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    Solid polymer electrolyte membrane and process for producing the same, and fuel cell
    1.
    发明授权
    Solid polymer electrolyte membrane and process for producing the same, and fuel cell 失效
    固体高分子电解质膜及其制造方法及燃料电池

    公开(公告)号：US07629393B2

    公开(公告)日：2009-12-08

    申请号：US11401249

    申请日：2006-04-11

    申请人： Norifumi Takahashi ,  Toshio Ohba ,  Nobuo Kawada

    发明人： Norifumi Takahashi ,  Toshio Ohba ,  Nobuo Kawada

    IPC分类号： C08J5/20

    CPC分类号： H01M8/1088 ,  C08J5/225 ,  C08J2323/06 ,  C08J2327/18 ,  H01B1/122 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/106 ,  H01M8/1072 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02P70/56

    摘要： The present invention relates to a solid polymer electrolyte membrane having both of a higher proton conductivity and a smaller methanol permeability, which can be produced by conducting a graft polymerization of a fluororesin thin membrane irradiated with a radiation with a monofunctional monomer and again irradiating the resulting film with a radiation, followed by conducting a graft polymerization thereof with a polyfunctional monomer; and a high-performance fuel cell comprising the solid polymer electrolyte membrane, a fuel electrode and an air electrode, said solid polymer electrolyte membrane being disposed between the fuel electrode and the air electrode.

    摘要翻译： 本发明涉及具有较高质子传导性和较小的甲醇渗透性的固体高分子电解质膜，其可以通过用单功能单体进行辐射照射的氟树脂薄膜进行接枝聚合而产生，并再次照射所得到的 膜，然后用多官能单体进行接枝聚合; 以及包含所述固体高分子电解质膜，燃料极和空气极的高性能燃料电池，所述固体高分子电解质膜设置在所述燃料电极和所述空气极之间。

    Method for curing optical fiber coating material
    4.
    发明授权
    Method for curing optical fiber coating material 有权

    公开(公告)号：US06432489B1

    公开(公告)日：2002-08-13

    申请号：US09805979

    申请日：2001-03-15

    申请人： Toshio Ohba ,  Nobuo Kawada ,  Masaya Ueno

    发明人： Toshio Ohba ,  Nobuo Kawada ,  Masaya Ueno

    IPC分类号： C08F246

    摘要： Methods for curing a coating material, including a primary coating material, a secondary coating material, and a taping material, on an optical fiber. An optical fiber coating material having (A) 100 parts by weight of a polyether polyurethane bearing at least two ethylenically unsaturated groups with a Mn of 800-10,000, and (B) 1-40 parts by weight of a nitrogenous reactive diluent is cured by irradiating thereto electron beams, produced by driving electrons under an accelerating voltage of 50-190 kV, in a dose of 10-100 kGy. The method succeeds in effectively curing the optical fiber coating material into a cured coating having stable properties.

    ELECTROLYTE MEMBRANE-ELECTRODE ASSEMBLY FOR DIRECT METHANOL FUEL CELL
    5.
    发明申请
    ELECTROLYTE MEMBRANE-ELECTRODE ASSEMBLY FOR DIRECT METHANOL FUEL CELL 有权
    直接甲醇燃料电池用电解质膜电极组件

    公开(公告)号：US20100248071A1

    公开(公告)日：2010-09-30

    申请号：US12304061

    申请日：2007-05-23

    申请人： Shigeru Konishi ,  Hiroshi Matsukawa ,  Nobuo Kawada ,  Toshio Ohba

    发明人： Shigeru Konishi ,  Hiroshi Matsukawa ,  Nobuo Kawada ,  Toshio Ohba

    IPC分类号： H01M8/10

    CPC分类号： H01M8/1011 ,  H01M4/92 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0234 ,  H01M8/1037 ,  H01M8/1072 ,  H01M2250/30 ,  H01M2300/0082 ,  Y02B90/18 ,  Y02E60/523 ,  Y02P70/56

