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1.发明授权Process for controlled radical polymerization or copolymerization of (meth)acrylic and vinyl monomers and (co)polymers obtained 失效获得的（甲基）丙烯酸和乙烯基单体和（共）聚合物的受控自由基聚合或共聚方法
公开(公告)号：US5767210A
公开(公告)日：1998-06-16
申请号：US827386
申请日：1997-03-27
IPC分类号： C08F2/24 , C08F2/02 , C08F2/38 , C08F4/00 , C08F4/04 , C08F4/26 , C08F4/28 , C08F4/72 , C08F4/80 , C08F20/00 , C08F20/14 , C08F2/00 , C08F20/06
摘要： This process is characterized by the fact that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature that can be as low as 0.degree. C., in the presence of an initiation system including: at least one compound generating radicals, other than bromofluorene, and at least one catalyst consisting of a complex of palladium in the 0 oxidation state, denoted by the following formula (I): Pd(0)L.sup.1 L.sup.2 L.sup.3 L.sup.4 in which each of L.sup.1, L.sup.2, L.sup.3 and L.sup.4, which are identical or different, denotes a ligand which may be a chiral ligand, which is chosen from PRR'R", P(OR)(OR')(OR"), NRR'R", ORR', SRR', SeRR', AsRR'R", SbRR'R", where each of R, R' and R" independently denotes a C.sub.1 -C.sub.14 alkyl group, optionally substituted, or an optionally substituted aromatic group, it being possible for at least two of these ligands to be joined to one another by one or more divalent radicals.
摘要翻译： 该方法的特征在于，在起始系统存在下，至少一种所述单体在本体，溶液，乳液或悬浮液中在可低至0℃的温度下聚合或共聚，包括 ：除了溴芴之外，至少一种产生自由基的化合物和至少一种由O型氧化态的钯络合物组成的催化剂，由下式（I）表示：Pd（0）L1L2L3L4，其中L1，L2 表示可以是手性配体的配体，其选自PRR'R“，P（OR）（OR'）（OR”）（OR“），NRR'R” ，ORR'，SRR'，SeRR'，AsRR'R“，SbRR'R”，其中R，R'和R“各自独立地表示任选取代的C 1 -C 14烷基或任选取代的芳族 这些配体中的至少两个可能通过一个或多个二价基团彼此连接。
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2.发明授权Process for the controlled radical (CO) polymerization of (Meth) acrylic vinyl vinylidene and diene monomers in the presence of an Rh Co OR Ir 失效（甲基）丙烯酸乙烯基亚乙烯基和二烯单体在Rh Co OR Ir存在下的受控自由基（CO）聚合方法
公开(公告)号：US5811500A
公开(公告)日：1998-09-22
申请号：US884219
申请日：1997-06-27
IPC分类号： C08F2/24 , C08F2/38 , C08F4/00 , C08F4/04 , C08F4/28 , C08F4/60 , C08F4/72 , C08F4/80 , C08F12/08 , C08F14/00 , C08F18/08 , C08F20/10 , C08F20/14 , C08F297/06 , C08F4/06
CPC分类号： C08F4/00
摘要： This process is characterized in that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature which may be as low as 0.degree. C., in the presence of an initiator system comprising at least one non-peroxy radical-generator compound and at least one catalyst consisting of a metal complex represented by formula Ma.sub.a (L).sub.n in which M represents Rh, Co or Ir; A represents, a halogen or a pseudohalogen; the groups L, which may be identical or different, each represent a ligand which may be a chiral ligand, which is chosen from cyclooctadiene, PRR'R", P(OR) (OR') (OR"), NRR'R", ORR', SRR', SeRR', AsRR'R", SbRR'R", each radical R, R' and R" independently representing an optionally substituted C.sub.1 -C.sub.14 alkyl group or an optionally substituted aromatic group, it being possible for at least two of these ligands to be joined together by one or more divalent radicals; a is an integer such that 1.ltoreq.a.ltoreq.3 ; n is an integer such that 1.ltoreq.n.ltoreq.5, and in the absence of activator.
