0877 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/1276 , C01B2203/146 , C01B2203/148 , C01B2203/1604 , C01B2203/1609 , Y02P20/52
摘要： An improved process for the catalytic partial oxidation of hydrocarbons to produce hydrogen and carbon monoxide and less than ˜2% carbon dioxide is disclosed. The process further permits the reaction to be initiated at room temperature, and utilizes a metal catalyst deposited on a ceria-coated zirconia monolith support, which exhibits high conversions of hydrocarbons to synthesis gas (hydrogen and carbon monoxide).
摘要翻译： 公开了一种用于烃的催化部分氧化以产生氢气和一氧化碳和小于2％二氧化碳的改进方法。 该方法进一步允许反应在室温下开始，并且利用沉积在二氧化铈涂覆的氧化锆整料载体上的金属催化剂，其表现出高的烃转化为合成气（氢气和一氧化碳）。
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公开(公告)号：US07303606B2
公开(公告)日：2007-12-04
申请号：US11092345
申请日：2005-03-29
申请人： Yongxian Zeng , Divyanshu R. Acharya , Satish S. Tamhankar , Narayanan Ramprasad , Ramakrishnan Ramachandran , Frank R. Fitch , Donald L. MacLean , Jerry Y. S. Lin , Richard H. Clarke
发明人： Yongxian Zeng , Divyanshu R. Acharya , Satish S. Tamhankar , Narayanan Ramprasad , Ramakrishnan Ramachandran , Frank R. Fitch , Donald L. MacLean , Jerry Y. S. Lin , Richard H. Clarke
IPC分类号： B01D53/04
CPC分类号： B01D53/04 , B01D53/047 , B01D2253/10 , B01D2256/12 , B01D2257/102 , B01D2259/40001 , C01B13/0259 , C01B2210/0046 , F23C9/00 , F23C2202/30 , F23L7/007 , F23L2900/07001 , Y02E20/322 , Y02E20/344 , Y02P20/124 , Y10S502/525
摘要： Production of oxygen-enriched gas streams is disclosed herein. Air streams contact an oxygen-selective mixed conductor particularly a perovskite material whereby oxygen is retained or adsorbed on the perovskite and can be employed in a variety of processes such as in combusting a fuel gas, heat recovery and boiler related operations.
摘要翻译： 本文公开了富氧气流的生产。 空气流接触氧选择性混合导体，特别是钙钛矿材料，由此氧气保留或吸附在钙钛矿上，可用于燃烧燃气，热回收和锅炉相关操作等各种工艺。
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公开(公告)号：US5468459A
公开(公告)日：1995-11-21
申请号：US395344
申请日：1995-02-28
摘要： A per-fluorocarbon containing gas is treated by contacting per-fluorocarbon contained within the gas with calcium hydride at a temperature in a range of between about 450 and 900.degree. C. The calcium hydride can be contained in a bed mixed with silicon or calcium oxide and such bed can be used in conjunction with a downstream bed of calcium oxide to remove any hydrogen fluoride produced. Also, an upstream bed of calcium fluoride can be used to treat acid gases in case of semiconductor processing applications of the present invention.
摘要翻译： 通过使气体中所含的碳氟化合物与氢化钙在约450-900℃之间的温度下接触来处理含碳氟化合物的气体。氢化钙可以包含在与硅或氧化钙混合的床中 并且这种床可以与氧化钙的下游床结合使用以除去所产生的任何氟化氢。 此外，在本发明的半导体加工应用的情况下，可以使用氟化钙的上游床来处理酸性气体。
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公开(公告)号：US5693856A
公开(公告)日：1997-12-02
申请号：US587174
申请日：1996-01-16
IPC分类号： B01J27/128 , B01J19/18 , C07C51/265 , C07C63/15 , C07C63/26 , C07C51/16
CPC分类号： C07C51/265 , B01J19/18 , B01J2219/185 , Y02P20/52
摘要： Terephthalic acid is produced by reacting paraxylene with oxygen in a reactor having several vertical stages, the reaction taking place in the liquid phase using acetic acid as solvent and a cobalt-manganese-bromine complex catalyst. During the reaction, a carbon dioxide-containing gas phase is withdrawn from the vapor space of the reactor. The gas phase is cooled to condense vaporized acetic acid therefrom and carbon dioxide is separated from the gas phase and recycled to the vapor space or to the liquid phase or to both of these. In an alternate embodiment, the gas remaining after condensing acetic acid is subjected to catalytic oxidation to oxidize carbon monoxide and methane, if present, to carbon dioxide, and some or all of the carbon dioxide is recycled to the reactor.
