公开(公告)号：US4659742A

公开(公告)日：1987-04-21

申请号：US750240

申请日：1985-07-01

申请人： Philippe Courty ,  Daniel Durand ,  Andre Sugier ,  Edouard Freund

发明人： Philippe Courty ,  Daniel Durand ,  Andre Sugier ,  Edouard Freund

IPC分类号： C07C27/06 ,  B01J23/00 ,  B01J23/78 ,  B01J23/80 ,  B01J23/84 ,  B01J23/86 ,  C07B61/00 ,  C07C27/00 ,  C07C29/15 ,  C07C29/153 ,  C07C29/156 ,  C07C29/157 ,  C07C29/158 ,  C07C31/02 ,  C07C31/04 ,  C07C67/00

CPC分类号： B01J23/78 ,  C07C29/156 ,  B01J35/0093 ,  Y02P20/52

摘要： Process for manufacturing a mixture of methanol and higher alcohols by reacting carbon oxides with hydrogen in the presence of a catalyst containing simultaneously copper, cobalt, aluminum and at least one alkali or alkaline-earth metal A selected from lithium, sodium, potassium, rubidium, caesium, beryllium, magnesium, calcium, strontium and barium, in respective atomic ratios of Cu/Co=0.1-5, Al/co=0.7-4, A metals/Co=0.05-3.5, the proportion by weight of each metal to the total metals weight being respectively: copper: 10-65%, cobalt: 5-50%, aluminum: 5-40%, metal A: 0.1-15%, the homogeneity of the catalyst being such that the atomic ratio cobalt/aluminum does not vary by more than 15% with respect to its average value, on a scale of 5 nanometers.

摘要翻译： 在同时含有铜，钴，铝和至少一种碱金属或碱土金属的催化剂存在下，通过使碳氧化物与氢反应制备甲醇和高级醇的混合物的方法，该催化剂选自锂，钠，钾，铷， 铯，铍，镁，钙，锶和钡，原子比分别为Cu / Co = 0.1-5，Al / co = 0.7-4，A金属/ Co = 0.05-3.5，各金属的重量比 总金属重量分别为：铜：10-65％，钴：5-50％，铝：5-40％，金属A：0.1-15％，催化剂的均匀性使钴/铝的原子比 相对于其平均值不超过15％，尺寸为5纳米。

公开(公告)号：US4257920A

公开(公告)日：1981-03-24

申请号：US95007

申请日：1979-11-16

申请人： Andre Sugier ,  Philippe Courty ,  Edouard Freund

发明人： Andre Sugier ,  Philippe Courty ,  Edouard Freund

IPC分类号： C07C29/15 ,  B01J23/80 ,  B01J23/89 ,  C01B3/16 ,  C07C27/00 ,  C07C29/154 ,  C07C29/157 ,  C07C31/04 ,  C07C67/00 ,  B01J21/04 ,  B01J23/10 ,  B01J23/60 ,  B01J23/72

CPC分类号： C01B3/16 ,  B01J23/80 ,  B01J23/8953 ,  C07C29/154 ,  Y02P20/52

摘要： Catalyst for producing hydrogen by reaction of carbon monoxide with water or for producing methanol by reaction of carbon monoxide with hydrogen, containing by weight 10-60% of copper oxide, 5-40% of zinc oxide, 1-20% of a rare earth metal oxide, 30-70% of aluminous cement and optionally 0.01-1% of a noble metal from group VIII.

摘要翻译： 通过一氧化碳与水反应或通过一氧化碳与氢的反应来生产氢的催化剂，其含有10-60％的氧化铜，5-40％的氧化锌，1-20％的稀土 金属氧化物，30-70％的铝水泥和任选的0.01-1％的来自VIII族的贵金属。

公开(公告)号：US4126581A

公开(公告)日：1978-11-21

申请号：US801261

申请日：1977-05-27

申请人： Andre Sugier ,  Philippe Courty ,  Edouard Freund

发明人： Andre Sugier ,  Philippe Courty ,  Edouard Freund

IPC分类号： B01D53/94 ,  B01D53/86 ,  B01J23/80 ,  C01B3/16 ,  C07C27/00 ,  C07C29/15 ,  C07C29/151 ,  C07C29/154 ,  C07C67/00 ,  B01J21/04 ,  B01J23/06

CPC分类号： C01B3/16 ,  B01J23/80 ,  C07C29/151 ,  C07C29/154 ,  Y02P20/52

摘要： Catalyst for the conversion of carbon monoxide in the presence of water, to produce hydrogen, or in the presence of hydrogen, to produce methanol, said catalyst containing 10 - 60% by weight of copper oxide, 5 - 40% by weight of zinc oxide and 30 - 70% by weight of aluminous cement, the total content of copper oxide and zinc oxide being from 30 to 70% by weight.

