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    Production of hydroperoxized functionalized olefinic compounds
    1.
    发明授权
    Production of hydroperoxized functionalized olefinic compounds 失效
    氢过氧化官能化烯烃化合物的生产

    公开(公告)号：US07476769B1

    公开(公告)日：2009-01-13

    申请号：US11983685

    申请日：2007-11-09

    申请人： Olga Khabasheshku ,  Jason Clark ,  Steve Harden ,  Steven Gray ,  Vance Stevens ,  Carlos Corleto

    发明人： Olga Khabasheshku ,  Jason Clark ,  Steve Harden ,  Steven Gray ,  Vance Stevens ,  Carlos Corleto

    IPC分类号： C07C409/02 ,  C08J3/28

    CPC分类号： C08J3/28 ,  C08J2321/00

    摘要： Process for the preparation of a hydroperoxide functionalized olefinic compound in an oxidation reactor containing a particulate catalyst bed comprising a light induced photosensitized catalyst component supported on a particulate substrate material forming a permeable catalyst bed. The photoenergized catalyst component is a photoreductant material which is effective for the conversion of triplet oxygen to singlet oxygen under illumination with ultraviolet or visible light. An oxygen containing feed stream containing triplet oxygen is supplied to the catalyst bed. The catalyst bed is irradiated at an intensity to convert triplet oxygen to singlet oxygen to produce a singlet oxygen enriched gas stream. The enriched gas stream is supplied to a second reactor which contains a dispersion of an olefinic component having an allylic hydrogen which is contacted with the enriched gas stream under conditions effective to cause an allylic rearrangement and introduce hydroperoxide functionalization into the olefinic component.

    摘要翻译： 在含有颗粒催化剂床的氧化反应器中制备氢过氧化物官能化烯烃化合物的方法，所述颗粒催化剂床包含负载在形成可渗透催化剂床的颗粒基质材料上的光诱导的光敏催化剂组分。 光电催化剂组分是一种光致抗蚀剂材料，其在用紫外线或可见光照明下有效地将三线态氧转化为单线态氧。 将含有三重态氧的含氧进料流供给催化剂床。 以强度照射催化剂床，以将三线态氧转化为单线态氧以产生单线态富氧气流。 将富集的气体流供应到第二反应器，该第二反应器含有具有烯丙基氢的烯烃组分的分散体，所述烯烃组分在有效引起烯丙基重排并将氢过氧化物官能化引入到烯烃组分中的条件下与富集气流接触。

    Polystyrene Blends
    7.
    发明申请
    Polystyrene Blends 有权
    聚苯乙烯共混物

    公开(公告)号：US20120259071A1

    公开(公告)日：2012-10-11

    申请号：US13530212

    申请日：2012-06-22

    申请人： Camille Grossetete ,  David W. Knoeppel ,  Jose M. Sosa ,  Shane Steagall ,  Carlos Corleto

    发明人： Camille Grossetete ,  David W. Knoeppel ,  Jose M. Sosa ,  Shane Steagall ,  Carlos Corleto

    IPC分类号： C08L25/06

    CPC分类号： C08L25/06 ,  C08L2205/02 ,  C08L2207/20

    摘要： A method of preparing a polystyrene blend that includes combining a first polystyrene composition having a first melt flow index with a second polystyrene composition having a second melt flow index and forming a polystyrene blend, the second melt flow index being at least 2 dg/min higher that the first melt flow index. The polystyrene blend has an observed tensile strength value greater than 3% above the expected tensile strength value. The second polystyrene composition can include a recycled polystyrene material, which can include expanded polystyrene. An alternate method of preparing the polystyrene blend includes combining a polystyrene composition with a styrene monomer to form a reaction mixture, polymerizing the reaction mixture and obtaining a polystyrene blend, where the polystyrene containing composition has a melt flow index at least 2 dg/min higher than the melt flow index of the styrene monomer after it has been polymerized.

    摘要翻译： 一种制备聚苯乙烯共混物的方法，其包括将具有第一熔体流动指数的第一聚苯乙烯组合物与具有第二熔体流动指数的第二聚苯乙烯组合物组合并形成聚苯乙烯共混物，所述第二熔体流动指数至少为2dg / min 第一个熔体流动指数。 聚苯乙烯共混物的观测拉伸强度值大于预期拉伸强度值的3％以上。 第二聚苯乙烯组合物可以包括再循环的聚苯乙烯材料，其可以包括发泡聚苯乙烯。 制备聚苯乙烯共混物的替代方法包括将聚苯乙烯组合物与苯乙烯单体组合以形成反应混合物，使反应混合物聚合并获得聚苯乙烯共混物，其中含聚苯乙烯的组合物的熔体流动指数至少为2dg / min 比苯乙烯单体聚合后的熔体流动指数高。

    Accelerated method to determine or predict failure time in polyethylenes
    8.
    发明授权
    Accelerated method to determine or predict failure time in polyethylenes 失效
    加快确定或预测聚乙烯中失效时间的方法

    公开(公告)号：US06935185B2

    公开(公告)日：2005-08-30

    申请号：US10737624

    申请日：2003-12-16

    申请人： Carlos Corleto

    发明人： Carlos Corleto

    IPC分类号： G01N3/00 ,  G01N3/06 ,  G01N3/60 ,  G01N19/08

    CPC分类号： G01N3/60 ,  G01N2203/0066 ,  G01N2203/0647

    摘要： An accelerated method of determining the failure time of a polyethylene resin by determining the minimum displacement rate, or the time at minimum displacement rate, using ASTM F 1473-01, then following one of these routes: (1) If failure has not yet occurred, cryogenically fracturing the resin specimen and examining it for slow crack growth to determine whether the anticipated, or desired, failure time is generally before or after the predicted failure time; or (2) Applying the minimum displacement rate, or the time at minimum displacement rate, in the appropriate mathematical formula to predict the failure time for the resin. The mathematical formula is derived from the discovery of a power law relationship between the failure time and minimum displacement rate, or between failure time and the time at minimum displacement rate. Thus, it is not necessary to actually test all the way to failure using ASTM F 1473-01, thereby accelerating testing capability and consequently enabling more rapid development of new resins.

