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1.发明授权Fischer-Tropsch processes and catalysts made from a material comprising boehmite 有权费 - 托法和由勃姆石构成的材料制成公开(公告)号：US07012104B2
公开(公告)日：2006-03-14
申请号：US10686977
申请日：2003-10-16
IPC分类号： C07C27/00
CPC分类号： C10G2/33 , B01J21/04 , B01J23/74 , B01J23/75 , B01J23/8913 , B01J35/023 , B01J37/0045 , B01J37/0201 , B01J37/0205 , B01J37/0207 , C10G2/331 , C10G2/332
摘要： A hydrothermally-stable catalyst, method for making the same, and process for producing hydrocarbon, wherein the catalyst is used in synthesis gas conversion to hydrocarbons. In one embodiment, the method comprises depositing a compound of a catalytic metal selected from Groups 8, 9, and 10 of the Periodic Table on a support material comprising boehmite to form a composite material; and calcining the composite material to form the catalyst. In other embodiments, the support material comprises synthetic boehmite, natural boehmite, pseudo-boehmite, or combinations thereof.
摘要翻译： 水热稳定催化剂及其制造方法以及烃的制造方法，其中将催化剂用于合成气转化成烃类。 在一个实施方案中，该方法包括将选自周期表第8,9和10族的催化金属的化合物沉积在包含勃姆石的载体材料上以形成复合材料; 并煅烧复合材料以形成催化剂。 在其它实施方案中，载体材料包括合成勃姆石，天然勃姆石，假勃姆石或其组合。
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2.发明授权Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same 有权二氧化硅 - 氧化铝催化剂载体，由其制备的催化剂及其制备和使用方法公开(公告)号：US07541310B2
公开(公告)日：2009-06-02
申请号：US10962702
申请日：2004-10-12
申请人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Kevin L. Coy , James Dale Ortego, Jr. , Nithya Srinivasan , Olga P. Ionkina
发明人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Kevin L. Coy , James Dale Ortego, Jr. , Nithya Srinivasan , Olga P. Ionkina
CPC分类号： B01J21/12 , B01J21/08 , B01J23/75 , B01J23/89 , B01J23/8913 , B01J35/0053 , B01J35/006 , B01J35/0066 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/036 , C10G2/33 , C10G2/332 , C10G2/333
摘要： This invention relates to catalysts comprising a catalytic metal deposited on a composite support with well-dispersed chemical “anchor” species acting as nucleation centers for catalytic metal crystallites growth. The catalysts have the advantage that the average catalytic metal crystallite size can be controlled by the molar ratio of catalytic metal to chemical “anchor,” and is not limited by the porous structure of the support. A preferred embodiment comprises a cobalt-based catalyst on a silica-alumina support made by a co-gel method, wherein its average pore size can be controlled by the pH. The alumina species in the support most likely serve as chemical “anchors” to control the dispersion of cobalt species, such that the average cobalt crystallite size can be greater than the average pore size.
摘要翻译： 本发明涉及包含沉积在复合载体上的催化金属的催化剂，其具有充分分散的作为催化金属微晶生长的成核中心的化学“锚”物质。 催化剂的优点在于，催化金属的平均催化金属粒度可以通过催化金属与化学“锚”的摩尔比来控制，并不受支持体的多孔结构的限制。 优选的实施方案包括在通过共凝胶法制备的二氧化硅 - 氧化铝载体上的钴基催化剂，其中其平均孔径可以由pH控制。 载体中的氧化铝物质最有可能用作化学“锚”以控制钴物质的分散体，使得平均钴微晶尺寸可以大于平均孔径。
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3.发明授权公开(公告)号：US07056955B2
公开(公告)日：2006-06-06
申请号：US10743856
申请日：2003-12-22
申请人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Ajoy P. Raje , Kevin L. Coy , Nithya Srinivasan
发明人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Ajoy P. Raje , Kevin L. Coy , Nithya Srinivasan
IPC分类号： C07C27/00
CPC分类号： B01J21/066 , B01J21/06 , B01J23/78 , B01J23/83 , B01J23/864 , B01J35/0013 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B01J37/03 , B01J37/031 , C10G2/332
摘要： According to a preferred embodiment, the present invention features a bulk catalyst that includes precipitated cobalt metal. The precipitated cobalt catalyst further includes a textural promoter, a binder and optionally a Group I metal. The method of making the catalyst is optimized so as to enhance attrition resistance and improve activity. According to some embodiments, the present catalyst is made by a method that includes one or a combination of: calcination under optimized temperature conditions; exposure to an acidic solution; and addition of a binder to a suspension of a precipitate. According to some embodiments, a Fischer-Tropsch process includes contacting the present catalyst with a feed stream containing carbon monoxide and hydrogen so as to produce hydrocarbons.