摘要翻译： 用于在水存在下转化一氧化碳，产生氢气或在氢存在下转化生成甲醇的催化剂，所述催化剂含有10-60重量％的氧化铜，5-40重量％的氧化锌 和30-70重量％的铝水泥，氧化铜和氧化锌的总含量为30至70重量％。

公开(公告)号：US4122110A

公开(公告)日：1978-10-24

申请号：US846486

申请日：1977-10-28

申请人： Andre Sugier ,  Edouard Freund

发明人： Andre Sugier ,  Edouard Freund

IPC分类号： B01J23/78 ,  B01J23/84 ,  C07C29/151 ,  C07C29/156 ,  C07C29/00 ,  C07C31/06 ,  C07C31/08

CPC分类号： B01J23/868 ,  B01J23/78 ,  B01J23/84 ,  B01J23/8472 ,  B01J23/8892 ,  C07C29/1512 ,  C07C29/156 ,  Y02P20/52

摘要： Alcohols, particularly linear saturated primary alcohols, are manufactured from CO and H.sub.2 in the presence of a catalyst comprising at least 4 essential elements, copper, cobalt, a third metal selected from chromium, iron, vanadium and manganese, and at least one alkali metal. A preferred method for manufacturing the catalyst is also described; it comprises the use of a complexant, such as citric acid.

摘要翻译： 醇，特别是直链饱和伯醇由CO和H 2在催化剂存在下制备，催化剂包含至少4种必需元素，铜，钴，选自铬，铁，钒和锰的第三种金属，以及至少一种碱金属 。 还描述了制造催化剂的优选方法; 它包括使用络合剂，例如柠檬酸。

公开(公告)号：US4915176A

公开(公告)日：1990-04-10

申请号：US288985

申请日：1988-12-23

申请人： Andre Sugier ,  Paul Bourgmayer ,  Emmanuel Behar ,  Edouard Freund

发明人： Andre Sugier ,  Paul Bourgmayer ,  Emmanuel Behar ,  Edouard Freund

IPC分类号： E21B43/00 ,  C07C7/20 ,  C10L3/00 ,  E21B37/06 ,  F17D1/05

CPC分类号： F17D1/05 ,  C07C7/20 ,  C10L3/00 ,  Y10S166/902 ,  Y10T137/0391

摘要： A method is provided for transporting in a duct a fluid comprising gas and water, and being under conditions where at least one hydrate is formed, the hydrates being formed from said gas and said water, wherein, before or during the formation of the hydrate or hydrates, an additive is injected into said fluid for reducing the tendency to agglomeration of the hydrate so as to obtain one or more hydrates in dispersed form, and said fluid is transported containing said hydrate or hydrates in dispersed form.

摘要翻译： 提供一种用于在管道中输送包含气体和水的流体并且处于形成至少一种水合物的条件下的水合物，所述水合物由所述气体和所述水形成，其中在形成水合物之前或期间 水合物，将添加剂注入所述流体中以减少水合物凝聚的倾向，从而获得分散形式的一种或多种水合物，并且所述流体以分散形式运输含有所述水合物或水合物。

公开(公告)号：US4346179A

公开(公告)日：1982-08-24

申请号：US137098

申请日：1980-04-04

申请人： Andre Sugier ,  Edouard Freund ,  Jean-Francois Le Page

发明人： Andre Sugier ,  Edouard Freund ,  Jean-Francois Le Page

IPC分类号： C07C27/06 ,  B01J23/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/15 ,  C07C29/151 ,  C07C29/152 ,  C07C29/156 ,  C07C29/78 ,  C07C31/02 ,  C07C67/00 ,  C07C31/04

CPC分类号： C07C29/1512 ,  C07C29/1516 ,  C07C29/156 ,  C07C29/78 ,  C12C11/02 ,  Y02P20/52

摘要： Process for manufacturing a constituent for motor car gasoline from a synthesis gas containing essentially carbon dioxide, carbon monoxide and hydrogen, comprising producing methanol and its higher homologs by treatment of said synthesis gas in a first catalytic reaction zone at 230.degree.-350.degree. C., cooling and condensing the effluent therefrom, separating from the liquid condensate a gas fraction, treating the latter at 240.degree.-300.degree. C. in a second catalytic reaction zone to produce a liquid methanol fraction and admixing said methanol fraction with said liquid condensate to form said gasoline constituent.