    摘要翻译： 通过使用ASTM F 1473-01确定最小位移速率或最小位移速率的时间来确定聚乙烯树脂的故障时间的加速方法，然后遵循以下路线之一：（1）如果还没有发生故障 对树脂样品进行低温压裂并检查其是否有缓慢的裂纹扩展，以确定预期的或期望的故障时间是否通常在预测的故障时间之前或之后; 或（2）以适当的数学公式应用最小位移速率或最小位移速率时间来预测树脂的失效时间。 数学公式是从发现故障时间和最小位移速率之间的幂律关系，或者在故障时间与最小位移速率时间之间发现的。 因此，不需要使用ASTM F 1473-01实际测试所有的故障，从而加快了测试能力，从而可以更快速地开发新型树脂。

    Methods of Making High Impact Polystyrene
    9.
    发明申请
    Methods of Making High Impact Polystyrene 有权
    制造高抗冲聚苯乙烯的方法

    公开(公告)号：US20120108747A1

    公开(公告)日：2012-05-03

    申请号：US13249383

    申请日：2011-09-30

    申请人： Likuo Sun ,  Jose M. Sosa ,  Serge Eon ,  Carlos Corleto ,  Scott Cooper

    发明人： Likuo Sun ,  Jose M. Sosa ,  Serge Eon ,  Carlos Corleto ,  Scott Cooper

    IPC分类号： C08F279/02 ,  C08F2/01

    CPC分类号： C08F2/001 ,  C08F212/08 ,  C08F279/02 ,  C08L9/06 ,  C08L2555/84

    摘要： A process for producing high impact polystyrene including feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture. Polymerizing the reaction mixture in the first linear flow reactor to a point below the point at which phase inversion occurs to produce a first polymerization mixture and feeding the first polymerization mixture from the first linear flow reactor to a second linear flow reactor. Polymerizing the reaction mixture in the second linear flow reactor to at least a phase inversion point of the mixture to produce a second polymerization mixture and feeding the second polymerization mixture from the second linear flow reactor to at least a third linear flow reactor for post-inversion polymerization of the second polymerization mixture. The product stream can have an ESCR value of at least 10% toughness retained with less than 10 wt % rubber content.

    摘要翻译： 一种生产高抗冲聚苯乙烯的方法，包括将至少一种乙烯基芳族单体，弹性体和自由基引发剂进料至第一线性流动反应器以形成反应混合物。 将第一线性流动反应器中的反应混合物聚合到低于发生相转移点的点以产生第一聚合混合物并将第一聚合混合物从第一线性流动反应器进料到第二线性流动反应器。 将第二线性流动反应器中的反应混合物聚合到混合物的至少相转变点，以产生第二聚合混合物，并将第二聚合混合物从第二线性流动反应器进料到至少第三线性流动反应器用于后反转 第二聚合混合物的聚合。 产品流的ESCR值可以保持至少10％的韧性，橡胶含量小于10wt％。

    Methods of making high impact polystyrene
    10.
    发明授权
    Methods of making high impact polystyrene 有权
    制造高抗冲聚苯乙烯的方法

    公开(公告)号：US09079982B2

    公开(公告)日：2015-07-14

    申请号：US13249383

    申请日：2011-09-30

    申请人： Likuo Sun ,  Jose M. Sosa ,  Serge Eon ,  Carlos Corleto ,  Scott Cooper

    发明人： Likuo Sun ,  Jose M. Sosa ,  Serge Eon ,  Carlos Corleto ,  Scott Cooper

    IPC分类号： C08F279/02 ,  C08F212/08 ,  C08F2/00

    CPC分类号： C08F2/001 ,  C08F212/08 ,  C08F279/02 ,  C08L9/06 ,  C08L2555/84

    摘要： A process for producing high impact polystyrene including feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture. Polymerizing the reaction mixture in the first linear flow reactor to a point below the point at which phase inversion occurs to produce a first polymerization mixture and feeding the first polymerization mixture from the first linear flow reactor to a second linear flow reactor. Polymerizing the reaction mixture in the second linear flow reactor to at least a phase inversion point of the mixture to produce a second polymerization mixture and feeding the second polymerization mixture from the second linear flow reactor to at least a third linear flow reactor for post-inversion polymerization of the second polymerization mixture. The product stream can have an ESCR value of at least 10% toughness retained with less than 10 wt % rubber content.

    摘要翻译： 一种生产高抗冲聚苯乙烯的方法，包括将至少一种乙烯基芳族单体，弹性体和自由基引发剂进料至第一线性流动反应器以形成反应混合物。 将第一线性流动反应器中的反应混合物聚合到低于发生相转移点的点以产生第一聚合混合物并将第一聚合混合物从第一线性流动反应器进料到第二线性流动反应器。 将第二线性流动反应器中的反应混合物聚合到混合物的至少相转变点，以产生第二聚合混合物，并将第二聚合混合物从第二线性流动反应器进料到至少第三线性流动反应器用于后反转 第二聚合混合物的聚合。 产品流的ESCR值可以保持至少10％的韧性，橡胶含量小于10wt％。