摘要翻译： 该方法的特征在于，至少一种所述单体在本体，溶液，乳液或悬浮液中，在可能低至0℃的温度下，在至少包含至少 一种非过氧自由基产生剂化合物和至少一种由式Ma（L）n表示的金属配合物组成的催化剂，其中M表示Rh，Co或Ir; A表示卤素或假卤素; 可以相同或不同的基团L各自表示可以是手性配体的配体，其选自环辛二烯，PRR'R“，P（OR）（OR'）（OR”），NRR' R“，ORR'，SRR'，SeRR'，AsRR'R”，SbRR'R“，每个基团R，R'和R”独立地表示任选取代的C 1 -C 14烷基或任选取代的芳族 这些配体中的至少两个可能通过一个或多个二价基团连接在一起; a是整数，使得1
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公开(公告)号：US08287950B2
公开(公告)日：2012-10-16
申请号：US11719153
申请日：2005-11-10
申请人： Thierry Ouvrard , Thierry Senninger , Karine Loyen , Holger Senff
发明人： Thierry Ouvrard , Thierry Senninger , Karine Loyen , Holger Senff
IPC分类号： B05D7/00
CPC分类号： C08J3/12 , B33Y70/00 , C08J3/14 , C08J2377/00 , C08K3/36 , Y10T428/2982 , Y10T428/2991
摘要： The invention relates to a method for obtaining polyamide or copolyamide particles which are spheroidal and whose average diameter is between 40 and 150 μm, preferably between 60 and 100 μm. Said method consists of introducing a mineral charge, preferably silica, having an average diameter of 1-30 μm into the reaction mixture. The invention also relates to a polyamide or copolyester amide powder and to the use thereof in order to manufacture coatings, ink compositions, paint compositions, cosmetic compositions, pharmaceutical compositions, alloys with metal powders or metal oxide powders and parts by agglomerating said powder by laser sintering, IR radiation or UV radiation.
摘要翻译： 本发明涉及一种获得球形的平均直径为40-150μm，优选为60-100μm的聚酰胺或共聚酰胺颗粒的方法。 所述方法包括将平均直径为1-30μm的矿物质，优选二氧化硅引入反应混合物中。 本发明还涉及一种聚酰胺或共聚酯酰胺粉末及其用途，以制造涂料，油墨组合物，油漆组合物，化妆品组合物，药物组合物，具有金属粉末或金属氧化物粉末的合金以及通过激光凝聚所述粉末的部件 烧结，IR辐射或UV辐射。
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4.发明授权公开(公告)号：US06706832B2
公开(公告)日：2004-03-16
申请号：US10351904
申请日：2003-01-27
申请人： Eric Minaux , Lucedio Greci , Michael Buback , Paul Tordo , Thierry Senninger , Pierluigi Stipa , Patricia Carloni , Elisabetta Damiani , Giampaolo Tommasi
发明人： Eric Minaux , Lucedio Greci , Michael Buback , Paul Tordo , Thierry Senninger , Pierluigi Stipa , Patricia Carloni , Elisabetta Damiani , Giampaolo Tommasi
IPC分类号： C08F238
CPC分类号： C08F293/005 , C08F4/00 , C08F10/02 , C08F2438/02 , C08F2/40
摘要： Polymers are obtained by a radical (co)polymerization of ethylene under high pressure in the presence of at least one initiating free radical (Z*) and of at least one controlling stable free radical (SFR*) which comprises the indoline nitroxide backbone represented by the formula (I). A is a hydrocarbonaceous chain forming an aromatic ring with the two carbon atoms to which it is attached, this ring being able to carry substituents or being able to carry one or more rings placed side by side, which rings are aromatic or aliphatic and optionally substituted, the carbon atoms forming the nitrogenous ring and in the alpha- and beta-position with respect to the nitrogen atom being, able to carry hydrogen atoms or substituents.
摘要翻译： 在至少一种起始自由基（Z *）和至少一种控制稳定的自由基（SFR *）的存在下，在高压下，通过乙烯的自由基（共）聚合获得聚合物，所述控制稳定的自由基（SFR *）包含由 式（I）.A是形成具有与其连接的两个碳原子的芳香环的烃链，该环能够携带取代基或能够携带一个或多个并排放置的环，该环是 芳族或脂族和任选取代的，形成氮环的碳原子和相对于氮原子的α-和β-位能够携带氢原子或取代基的碳原子。
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5.发明授权公开(公告)号：US06531556B2
公开(公告)日：2003-03-11
申请号：US09767988
申请日：2001-01-23
申请人： Eric Minaux , Lucedio Greci , Michael Buback , Paul Tordo , Thierry Senninger , Pierluigi Stipa , Patricia Carloni , Elisabetta Damiani , Giampaolo Tommasi
发明人： Eric Minaux , Lucedio Greci , Michael Buback , Paul Tordo , Thierry Senninger , Pierluigi Stipa , Patricia Carloni , Elisabetta Damiani , Giampaolo Tommasi
IPC分类号： C08F200
CPC分类号： C08F293/005 , C08F4/00 , C08F10/02 , C08F2438/02 , C08F2/40
摘要： A radical (co)polymerization of ethylene is carried out under high pressure in the presence of at least one initiating free radical (Z•) and of at least one controlling stable free radical (SFR•) which comprises the indoline nitroxide backbone represented by the formula (I). A is a hydrocarbonaceous chain forming an aromatic ring with the two carbon atoms to which it is attached, this ring being able to carry substituents or being able to carry one or more rings placed side by side, which rings are aromatic or aliphatic and optionally substituted, the carbon atoms forming the nitrogenous ring and in the alpha- and beta-position with respect to the nitrogen atom being able to carry hydrogen atoms or substituents.
