摘要:
A hydrogen-absorbing alloy electrode for an alkaline storage cell, the electrode including a hydrogen-absorbing alloy expressed by a composition formula ReBxMy, wherein Re is at least one element selected from a group consisting of rare earth elements and alkali earth elements, B is boron, and M is at least one element selected from a group consisting of Ni, Co, Mn, Al, Cr, Fe, Cu. Sn, Sb, Mo, V, Nb, Ta, Zn, Zr and Ti. The alloy consists essentially of an RM.sub.y main metal phase, and a subordinate boron-containing phase, such as a compound phase of boron and a IV-a, V-a, or VI-a group metal.
摘要:
A hydrogen-absorbing alloy electrode for use in an alkaline storage cell, comprising a hydrogen-absorbing alloy for reversibly absorbing and desorbing hydrogen; and a metal oxide or metal hydroxide existing in the state of a metal in a range of electric potential where said hydrogen-absorbing alloy electrochemically absorbs and desorbs hydrogen in an alkaline electrolyte.
摘要:
A hydrogen-absorbing alloy electrode comprising a hydrogen-absorbing alloy represented by a formula ANi.sub.a Co.sub.b Mn.sub.c or ANi.sub.a Co.sub.b Mn.sub.c X.sub.d, A representing a mixture of rare earth elements including La and X representing at least one element selected from a group of Fe, Cu, Mo, W, B, Al, Si and Sn, wherein 2.5.ltoreq.a.ltoreq.3.5, 0.4.ltoreq.b.ltoreq.1.5, 0.2.ltoreq.c.ltoreq.1.0, and 3.85.ltoreq.a+b+c.ltoreq.4.78 in the case of ANi.sub.a Co.sub.b Mn.sub.c or 2.5.ltoreq.a.ltoreq.3.5, 0.4.ltoreq.b.ltoreq.1.5, 0.2.ltoreq.c.ltoreq.1.0, 0
摘要翻译:一种吸氢合金电极,其包含由式ANiaCobMnc或ANiaCobMncXd表示的吸氢合金,A表示包含La和X的稀土元素的混合物,所述稀土元素表示选自Fe,Cu,Mo,W, B,Al,Si和Sn,其中2.5≤a≤3.5,0.4≤b= 1.5,0.2,c = 1.0,和3.85 a + b + c < 在ANiaCobMnc或2.5 = a <3.5,0.4 = b = 1.5,0.2 = c <1.0,0
摘要:
A hydrogen-absorbing alloy electrode for use in an alkaline storage cell, comprising a hydrogen-absorbing alloy for reversibly absorbing and desorbing hydrogen; and a metal oxide or metal hydroxide existing in the state of a metal in a range of electric potential where said hydrogen-absorbing alloy electrochemically absorbs and desorbs hydrogen in an alkaline electrolyte.
摘要:
A hydrogen-absorbing alloy electrode comprises a conductive substrate, a layer of hydrogen-absorbing alloy granules disposed on the conductive substrate and a binder for binding the granules together and to the conductive substrate. A part of the granules is exposed on a surface of the layer on the electrode. The layer may have a predetermined thickness and the granules may include large size granules having a maximum diameter larger than half the thickness of the layer but smaller than the thickness of the layer. The granules may include first granules having a first average diameter and second granules having a second average diameter smaller than the first average diameter; the first granules may be 5 wt % or more but less than 20 wt % of the total weight of the granules.
摘要:
A hermetically sealed battery is provided, equipped with a opening sealing unit 10 including a Positive Temperature Coefficient (PTC) element without reducing the volume of the outside can, and capable of preventing the generation of a large current in case a short circuit occurs as well as enhancing operational security. The opening sealing unit 10 according to the invention comprises a bottom plate 11 for closing the opening of the outside can 18, a positive electrode cap 12 forming a space for storing a pressure valve, said positive electrode cap being used as a terminal for the positive electrode, a resilient valve 14 having a steel plate 14a on the upper surface, a spring 15 and a PTC element ring 16 disposed on the flange 12a in the positive electrode cap 12. An insulation gasket 17 is mounted onto the periphery of the opening sealing unit 10 to hermetically close the opening of the outside can 18.
摘要:
After coating a hydrogen absorbing alloy slurry obtained by kneading a hydrogen absorbing alloy powder 12a, a polyethylene oxide (PEO) powder as a binder 12b, and a suitable amount of water (a solvent for binder) to both surfaces of a metal core plate (active material holder) made of a punching metal, the core plate is dried. Then, after removing the active material layer 13 from the core plate 11 by a means such as cutting and the like, a definite amount of water (a solvent for binder) is sprayed to the cut surface (the exposed surface of the core plate 11) to attach the water to the cur surface followed by drying to provide a hydrogen absorbing alloy electrode 10, which is disposed at the outermost side of the electrode group.
摘要:
An alkaline storage battery comprising a positive electrode active material mainly composed of nickel hydroxide, characterized in that the nickel hydroxide is a higher order nickel hydroxide covered with a cobalt compound on the surface thereof or in the vicinity thereof and the higher order nickel hydroxide is provided with at least one compound selected from the group consisting of yttrium compound, erbium compound and ytterbium compound on the surface thereof or in the vicinity
摘要:
A nickel active material for an alkali storage cell whose surface is covered with a cobalt compound, wherein the diffusion and permeation into the nickel hydroxide mother particles of cobalt compound during excessive discharging, which act to reduce the active material efficiency and the excessive discharging characteristics, are prevented. This is achieved by having a covering layer, including one or more of the following metal compounds; an aluminum compound, a magnesium compound, an indium compound and a zinc compound, in addition to a cobalt compound, formed on the surface of a mother particle of nickel hydroxide, and by heat treating the covered mother particles in the presence of alkali and oxygen so as to convert the cobalt compound into a compound of cobalt where an oxidization number of cobalt is greater than 2.
摘要:
A hermetically sealed battery with an opening-sealing unit 10 according to the present invention comprises a PTC element ring 16 elastically clamped between the flange 12a of a positive electrode cap 12 and a fold portion 11d formed at the peripheral portion 11c of a bottom plate 11, such that when the temperature of the PTC element rises due to overcurrent or overheating, the PTC element ring 16 can easily expand, thereby tripping the large current with its resistance capacity increased to a predetermined level at a predetermined temperature, thereby enhancing operational security of the battery.