摘要:
The present invention relates to a process for producing spherical particles of at least one material, which comprises the steps: (A) preparation of a solution or dispersion of the at least one material in at least one water-miscible solvent or dispersion medium, (B) conversion of the solution or dispersion obtained in step (A) into individual portions comprising an amount of the at least one material corresponding to the amount present in the spherical particles by underwater pelletization and (C) introduction of the portions obtained in step (B) into a medium which is miscible with the solvent or dispersion medium from step (A) and in which the material used in step (A) is insoluble so that the solvent or dispersion medium used in step (A) is replaced by the medium which is miscible with the solvent or dispersion medium from step (A) and the material solidifies to form the spherical particle.
摘要:
A solution system for biopolymers in the form of carbohydrates based on a molten ionic liquid, additives optionally being contained in the solution system, is described. This solution system contains a protic solvent or a mixture of several protic solvents, and in the case where the protic solvent is solely water, this is present in the solution system in an amount of more than about 5 wt. %. Carbohydrates can be incorporated into the solution system, in particular in the form of starch, cellulose and derivatives thereof, and it can then be used for regeneration of the carbohydrates contained therein. A particularly advantageous process for the preparation of the solution system containing the carbohydrates and for the preparation of regenerated carbohydrates, in particular in the form of regenerated cellulose fibers, is moreover described. The invention accordingly also provides such spun fibers as are distinguished in that they are non-fibrillating. The invention offers in particular economic advantages over the systems of the prior art.
摘要:
A solution system for biopolymers in the form of carbohydrates based on a molten ionic liquid, additives optionally being contained in the solution system, is described. This solution system contains a protic solvent or a mixture of several protic solvents, and in the case where the protic solvent is solely water, this is present in the solution system in an amount of more than about 5 wt. %. Carbohydrates can be incorporated into the solution system, in particular in the form of starch, cellulose and derivatives thereof, and it can then be used for regeneration of the carbohydrates contained therein. A particularly advantageous process for the preparation of the solution system containing the carbohydrates and for the preparation of regenerated carbohydrates, in particular in the form of regenerated cellulose fibers, is moreover described. The invention accordingly also provides such spun fibers as are distinguished in that they are non-fibrillating. The invention offers in particular economic advantages over the systems of the prior art.
摘要:
The invention relates to a method for producing regenerated biopolymers in the form of carbohydrates, using a solvent system that contains the biopolymers dissolved therein. The solvent system is based on a melted ionic liquid and optionally a protic solvent or a mixture thereof. The biopolymers dissolved in the solvent system are precipitated in a coagulation medium, said medium comprising a protic coagulant or a mixture of protic coagulants. The method according to the invention is characterized in that the surface tension σ of the coagulant or the mixture of coagulants is 99% to 30% of the surface tension σ of water, the surface tension being measured according to ASTM D 1590-60 at a temperature of 50° C. The method according to the invention is economical and flexible and leads to advantageous products, especially in the form of staple fibers which are especially not fibrillated and have an advantageous wet to dry strength ratio.
摘要:
The invention relates to a method for producing regenerated biopolymers in the form of carbohydrates, using a solvent system that contains the biopolymers dissolved therein. The solvent system is based on a melted ionic liquid and optionally a protic solvent or a mixture thereof. The biopolymers dissolved in the solvent system are precipitated in a coagulation medium, said medium comprising a protic coagulant or a mixture of protic coagulants. The method according to the invention is characterized in that the surface tension a of the coagulant or the mixture of coagulants is 99% to 30% of the surface tension a of water, the surface tension being measured according to ASTM D 1590-60 at a temperature of 50° C. The method according to the invention is economical and flexible and leads to advantageous products, especially in the form of staple fibers which are especially not fibrillated and have an advantageous wet to dry strength ratio.
摘要翻译:本发明涉及使用含有溶解于其中的生物聚合物的溶剂系统生产碳水化合物形式的再生生物聚合物的方法。 溶剂系统基于熔融的离子液体和任选的质子溶剂或其混合物。 溶解在溶剂体系中的生物聚合物在凝固介质中沉淀,所述介质包含质子凝结剂或质子凝结剂的混合物。 根据本发明的方法的特征在于,凝结剂或凝结剂混合物的表面张力a为水的表面张力a的99%至30%,表面张力根据ASTM D 1590-60测量, 温度为50℃。根据本发明的方法是经济和灵活的,并且导致有利的产品,特别是以特别不原纤化并且具有有利的湿干比强度的短纤维的形式。
摘要:
Crosslinked cellulose beads or lignocellulose beads (referred to as beads for short), wherein at least 50% by weight of the beads have a particle diameter greater than 800 μm (21° C., 1 bar, determined by sieve analysis).
摘要:
A binder-consolidated cellulose bead or lignocellulose bead (referred to as consolidated bead for short), obtainable by mixing of cellulose or lignocellulose beads with a binder and subsequent crosslinking of the binder.
摘要:
The present invention provides a process for producing low fibrillating cellulose fibers by a dry-jet-wet spinning process wherein cellulose is treated with a solvent containing imidazolium ionic salt in a spinneret maintained at a temperature of 100-120° C. and the spun fibers drawn to the coagulation bath containing ionic salt with the draw ratio less than 5, to produce fibers with fibrillating index less than or equal to 3.