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1.发明授权Addition of (a) blocking agent(s) in a ceramic membrane for clocking crystalline growth of grains during atmospheric sintering 有权（a）在陶瓷膜中加入封闭剂，用于在大气烧结过程中晶粒生长公开(公告)号：US07955526B2
公开(公告)日：2011-06-07
申请号：US10577867
申请日：2004-11-05
IPC分类号： H01B1/00
CPC分类号： B01D71/024 , B01D67/0041 , B01D71/02 , B01D71/022 , B01D2323/08 , B01D2323/18 , B01J8/009 , B01J19/2475 , B01J23/002 , B01J23/02 , B01J23/10 , B01J23/78 , B01J23/83 , B01J35/0006 , B01J35/065 , B01J2523/00 , C01B3/386 , C01B13/0255 , C01B2203/0261 , C01B2203/1241 , C01B2203/1258 , C01B2210/0046 , C01G49/009 , C01P2004/80 , C04B35/2641 , C04B35/62685 , C04B2235/3206 , C04B2235/3213 , C04B2235/3227 , C04B2235/3232 , C04B2235/3236 , C04B2235/3274 , C04B2235/3286 , C04B2235/768 , C04B2235/786 , C04B2235/80 , Y02P20/52 , B01J2523/24 , B01J2523/3706 , B01J2523/842 , B01J2523/22 , B01J2523/47 , B01J2523/31 , B01J2523/32
摘要： A composite material (M) comprising: at least 75% by volume of a mixed electronic conductor compound oxygen anions O (C1) selected from doped ceramic compounds which, at the temperature of use, are present in the form of a crystalline network having ion oxide lattice vacancies and, more particularly, in the form of a cubic phase, a fluorite phase, a perovskite phase, of the aurivillius variety, a Brown-Millerite phase or a pyrochlore phase; and 0.01%-25% by volume of a compound (C2) which is different from compound (C1), selected from oxide-type ceramic materials, non-oxide type ceramic materials, metals, metal alloys or mixtures of said different types of material; and 0%-2.5% by volume of a compound (C3) produced from at least one chemical reaction represented by the equation: xFC1+yFC2 - - - >zFC3, wherein FC1, FC2 and FC3 represent the raw formulae of compounds (C1), (C2) and (C3) and x, y and z represent rational numbers above or equal to 0. The invention also relates to a method for the preparation and use thereof as mixed conductor material for a membrane catalytic reactor used to synthesize synthetic gas by catalytic oxidation of methane or natural gas and/or as mixed conductor material for a ceramic membrane.
摘要翻译： 一种复合材料（M），其包含：至少75体积％的混合电子导体化合物氧阴离子O 2（C1），其选自掺杂的陶瓷化合物，其在使用温度下以 具有离子氧化物晶格空位的晶体网络，更具体地，呈立方相，萤石相，钙钛矿相，褐铁矿相或烧绿石相的形式; 和0.01％-25％体积的选自氧化物型陶瓷材料，非氧化物型陶瓷材料，金属，金属合金或所述不同类型材料的混合物的不同于化合物（C1）的化合物（C2） ; 和由下式表示的至少一种化学反应产生的化合物（C3）的0％-2.5％（体积）：其中FC1，FC2和FC3代表化合物（C1）的原始化学式， ，（C2）和（C3），x，y和z表示高于或等于0的有理数。本发明还涉及一种制备和使用它作为用于合成合成气体的膜催化反应器的混合导体材料的方法 通过甲烷或天然气的催化氧化和/或用作陶瓷膜的混合导体材料。
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2.发明申请Perovskite material, preparation method and use in catalytic membrane reactor 审中-公开钙钛矿材料，制备方法和用于催化膜反应器公开(公告)号：US20060145126A1
公开(公告)日：2006-07-06
申请号：US10562521
申请日：2004-07-08
IPC分类号： H01B1/12
CPC分类号： B01D71/024 , B01D53/228 , B01D53/32 , B01D71/02 , B01D2325/26 , B01J23/002 , B01J35/065 , B01J37/0018 , B01J2523/00 , C01B3/36 , C01B13/0255 , C01B2210/0046 , C04B35/2641 , Y02C20/20 , B01J2523/24 , B01J2523/32 , B01J2523/3706 , B01J2523/842