摘要翻译： 用于从基本上包含二氧化碳，一氧化碳和氢气的合成气制造汽车汽油的成分的方法，包括通过在230-350℃的第一催化反应区中处理所述合成气来生产甲醇及其高级同系物。 ，冷却并冷凝来自其的流出物，从液体冷凝物中分离出气体馏分，在第二催化反应区中在240℃-300℃下处理废液，以产生液体甲醇馏分并将所述甲醇馏分与所述液体冷凝物混合 形成汽油成分。

公开(公告)号：US4291126A

公开(公告)日：1981-09-22

申请号：US105312

申请日：1979-12-19

申请人： Andre Sugier ,  Edouard Freund

发明人： Andre Sugier ,  Edouard Freund

IPC分类号： C07C27/06 ,  B01J23/00 ,  B01J23/76 ,  B01J23/78 ,  B01J23/84 ,  C07B61/00 ,  C07C27/00 ,  C07C29/15 ,  C07C29/156 ,  C07C29/157 ,  C07C31/02 ,  C07C67/00

CPC分类号： B01J23/868 ,  B01J23/78 ,  B01J23/84 ,  B01J23/8472 ,  B01J23/8892 ,  C07C29/156 ,  C07C29/157 ,  Y02P20/52

摘要： Process for manufacturing alcohols by reaction of carbon monoxide with hydrogen in the presence of a catalyst containing from 20 to 60% of copper, from 5 to 50% of cobalt, from 5 to 30% of a metal selected from chromium, iron, vanadium and manganese, from 5 to 40% of a rare earth metal, from 0.1 to 5% of an alkali or earth-alkali metal and, optionally, zinc and/or a noble metal from group VIII and/or a binder selected from alumina, magnesia and cements.

摘要翻译： 在含有20〜60％的铜，5〜50％的钴，5〜30％的选自铬，铁，钒和钒的金属的催化剂的存在下，通过一氧化碳与氢的反应来制造醇的方法，以及 锰，5至40％的稀土金属，0.1至5％的碱金属或碱土金属和任选的锌和/或第VIII族的贵金属和/或选自氧化铝，氧化镁的粘合剂 和水泥。

公开(公告)号：US4501656A

公开(公告)日：1985-02-26

申请号：US507415

申请日：1983-06-23

申请人： Pierre Dufresne ,  Edouard Freund ,  Christian Marcilly ,  Francis Raatz

发明人： Pierre Dufresne ,  Edouard Freund ,  Christian Marcilly ,  Francis Raatz

IPC分类号： B01J29/26 ,  C10G45/12 ,  C10G45/58 ,  C10G45/64 ,  C10G47/20

CPC分类号： B01J29/26 ,  C10G2400/06

摘要： A new catalyst with a highly dealuminated mordenite base, useful in particular in hydrotreatment processes for improving the low temperature properties and the pour point and cloud point of oil cuts contains:(1) an acidic carrier comprising(a) at least 50% (calculated as dry base) of highly dealuminated mordenite and characterized by a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 higher than 110 and a sodium content lower than or equal to 0.5% by weight, and(b) an amorphous matrix, and(2) said acid carrier containing in association at least one oxide of a metal from group VIII and at least one oxide of a metal from group VI of the periodic classification of elements.

摘要翻译： 具有高脱铝丝光沸石基质的新型催化剂，尤其用于改进油料的低温性能和倾点和浊点的加氢处理方法中包含：（1）酸性载体，其包含（a）至少50％（计算值 作为干碱），其特征在于SiO 2 / Al 2 O 3的摩尔比高于110，钠含量低于或等于0.5重量％，和（b）无定形基质，和（2）所述酸性载体含有 关于来自第VIII族的金属的至少一种氧化物和至少一种元素的周期性分类的来自第VI族的金属的氧化物。

