公开(公告)号：US4239760A

公开(公告)日：1980-12-16

申请号：US2053

申请日：1979-01-08

申请人： Klaus Sasse ,  Walter Gauss ,  Paul-Ernst Frohberger ,  Peter Kraus ,  Volker Paul

发明人： Klaus Sasse ,  Walter Gauss ,  Paul-Ernst Frohberger ,  Peter Kraus ,  Volker Paul

IPC分类号： A01N43/707 ,  C07D253/10 ,  C07D403/04 ,  C07D521/00 ,  C07D253/08 ,  A61K31/415 ,  A61K31/53

CPC分类号： C07D253/10 ,  A01N43/707 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： 3-Azolyl-benzo-1,2,4-triazines or 1-oxides thereof of the formula ##STR1## in which X represents halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylmercapto, C.sub.1 -C.sub.4 alkylsulphonyl, nitro or trifluoromethyl,m represents 0, 1, 2, 3 or 4, the substituents X being selected independently of one another when m is 2 or more,n represents 0 or 1 andAz represents a five-membered hetero-aromatic ring with 2 or 3 nitrogen atoms, which is bonded via nitrogen and which can be optionally substituted, which possess fungicidal and bactericidal properties.

摘要翻译： 其中X表示卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4烷基巯基，C 1 -C 4烷基磺酰基，C 1 -C 4烷基磺酰基， 硝基或三氟甲基，m表示0,1,2,3或4，当m为2或更多时，取代基X彼此独立地选择，n表示0或1，并且Az表示具有2个的五元杂芳环 或3个氮原子，其通过氮键合并且可以任选被取代，其具有杀真菌性和杀菌性。

公开(公告)号：US4027032A

公开(公告)日：1977-05-31

申请号：US627412

申请日：1975-10-30

申请人： Paul-Ernst Frohberger ,  Walter Gauss

发明人： Paul-Ernst Frohberger ,  Walter Gauss

IPC分类号： A01N43/56 ,  A01N20060101 ,  A01N43/48 ,  C07D403/04 ,  A01N9/22

CPC分类号： C07D491/04

摘要： Combating fungi of the genus Helminthosporium with the known compound 2-[3',5'-dimethylpyrazolyl-(1')]-benzimidazole of the formula ##STR1##

摘要翻译： 将Helminthosporium属的真菌与已知的式[IMAGE]的化合物2- [3'，5'-二甲基吡唑基 - （1'）] - 苯并咪唑

公开(公告)号：US4904296A

公开(公告)日：1990-02-27

申请号：US121552

申请日：1987-11-17

申请人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D521/00

CPC分类号： C07D303/22 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： Compounds which are substituted 1-hydroxyalkylazolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cycloalkyl or optionally substituted phenyl group, Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.

公开(公告)号：US4868196A

公开(公告)日：1989-09-19

申请号：US859276

申请日：1986-05-02

申请人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Klaus Lurssen

发明人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Klaus Lurssen

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00

CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

摘要： Compounds which are ether derivatives of substituted 1-hydroxyalkyl-azoles, of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R.sup.1 represents a substituted alkyl, optionally substituted cycloalkyl or optionally substituted phenyl radical or, if either A represents a nitrogen atom, or if A represents the CH group and at the same B represents oxygen or sulphur, R.sup.1 also represents an unsubstituted alkyl radical,R.sup.2 represents an alkyl, alkenyl, alkinyl, optionally substituted phenyl or optionally substituted benzyl radical,Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy radical andm is 0, 1, 2 or 3,and acid addition salts and metal salt complexes thereof, are novel, are prepared as described, and find use as fungicides and as agents for regulating plant growth.

摘要翻译： 作为其中A表示氮原子或CH基团的通式为：（I）的取代的1-羟基烷基 - 唑的醚衍生物的化合物，B表示氧，硫或CH2基，R1表示取代的烷基 ，任选取代的环烷基或任选取代的苯基，或者如果A表示氮原子，或者如果A表示CH基团，而相同的B表示氧或硫，则R1还表示未取代的烷基，R2表示烷基，烯基 烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基，任选取代的苯氧基，任意取代的苯基烷基或任意取代的苯基烷氧基，m为0， 1,2或3及其酸加成盐和金属盐络合物是新颖的，按照所述制备，可用作杀真菌剂和如年龄 用于调节植物生长。

公开(公告)号：US4797499A

公开(公告)日：1989-01-10

申请号：US895089

申请日：1986-08-11

申请人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D521/00 ,  C07D303/08

CPC分类号： C07D303/22 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： Compounds which are substituted 1-hydroxyalkyl-azolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cycloalkyl or optionally substituted phenyl group,Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.

