公开(公告)号：US06685900B2

公开(公告)日：2004-02-03

申请号：US09789718

申请日：2001-02-22

申请人： Rainer Domesle ,  Harald Klein ,  Thomas Kreuzer ,  Egbert Lox

发明人： Rainer Domesle ,  Harald Klein ,  Thomas Kreuzer ,  Egbert Lox

IPC分类号： B01J802

CPC分类号： B01J29/068 ,  B01D53/944 ,  B01D53/945 ,  B01J21/12 ,  B01J23/42 ,  B01J37/0246 ,  B01J37/0248 ,  F01N3/022 ,  F01N3/2803 ,  F01N2370/04 ,  Y02A50/2324 ,  Y02A50/2341 ,  Y02T10/22

摘要： A catalyst for purifying the exhaust gases of diesel engines, which catalyst contains at least one zeolite and, additionally, at least one of the support oxides aluminum oxide, silicon dioxide, titanium dioxide and aluminum silicate and at least one of the noble metals platinum, palladium, rhodium and iridium. In this catalyst the atoms of the noble metals have a mean oxidation number of less than +2.5, on average more than 3 metal ligands and less than 3 oxygen ligands and are present on the zeolites and support oxides in the form of crystallites having a mean particle size of from 1 to 6 nm.

摘要翻译： 一种用于净化柴油发动机废气的催化剂，该催化剂含有至少一种沸石，另外，至少一种载体氧化物氧化铝，二氧化硅，二氧化钛和硅酸铝以及至少一种贵金属铂， 钯，铑和铱。 在该催化剂中，贵金属的原子具有平均氧化数小于+2.5，平均多于3个金属配体和少于3个氧配体，并且存在于沸石和以平均形式存在的微晶形式的载体氧化物上 粒度为1〜6nm。

公开(公告)号：US06342465B1

公开(公告)日：2002-01-29

申请号：US09205280

申请日：1998-12-04

申请人： Harald Klein ,  Jürgen Leyrer ,  Rainer Domesle ,  Egbert Lox ,  Thomas Kreuzer

发明人： Harald Klein ,  Jürgen Leyrer ,  Rainer Domesle ,  Egbert Lox ,  Thomas Kreuzer

IPC分类号： B01J2342

CPC分类号： B01J23/40 ,  B01J37/0248

摘要： A process for preparing a catalyst which has a catalytically active coating of high surface area finely divided materials and catalytically active components on an inert carrier structure. A powder mixture of the finely divided materials used is impregnated with a solution of precursor compounds of the catalytically active components. By suitable combination of the finely divided materials and the precursor compounds and appropriate management of the impregnation process, a highly dispersed deposition and adsorption of the catalytically active components is ensured on the finely divided materials. Then ai aqueous coating dispersion is produced using the impregnated powder mixture and the carrier structure is coated therewith. The coating is then dried and calcined.

摘要翻译： 一种在惰性载体结构上制备具有高表面积细碎材料和催化活性组分的催化活性涂层的催化剂的方法。 所使用的细碎材料的粉末混合物用催化活性组分的前体化合物的溶液浸渍。 通过精细分散的材料和前体化合物的合适组合以及浸渍过程的适当管理，在精细分散的材料上确保高度分散的催化活性组分的沉积和吸附。 然后使用浸渍的粉末混合物制备ai水性涂料分散体，并用其涂覆载体结构。 然后将涂层干燥并煅烧。

公开(公告)号：US20060154816A1

公开(公告)日：2006-07-13

申请号：US10535589

申请日：2003-11-04

申请人： Rainer Domesle ,  Thomas Kreuzer ,  Egbert Lox

发明人： Rainer Domesle ,  Thomas Kreuzer ,  Egbert Lox

IPC分类号： B01J21/04

CPC分类号： B01J37/0018 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/06 ,  B01J37/0217 ,  F01N2250/02 ,  F01N2330/10

摘要： The invention relates to a process for the coating of a catalyst support with a catalytically active coat using a coating dispersion, the catalyst support containing at least two partial structures which differ in their absorptivity for the coating dispersion. The process is characterised in that the absorptivity of the partial structures is modified relative to one another by precoating of the catalyst support with a material which can be burnt out or with liquid, and the catalytic coat is then applied to the filter body in a known manner, dried and/or calcined.