摘要： The invention concerns a mixed electronic and O2− anion conductive perovskite material, of formula (I): A(a)(1-x-u)A′(a−1)xA″(a″)uB(b)(1-s-y-v)B(b+1)sB′(b+β)yB″(b″)vO3-d, wherein: a, a−1, a″, b, b+1, b+β et b″ are integers representing respective valences of the atoms A, A′, A″, B, B′, B″; a, a″, b, b″, β, x, y, s, u, v et δ such that the electrical neutrality of the crystal lattice is preserved; A represents an atom selected among scandium, yttrium or in the families of lanthanides, actinides or alkaline-earth metals; A″ represents an atom selected among Al, Ga, In, or Tl; B, B′, B″ represents an atom selected among the transition metals, Al, In, Ga, Ge, Sb, Bi, Sn or Pb. The invention also concerns the method for preparing said material and its use as mixed conductive material of a catalytic membrane reactor, for use in synthesizing synthetic gas by oxidation of methane or natural gas.
摘要翻译： 本发明涉及式（I）的混合电子和O 2 - 阴离子导电钙钛矿材料：A（a）（1-xu） > A'（a-1） （b）＆lt; / SUP＆gt;（1-syv）B（b + 1） （b“）其中：a（a）和（b） ，a-1，a“，b，b + 1，b +β等b是表示原子A，A'，A”，B，B'，B“的各自的价数的整数。 a，a'，b，b“，β，x，y，s，u，v et delta，使得保持晶格的电中性; A表示选自钪，钇或镧系元素，锕系元素或碱土金属的族中的原子; A“表示选自Al，Ga，In或Tl中的原子; B，B'，B“表示选自过渡金属Al，In，Ga，Ge，Sb，Bi，Sn或Pb中的原子。 本发明还涉及制备所述材料的方法及其作为催化膜反应器的混合导电材料的用途，用于通过甲烷或天然气的氧化合成合成气体。
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3.发明申请Addition of (A) Blocking Agent(S) in a Ceramic Membrane for Clocking Crystalline Growth of Grains During Atmospheric Sintering 有权在陶瓷膜中加入（A）封闭剂（S），用于在大气烧结过程中晶粒的晶体生长公开(公告)号：US20070228323A1
公开(公告)日：2007-10-04
申请号：US10577867
申请日：2004-11-05
IPC分类号： C01B13/02
CPC分类号： B01D71/024 , B01D67/0041 , B01D71/02 , B01D71/022 , B01D2323/08 , B01D2323/18 , B01J8/009 , B01J19/2475 , B01J23/002 , B01J23/02 , B01J23/10 , B01J23/78 , B01J23/83 , B01J35/0006 , B01J35/065 , B01J2523/00 , C01B3/386 , C01B13/0255 , C01B2203/0261 , C01B2203/1241 , C01B2203/1258 , C01B2210/0046 , C01G49/009 , C01P2004/80 , C04B35/2641 , C04B35/62685 , C04B2235/3206 , C04B2235/3213 , C04B2235/3227 , C04B2235/3232 , C04B2235/3236 , C04B2235/3274 , C04B2235/3286 , C04B2235/768 , C04B2235/786 , C04B2235/80 , Y02P20/52 , B01J2523/24 , B01J2523/3706 , B01J2523/842 , B01J2523/22 , B01J2523/47 , B01J2523/31 , B01J2523/32
摘要： A composite material (M) comprising: at least 75% by volume of a mixed electronic conductor compound oxygen anions O (C1) selected from doped ceramic compounds which, at the temperature of use, are present in the form of a crystalline network having ion oxide lattice vacancies and, more particularly, in the form of a cubic phase, a fluorite phase, a perovskite phase, of the aurivillius variety, a Brown-Millerite phase or a pyrochlore phase; and 0.01%-25% by volume of a compound (C2) which is different from compound (C1), selected from oxide-type ceramic materials, non-oxide type ceramic materials, metals, metal alloys or mixtures of said different types of material; and 0%-2.5% by volume of a compound (C3) produced from at least one chemical reaction represented by the equation: xFC1+yFC2 - - - >zFC3, wherein FC1, FC2 and FC3 represent the raw formulae of compounds (C1), (C2) and (C3) and x, y and z represent rational numbers above or equal to 0. The invention also relates to a method for the preparation and use thereof as mixed conductor material for a membrane catalytic reactor used to synthesize synthetic gas by catalytic oxidation of methane or natural gas and/or as mixed conductor material for a ceramic membrane.