公开(公告)号：US20070131909A1

公开(公告)日：2007-06-14

申请号：US11592324

申请日：2006-11-03

申请人： Alexandre Rojey ,  Edouard Freund ,  Nicolas Boudet

发明人： Alexandre Rojey ,  Edouard Freund ,  Nicolas Boudet

IPC分类号： C01B3/38 ,  C25C1/02

CPC分类号： C10J3/66 ,  C10J3/00 ,  C10J2300/0909 ,  C10J2300/0916 ,  C10J2300/092 ,  C10J2300/093 ,  C10J2300/0946 ,  C10J2300/1284 ,  C10J2300/16 ,  C10J2300/1618 ,  C10J2300/1665 ,  C10J2300/1684 ,  C10J2300/1846 ,  Y02E50/18 ,  Y02E50/32 ,  Y02E60/366 ,  Y02P20/145

摘要： The invention relates to a process for the production of a synthesis gas SG 1. Process for the production of a synthesis gas SG that has an H2/CO ratio of between 1.9 and 2.3 starting from a carbon-containing material that is relatively low in hydrogen, water and electrical energy, in which: Electrolysis of the water is carried out to produce, on the one hand, oxygen, and, on the other hand, hydrogen, A CF current that comprises at least the majority of the carbon contained in the carbon-containing material CF is subjected to a partial oxidation POX with essentially pure oxygen produced by electrolysis, At least a portion of the hydrogen that is produced by electrolysis is added to the CF current upstream and/or downstream from the partial oxidation POX, in such an amount that the H2/CO ratio of the final synthesis gas SG is between 1.9 and 2.3, the carbon-containing material being dried upstream from the POX so that the O2/H2 molar ratio of the POX-supplied oxygen to the added hydrogen is between 0.45 and 0.55.

摘要翻译： 本发明涉及一种生产合成气SG的方法。1.一种从含氢量相对较低的含碳材料开始制备H 2 / CO比为1.9至2.3的合成气SG的方法 ，水和电能，其中：进行水的电解，一方面是氧气，另一方面是产生氢，A CF电流，其至少包括在 含碳材料CF通过电解产生的基本上纯的氧进行部分氧化POX，通过电解产生的至少一部分氢被添加到部分氧化POX的上游和/或下游的CF电流中 使得最终合成气SG的H 2 / CO比在1.9和2.3之间的量使得含PO的材料在POX的上游被干燥，使得POX供应的氧气与添加的水压的O 2 / H 2摩尔比 n在0.45和0.55之间。

公开(公告)号：US5266270A

公开(公告)日：1993-11-30

申请号：US915391

申请日：1992-07-20

申请人： Hubert Ajot ,  Edouard Freund ,  Pierre Grandvallet

发明人： Hubert Ajot ,  Edouard Freund ,  Pierre Grandvallet

IPC分类号： G01N31/00 ,  G01N31/10 ,  G01N35/00

CPC分类号： G01N31/00 ,  G01N31/10 ,  Y10T436/25 ,  Y10T436/25875

摘要： On-line test and analysis equipment equivalent for establishing a material balance of a chemical reaction comprising: a reactor; an injection system for a charge having a certain flow and composition, connected to the reactor; instrumentation for measuring the flow and composition of the charge; a heater to heat the reactor so as to provide a gaseous effluent; first analysis instrumentation to provide a qualitative and quantitative analysis of effluents contained in sampling valves; expansion device for the effluents; second analysis instrumentation for expanded effluent; an instrument to measure the volume of the effluents connected to the outlet of the first analysis means; and instrumentation connected to the instrumentation for measuring the flow and composition of the charge, to the instrument for measuring the volume, and to the first and second analysis instrumentation, the processing instrumentation being capable of determining a material balance from the measurements of flow and composition of the charge and the analysis of the charge, and from the analysis of the effluents.

摘要翻译： 用于建立化学反应的物料平衡的等效的在线测试和分析设备，包括：反应器; 用于具有连接到反应器的一定流量和组成的装料的注射系统; 用于测量电荷的流量和组成的仪器; 加热器以加热反应器以提供气态流出物; 首次分析仪器，对采样阀中所含的废水进行定性和定量分析; 污水膨胀装置; 膨胀污水二次分析仪器; 测量连接到第一分析装置的出口的流出物的体积的仪器; 以及与仪器连接的用于测量电荷的流量和组成的仪器，用于测量体积的仪器，以及第一和第二分析仪器，处理仪器能够根据流量和组成的测量来确定材料平衡 的费用和费用的分析，以及从流出物的分析。