    摘要： Disclosed is an electrolyte membrane-electrode assembly for direct methanol fuel cells, wherein a solid polymer electrolyte membrane is held between a pair of electrodes each composed of a catalyst layer coated over and/or impregnated in a porous supporting body. This electrolyte membrane-electrode assembly for direct methanol fuel cells is characterized in that the solid polymer electrolyte membrane is obtained by irradiating a resin membrane with radiation and graft-polymerizing a radically polymerizable monomer. The electrolyte membrane-electrode assembly for direct methanol fuel cells is further characterized in that the catalyst layer of the anode electrode comprises a catalyst, wherein platinum group metal or platinum-containing alloy particles having a particle size of 5 nm or less are supported by carbon particles, and a solid polymer electrolyte, and the noble metal amount in the catalyst layer of the anode electrode is not more than 5 mg/cm2. By using such a catalyst, there can be obtained a direct methanol fuel cell wherein high output is achieved by using high methanol concentration.

    摘要翻译： 公开了一种用于直接甲醇燃料电池的电解质膜 - 电极组件，其中固体聚合物电解质膜保持在一对电极之间，每对电极由涂覆在多孔支撑体上的和/或浸渍在多孔支撑体中的催化剂层组成。 该直接甲醇燃料电池用电解质膜 - 电极组件的特征在于，固体高分子电解质膜通过用辐射照射树脂膜并使自由基聚合性单体进行接枝聚合而获得。 用于直接甲醇燃料电池的电解质膜 - 电极组件的特征还在于，阳极电极的催化剂层包括催化剂，其中具有5nm或更小的粒径的铂族金属或含铂合金颗粒由碳负载 颗粒和固体聚合物电解质，并且阳极电极的催化剂层中的贵金属量不大于5mg / cm 2。 通过使用这样的催化剂，可以获得通过使用高甲醇浓度实现高产量的直接甲醇燃料电池。

    Electrolyte membrane-electrode assembly for direct methanol fuel cell
    6.
    发明授权
    Electrolyte membrane-electrode assembly for direct methanol fuel cell 有权
    用于直接甲醇燃料电池的电解质膜 - 电极组件

    公开(公告)号：US09083026B2

    公开(公告)日：2015-07-14

    申请号：US12304061

    申请日：2007-05-23

    申请人： Shigeru Konishi ,  Hiroshi Matsukawa ,  Nobuo Kawada ,  Toshio Ohba

    发明人： Shigeru Konishi ,  Hiroshi Matsukawa ,  Nobuo Kawada ,  Toshio Ohba

    IPC分类号： H01M4/02 ,  H01M8/10 ,  H01M4/92 ,  H01M8/02

    CPC分类号： H01M8/1011 ,  H01M4/92 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0234 ,  H01M8/1037 ,  H01M8/1072 ,  H01M2250/30 ,  H01M2300/0082 ,  Y02B90/18 ,  Y02E60/523 ,  Y02P70/56

    摘要： Disclosed is an electrolyte membrane-electrode assembly for direct methanol fuel cells, wherein a solid polymer electrolyte membrane is held between a pair of electrodes each composed of a catalyst layer coated over and/or impregnated in a porous supporting body. This electrolyte membrane-electrode assembly for direct methanol fuel cells is characterized in that the solid polymer electrolyte membrane is obtained by irradiating a resin membrane with radiation and graft-polymerizing a radically polymerizable monomer. The electrolyte membrane-electrode assembly for direct methanol fuel cells is further characterized in that the catalyst layer of the anode electrode comprises a catalyst, wherein platinum group metal or platinum-containing alloy particles having a particle size of 5 nm or less are supported by carbon particles, and a solid polymer electrolyte, and the noble metal amount in the catalyst layer of the anode electrode is not more than 5 mg/cm2. By using such a catalyst, there can be obtained a direct methanol fuel cell wherein high output is achieved by using high methanol concentration.

    摘要翻译： 公开了一种用于直接甲醇燃料电池的电解质膜 - 电极组件，其中固体聚合物电解质膜保持在一对电极之间，每对电极由涂覆在多孔支撑体上的和/或浸渍在多孔支撑体中的催化剂层组成。 该直接甲醇燃料电池用电解质膜 - 电极组件的特征在于，固体高分子电解质膜通过用辐射照射树脂膜并使自由基聚合性单体进行接枝聚合而获得。 用于直接甲醇燃料电池的电解质膜 - 电极组件的特征还在于，阳极电极的催化剂层包括催化剂，其中具有5nm或更小的粒径的铂族金属或含铂合金颗粒由碳负载 颗粒和固体聚合物电解质，并且阳极电极的催化剂层中的贵金属量不大于5mg / cm 2。 通过使用这样的催化剂，可以获得通过使用高甲醇浓度实现高产量的直接甲醇燃料电池。

