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1.发明授权Method for preparation of catalytic material for selective oxidation and catalyst members thereof 有权制备选择性氧化催化剂材料的方法及其催化剂成分公开(公告)号：US06559094B1
公开(公告)日：2003-05-06
申请号：US09392813
申请日：1999-09-09
IPC分类号： B01J2389
CPC分类号： B01J37/34 , B01D53/864 , B01J23/8906 , B01J37/0225 , B01J37/0244 , C01B3/583 , C01B2203/044 , C01B2203/047
摘要： The invention pertains to the preparation and use of catalytic materials and catalyst members for the selective oxidation of carbon monoxide in a gas stream that contains hydrogen. One such catalyst member may be produced by depositing by electric arc spraying a metal feedstock onto a metal substrate to provide a metal anchor layer on the substrate, and depositing a catalytic material comprising platinum and iron dispersed on a refractory inorganic oxide support material onto the metal substrate. The catalytic material may optionally be produced by wetting the support material, especially a particulate support material, with a platinum group metal solution and iron solution and drying and calcining the wetted support material in air at a temperature in the range of from 200° C. to 300° C., preferably using a solution containing bivalent platinum ion species. The catalyst member may be used by flowing the gas stream therethrough at a temperature at about 90° C. with a O2:CO ratio of about 1:1 and a space velocity of about 20,000/hr or, alternatively, at a temperature of about 150° C. with a O2:CO ratio of about 1.5:1 and a space velocity of about 80,000/hr.
摘要翻译： 本发明涉及用于在含有氢气的气流中选择性氧化一氧化碳的催化材料和催化剂构件的制备和使用。 一种这样的催化剂构件可以通过电弧喷涂金属原料沉积到金属基底上以在基底上提供金属锚定层并且将分散在耐火无机氧化物载体材料上的铂和铁的催化材料沉积到金属上 基质。 催化材料可以任选地通过用铂族金属溶液和铁溶液润湿载体材料，特别是颗粒状载体材料，并在200℃的温度下干燥和煅烧润湿的载体材料在空气中来制备。 至300℃，优选使用含有二价铂离子种类的溶液。 催化剂构件可以通过在大约90℃的温度下流过气体流而使用，其中O 2 :CO比约为1:1，空速约为20,000 /小时，或者在大约温度下 150℃，O 2 :CO比约1.5:1，空速约80,000 /小时。
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2.发明授权Use of a radial zone coating to facilitate a two-stage prox system with single air injection 有权使用径向区域涂层以促进具有单次空气注入的两级prox系统公开(公告)号：US08221693B2
公开(公告)日：2012-07-17
申请号：US11194816
申请日：2005-08-01
申请人： Lawrence Shore , Robert J. Farrauto
发明人： Lawrence Shore , Robert J. Farrauto
IPC分类号： B01D53/62
CPC分类号： B01J12/007 , B01J19/2485 , B01J2219/00164 , C01B3/583 , C01B2203/044 , C01B2203/047
摘要： A two stage-carbon monoxide preferential oxidation article and method that uses a single injection of an O2-containing gas.
摘要翻译： 一种二氧化碳优先氧化制品和使用单次注入含氧气体的方法。
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3.发明授权Precious metal water-gas shift catalyst with oxide support modified with rare earth elements 失效贵金属水煤气变换催化剂与稀土元素改性氧化物载体公开(公告)号：US07704486B2
公开(公告)日：2010-04-27
申请号：US11059148
申请日：2005-02-16
IPC分类号： C01B3/16
CPC分类号： C01B3/16 , B01J23/63 , B01J37/0018 , B01J2523/00 , C01B2203/107 , C01B2203/1082 , Y02P20/52 , B01J2523/31 , B01J2523/3718 , B01J2523/828 , B01J2523/3725
摘要： A water gas shift catalyst comprising a platinum group metal dispersed on an inorganic oxide support modified with a carbon-containing burn-out additive and a rare earth oxide. A water gas shift catalyst containing alumina, a platinum group metal, and oxides of Pr and Nd are also disclosed.