摘要翻译： 化合物，其中A表示氮原子或CH基团，B表示氧，硫或CH2基团，其中R表示取代的烷基，且表示取代的烷基， B代表硫的情况也代表未取代的烷基，任选取代的环烷基或任选取代的苯基，Z代表卤素原子或烷基，环烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基，任选取代的苯基， 苯氧基，任选取代的苯基烷基或任选取代的苯基烷氧基，m为0,1,2或3，其酸加成盐和金属盐络合物是新的，如上所述制备，可用作杀真菌剂和植物生长调节剂。

公开(公告)号：US4723984A

公开(公告)日：1988-02-09

申请号：US621968

申请日：1984-06-18

申请人： Graham Holmwood ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

发明人： Graham Holmwood ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

IPC分类号： A01N20060101 ,  A01N43/20 ,  A01N43/50 ,  A01N43/64 ,  A01N43/653 ,  C07D20060101 ,  C07D233/60 ,  C07D249/08 ,  C07D301/00 ,  C07D301/02 ,  C07D303/02 ,  C07D303/04 ,  C07D303/08 ,  C07D303/20 ,  C07D303/22 ,  C07D521/00 ,  A61K31/41

CPC分类号： A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D303/02 ,  C07D303/04 ,  C07D303/08 ,  C07D303/22

摘要： New 1-hydroxyethyl-azole derivatives of the general formula ##STR1## in which R represents an alkyl radical, an optionally substituted cycloalkyl radical or an optionally substituted phenyl radical,X represents a nitrogen atom or a CH group,Y represents a grouping --OCH.sub.2 --, -- CH.sub.2 CH.sub.2 -- or --CH.dbd.CH--,Z represents a halogen atom, an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy or halogenoalkylthio radical, an optionally substituted phenyl radical, an optionally substituted phenoxy radical, an optionally substituted phenylalkyl radical or an optionally substituted phenylalkoxy radical andm is 0, 1, 2 or 3,a process for their preparation and their use as plant growth regulators and fungicides.

摘要翻译： 其中R表示烷基，任选取代的环烷基或任选取代的苯基的新的1-羟乙基 - 唑衍生物，其中R表示氮原子或CH基团，Y表示 分组-OCH 2 - ， - CH 2 CH 2 - 或-CH = CH-，Z表示卤素原子，烷基，环烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基或卤代烷硫基，任选取代的苯基，任选取代的苯氧基， 任选取代的苯基烷基或任选取代的苯基烷氧基，m为0,1,2或3，其制备方法及其用作植物生长调节剂和杀真菌剂。

公开(公告)号：US4515617A

公开(公告)日：1985-05-07

申请号：US519609

申请日：1983-08-02

申请人： Graham Holmwood ,  Klaus Lurssen ,  Paul-Ernst Frohberger

发明人： Graham Holmwood ,  Klaus Lurssen ,  Paul-Ernst Frohberger

IPC分类号： A01N43/54 ,  C07D239/26

CPC分类号： C07D239/26 ,  A01N43/54

摘要： A benzyl-pyrimidinylalkyl-ether of the formula ##STR1## in which R is alkyl, optionally substituted cycloalkyl or optionally substituted phenyl, andX.sup.1, X.sup.2 and X.sup.3 each independently is hydrogen, halogen, alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, cyano, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy,or an acid addition salt or metal salt complex thereof, which possesses fungicidal and plant growth-regulating properties. The corresponding pyrimidinyl-carbinols are also new.

摘要翻译： 其中R为烷基，任选取代的环烷基或任选取代的苯基，且X 1，X 2和X 3各自独立地为氢，卤素，烷基，环烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基的苄基 - 嘧啶基烷基 - 醚 ，卤代烷硫基，氰基，任选取代的苯氧基，任选取代的苯基烷基或任选取代的苯基烷氧基，或其酸加成盐或金属盐络合物，其具有杀真菌剂和植物生长调节性质。 相应的嘧啶基 - 甲醇也是新的。

公开(公告)号：US4514409A

公开(公告)日：1985-04-30

申请号：US398028

申请日：1982-07-14

申请人： Gerhard Jager ,  Manfred Jautelat ,  Karl H. Buchel ,  Wilhelm Brandes ,  Paul-Ernst Frohberger

发明人： Gerhard Jager ,  Manfred Jautelat ,  Karl H. Buchel ,  Wilhelm Brandes ,  Paul-Ernst Frohberger

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07C17/25 ,  C07C43/225 ,  C07C45/51 ,  C07C45/63 ,  C07C45/71 ,  C07C49/227 ,  C07C49/255 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00 ,  A01N43/64

CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07C17/25 ,  C07C43/225 ,  C07C45/513 ,  C07C45/63 ,  C07C45/71 ,  C07C49/227 ,  C07C49/255 ,  C07D233/56 ,  C07D249/08

摘要： 5-Aryloxy-5-azolyl-3,3-dimethylpent-1-en-4-ones and -ols of the formula ##STR1## in which Ar is an optionally substituted aryl group,Az is a 1,2,4-triazol-1-yl, 1,2,4-triazol-4-yl or imidazol-1-yl group, andB is a keto group of a CH(OH) grouping,or addition products thereof with physiologically acceptable acids or metal salts are suitable for use as plant protection agents, and can be employed with particularly good success for combating those fungi which cause powdery mildew diseases, thus for combating Erysiphe species, Sphaerotheca species and Podosphaera species, and for combating diseases of rice.

