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    DENTAL MATERIALS BASED ON MONOMERS HAVING DEBONDING-ON-DEMAND PROPERTIES
    2.
    发明申请
    DENTAL MATERIALS BASED ON MONOMERS HAVING DEBONDING-ON-DEMAND PROPERTIES 有权

    公开(公告)号：US20140329929A1

    公开(公告)日：2014-11-06

    申请号：US14343297

    申请日：2012-09-10

    申请人： Norbert Moszner ,  Iris Lamparth ,  Thorsten Bock ,  Urs Karl Fischer ,  Ulrich Salz ,  Volker Rheinberger ,  Robert Liska

    发明人： Norbert Moszner ,  Iris Lamparth ,  Thorsten Bock ,  Urs Karl Fischer ,  Ulrich Salz ,  Volker Rheinberger ,  Robert Liska

    IPC分类号： A61K6/083

    CPC分类号： A61K6/0835 ,  A61K6/0002 ,  A61K6/0023 ,  A61K6/083 ,  C07D239/47 ,  C07F3/06 ,  C08F122/22 ,  C08L33/00

    摘要： The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]1  Formula I, in which T represents a thermolabile or photolabile group, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, wherein at least one Z1 or Z2 is a polymerizable group, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical and k, l, m and n in each case independently are 1, 2 or 3.

    Dental materials with improved hydrolysis stability based on phthalic acid monomers
    3.
    发明授权
    Dental materials with improved hydrolysis stability based on phthalic acid monomers 有权
    具有改善的基于邻苯二甲酸单体的水解稳定性的牙科材料

    公开(公告)号：US09393181B2

    公开(公告)日：2016-07-19

    申请号：US13630491

    申请日：2012-09-28

    申请人： Thorsten Bock ,  Urs Karl Fischer ,  Iris Lamparth ,  Norbert Moszner ,  Volker Rheinberger

    发明人： Thorsten Bock ,  Urs Karl Fischer ,  Iris Lamparth ,  Norbert Moszner ,  Volker Rheinberger

    IPC分类号： A61K6/00 ,  A61K6/083 ,  C08F2/50

    CPC分类号： A61K6/0023 ,  A61K6/083 ,  C08L33/24

    摘要： Dental material which contains a polymerizable phthalic acid derivative of the general Formula I: with R1=H, methyl or a C1-C5 alkyl residue; R2=H, a phenyl, benzyl or C1-C8 alkyl residue; Q1=is absent or is a C1-C15 alkylene residue, wherein the carbon chain can be interrupted by O or S; Q2=is absent or a (n+1)-valent aliphatic C1-C20 residue, wherein the carbon chain can be interrupted by O or S and wherein Q1 and Q2 cannot be absent simultaneously; X=is absent, is O, S or (—CO—NR4—)—, wherein R4 is H, CH3 or C2H5; Y=is absent, is O, S or (—CO—NR5—)—, wherein R5 is H, CH3 or C2H5; n, m=independently of one another in each case mean 1, 2 or 3; R3=H, CH3, C2H5, Cl, Br or OCH3, and wherein the two carboxyl groups of the benzene ring can together form an anhydride group.

    摘要翻译： 含有通式I的可聚合邻苯二甲酸衍生物的牙科材料：其中R1 = H，甲基或C1-C5烷基残基; R2 = H，苯基，苄基或C1-C8烷基残基; Q1 =不存在或是C1-C15亚烷基残基，其中碳链可被O或S间隔; Q2 =不存在或（n + 1）价的脂族C1-C20残基，其中碳链可以被O或S中断，并且其中Q1和Q2不能同时存在; X =不存在，为O，S或（-CO-NR 4 - ） - ，其中R 4为H，CH 3或C 2 H 5; Y =不存在，是O，S或（-CO-NR 5 - ） - ，其中R 5是H，CH 3或C 2 H 5; 在每种情况下，n，m =彼此独立，意指1,2或3; R3 = H，CH3，C2H5，Cl，Br或OCH3，其中苯环的两个羧基可以一起形成酸酐基团。

    Polymerizable compositions with acylgermanium compounds
    8.
    发明授权
    Polymerizable compositions with acylgermanium compounds 有权
    具有酰基锗化合物的可聚合组合物

    公开(公告)号：US07605190B2

    公开(公告)日：2009-10-20

    申请号：US11902865

    申请日：2007-09-26

    申请人： Norbert Moszner ,  Ulrich Salz ,  Urs Karl Fischer ,  Robert Liska ,  Heinrich Gruber ,  Beate Ganster

    发明人： Norbert Moszner ,  Ulrich Salz ,  Urs Karl Fischer ,  Robert Liska ,  Heinrich Gruber ,  Beate Ganster