摘要翻译： 根据优选实施方案，本发明的特征在于包含沉淀的钴金属的本体催化剂。 沉淀的钴催化剂还包括结构促进剂，粘合剂和任选的第I族金属。 优化催化剂的制造方法，提高耐磨性，提高活性。 根据一些实施方案，本发明的催化剂通过包括以下组合的方法制备：在优化的温度条件下煅烧; 暴露于酸性溶液中; 并将粘合剂加入到沉淀物的悬浮液中。 根据一些实施方案，费 - 托法包括使本催化剂与含有一氧化碳和氢气的进料流接触以产生烃。
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公开(公告)号：US07056857B2
公开(公告)日：2006-06-06
申请号：US10965606
申请日：2004-10-14
CPC分类号： C10G2/33 , B01J23/40 , B01J23/74 , B01J23/89 , B01J23/8913 , B01J37/0205 , B01J37/024 , C10G2/331 , C10G2/332
摘要： A method for making a catalyst is provided that features loading a catalytic metal to a support using at least two different precursor compounds of that said metal; and loading the promoter to the support in an amount effective so as to achieve similar promotion as for a comparable catalyst comprising a greater amount of the promoter using only one precursor compound, where the catalytic metal is selected from among Group 8 metals, 9 metal, Group 10 metals, and combinations thereof. The promoter is preferably boron, silver, a noble metal, or combination thereof. Also provided are catalysts made by the method and Fischer-Tropsch processes that include contacting synthesis gas with a catalyst made by the method.
摘要翻译： 提供一种制备催化剂的方法，其特征在于使用所述金属的至少两种不同的前体化合物将催化金属负载到载体上; 并且将助催化剂以有效的量加载到载体上，以便实现与仅使用一种前体化合物的包含较大量促进剂的可比较催化剂相似的促进剂，其中催化金属选自第8族金属，9金属， 第10族金属及其组合。 促进剂优选为硼，银，贵金属或其组合。 还提供了通过该方法制备的催化剂和费 - 托法，其包括使合成气与通过该方法制备的催化剂接触。
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公开(公告)号：US06822008B2
公开(公告)日：2004-11-23
申请号：US10236759
申请日：2002-09-06
IPC分类号： C07C2700
CPC分类号： C10G2/33 , B01J23/40 , B01J23/74 , B01J23/89 , B01J23/8913 , B01J37/0205 , B01J37/024 , C10G2/331 , C10G2/332
摘要： A method for making a catalyst is provided that features loading a catalytic metal to a support using at least two different precursor compounds of that said metal; and loading the promoter to the support in an amount effective so as to achieve similar promotion as for a comparable catalyst comprising a greater amount of the promoter using only one precursor compound, where the catalytic metal is selected from among Group 8 metals, 9 metal, Group 10 metals, and combinations thereof. The promoter is preferably boron, silver, a noble metal, or combination thereof. Also provided are catalysts made by the method and Fischer-Tropsch processes that include contacting synthesis gas with a catalyst made by the method.