摘要翻译： 5-芳氧基-5-噻唑基-3,3-二甲基戊-1-烯-4-酮和式“IMAGE”的醇，其中Ar是任选取代的芳基，Az是1,2,4-三唑 -1-基，1,2,4-三唑-4-基或咪唑-1-基，B是CH（OH）基团的酮基，或其与生理上可接受的酸或金属盐的加成产物是 适合作为植物保护剂使用，可以特别成功地对抗那些引起白粉病的真菌，从而抵抗白粉菌，白纹枯病菌和Podosphaera物种，防治水稻病害。

公开(公告)号：US4472416A

公开(公告)日：1984-09-18

申请号：US403988

申请日：1982-08-02

申请人： Jorg Stetter ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Paul Reinecke ,  Wilhelm Brandes

发明人： Jorg Stetter ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Paul Reinecke ,  Wilhelm Brandes

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00 ,  A01N43/64 ,  C07D233/61

CPC分类号： C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： A substituted azolyl-phenoxy derivative of the formula ##STR1## in which A is a nitrogen atom or a CH group,B is a keto group or a CH(OH) grouping,R.sup.1 is an alkyl or halogenoalkyl group of an optionally substituted aryl group,R.sup.2 is a hydrogen atom, an alkyl group or an optionally substituted phenyl group,R.sup.3 is a hydrogen atom, an alkyl, alkenyl or alkinyl group,m is 1 or 2,X is a halogen atom, or an alkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy or halogenoalkylthio group, andn is 0, 1 or 2,or an addition product thereof with an acid or metal salt, which possesses fungicidal activity particularly for combating cereal diseases as well as rust and scab diseases.

摘要翻译： A为氮原子或CH基团的取代的吡唑基 - 苯氧基衍生物，其中A为氮原子或CH基团，B为酮基或CH（OH）基团，R 1为任选取代的芳基的烷基或卤代烷基 R2是氢原子，烷基或可以具有取代基的苯基，R3是氢原子，烷基，烯基或炔基，m是1或2，X是卤素原子或烷基，烷氧基，烷硫基 ，卤代烷基，卤代烷氧基或卤代烷硫基，n为0,1或2，或其与酸或金属盐的加成产物，其具有特别用于防治谷物疾病以及防锈和痂病的杀真菌活性。

公开(公告)号：US4427672A

公开(公告)日：1984-01-24

申请号：US281628

申请日：1981-07-09

申请人： Udo Kraatz ,  Jorg Stetter ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

发明人： Udo Kraatz ,  Jorg Stetter ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

IPC分类号： C07D401/12 ,  A01N43/653 ,  A61K31/44 ,  A61K31/4427 ,  A61P31/04 ,  C07C45/63 ,  C07C45/67 ,  C07C49/16 ,  C07C49/167 ,  C07D521/00 ,  A01N43/64 ,  A01N59/16 ,  C07F1/08

CPC分类号： C07D231/12 ,  A01N43/653 ,  C07C45/63 ,  C07C45/673 ,  C07C49/16 ,  C07C49/167 ,  C07D233/56 ,  C07D249/08

摘要： Substituted triazolylalkyl pyridyl ethers of the formula ##STR1## in which R.sup.1 is a halogen atom,R.sup.2 is a hydrogen or halogen atom,X is a keto group or a CH(OH) group,Y each independently is a halogen atom or an alkyl, alkoxy or cyano group, andn is 0, 1, 2, 3 or 4,or an addition product thereof with a physiologically acceptable acid or metal salt which possesses fungicidal activity. Intermediates therefor wherein X is a keto group and with a halogen atom in place of either the pyridinyloxy group or the azole group are also new.

摘要翻译： 其中R 1为卤素原子，R 2为氢原子或卤原子，X为酮基或CH（OH）基的式“IMAGE”的取代三唑基烷基吡啶基醚，Y各自独立地为卤素原子或烷基， 烷氧基或氰基，n为0,1,2,3或4，或其与具有杀真菌活性的生理上可接受的酸或金属盐的加成产物。 其中X是酮基并且卤素原子代替吡啶氧基或吡唑基的中间体也是新的。