摘要翻译： 一种水煤气变换催化剂，其包含分散在用含碳燃烧添加剂和稀土氧化物改性的无机氧化物载体上的铂族金属。 还公开了含有氧化铝，铂族金属和Pr和Nd的氧化物的水煤气变换催化剂。
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公开(公告)号：US5756053A
公开(公告)日：1998-05-26
申请号：US646180
申请日：1996-05-07
申请人： Jeffrey B. Hoke , Matthew P. Larkin , Robert J. Farrauto , Kenneth E. Voss , Robert E. Whiteley , Leonard M. Quick
发明人： Jeffrey B. Hoke , Matthew P. Larkin , Robert J. Farrauto , Kenneth E. Voss , Robert E. Whiteley , Leonard M. Quick
IPC分类号： B01D53/86 , B01D53/94 , B01J23/10 , B01J23/40 , B01J23/63 , B01J29/72 , B01J35/10 , B01J37/02 , F02B3/06 , F24C15/20 , B01D53/34
CPC分类号： B01D53/944 , B01D53/864 , B01D53/8668 , B01D53/9481 , B01J23/10 , B01J23/63 , B01J35/10 , B01J37/0215 , B01J37/0244 , F24C15/205 , B01J29/7215 , B01J35/1014 , B01J35/1019 , B01J35/1047 , B01J35/1061 , F02B3/06
摘要： A method for treating cooking fumes to oxidize oxidizeable particulate and gaseous components thereof includes contacting the fumes with a catalytic material containing ceria and alumina each having a BET surface of at least about 10 m.sup.2 /g, for example, ceria and activated alumina in a weight ratio of from about 1.5:1 and 1:1.5 and a BET surface area of from about 25 m.sup.2 /g to 200 m.sup.2 /g. Optionally, a catalytic metal component such as platinum or palladium may be included in the catalytic material. The foodstuffs cooking fumes are contacted with the catalyst composition (22 or 40) at a temperature of 200.degree. C. to 600.degree. C. to promote the oxidation of both particulate (atomized) animal and/or vegetable oils and fats and oxidizeable gas phase components of the fumes. Optionally, a separate, supplemental gas phase oxidation catalyst (42) may be used in conjunction with and downstream of the above-described catalyst (40) to provide a two-catalyst system for treating cooking fumes.
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公开(公告)号：US5750458A
公开(公告)日：1998-05-12
申请号：US271687
申请日：1994-07-07
摘要： A catalyst composition containing one or more binary oxides of palladium and rare earth metal such as Ce, La, Nd, Pr and/or Sm. The catalyst composition is used for the catalytic combustion of gaseous combustion mixtures of oxygen and carbonaceous fuels such as methane, e.g., a natural gas/air combustion mixture. Specific preferred binary oxides may be, for example, M.sub.2 O.sub.3.PdO (e.g., La.sub.2 O.sub.3.PdO) or 2M.sub.2 O.sub.3.PdO, wherein in each case M is La, Nd or Sm. A process of combusting gaseous carbonaceous fuels includes contacting a catalyst as described above under combustion conditions, e.g., 925.degree. C. to 1650.degree. C. and 1 to 20 atmospheres pressure, to carry out sustained combustion of the combustion mixture, including catalytically supported thermal combustion. Regeneration of over-temperatured M.sub.2 O.sub.3.PdO catalyst is also provided for.
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公开(公告)号：US5462907A
公开(公告)日：1995-10-31
申请号：US247625
申请日：1994-05-23
IPC分类号： B01D53/86 , B01D53/94 , B01J23/10 , B01J23/40 , B01J23/63 , B01J29/72 , B01J35/10 , B01J37/02 , F02B3/06 , F24C15/20 , B01J21/04 , B01J23/42
CPC分类号： B01D53/9481 , B01D53/864 , B01D53/8668 , B01D53/944 , B01J23/10 , B01J23/63 , B01J35/10 , B01J37/0215 , B01J37/0244 , B01J29/7215 , B01J35/1014 , B01J35/1019 , B01J35/1047 , B01J35/1061 , F02B3/06
摘要： Oxidation catalyst compositions include a catalytic material containing ceria and alumina each having a surface area of at least about 10 m.sup.2 /g, for example, ceria and activated alumina in a weight ratio of from about 1.5:1 to 1:1.5. Optionally, platinum may be included in the catalytic material in amounts which are sufficient to promote gas phase oxidation of CO and HC but which are limited to preclude excessive oxidation of SO.sub.2 to SO.sub.3. Alternatively, palladium in any desired amount may be included in the catalytic material. The catalyst compositions have utility as oxidation catalysts for pollution abatement of exhausts contianing unburned fuel or oil. For example, the catalyst compositions may be used in a method to treat diesel engine exhaust by contacting the hot exhaust with the catalyst composition to promote the oxidation of the volatile organic fraction component of particulates in the exhaust.
