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1.发明授权Ruthenium supported catalyst, its preparation and its use in the preparation of substituted or unsubstituted cyclohexylamine and substituted or unsubstituted dicyclohexylamine 失效钌负载催化剂及其制备及其在制备取代或未取代的环己基胺和取代或未取代的二环己基胺中的用途
公开(公告)号：US5023226A
公开(公告)日：1991-06-11
申请号：US294836
申请日：1989-01-09
申请人： Otto Immel , Hans-Helmut Schwarz , Reinhard Thiel
发明人： Otto Immel , Hans-Helmut Schwarz , Reinhard Thiel
IPC分类号： B01J23/46 , B01J23/652 , B01J23/656 , B01J27/232 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/18 , C07C209/22 , C07C209/72 , C07C211/35 , C07C213/08 , C07C217/52
CPC分类号： B01J23/462 , B01J23/6522 , B01J23/6562 , C07C209/72
摘要： Substituted or unsubstituted cyclohexylamine and substituted or unsubstituted dicyclohexylamine can be produced by catalytic hydrogenation of substituted or unsubstituted aniline by using a ruthenium catalyst which in addition to ruthenium also contains palladium, platinum or palladium and platinum on a support from the group consisting of Al.sub.2 O.sub.3 and aluminum spinel treated with chromium and manganese and containing the noble metals in a total amount of 0.05-5% by weight and a weight ratio of Ru:Pd, Ru:Pt, or Ru:Pd/Pt of 1:9-9:1. All percentages are based on the total weight of the catalyst.
摘要翻译： 取代或未取代的环己胺和取代或未取代的二环己胺可以通过使用钌催化剂通过催化氢化取代或未取代的苯胺来制备，钌催化剂除了钌之外还含有钯，铂或钯和铂在由Al 2 O 3和铝组成的组中的载体上 尖晶石用铬和锰处理并含有总量为0.05-5重量％，Ru：Pd，Ru：Pt或Ru:Pd / Pt的重量比为1:9-9:1的贵金属。 所有的百分比均基于催化剂的总重量。
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2.发明授权Supported ruthenium catalyst, its preparation and its use in the preparation of optionally substituted cyclohexylamine and optionally substituted dicyclohexylamine 失效负载型钌催化剂及其制备及其在制备任选取代的环己胺和任选取代的二环己胺中的应用
公开(公告)号：US4943549A
公开(公告)日：1990-07-24
申请号：US376109
申请日：1989-07-06
申请人： Otto Immel , Hans-Helmut Schwarz , Reinhard Thiel
发明人： Otto Immel , Hans-Helmut Schwarz , Reinhard Thiel
IPC分类号： B01J23/46 , B01J23/656 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/22 , C07C209/70 , C07C211/17
CPC分类号： B01J23/462 , B01J23/6562
摘要： Optionally substituted cyclohexylamine and optionally substituted dicyclohexylamine can be obtained by the catalytic hydrogenation of optionally substituted aniline, a ruthenium catalyst which is supported in Al.sub.2 O.sub.3 treated with compounds of rare earth metals and of manganese and which has a ruthenium content of 0.05-5% by weight, relative to the total weight of the catalyst, being employed.
摘要翻译： 任选取代的环己胺和任选取代的二环己基胺可以通过任选取代的苯胺的催化氢化获得，钌催化剂负载在用稀土金属和锰化合物处理的Al 2 O 3中，钌含量为0.05-5重量％ ，相对于催化剂的总重量。
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公开(公告)号：US5174985A
公开(公告)日：1992-12-29
申请号：US642105
申请日：1991-01-16
IPC分类号： A62D3/38 , A62D101/22 , A62D101/28 , C07B33/00
CPC分类号： A62D3/38 , A62D2101/22 , A62D2101/28
摘要： Water-insoluble chlorinated hydrocarbons can be largely degraded by mixing with nitric acid and heating to temperatures of 150.degree. C. to 350.degree. C. under pressures of 6 bar to 350 bar.
摘要翻译： 水溶性氯化烃可以通过与硝酸混合并在6巴至350巴的压力下加热至150℃至350℃的温度而大大降解。
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公开(公告)号：US4148792A
公开(公告)日：1979-04-10
申请号：US915732
申请日：1978-06-15
IPC分类号： C07D201/16
CPC分类号： C07D201/16
摘要： A process for the purification of .epsilon.-caprolactam, wherein .epsilon.-caprolactam is treated with potassium permanganate in the presence of from 0.01 to 5% by weight of water, based on caprolactam, and subsequently crystallized from toluene, benzene, ethylbenzene or xylene.