摘要翻译： 提供一种制备催化剂的方法，其特征在于使用所述金属的至少两种不同的前体化合物将催化金属负载到载体上; 并且将助催化剂以有效的量加载到载体上，以便实现与仅使用一种前体化合物的包含较大量促进剂的可比较催化剂相似的促进剂，其中催化金属选自第8族金属，9金属， 第10族金属及其组合。 促进剂优选为硼，银，贵金属或其组合。 还提供了通过该方法制备的催化剂和费 - 托法，其包括使合成气与通过该方法制备的催化剂接触。
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6.发明授权Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using 有权稳定的勃姆石衍生的催化剂载体，催化剂，制备和使用方法公开(公告)号：US07449496B2
公开(公告)日：2008-11-11
申请号：US11875484
申请日：2007-10-19
申请人： Yaming Jin , Kandaswamy Jothimurugesan , Kristi A. Fjare , J. Dale Ortego, Jr. , Beatrice C. Ortego , Rafael L. Espinoza
发明人： Yaming Jin , Kandaswamy Jothimurugesan , Kristi A. Fjare , J. Dale Ortego, Jr. , Beatrice C. Ortego , Rafael L. Espinoza
CPC分类号： B01J37/0207 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/8913 , B01J32/00 , B01J35/006 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B82Y30/00 , C01F7/442 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C10G2/33 , C10G2/332 , C10G2300/70
摘要： A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.
摘要翻译： 具有改进的水热稳定性的稳定的催化剂载体，由其制备的催化剂，以及使用所述催化剂从合成气生产烃的方法。 稳定的载体通过包括处理与至少一种结构稳定剂或其化合物接触的结晶含水氧化铝前体的方法制备。 结晶含水氧化铝前体优选包括平均微晶尺寸，其选自由期望的耐热热性和所需孔隙率限定的最佳范围。 结晶含水氧化铝前体优选包括平均微晶尺寸不同至少约1nm的氧化铝氢氧化物，例如结晶勃姆石，结晶三羟铝石或其多个。 结晶含水氧化铝前体可以在与结构稳定剂或其化合物接触之前或之后成型。 处理包括在450℃或更高温度下煅烧。 优选的结构稳定剂可包括钴，镁，锰，锰，锆，硼，铝，钡，硅，镧，氧化物或其组合。
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公开(公告)号：US07341976B2
公开(公告)日：2008-03-11
申请号：US11114804
申请日：2005-04-26
申请人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Dale Ortego, Jr. , Kristi A. Fjare , Beatrice C. Ortego
发明人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Dale Ortego, Jr. , Kristi A. Fjare , Beatrice C. Ortego
CPC分类号： B01J37/0207 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/8913 , B01J32/00 , B01J35/006 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B82Y30/00 , C01F7/442 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C10G2/33 , C10G2/332 , C10G2300/70
摘要： A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.
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8.发明授权公开(公告)号：US07176160B2
公开(公告)日：2007-02-13
申请号：US10688412
申请日：2003-10-16
CPC分类号： C10G2/332 , B01J21/04 , B01J23/74 , B01J23/75 , B01J23/8913 , B01J37/0045 , B01J37/0201 , B01J37/0205 , B01J37/0207
摘要： A method is provided for forming a highly active Fischer-Tropsch catalyst using boehmite having a particular crystallite size. In this method, a support material comprising boehmite is contacted with a catalytic metal-containing compound to form a catalyst precursor. The boehmite is selected to have an average crystallite size in the range of from about 6 nanometers (nm) to about 30 nm. An alternate embodiment uses a mixture of boehmites with various average crystallite sizes in the range of from about 4 nm to about 30 nm, differing by at least by 1 nm. Subsequently, the catalyst precursor is calcined to convert the boehmite to a stabilized aluminum oxide structure, thereby forming a catalyst support having a good attrition resistance and a relatively high hydrothermal stability.