摘要翻译： 乙烯的自由基（共）聚合在高压下在至少一种起始自由基（Z）和至少一种控制稳定的自由基（SFR）的存在下进行，所述至少一种控制稳定的自由基（SFR）包含由 式（I）.A是形成具有与其连接的两个碳原子的芳香环的烃链，该环能够携带取代基或能够携带一个或多个并排放置的环，该环是芳族的 或脂族和任选取代的，形成氮环的碳原子和相对于能够携带氢原子或取代基的氮原子的α位和β位。
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6.发明授权Process for the preparation of functionalized elastomer/bitumen compositions and their use in coatings 失效功能化弹性体/沥青组合物的制备方法及其在涂料中的应用公开(公告)号：US06218449B1
公开(公告)日：2001-04-17
申请号：US09194705
申请日：1999-04-12
申请人： Jean-Pascal Planche , Paul Maldonado , Bernard Neff , Thierry Senninger , Annie Zins , St{overscore (e)}phane Drouilhet
发明人： Jean-Pascal Planche , Paul Maldonado , Bernard Neff , Thierry Senninger , Annie Zins , St{overscore (e)}phane Drouilhet
IPC分类号： C08L9500
CPC分类号： C10C3/026 , C08G81/022 , C08L95/00 , C08L2666/08 , C08L53/00 , C08L81/00 , C08L25/00
摘要： The invention provides a method comprising contacting, between 100° C. and 230° C. and under agitation, an elastomer, a functionalising agent and optionally, a peroxide compound. The functionalising agent is a thiolcarboxylic acid polyester or a reaction product of a thiolcarboxylic acid or ester with ethylene sulphide. The functionalised elastomer can also be pre-formed, then incorporated into the bitumen. The resulting compositions are usable directly or after dilution, for forming bituminous binders to produce surfacing, coating and waterproofing materials.
摘要翻译： 本发明提供一种方法，包括在100℃和230℃之间和在搅拌下接触弹性体，官能化剂和任选的过氧化物化合物。 官能化剂是硫醇羧酸聚酯或硫醇羧酸或酯与乙烯硫化物的反应产物。 功能化的弹性体也可以预先形成，然后并入沥青中。 所得组合物可直接使用或稀释后使用，用于形成沥青粘合剂以产生表面，涂层和防水材料
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7.发明申请Process for trapping residual monomer with an epoxide functional group in a thermoplastic composition 失效在热塑性组合物中捕获残留单体与环氧官能团的方法公开(公告)号：US20050101733A1
公开(公告)日：2005-05-12
申请号：US11014453
申请日：2004-12-17
申请人： Thierry Senninger
发明人： Thierry Senninger
IPC分类号： C08L23/02 , C08F6/00 , C08F6/20 , C08K3/34 , C08K7/26 , C08L23/08 , C08L23/14 , C08L33/14 , C08L67/02 , C08L39/04
摘要： The invention relates to a process for trapping a free monomer which has not reacted by copolymerization or by grafting comprising at least one epoxide functional group in a thermoplastic composition based on ethylene and/or on propylene and based on at least one monomer comprising at least one epoxide functional group, the said process comprising the following stages: preparation of the said thermoplastic composition, addition of a sufficient amount of a solid trapping additive exhibiting, at its surface, sites with a basic nature within the Lewis or Brönsted meaning. The trapping additive is a porous zeolite, the diameter of the pores of which is between 5 and 15 angströms, preferably between 6 and 13 angströms. The invention also relates to the composition obtained by such a process and to the blends comprising such a composition.