摘要翻译： 一种复合材料（M），其包含：至少75体积％的混合电子导体化合物氧阴离子O 2（C1），其选自掺杂的陶瓷化合物，其在使用温度下以 具有离子氧化物晶格空位的晶体网络，更具体地，呈立方相，萤石相，钙钛矿相，褐铁矿相或烧绿石相的形式; 和不同于化合物（C1）的化合物（C 2 H 2）的0.01体积％〜25体积％，选自氧化物型陶瓷材料，非氧化物型陶瓷材料，金属，金属合金 或所述不同类型材料的混合物; 和由以下等式表示的至少一种化学反应产生的化合物（C 3 S 3）的0％-2.5体积％，其中FC1，FC2和FC3表示 化合物（C1），（C2H2）和（C3-C3）的原始化学式，x，y和z表示高于或等于0的有理数。本发明还 涉及一种用于制备和用作用于通过甲烷或天然气的催化氧化和/或作为陶瓷膜的混合导体材料合成合成气体的膜催化反应器的混合导体材料的方法。
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公开(公告)号：US08241715B2
公开(公告)日：2012-08-14
申请号：US12877855
申请日：2010-09-08
申请人： Gilles Cannet , Pascal Del Gallo , Thierry Chartier , Emmanuel Baune , Jérome Cantonnet , Jean-François Imbault
发明人： Gilles Cannet , Pascal Del Gallo , Thierry Chartier , Emmanuel Baune , Jérome Cantonnet , Jean-François Imbault
CPC分类号： C04B28/18 , B01D5/0015 , B01D5/009 , C04B2/10 , C04B35/22 , C04B35/62655 , C04B2111/00948 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3272 , C04B2235/3418 , C04B2235/3454 , C04B2235/5427 , C04B2235/80 , C04B2235/96 , F17C11/00 , F17C11/002 , Y02E60/321 , Y02P40/615 , Y02W30/97 , Y10T428/13 , Y10T428/131 , Y10T428/249932 , C04B14/043 , C04B14/06 , C04B14/42 , C04B18/24 , C04B40/024 , C04B14/28 , C04B14/386
摘要： The present invention relates to a container packing structure, characterized in that it comprises a crystalline phase containing 55 to 97% by weight of xonotlite crystallites and 3 to 45% by weight of tobermorite crystallites. It also relates to a method for fabricating such a packing structure, and the container containing same, and its use for storing fluids such as gases.
摘要翻译： 本发明涉及一种容器包装结构，其特征在于，其包含含有55-97重量％的硬硅钙石微晶和3〜45重量％的雪硅钙石微晶的结晶相。 它还涉及一种用于制造这种包装结构的方法，以及包含其的容器及其用于储存诸如气体的流体的用途。
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5.发明申请Process for manufacturing of ceramic catalytic membrane reactors by co-extrusion 审中-公开通过共挤出制造陶瓷催化膜反应器的方法公开(公告)号：US20050253312A1
公开(公告)日：2005-11-17
申请号：US11128047
申请日：2005-05-12
CPC分类号： B28B3/20 , B01D53/228 , B01D67/0041 , B01D69/088 , B01D69/12 , B01D71/024 , B01D2323/12 , B01D2323/18 , B28B3/2636 , B29C48/09 , B29C48/21
摘要： Preparation of a supported tubular ceramic membrane composed of two coaxial layers along a axis (x), a first layer with a non-zero thickness es of a support material (S) and a second layer with a non-zero thickness eM of an active material (M), characterised in that it comprises the following steps in sequence: a step (a) to shape said supported membrane by simultaneous coaxial co-extrusion of a paste PS of the support material (S) at a flow velocity along the axis (x) VS and a paste PM of active material (M) with a flow velocity along the axis (x) VM, where VS=VM; a step (b) to dry the co-extrudate formed in step (a); a step (c) to debind the co-extrudate dried in step (b), and a step (d) to apply a heat treatment to co-sinter the two coaxial layers of the product obtained in step (c); Device for implementation of step (a).