摘要翻译： 对苯二甲酸是通过在具有几个垂直级的反应器中使对二甲苯与氧反应制备的，反应在液相中使用乙酸作为溶剂和钴 - 锰 - 溴络合物催化剂进行。 在反应过程中，含有二氧化碳的气相从反应器的蒸汽空间排出。 将气相冷却以冷凝蒸发的乙酸，并将二氧化碳与气相分离并再循环至蒸气空间或液相或两者。 在另一个实施方案中，将乙酸缩合后剩余的气体进行催化氧化，以将一氧化碳和甲烷（如果存在）氧化成二氧化碳，并且将一些或全部二氧化碳再循环到反应器中。
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公开(公告)号：US5620501A
公开(公告)日：1997-04-15
申请号：US515444
申请日：1995-08-15
IPC分类号： B01D53/053
CPC分类号： B01D53/053 , B01D2257/206 , B01D2258/0216 , B01D2259/40001 , B01D2259/40081 , B01D2259/401 , B01D2259/416 , B01D53/0446
摘要： Selected strongly adsorbed gaseous impurities are removed from a gas stream by pressure swing adsorption in an adsorption system which includes a single adsorption vessel, a gas storage vessel and a single gas pump. Feed gas is pumped at a selected adsorption pressure cocurrently through the adsorption vessel, which contains an adsorbent that selectively adsorbs the selected impurity or impurities. The less strongly adsorbed components of the gas mixture pass out the adsorption vessel through the nonadsorbed gas outlet end of the adsorption vessel. When the adsorbed gas front reaches a certain point in the adsorption vessel, the adsorption step is terminated and gas is countercurrently transferred from the adsorption vessel to a gas storage vessel, optionally with use of the gas pump. The adsorption vessel is then countercurrently evacuated by use of the pump and a selected gas-enriched product is recovered and sent to storage or further processed in downstream treatment operations. Following bed regeneration, the adsorption vessel is partially repressurized by transferring gas from the storage vessel to the adsorption vessel, optionally with use of the pump, and then the adsorption vessel is pressurized to the selected adsorption pressure using the pump.
摘要翻译： 通过在包括单个吸附容器，气体存储容器和单个气体泵的吸附系统中通过变压吸附从气流中除去选择的强吸附气态杂质。 进料气体以选定的吸附压力并流地泵送通过吸附容器，该吸附容器包含选择性吸附所选择的杂质或杂质的吸附剂。 气体混合物吸附较少的组分通过吸附容器的非吸附气体出口端排出吸附容器。 当吸附气体前端到达吸附容器中的某一点时，终止吸附步骤，并且可选地使用气泵将气体从吸附容器逆流转移到气体存储容器。 然后通过使用泵逆流抽吸吸附容器，回收选择的富含气体的产物，并将其送入储存或在下游处理操作中进一步处理。 在床再生后，通过将气体从储存容器转移到吸附容器，任选地使用泵将吸附容器部分地再加压，然后使用泵将吸附容器加压到选定的吸附压力。
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公开(公告)号：US5417742A
公开(公告)日：1995-05-23
申请号：US160999
申请日：1993-12-03
IPC分类号： B01D53/04 , B01D53/047 , C07C17/38
CPC分类号： C07C17/38 , B01D53/0462 , B01D53/047 , C07C17/389 , B01D2253/108 , B01D2253/30 , B01D2253/308 , B01D2257/2066 , B01D2259/4006 , B01D2259/40064 , Y02C20/30 , Y02P20/154 , Y02P20/155 , Y10S95/902 , Y10S95/903
摘要： Perfluorocarbons are recovered from gas streams by subjecting the gas stream to an adsorption process in a bed of one or more energetically homogeneous adsorbents such as silicon-rich adsorbents of the FAU structure, silicon-rich adsorbents of the BEA structure, silicon-rich adsorbents of the MOR structure. The adsorption process is preferably pressure swing adsorption or temperature swing adsorption.