    IPC分类号： A61C13/00 ,  A61C13/225 ,  A61K6/00 ,  C08F2/50 ,  C08J3/28

    CPC分类号： C08F2/50 ,  A61K6/083 ,  C08F4/72 ,  Y10S522/908 ,  C08L33/00

    摘要： Composition with at least one polymerizable binder and at least one polymerization initiator, which contains at least one acylgermanium compound according to general Formula (I), in which R0 is a substituted or unsubstituted C1-18-alkyl radical or an acyl group; R1 and R2 are H, an acyl group or have one of the meanings given for R3; R3 is a branched or linear C1-18-alkyl radical which can be unsubstituted or substituted one or more times by —O—, —NH—, —NR—, —S— or interrupted by other groups, trimethylsilyl, hal-(CH3)2Si—[OSi(CH3)2]r−, (CH3)3Si—[OSi(CH3)2]r—, —COOH, —COO—R10, —CO—NR11R12, —CO-vinyl, —CO-phenyl, phenyl-C1-4-alkyl, phenyl, naphthyl or biphenyl, C5-12 cycloalkyl, a 5 or 6-membered O, S or N-containing heterocyclic ring, halogen, OH, an aromatic C6-30 radical which can be substituted or unsubstituted and/or interrupted by O, S or —NR—, or a branched, cyclic or linear C1-20 alkyl, -alkenyl, -alkoxy or -alkenoxy radical; m is 1, 2 or 3; n is 0 or 1 and p is 0 or 1; wherein in each case two of the radicals R0, R1, R2 or R3 can be connected to each other accompanied by the formulation of a 5 to 8 member ring; and the use of acylegermanium compounds of Formula (I), for example, as initiator for radical polymerization.

    摘要翻译： 含有至少一种可聚合粘合剂和至少一种聚合引发剂的组合物，其含有至少一种根据通式（I）的酰基锗化合物，其中R 0是取代或未取代的C 1-18 - 烷基或酰基; R 1和R 2是H，酰基或具有R 3给出的含义之一; R3是支链或直链的C1-18 - 烷基，其可以是未取代的或被-O - ， - NH - ， - NR - ， - S-取代或被其它基团间隔的一个或多个，三甲基甲硅烷基，hal-（CH 3 ）2Si- [OSi（CH 3）2] r - ，（CH 3）3 Si- [OSi（CH 3）2] r - ，-COOH，-COO-R 10，-CO-NR 11 R 12，-CO-乙烯基， 苯基，C 1-4 - 烷基，苯基，萘基或联苯基，C 5-12环烷基，5或6元O，S或N的杂环，卤素，OH，可被取代的芳族C 6-30基团 或未取代和/或被O，S或-NR-或支链，环状或直链的C 1-20烷基， - 烯基， - 烷氧基或 - m为1,2或3; n为0或1，p为0或1; 其中在每种情况下，基团R 0，R 1，R 2或R 3中的两个可以相互连接，伴随着5-8元环的配制; 以及使用式（I）的乙烯基锗化合物，例如作为自由基聚合的引发剂。

    Polymerizable compositions with acylgermanes as initiatiors
    9.
    发明申请
    Polymerizable compositions with acylgermanes as initiatiors 审中-公开
    具有酰基作为起始物的可聚合组合物

    公开(公告)号：US20080076847A1

    公开(公告)日：2008-03-27

    申请号：US11730533

    申请日：2007-04-02

    申请人： Norbert Moszner ,  Ulrich Salz ,  Urs Karl Fischer ,  Robert Liska ,  Heinrich Gruber ,  Beate Ganster

    发明人： Norbert Moszner ,  Ulrich Salz ,  Urs Karl Fischer ,  Robert Liska ,  Heinrich Gruber ,  Beate Ganster

    IPC分类号： C08F2/50 ,  A61K6/08 ,  C08J3/28 ,  C08F2/46

    CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/0052 ,  A61K6/083 ,  C08F2/50 ,  C08F4/72 ,  C08F222/1006 ,  C08F230/10 ,  C08L33/00