摘要翻译： 制备由轴（x）两个同轴层组成的支撑管状陶瓷膜，具有非零厚度的支承材料（S）的第一层和非零厚度的第二层 M的活性物质（M），其特征在于，其顺序包括以下步骤：步骤（a）通过同时同时共挤出糊状物来形成所述负载膜， 沿着轴线（x）V S S的流速和活性材料（M）的浆料P M M的流速（S）的支撑材料（S） 沿着轴线（x）V M M，其中V S = V M; 步骤（b）干燥步骤（a）中形成的共挤出物; 剥离步骤（b）中干燥的共挤出物的步骤（c）和步骤（d），以进行热处理以共烧烧步骤（c）中获得的产物的两个同轴层; 用于实施步骤（a）的装置。
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6.发明申请Supported Catalyst For Producing H2 And/Or CO From Low Molecular Weight Hydrocarbons 有权用于从低分子量烃生产H2和/或CO的负载型催化剂公开(公告)号：US20110118112A1
公开(公告)日：2011-05-19
申请号：US12949289
申请日：2010-11-18
申请人： Francesco Basile , Pascal Del Gallo , Giuseppe Fornasari , Daniel Gary , Valentina Rosetti , Angelo Vaccari
发明人： Francesco Basile , Pascal Del Gallo , Giuseppe Fornasari , Daniel Gary , Valentina Rosetti , Angelo Vaccari
IPC分类号： B01J21/10
CPC分类号： C01B3/40 , B01J23/002 , B01J23/005 , B01J23/892 , B01J37/08 , B01J2523/00 , C01B3/386 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/1011 , C01B2203/1023 , C01B2203/1052 , C01B2203/1064 , C01P2002/72 , Y02P20/52 , B01J2523/22 , B01J2523/31 , B01J2523/822 , B01J2523/847
摘要： Chemical combination (C) between an active solid phase which is covalently bound to the surface of an inert solid phase, characterized in that said solid active phase essentially consists in a solid solution of a mixture of at least a magnesium oxide type phase compound and at least a magnesium silicate type phase compound in which Al, and Rh and/or Ni cations are soluted and characterized in that said inert solid phase is either a compound represented by the general formula (I): AlaNibRhcMgdSieOf (I) wherein a, b, c, d, and e are integers which are greater than or equal to 0, f is an integer greater than 0, the sum a+b+c+d≠0, and wherein (3a+2b+3c+2d+4e)/2=f, or a mixture of compounds represented by the said general formula (I), provided that at least one of the Si, Al, Mg, Rh or Ni elements, which is present in the solid active phase, is also present in the solid inert phase. Use of a catalyst in chemical reactions involving the conversion of hydrocarbonaceous feedstocks.