摘要翻译： 用于纯化ε-己内酰胺的方法，其中ε-己内酰胺在高碱性高锰酸盐存在下，在0.01至5重量％的水的存在下，以己内酰胺为基础，随后在甲苯，苯，乙苯或二甲苯中结晶。
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公开(公告)号：US4028347A
公开(公告)日：1977-06-07
申请号：US584219
申请日：1975-06-05
申请人： Hans-Helmut Schwarz , Otto Immel
发明人： Hans-Helmut Schwarz , Otto Immel
IPC分类号： C07D201/16
CPC分类号： C07D201/16
摘要： Object of the invention is a process for the treatment of a lactam distillation residue which contains boric acid in which a polyhydric alcohol is added to the crude lactam. By these means the formation of deposits and incrustations on the heating surfaces of the distillation apparatus can be prevented.
摘要翻译： 本发明的目的是一种处理含有硼酸的内酰胺蒸馏残余物的方法，其中将多元醇加入到粗内酰胺中。 通过这些方法，可以防止在蒸馏装置的加热面上形成沉积物和结垢。
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6.发明授权Process for the production of di-(4-aminocyclohexyl)-methane containing 15 to 25% by weight of the trans-trans isomer 失效制备含有15至25重量％反式异构体的二（4-氨基环己基）甲烷的方法
公开(公告)号：US5245082A
公开(公告)日：1993-09-14
申请号：US4382
申请日：1993-01-14
IPC分类号： B01J23/46 , C07C209/72
CPC分类号： B01J23/462 , C07C209/72 , C07C2101/14
摘要： Di-(4-aminocyclohexyl)-methane containing 15 to 25% by weight of the trans-trans isomer can be obtained by the catalytic hydrogenation of di-(4-aminophenyl)-methane at elevated temperature and elevated hydrogen pressure in the presence of a ruthenium-containing supported catalyst containing 0.05 to 5% by weight ruthenium on an Al.sub.2 O.sub.3 support which has been treated with compounds of rare earth metals and manganese.
摘要翻译： 含有15-25％（重量）反式异构体的二 - （4-氨基环己基） - 甲烷可以通过二 - （4-氨基苯基） - 甲烷在升高的温度下催化氢化和升高氢气压力 含有0.05〜5重量％钌的含钌载体的Al 2 O 3载体上已经用稀土金属和锰化合物处理。
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7.发明授权Supported catalyst, process for its preparation and its use for the preparation of hydroxydiphenyl 失效负载催化剂，其制备方法及其在制备羟基二苯基中的应用
公开(公告)号：US4729977A
公开(公告)日：1988-03-08
申请号：US872796
申请日：1986-06-11
申请人： Otto Immel , Oskar Weissel , Hans-Helmut Schwarz
发明人： Otto Immel , Oskar Weissel , Hans-Helmut Schwarz
IPC分类号： B01J23/64 , B01J23/656 , B01J27/02 , C07B61/00 , C07C27/00 , C07C37/06 , C07C37/07 , C07C39/15 , C07C67/00 , B01J31/04 , B01J23/26 , B01J31/02
CPC分类号： C07C37/07 , B01J23/6562 , B01J27/02 , C07C37/06
摘要： A supported catalyst containing rhodium and compounds of chromium, manganese, alkali metals and, if appropriate, compounds of sulphur is prepared by first applying compounds of chromium and manganese to the catalyst support, subsequently heating the catalyst support thus charged to elevated temperatures and then impregnating it with a rhodium solution, drying it, treating it with an alkali metal solution and, if appropriate, applying sulphur compounds to the catalyst support thus treated. The supported catalyst thus prepared can be used for the dehydrogenation of compounds and/or compound mixtures consisting of completely and/or partly hydrogenated hydroxydiphenyl.