    摘要： Composition with at least one polymerizable binder and a polymerization initiator, which contains at least one acylgermane according to general Formula (I), in which R0 is a substituted or unsubstituted C1-18-alkyl radical or an acyl group; R1 and R2 are H, an acyl group or have one of the meanings given for R3; R3 is a branched or linear C1-18-alkyl radical which can be unsubstituted or substituted one or more times by —O—, —NH—, —NR—, —S— or interrupted by other groups, trimethylsilyl, hal-(CH3)2Si—[OSi(CH3)2]r−, (CH3)3Si—[OSi(CH3)2]r—, —COOH, —COO—R10, —CO—NR11R12, —CO-vinyl, —CO-phenyl, phenyl-C1-4-alkyl, phenyl, naphthyl or biphenyl, C5-12 cycloalkyl, a 5 or 6-membered O, S or N-containing heterocyclic ring, halogen, OH, an aromatic C6-30 radical which can be substituted or unsubstituted and/or interrupted by O, S or —NR—, or a branched, cyclic or linear C1-20 alkyl, -alkenyl, -alkoxy or -alkenoxy radical; m is 1, 2 or 3; n is 0 or 1 and p is 0 or 1; and the use of acyl germanes of Formula (I) for example as initiator for radical polymerization.

    摘要翻译： 含有至少一种可聚合粘合剂和聚合引发剂的组合物，其含有至少一种根据通式（I）的酰基锗烷，其中R 0是取代或未取代的C 1-18烷基， /烷基或酰基; R 1和R 2均为H，酰基或具有R 3给出的含义之一; R 3是支链或直链C 1-18 - 烷基，其可以是未取代的或被-O - ， - NH-，-NR- ，-S-或被其它基团中断，三甲基甲硅烷基，卤代（CH 3）2 Si- [OSi（CH 3）3） （CH 3）3 Si- [OSi（CH 3）3） -COOH，-COO-R 10，-CO-NR， - ， - SO 2 - ， - 11- 12，-CO-乙烯基，-CO-苯基，苯基-C 1-4 - 烷基，苯基，萘基或联苯基，C

    Polymerizable compositions with acylgermanium compounds
    10.
    发明申请
    Polymerizable compositions with acylgermanium compounds 有权
    具有酰基锗化合物的可聚合组合物

    公开(公告)号：US20080277814A1

    公开(公告)日：2008-11-13

    申请号：US11902865

    申请日：2007-09-26

    申请人： Norbert Moszner ,  Ulrich Salz ,  Urs Karl Fischer ,  Robert Liska ,  Heinrich Gruber ,  Beate Ganster

    发明人： Norbert Moszner ,  Ulrich Salz ,  Urs Karl Fischer ,  Robert Liska ,  Heinrich Gruber ,  Beate Ganster

    IPC分类号： A61C13/087

    CPC分类号： C08F2/50 ,  A61K6/083 ,  C08F4/72 ,  Y10S522/908 ,  C08L33/00

    摘要： Composition with at least one polymerizable binder and at least one polymerization initiator, which contains at least one acylgermanium compound according to general Formula (I), in which R0 is a substituted or unsubstituted C1-18-alkyl radical or an acyl group; R1 and R2 are H, an acyl group or have one of the meanings given for R3; R3 is a branched or linear C1-18-alkyl radical which can be unsubstituted or substituted one or more times by —O—, —NH—, —NR—, —S— or interrupted by other groups, trimethylsilyl, hal-(CH3)2Si—[OSi(CH3)2]r−, (CH3)3Si—[OSi(CH3)2]r—, —COOH, —COO—R10, —CO—NR11R12, —CO-vinyl, —CO-phenyl, phenyl-C1-4-alkyl, phenyl, naphthyl or biphenyl, C5-12 cycloalkyl, a 5 or 6-membered O, S or N-containing heterocyclic ring, halogen, OH, an aromatic C6-30 radical which can be substituted or unsubstituted and/or interrupted by O, S or —NR—, or a branched, cyclic or linear C1-20 alkyl, -alkenyl, -alkoxy or -alkenoxy radical; m is 1, 2 or 3; n is 0 or 1 and p is 0 or 1; wherein in each case two of the radicals R0, R1, R2 or R3 can be connected to each other accompanied by the formulation of a 5 to 8 member ring; and the use of acylegermanium compounds of Formula (I), for example, as initiator for radical polymerization.

    摘要翻译： 含有至少一种可聚合粘合剂和至少一种聚合引发剂的组合物，其含有至少一种根据通式（I）的酰基锗化合物，其中R 0是取代或未取代的C 1 -18-烷基或酰基; R 1和R 2均为H，酰基或具有R 3给出的含义之一; R 3是支链或直链C 1-18 - 烷基，其可以是未取代的或被-O - ， - NH-，-NR- ，-S-或被其它基团中断，三甲基甲硅烷基，卤代（CH 3）2 Si- [OSi（CH 3）3） （CH 3）3 Si- [OSi（CH 3）3） -COOH，-COO-R 10，-CO-NR， - ， - SO 2 - ， - 11- 12，-CO-乙烯基，-CO-苯基，苯基-C 1-4 - 烷基，苯基，萘基或联苯基，C