    Preparation of optical fiber
    7.
    发明授权
    Preparation of optical fiber 失效
    光纤的制备

    公开(公告)号：US06877344B2

    公开(公告)日：2005-04-12

    申请号：US10077975

    申请日：2002-02-20

    申请人： Toshio Ohba ,  Nobuo Kawada ,  Masaya Ueno

    发明人： Toshio Ohba ,  Nobuo Kawada ,  Masaya Ueno

    IPC分类号： G02B6/44 ,  B29C35/08 ,  B29C35/10 ,  C03C25/10 ,  C03C25/12 ,  C03C25/24 ,  C03C25/62 ,  C08F2/46 ,  C03B37/01 ,  G21G5/00

    CPC分类号： C03C25/12 ,  B29C35/10 ,  B29C2035/0877 ,  B29L2011/0075

    摘要： An optical fiber is prepared by applying a liquid electron beam-curable resin composition to a bare optical fiber or a coated optical fiber having a primary or secondary coating on a bare optical fiber, irradiating electron beams to the resin composition on the optical fiber for curing while the optical fiber passes a zone under substantially atmospheric pressure, and providing a magnetic field and optionally an electric field in the zone for thereby improving the efficiency of electron irradiation. The method can comply with the increased drawing speed of the bare optical fiber and does not detract from the transmission properties of the optical fiber.

    摘要翻译： 通过将液态电子束固化性树脂组合物涂布在裸光纤或裸光纤上具有初级或次级涂层的涂布光纤上，将电子束照射到光纤上的树脂组合物进行固化来制备光纤 而光纤通过基本上大气压下的区域，并且在该区域中提供磁场和任选的电场，从而提高电子辐射的效率。 该方法可以符合裸光纤的提高的拉丝速度，并且不会降低光纤的传输特性。

    Electron beam system for treating filamentary workpiece, and method of fabricating optical fibers
    8.
    发明授权
    Electron beam system for treating filamentary workpiece, and method of fabricating optical fibers 失效
    用于处理丝状工件的电子束系统和制造光纤的方法

    公开(公告)号：US06774381B2

    公开(公告)日：2004-08-10

    申请号：US09908808

    申请日：2001-07-20

    申请人： Nobuo Kawada ,  Toshio Ohba

    发明人： Nobuo Kawada ,  Toshio Ohba

    IPC分类号： A61N500

    CPC分类号： G21K5/10 ,  H01J37/317 ,  H01J2237/204 ,  H01J2237/3156

    摘要： An electron beam system for treating filamentary workpieces includes an electron beam irradiation chamber having openings through which passes a filamentary workpiece, an electron beam generator including means for generating, accelerating and focusing electrons, and a communicating section which connects the electron beam generator with the electron beam irradiation chamber. The system also has a differential evacuating means for holding the pressure within the electron beam generator below that within the electron beam irradiation chamber. Electrons are generated, accelerated, and focused by the electron beam generator into a beam which passes from the generator through the communicating section to the electron beam irradiation chamber where the beam is directed at a filamentary workpiece. The system is able to uniformly, efficiently, and continuously apply electron beam irradiation to a traveling filamentary workpiece. When used in the fabrication of optical fiber, this system can accommodate higher fiber drawing speeds without compromising the transmission characteristics of the resulting optical fiber.

    摘要翻译： 一种用于处理丝状工件的电子束系统包括具有穿过丝状工件的开口的电子束照射室，包括用于产生，加速和聚焦电子的装置的电子束发生器和将电子束发生器与电子连接的连通部分 光束照射室。 该系统还具有用于将电子束发生器内的压力保持在电子束照射室内的压差的差分排气装置。 电子被电子束发生器产生，加速和聚焦成从发生器通过连通部分到电子束照射室的光束，其中光束被引导到丝状工件。 该系统能够均匀，有效并且连续地对行进的丝状工件施加电子束照射。 当用于光纤制造时，该系统可以适应较高的纤维拉伸速度，而不会影响所得光纤的传输特性。