摘要翻译： 在与惰性固相表面共价结合的活性固相之间的化学组合（C），其特征在于所述固体活性相基本上由至少一种氧化镁型相化合物的混合物和 至少一种其中Al和Rh和/或Ni阳离子被溶解并表征的硅酸镁型相化合物，其特征在于所述惰性固相是由通式（I）表示的化合物：AlaNibRhcMgdSieOf（I）其中a，b， c，d和e是大于或等于0的整数，f是大于0的整数，和a + b + c + d≠0，其中（3a + 2b + 3c + 2d + 4e） / 2 = f或由所述通式（I）表示的化合物的混合物，条件是存在于固体活性相中的Si，Al，Mg，Rh或Ni元素中的至少一种也存在 在固体惰性相中。 在涉及烃类原料转化的化学反应中使用催化剂。
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7.发明授权Process for preparing a composite electrolyte based on BIMEVOX and the use of said compound in separating oxygen from a gas mixture 失效基于BIMEVOX制备复合电解质的方法以及所述化合物在从气体混合物中分离氧气中的用途公开(公告)号：US06207038B1
公开(公告)日：2001-03-27
申请号：US09346308
申请日：1999-07-02
申请人： César Marlu Steil , Jacques Fouletier , Michel Kleitz , Gilles Lagrange , Pascal Del Gallo , Gaëtan Mairesse , Jean-Claude Boivin
发明人： César Marlu Steil , Jacques Fouletier , Michel Kleitz , Gilles Lagrange , Pascal Del Gallo , Gaëtan Mairesse , Jean-Claude Boivin
IPC分类号： C25C110
CPC分类号： C01G31/006 , B01D53/326 , B01D2257/104 , C01B13/0233 , C01B2210/0046 , C01P2002/54 , C01P2004/03 , C01P2006/40 , G01N27/4073
摘要： A process for preparing a solid composite electrolyte comprising at least one compound of the BIMEVOX family is provided. The process comprises at least one step of preparing a mixture of one or more compounds of the BIMEVOX family with one or more chemically inert compounds, at least one step of compacting the mixture obtained, and at least one sintering step during which the temperature reached, over a nonzero time interval, has a value greater than the optimum sintering temperature for the compound of the BIMEVOX family.
摘要翻译： 提供了一种制备包含至少一种BIMEVOX族化合物的固体复合电解质的方法。 该方法包括至少一个步骤：制备一种或多种BIMEVOX族化合物与一种或多种化学惰性化合物的混合物，至少一个压实所获得混合物的步骤和至少一个烧结步骤， 在非零时间间隔内，具有大于BIMEVOX系列化合物的最佳烧结温度的值。
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8.发明授权Supported catalyst for producing H2 and/or CO from low molecular weight hydrocarbons 有权用于从低分子量烃生产H2和/或CO的负载型催化剂公开(公告)号：US08105973B2
公开(公告)日：2012-01-31
申请号：US12949289
申请日：2010-11-18
申请人： Francesco Basile , Pascal Del Gallo , Giuseppe Fornasari , Daniel Gary , Valentina Rosetti , Angelo Vaccari
发明人： Francesco Basile , Pascal Del Gallo , Giuseppe Fornasari , Daniel Gary , Valentina Rosetti , Angelo Vaccari
CPC分类号： C01B3/40 , B01J23/002 , B01J23/005 , B01J23/892 , B01J37/08 , B01J2523/00 , C01B3/386 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/1011 , C01B2203/1023 , C01B2203/1052 , C01B2203/1064 , C01P2002/72 , Y02P20/52 , B01J2523/22 , B01J2523/31 , B01J2523/822 , B01J2523/847
摘要： Chemical combination (C) between an active solid phase which is covalently bound to the surface of an inert solid phase, characterized in that said solid active phase essentially consists in a solid solution of a mixture of at least a magnesium oxide type phase compound and at least a magnesium silicate type phase compound in which Al, and Rh and/or Ni cations are soluted and characterized in that said inert solid phase is either a compound represented by the general formula (I): AlaNibRhcMgdSieOf (I) wherein a, b, c, d, and e are integers which are greater than or equal to 0, f is an integer greater than 0, the sum a+b+c+d≠0, and wherein (3a+2b+3c+2d+4e)/2=f, or a mixture of compounds represented by the said general formula (I), provided that at least one of the Si, Al, Mg, Rh or Ni elements, which is present in the solid active phase, is also present in the solid inert phase.Use of a catalyst in chemical reactions involving the conversion of hydrocarbonaceous feedstocks.