摘要翻译： 本发明涉及一种捕获未在基于乙烯和/或丙烯的热塑性组合物中通过共聚或通过接枝包含至少一个环氧官能团的游离单体的方法，并且基于至少一种包含至少一种 环氧官能团，所述方法包括以下步骤：制备所述热塑性组合物，加入足量的固体捕获添加剂，其表面具有在路易斯或布朗斯台德含义中具有碱性的位点。 捕集添加剂是多孔沸石，孔的直径在5和15埃之间，优选在6和13埃之间。 本发明还涉及通过这种方法获得的组合物和包含这种组合物的共混物。
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公开(公告)号：US06723812B2
公开(公告)日：2004-04-20
申请号：US09963892
申请日：2001-09-26
申请人： Thierry Senninger
发明人： Thierry Senninger
IPC分类号： C08F11418
摘要： The invention relates to a continuous process for the manufacture of PVDF homopolymer or copolymer. The optional comonomer comprises a vinyl group polymerized by free radicals, and comprises at least one fluorine atom, a fluoroalkyl group or a fluoroalkoxy group, directly attached to this vinyl group. The invention also relates to PVDF homopolymers made by processes of the invention. The invention further relates to a process for deoxygenating a flow.
摘要翻译： 本发明涉及用于制造PVDF均聚物或共聚物的连续方法。 任选的共聚单体包括由自由基聚合的乙烯基，并且包含直接连接到该乙烯基上的至少一个氟原子，氟代烷基或氟代烷氧基。 本发明还涉及通过本发明的方法制备的PVDF均聚物。 本发明还涉及一种用于使流动脱氧的方法。
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9.发明授权Process for trapping residual monomer with an epoxide functional group in a thermoplastic composition 失效在热塑性组合物中捕获残留单体与环氧官能团的方法公开(公告)号：US07189779B2
公开(公告)日：2007-03-13
申请号：US11014453
申请日：2004-12-17
申请人： Thierry Senninger
发明人： Thierry Senninger
IPC分类号： C08K3/34
摘要： The invention relates to a process for trapping a free monomer which has not reacted by copolymerization or by grafting comprising at least one epoxide functional group in a thermoplastic composition based on ethylene and/or on propylene and based on at least one monomer comprising at least one epoxide functional group, the said process comprising the following stages:preparation of the said thermoplastic composition,addition of a sufficient amount of a solid trapping additive exhibiting, at its surface, sites with a basic nature within the Lewis or Brönsted meaning.The trapping additive is a porous zeolite, the diameter of the pores of which is between 5 and 15 angströms, preferably between 6 and 13 angströms. The invention also relates to the composition obtained by such a process and to the blends comprising such a composition.
摘要翻译： 本发明涉及一种捕获未在基于乙烯和/或丙烯的热塑性组合物中通过共聚合或通过接枝包含至少一个环氧官能团的游离单体的方法，并且基于至少一种包含至少一种 环氧官能团，所述方法包括以下步骤：制备所述热塑性组合物，加入足量的固体捕获添加剂，其表面具有在路易斯或布朗斯台德含义中具有碱性的位点。 捕集添加剂是多孔沸石，孔的直径在5和15埃之间，优选在6和13埃之间。 本发明还涉及通过这种方法获得的组合物和包含这种组合物的共混物。
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10.发明授权Method for trapping a residual monomer with epoxide function in a thermoplastic composition 失效在热塑性组合物中捕获具有环氧官能团的残余单体的方法公开(公告)号：US06855800B2
公开(公告)日：2005-02-15
申请号：US10239220
申请日：2002-01-22
申请人： Thierry Senninger
发明人： Thierry Senninger
摘要： For trapping a residual monomer containing an expoxide function that has not reacted by copolymerization or by grafting, in a thermoplastic composition based on a copolymer of ethylene and/or propylene, a sufficient amount of an acidic trapping additive is added to remove the residual monomer. The trapping additive is preferably a porous zeolite with a pore diameter of between 2 and 10 angstroms. Improved compositions and blends are thereby obtained.
摘要翻译： 为了捕获在基于乙烯和/或丙烯的共聚物的热塑性组合物中含有没有通过共聚合或接枝反应的过氧化物功能的残余单体，加入足够量的酸性捕获添加剂以除去残留的单体。 捕获添加剂优选为孔径在2至10埃之间的多孔沸石。 从而获得改进的组合物和共混物。
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