摘要翻译： 氧化催化剂组合物包括含有表面积至少约10m 2 / g的二氧化铈和氧化铝的催化材料，例如二氧化铈和活性氧化铝，重量比为约1.5:1至1:1.5。 任选地，铂可以以足以促进CO和HC的气相氧化的量包含在催化材料中，但限制为排除SO2过度氧化成SO 3。 或者，任何所需量的钯可以包括在催化材料中。 催化剂组合物可用作氧化催化剂，用于污染消除未燃燃料或油的废气。 例如，催化剂组合物可用于通过使热排气与催化剂组合物接触来促进废气中的微粒的挥发性有机部分组分的氧化来处理柴油发动机排气的方法。
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7.发明授权Process conditions for operation of ignition catalyst for natural gas combustion 失效用于天然气燃烧的点火催化剂的操作条件
公开(公告)号：US5214912A
公开(公告)日：1993-06-01
申请号：US776907
申请日：1991-10-16
摘要： A method for operating a palladium oxide containing catalytic combustor useful, e.g., for powering a gas turbine, wherein the palladium oxide is supported on a metal oxide such as alumina, ceria, titania or tantalum oxide. The method involves maintaining control of the temperature within the combustor in such a manner as to insure the presence of palladium oxide. By maintaining the temperature below about 800.degree. C. decomposition of palladium oxide into metallic palladium is avoided and high catalytic activity is retained. Regeneration of catalyst following inactivation resulting from an over-temperature is accomplished by using a heat soak in a temperature range which varies depending on the metal oxide used to support the palladium oxide.
摘要翻译： 一种用于操作含氧化钯的催化燃烧器的方法，其可用于例如为燃气轮机供电，其中氧化钯负载在诸如氧化铝，二氧化铈，二氧化钛或氧化钽的金属氧化物上。 该方法包括以确保氧化钯存在的方式维持燃烧室内温度的控制。 通过保持温度低于约800℃，避免氧化钯分解成金属钯，并保持高催化活性。 通过在根据用于负载氧化钯的金属氧化物而变化的温度范围内的热浸泡来实现由过温引起的失活后催化剂的再生。
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公开(公告)号：US4863893A
公开(公告)日：1989-09-05
申请号：US888179
申请日：1986-08-06
CPC分类号： C01B21/265 , B01J23/464 , B01J35/06 , C01B21/267
摘要： Platinum-rhodium and platinum-palladium-rhodium gauzes bearing a high surface area coating (in excess of 50 cm.sup.2 /g) of platinum ease initiation of ammonia oxidation.
摘要翻译： 具有高表面积涂层（超过50cm2 / g）铂的铂 - 铑和铂 - 铑 - 铑纱布容易引发氨氧化。
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9.发明授权Method of desulfurizing a hydrocarbon gas by selective partial oxidation and adsorption 有权通过选择性部分氧化和吸附来脱硫烃气的方法公开(公告)号：US07074375B2
公开(公告)日：2006-07-11
申请号：US10308356
申请日：2002-12-03
CPC分类号： C10L3/12 , B01D53/8609 , C01B3/38 , C01B2203/0227 , C01B2203/061 , C01B2203/062 , C01B2203/066 , C01B2203/127 , C07C7/12 , C07C7/14816 , C10G25/00 , C10G27/04 , C10G2300/202 , C10G2300/207 , Y02P20/52 , C07C9/04
摘要： A hydrocarbon gas such as methane and LPG is desulfurized in the presence of oxygen and an oxidation catalyst to convert sulfur compounds in the gas to sulfur oxides. The sulfur oxides are then trapped downstream of the oxidation by an adsorbent. The amount of oxygen added to the hydrocarbon gas to promote oxidation is such that the sulfur compounds are selectively oxidized and the oxidation of the hydrocarbon gas is minimized to reduce hydrogen formation.
摘要翻译： 甲烷和LPG等烃类气体在氧气和氧化催化剂的存在下脱硫，将气体中的硫化合物转化为硫氧化物。 硫氧化物然后被吸附剂捕获在氧化下游。 添加到烃气体中以促进氧化的氧气的量使得硫化合物被选择性氧化并且烃气体的氧化被最小化以减少氢气形成。
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公开(公告)号：US06977067B2
公开(公告)日：2005-12-20
申请号：US10365165
申请日：2003-02-12
申请人： Shinn H. Hwang , Robert J. Farrauto
发明人： Shinn H. Hwang , Robert J. Farrauto
CPC分类号： C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0844 , C01B2203/1247 , C01B2203/1264 , C01B2203/142 , C01B2203/143 , C01B2203/82
摘要： Provided is a method of generating a hydrogen-rich reformate from a hydrocarbon feed stream comprising olefins and alkanes (e.g., LPG). An inlet gas stream containing the hydrocarbon feed stream and an oxygen containing gas stream, is preheated to a temperature of from 180 to 300° C. The preheated inlet gas stream is then contacted with a sulfur tolerant partial oxidation catalyst to form a pre-reformed gas stream, which is preferably maintained below about 400° C. The pre-reformed gas stream is then subjected to a reforming process to form the hydrogen-rich reformate.
摘要翻译： 提供了从包含烯烃和烷烃（例如LPG）的烃进料流产生富氢重整产物的方法。 将含有烃进料流和含氧气流的入口气流预热至180℃至300℃的温度。然后将预热的入口气流与耐硫部分氧化催化剂接触以形成预转化 气流优选保持在约400℃以下。然后将预重整气流进行重整过程以形成富氢重整产物。
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