摘要翻译： 在与惰性固相表面共价结合的活性固相之间的化学组合（C），其特征在于所述固体活性相基本上由至少一种氧化镁型相化合物的混合物和 至少一种其中Al和Rh和/或Ni阳离子被溶解并表征的硅酸镁型相化合物，其特征在于所述惰性固相是由通式（I）表示的化合物：AlaNibRhcMgdSieOf（I）其中a，b， c，d和e是大于或等于0的整数，f是大于0的整数，和a + b + c + d≠0，其中（3a + 2b + 3c + 2d + 4e） / 2 = f或由所述通式（I）表示的化合物的混合物，条件是存在于固体活性相中的Si，Al，Mg，Rh或Ni元素中的至少一种也存在 在固体惰性相中。 在涉及烃类原料转化的化学反应中使用催化剂。
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公开(公告)号：US07329691B2
公开(公告)日：2008-02-12
申请号：US10712691
申请日：2003-11-13
CPC分类号： C01B3/40 , B01J23/002 , B01J23/63 , B01J23/83 , B01J23/894 , B01J23/8946 , B01J2523/00 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/044 , C01B2203/1052 , C01B2203/1064 , Y02P20/142 , Y02P20/52 , B01J2523/3706 , B01J2523/3712 , B01J2523/822 , B01J2523/842 , B01J2523/847
摘要： A composition and method for a Catalytic Partial Oxidation (CPO) of methane to synthesis gas. The catalyst allows the process to proceed at low residence time providing a long time thermal stability. The perovskite structure [AzA′1-z][B1-x-yNix Rhy] O3-δ of the catalyst is obtained using mainly La, Sr, as A and A′ cation sites (A, A′: actinide and/or lanthanide, elements and/or elements from Group I and II) and mainly Fe, Ni, as B cation sites (B: transition metal element and/or element from Group III to V).
摘要翻译： 甲烷对合成气的催化部分氧化（CPO）的组成和方法。 催化剂允许该方法在低停留时间下进行，提供长时间的热稳定性。 钙钛矿结构[A 1 Z 1 -Z 1] - [B 1-xy N 2 N z N 2 使用主要为La，Sr作为A和A'阳离子位点（A，A'：锕系元素和/或镧系元素，元素和/或镧系元素）获得催化剂的O 3-δ /或来自组I和II的元素）和主要是Fe，Ni，作为B阳离子位点（B：过渡金属元素和/或从III至V族的元素）。
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10.发明授权Oxide ion conductive ceramic membrane stacked microstructures; use for separating oxygen from air 有权氧化物离子导电陶瓷膜堆叠微结构; 用于从空气中分离氧气公开(公告)号：US07300561B2
公开(公告)日：2007-11-27
申请号：US10470172
申请日：2001-12-18
IPC分类号： C25B13/04
CPC分类号： B01D69/12 , B01D53/228 , B01D53/326 , B01D69/02 , B01D71/024 , C01B13/0255 , C01B2210/0046
摘要： The invention concerns an oxide ion conductive ceramic membrane, characterized in that it comprises a non-null finite volume with non-null total thickness E, comprising a dense layer (CD) of a solid electrolyte, a so-called bonding layer (CA), of two porous electrodes (EP) and (EP′), two porous current collectors (CC) and (CC′), and at least at least a coating porous layer (ER), characterized in that the thickness E of the volume of said membrane, is equal to the sum of the thickness of each of said elements. The membrane is used for separating oxygen from air or from a gas mixture containing same.
摘要翻译： 本发明涉及一种氧化物离子传导性陶瓷膜，其特征在于，其包括具有非零无效总厚度E的非零有限体积，包括固体电解质的致密层（CD），即所谓的结合层（CA） 的两个多孔电极（EP）和（EP'），两个多孔集电器（CC）和（CC'），以及至少一个涂覆多孔层（ER），其特征在于， 所述膜等于每个所述元件的厚度之和。 膜用于从空气或含有它们的气体混合物中分离氧气。
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