摘要翻译： 通过使气流在一种或多种能量均匀的吸附剂的床中进行吸附过程，例如FAU结构的富硅吸附剂，BEA结构的富含硅吸附剂，富含硅的吸附剂的富含硅的吸附剂，从气流中回收全氟化碳 MOR结构。 吸附过程优选为变压吸附或变温吸附。
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公开(公告)号：US20060204415A1
公开(公告)日：2006-09-14
申请号：US11431796
申请日：2006-05-10
申请人： Weibin Jiang , Seungdoo Park , Mark Tomczak , Divyanshu Acharya , Satish Tamhankar , Ramakrishnan Ramachandran
发明人： Weibin Jiang , Seungdoo Park , Mark Tomczak , Divyanshu Acharya , Satish Tamhankar , Ramakrishnan Ramachandran
CPC分类号： C01B3/386 , C01B2203/0261 , C01B2203/043 , C01B2203/046 , C01B2203/047 , C01B2203/0877 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/1276 , C01B2203/146 , C01B2203/148 , C01B2203/1604 , C01B2203/1609 , Y02P20/52
摘要： An improved process for the catalytic partial oxidation of hydrocarbons to produce hydrogen and carbon monoxide and less than ˜2% carbon dioxide is disclosed. The process further permits the reaction to be initiated at room temperature, and utilizes a metal catalyst deposited on a ceria-coated zirconia monolith support, which exhibits high conversions of hydrocarbons to synthesis gas (hydrogen and carbon monoxide).
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9.发明授权Sparger configuration for fluidized bed hydrocarbon partial oxidation reactors 失效用于流化床烃部分氧化反应器的分布器配置公开(公告)号：US06743400B2
公开(公告)日：2004-06-01
申请号：US09813508
申请日：2001-03-21
IPC分类号： B32B1902
CPC分类号： B01J8/1827 , B01J8/1818 , B01J2208/00548 , B01J2208/00628 , B01J2219/00024 , B01J2219/00259 , B01J2219/0286
摘要： The present invention is directed to a sparger system provided for appropriately feeding reactant streams to fluidized bed reactors of hydrocarbon partial oxidation processes that are retrofitted to selectively recover and recycle unreacted hydrocarbons. As a result of the sparger system, the reactor productivity and selectivity is enhanced while employing only two spargers. Also, the capital cost required for retrofitting existing sparging equipment is minimized, while at the same time, the desired fluidization and catalyst oxidation characteristics are achieved without the formation of flammable mixtures within the sparging system.
摘要翻译： 本发明涉及一种用于将反应物流适当地供给到烃部分氧化方法的流化床反应器的喷射器系统，其被改装以选择性地回收和再循环未反应的烃。 作为喷射器系统的结果，反应器的生产率和选择性得到提高，同时仅使用两个喷雾器。 此外，将现有喷射设备改造所需的资金成本降到最低，同时，在喷射系统内不形成易燃混合物的同时实现所需的流化和催化剂氧化特性。
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公开(公告)号：US5908804A
公开(公告)日：1999-06-01
申请号：US926330
申请日：1997-09-05
CPC分类号： C10G11/182 , B01D53/56 , Y02P30/446
摘要： Coke is burned in the regenerator vessel of an FCC complex with a combustion medium consisting of a diluent gas, such as air, enriched with oxygen, The regenerator is operated in partial combustion mode and excess oxygen is introduced into the combustion zone of the regenerator. Emission of nitrogen oxides to the atmosphere is reduced.
摘要翻译： 焦炭在FCC复合物的再生器容器中被燃烧介质组成，该燃烧介质由稀释气体（例如富氧的空气）组成。再生器以部分燃烧模式操作，并且过量的氧气被引入再生器的燃烧区。 氮氧化物向大气中的排放减少了。
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