摘要:
A non-homogeneous adsorbent is described, formed of a core and at least one continuous outer layer in which the core of said adsorbent has a volume adsorptive capacity representing at least 35% of the volume of the adsorbent and the outer layer has a diffusional selectivity greater than 5. The adsorbent is used in gas-separation processes or liquid-separation processes.
摘要:
A process for separating multibranched paraffins comprised in a hydrocarbon feed comprising hydrocarbons containing 5 to 8 carbon atoms per molecule comprises a separation unit functioning by adsorption and contains at least one zeolitic adsorbent with a mixed structure with principal channels with openings defined by a ring containing 10 oxygen atoms and secondary channels with openings defined by a ring of at least 12 oxygen atoms, the secondary channels only being accessible to the feed to be separated via the principal channels. Particular zeolitic adsorbents of the invention are zeolites with structure types EUO, NES and MWW. NU-85 and NU-86 zeolites are also particularly suitable for carrying out the process of the invention.
摘要:
For producing a gasoline stock with a high octane number, employed are at least one hydroisomerisation section and at least one section for adsorptively separating multibranched paraffins contained in a constituted by a C5 to C8 cut. The separation section contains at least one zeloitic adsorbent with a mixed structure with principal channels with openings defined by a ring containing 10 oxygen atoms and secondary channels with openings by a ring of at least 12 oxygen atoms, the secondary channels only being accessible to the feed to be separated via the principal channels.
摘要:
A non-homogeneous adsorbent is described, formed of a core and at least one continuous outer layer in which the core of said adsorbent has a volume adsorptive capacity representing at least 35% of the volume of the adsorbent and the outer layer has a diffusional selectivity greater than 5. The adsorbent is used in gas-separation processes or liquid-separation processes.
摘要:
The invention relates to a method of isomerising a charge comprising hydrocarbons containing between 5 and 8 carbon atoms per molecule. According to the invention, said charge is separated into at least two fractions: fraction A mostly comprising hydrocarbons containing 5 or 6 carbon atoms and fraction B mostly comprising hydrocarbons containing 7 or 8 carbon atoms. Subsequently, said fractions A and B are treated separately under specific conditions in different isomerisation reaction zones.
摘要:
The invention is concerned with the use of a TiO2-based composition for capturing halogenated compounds contained in a gaseous mixture, said composition comprising between 10 wt. % and 100 wt. % of TiO2 and between 1 wt. % and 30 wt. % of at least one sulfate of an alkaline-earth metal selected from calcium, barium, strontium and magnesium.
摘要:
The invention concerns a process for purification by elimination of chlorine in the form of hydrogen chloride and organochlorine compounds by contacting in the presence of hydrogen of at least a part of the effluent from a reforming, aromatics production, dehydrogenation, isomerisation or hydrogenation zone, said part of the effluent comprising olefins, hydrogen chloride and organochlorine compounds, on an elimination zone comprising a chain arrangement of two masses, the first mass being a mass comprising at least one metal from group VIII deposited on a mineral carrier and the second mass being a hydrogen chloride adsorbent.
摘要:
The invention is concerned with the use of a TiO2-based composition for capturing halogenated compounds contained in a gaseous mixture, said composition comprising between 10 wt. % and 100 wt. % of TiO2 and between 1 wt. % and 30 wt. % of at least one sulfate of an alkaline-earth metal selected from calcium, barium, strontium and magnesium.
摘要:
Process for activating a Fischer-Tropsch synthesis catalyst that comprises at least two stages: at least one stage for activation in the presence of hydrogen, or a mixture of hydrogen and an inert gas, and at least one stage for activation in the presence of carbon monoxide or a mixture of carbon monoxide and an inert gas, and optionally a third activation stage that is carried out either in the presence of hydrogen or a mixture of hydrogen and an inert gas, or in the presence of carbon monoxide or a mixture of carbon monoxide and an inert gas.
摘要:
Method for preparation of an adsorbent that comprises successive shaping stages by co-granulation of a faujasite-type zeolite powder A, with a powder B that consists of alumina, whereby the ratio per unit of mass of the powder A in the mixture of powders A and B is between 10 and 70%, for treatment under water vapor and drying.The invention also relates to a process for adsorption of organic contaminants that contain at least one heteroatom and that are present in an olefinic feedstock that comprises at least 50% by volume of hydrocarbons, whereby this process comprises the stage for bringing the olefinic feedstock into contact with the adsorbent that is obtained by the preparation method according to the invention.