摘要:
Polymeric hydroquinones of the structure ##STR1## , wherein n is from 3 to 10,000 inclusive and R and R' independently are hydrogen or a lower alkyl, are disclosed, as is the preparation and the use of such materials, especially as nonabsorbable polymeric antioxidants for edible materials.
摘要:
Polymeric hydroquinones of the structure ##STR1## WHEREIN N IS FROM 3 TO 10,000 INCLUSIVE AND R and R' independently are hydrogen or a lower alkyl, are disclosed, as is the preparation and the use of such materials, especially as nonabsorbable polymeric antioxidants for edible materials.
摘要:
The present invention provides a new water purification method and system using reverse osmosis. In particular, the present invention provides methods and water purification systems using an ion exchange resin and absorbent media for pretreatment of water being fed to a reverse osmosis treatment system, where the pretreatment reduces fouling of, or deposits or chemical attack on the membrane surfaces and passageways. Particularly, a macroporous resin having an average pore diameter in the range of 1,000 to 500,000 Angstroms and a crush strength or Chatillon value of at least 24 g/bead (710 μm bead diameter) is used.
摘要:
N-substituted maleimide polymers comprising the recurring structural units: ##STR1## wherein R and R' independently are lower alkyl groups of from 1 to 5 carbon atoms and n is an integer of from about 2 to about 2,000, are disclosed. Their preparation as well as the preparation of their monomer precursors and the preferred use of the polymers as antioxidants, particularly nonabsorbable food antioxidants, are also disclosed.
摘要:
N-substituted maleimide polymers comprising the recurring structural units: ##STR1## wherein R and R' independently are lower alkyl groups of from 1 to 5 carbon atoms and n is an integer of from about 2 to about 2,000, are disclosed. Their preparation as well as the preparation of their monomer precursors and the preferred use of the polymers as antioxidants, particularly nonabsorbable food antioxidants, are also disclosed.
摘要:
The present invention provides a macroporous copolymer having large pores, typically in the range of 5,000-200,000 Å and a typical breaking weight of at least 175 g/bead. The macroporous copolymers can be made using an interpenetrating polymer network (IPN) techniques. These macroporous copolymers may also form macroporous resins. The present invention also provides methods of using the macroporous copolymers and resins.
摘要:
Polymeric phenols of the formula ##STR1## WHEREIN N IS AN INTEGER FROM 3 TO 2,000, R.sub.1 is a lower alkyl and R.sub.2 is hydrogen or a lower alkyl, are disclosed. Their preparation and preferred use as antioxidants, especially nonabsorbable food antioxidants, are also disclosed.
摘要:
Phenolic polymers having 3 to 1000 repeating units of the general structural formula ##STR1## wherein X and X.sup.1 independently are hydrogens or methyls, R is a lower alkyl of from 1 to 6 carbon atoms or an aryl, alkaryl or aralkyl of from 6 to 14 carbon atoms, and R.sup.1, R.sup.2 and R.sup.3 independently are hydrogen, lower alkyls of from 1 to 6 carbon atoms, aralkyls of from 8 to 14 carbons, or alkoxys or aralkyloxys of from 1 to about 14 carbons, are prepared in one step by contacting an R.sup.1, R.sup.2 and R.sup.3 -containing phenol having two hydrogens ortho to the hydroxyl group with a low purity diolefinic hydrocarbon under ortho-alkylation conditions in the presence of an effective amount of an ortho-alkylation catalyst. These materials find use as antioxidants, especially for edibles, where their polymeric nature offers advantages.
摘要:
The present invention provides a new water purification method and system using reverse osmosis. In particular, the present invention provides methods and water purification systems using an ion exchange resin and absorbent media for pretreatment of water being fed to a reverse osmosis treatment system, where the pretreatment reduces fouling of, or deposits or chemical attack on the membrane surfaces and passageways. Particularly, a macroporous resin having an average pore diameter in the range of 1,000 to 500,000 Angstroms and a crush strength or Chatillon value of at least 24 g/bead (710 μm bead diameter) is used.
摘要:
The present invention provides methods of using a novel sulfonated resin catalyst, showing improved performance. The catalyst has reduced or partial functionalization, throughout the sulfonated region of the polymer, leading to reduced by-product formation and other desirable features. This catalyst has particular usefulness in reactions or processes sensitive to high acidity, e.g., esterification-transesterification.