摘要翻译： 通过首先将铬和锰的化合物施加到催化剂载体上，随后将催化剂载体加热至升高的温度，然后浸渍，从而制备含有铑的载体催化剂和铬，锰，碱金属的化合物，以及合适的硫化合物 用铑溶液干燥，用碱金属溶液处理，如果合适，将硫化合物施加到如此处理的催化剂载体上。 由此制备的负载催化剂可用于由完全和/或部分氢化的羟基二苯组成的化合物和/或化合物混合物的脱氢。
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8.发明授权Process for the preparation of propane-1,3-diols, disubstituted in the 2-position 失效用于制备2-位二取代的丙烷-1,3-二醇的方法
公开(公告)号：US4181810A
公开(公告)日：1980-01-01
申请号：US852117
申请日：1977-11-16
申请人： Otto Immel , Hans-Helmut Schwarz , Oskar Weissel
发明人： Otto Immel , Hans-Helmut Schwarz , Oskar Weissel
IPC分类号： B01J31/00 , C07B61/00 , C07C27/00 , C07C29/14 , C07C29/141 , C07C29/38 , C07C31/20 , C07C45/75 , C07C67/00 , C07C35/02
CPC分类号： C07C45/75 , C07C29/14 , C07C29/141
摘要： A process for the preparation of a propane-1,3-diol, disubstituted in the 2-position, which comprises contacting an ethanal disubstituted in the 2-position, which ethanal has the formula ##STR1## wherein R.sup.1 and R.sup.2 are identical or different and denote optionally substituted alkyl, cycloalkyl, aralkyl or aryl radicals or an optionally substituted heterocyclic radical, or together denote an optionally substituted divalent hydrocarbon radical with formaldehyde in the presence of an acid ion exchanger and thereafter contacting the resultant reaction product with hydrogen under hydrogenation conditions.
摘要翻译： 制备在2-位二取代的丙烷-1,3-二醇的方法，其包括使2-位二取代的乙醛接触，该乙醛具有式（I）其中R1和R2是 相同或不同，并且表示任选取代的烷基，环烷基，芳烷基或芳基或任选取代的杂环基，或在酸离子交换剂存在下一起表示任选取代的二价烃基与甲醛，然后使所得反应产物与氢 在氢化条件下。
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9.发明授权Process for the producing .epsilon.-caprolactam from the distillation of cyclohexanone oxime 失效从环己酮肟蒸馏生产{68-己内酰胺的方法
公开(公告)号：US4141896A
公开(公告)日：1979-02-27
申请号：US832008
申请日：1977-09-09
IPC分类号： C07D201/02 , C07D201/04
CPC分类号： C07D201/04
摘要： A process for the production of .epsilon.-caprolactum from cyclohexanone oxime by rearrangement in the gaseous phase on a fluid-bed catalyst containing boron oxide, wherein residues from the distillation of cyclohexanone oxime are introduced into the reaction in liquid form, and wherein from 5 to 500 times their quantity of cyclohexanone oxime in vapor form and at least 50 times their quantity of inert gas are present during the reaction.
摘要翻译： 一种通过在含有氧化硼的流化床催化剂上在气相中重新排列从环己酮肟生产ε-己内酰胺的方法，其中将来自环己酮肟蒸馏的残余物以液体形式引入反应中，其中从5至 蒸气形式的环己酮肟的量为其500倍，并且在反应期间存在至少50倍量的惰性气体。
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公开(公告)号：US4097540A
公开(公告)日：1978-06-27
申请号：US822963
申请日：1977-08-08
申请人： Otto Immel , Hans-Helmut Schwarz , Oskar Weissel
发明人： Otto Immel , Hans-Helmut Schwarz , Oskar Weissel
IPC分类号： C07C29/14 , B01J21/00 , B01J23/00 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/141 , C07C29/17 , C07C31/20 , C07C45/75 , C07C67/00
CPC分类号： C07C29/141 , C07C29/175 , C07C45/75
摘要： A process for the preparation of a dihydric alcohol with the formula ##STR1## wherein R represents an alkyl radical of 1 to 20 carbon atoms which comprises contacting a 2-alkylacrylaldehyde of the formula ##STR2## wherein R has the meaning given above with formaldehyde and thereafter contacting the resultant reaction mixture with hydrogen in the presence of a hydrogenation catalyst.
摘要翻译： 一种制备具有下式的二元醇的方法，其中R代表1-20个碳原子的烷基，其中包括使式（I）的2-烷基丙烯醛与式 然后在氢化催化剂存在下使所得反应混合物与氢气接触。
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