摘要翻译： 提供了使用具有特定微晶尺寸的勃姆石形成高活性费 - 托催化剂的方法。 在该方法中，将包含勃姆石的载体材料与含催化金属的化合物接触以形成催化剂前体。 勃姆石被选择为具有在约6纳米（nm）至约30nm范围内的平均微晶尺寸。 替代实施例使用具有在约4nm至约30nm范围内的各种平均微晶尺寸的勃氏混合物，至少不同于1nm。 随后，将催化剂前体煅烧以将勃姆石转化为稳定的氧化铝结构，从而形成具有良好耐磨性和较高水热稳定性的催化剂载体。
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公开(公告)号：US07230035B2
公开(公告)日：2007-06-12
申请号：US10747718
申请日：2003-12-29
申请人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Tianyan Niu , Harold A. Wright , Shuibo Xie , Mary E. Wolf
发明人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Tianyan Niu , Harold A. Wright , Shuibo Xie , Mary E. Wolf
CPC分类号： B01J37/0207 , B01J23/63 , B01J23/6567 , B01J35/008 , B01J35/023 , B01J37/08 , B01J37/18 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/062 , C01B2203/1011 , C01B2203/1047 , C01B2203/1064 , C01B2203/1082 , C01B2203/1094 , C01B2203/1247 , C01B2203/80 , Y02P20/52
摘要： The present invention relates to improved catalyst compositions, as well as methods of making and using such compositions to prepare synthesis gas and ultimately C5+ hydrocarbons. In particular, preferred embodiments of the present invention comprise catalyst systems comprising a core and an outer region disposed on said core, wherein a substantial amount of the catalytic metal is located in the outer region of the catalyst support matrix. In addition, the catalyst systems are able to maintain high conversion and selectivity values with very low catalytically active metal loadings. The catalyst systems are appropriate for improved syngas, oxidative dehydrogenation and other partial oxidation reactions, including improved reaction schemes for the conversion of hydrocarbon gas to C5+ hydrocarbons.
摘要翻译： 本发明涉及改进的催化剂组合物，以及制备和使用这些组合物来制备合成气和最终C 5+烃的方法。 特别地，本发明的优选实施方案包括催化剂体系，其包括芯和设置在所述芯上的外部区域，其中大量的催化金属位于催化剂载体基质的外部区域中。 此外，催化剂体系能够以非常低的催化活性金属负载维持高转化率和选择性值。 催化剂体系适合用于改进合成气，氧化脱氢和其它部分氧化反应，包括用于将烃气转化为C 5+烃的改进的反应方案。
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公开(公告)号：US07071239B2
公开(公告)日：2006-07-04
申请号：US10687022
申请日：2003-10-16
申请人： J. Dale Ortego, Jr. , Kandaswamy Jothimurugesan , Rafael L. Espinoza , Kevin L. Coy , Beatrice C. Ortego
发明人： J. Dale Ortego, Jr. , Kandaswamy Jothimurugesan , Rafael L. Espinoza , Kevin L. Coy , Beatrice C. Ortego
IPC分类号： C07C27/00
CPC分类号： B01J37/0207 , B01J21/005 , B01J21/04 , B01J21/06 , B01J21/12 , B01J23/74 , B01J23/8913 , B01J35/1014 , B01J35/1038 , B01J35/1061 , B01J37/0205 , C10G2/332
摘要： A catalyst and method for producing hydrocarbons using a catalyst support having an improved hydrothermal stability, such as under Fischer-Tropsch synthesis conditions. The stabilized support is made by a method comprising treating a boehmite material in contact with at least one structural stabilizer. Contacting the boehmite with at least one structural stabilizer can include forming a mixture comprising the boehmite material and at the least one structural stabilizer. The mixture can be a sol or a slurry. The treating preferably includes drying or spray drying the mixture, and calcining in an oxidizing atmosphere to obtain the stabilized support. Preferred structural stabilizers can include an element, such as cobalt, magnesium, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof; or can include precipitated oxides, such as a co-precipitated silica-alumina.
摘要翻译： 使用具有改进的水热稳定性的催化剂载体来制备烃的催化剂和方法，例如在费 - 托合成条件下。 通过包括处理与至少一种结构稳定剂接触的勃姆石材料的方法制备稳定的载体。 将勃姆石与至少一种结构稳定剂接触可包括形成包含勃姆石材料和至少一种结构稳定剂的混合物。 混合物可以是溶胶或浆料。 处理优选包括干燥或喷雾干燥混合物，并在氧化气氛中煅烧以获得稳定的载体。 优选的结构稳定剂可包括元素，例如钴，镁，锆，硼，铝，钡，硅，镧，氧化物或其组合; 或者可以包括沉淀氧化物，例如共沉淀二氧化硅 - 氧化铝。
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