摘要翻译： 本发明涉及一种使用涂料分散体涂覆具有催化活性涂层的催化剂载体的方法，所述催化剂载体含有至少两种对于涂料分散体的吸收率不同的部分结构。 该方法的特征在于，部分结构的吸收率相对于彼此通过用可燃烧或用液体的材料预涂覆催化剂载体而改变，然后将催化涂层以已知的方式施加到过滤器体上 方式，干燥和/或煅烧。

公开(公告)号：US06710014B2

公开(公告)日：2004-03-23

申请号：US09852151

申请日：2001-05-10

申请人： Rainer Domesle ,  Thomas Kreuzer ,  Egbert Lox

发明人： Rainer Domesle ,  Thomas Kreuzer ,  Egbert Lox

IPC分类号： B01J2104

CPC分类号： B01J37/0215 ,  B01J35/04 ,  Y10T29/49345 ,  Y10T428/24149 ,  Y10T428/2982 ,  Y10T428/2991

摘要： A honeycomb body made from a ceramic material with improved radial pressure resistance that is of cylindrical shape and features a first and a second end face and a cylindrical shell and that is traversed from one end face to the other by axially parallel channels formed by channel walls and distributed across the cross section of the honeycomb body in a regular grid pattern, in which design an outer marginal zone of the honeycomb body, the thickness of which amounts to several channel diameters, encloses a central area. The increase in radial pressure resistance of the honeycomb body is achieved by reinforcing the ceramic material of the cylindrical shell and of the channel walls in the outer marginal zone of the honeycomb body by depositing on or in it one or several inorganic substances for the purpose of increasing its mechanical stability.

摘要翻译： 一种由陶瓷材料制成的蜂窝体，其具有圆柱形形状的具有改进的径向耐压性，并且具有第一和第二端面和圆柱形壳体，并且通过由通道壁形成的轴向平行通道从一个端面横向延伸到另一个端面 并且以规则的格栅图案分布在蜂窝体的横截面上，其中设计为蜂窝体的外边缘区域，其厚度相当于几个通道直径，包围中心区域。 蜂窝体的径向耐压性的增加是通过在蜂窝体的外边缘区域中加载陶瓷材料和蜂窝体的外边缘区域中的通道壁来实现的，其中一个或几个无机物质用于 增加其机械稳定性。

公开(公告)号：US06475951B1

公开(公告)日：2002-11-05

申请号：US09513341

申请日：2000-02-25

申请人： Rainer Domesle ,  Ulrich Göbel ,  Lothar Mussmann ,  Egbert Lox ,  Thomas Kreuzer

发明人： Rainer Domesle ,  Ulrich Göbel ,  Lothar Mussmann ,  Egbert Lox ,  Thomas Kreuzer

IPC分类号： B01J2300

CPC分类号： B01D53/945 ,  B01J23/002 ,  B01J23/58 ,  B01J23/63 ,  B01J37/0205 ,  B01J37/0248 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/3712 ,  B01J2523/48

摘要： A powdered catalyst material based on aluminum oxide, which contains at least one basic metal oxide and at least one noble metal from the platinum group of the Periodic Table of Elements in addition to aluminum oxide. The catalyst material is obtainable by loading a support material already stabilized by basic oxides by renewed impregnation with further basic oxides. After drying and calcining this post-impregnated material at temperatures below 800° C., the catalytically active noble metals are also incorporated into the support material by impregnation.

摘要翻译： 基于氧化铝的粉末状催化剂材料，其除了氧化铝之外还含有至少一种碱金属氧化物和至少一种来自元素周期表的铂族的贵金属。 催化剂材料可以通过用另外的碱性氧化物再次浸渍加载已经通过碱性氧化物稳定的载体材料而获得。 在低于800℃的温度下干燥和煅烧该浸渍后材料之后，催化活性的贵金属也通过浸渍掺入载体材料中。

公开(公告)号：US06596056B2

公开(公告)日：2003-07-22

申请号：US09745176

申请日：2000-12-22

申请人： Rainer Domesle ,  Thomas Kreuzer ,  Egbert Lox

发明人： Rainer Domesle ,  Thomas Kreuzer ,  Egbert Lox

IPC分类号： B05D722

CPC分类号： C04B41/009 ,  B01J35/04 ,  B01J37/0217 ,  C04B41/52 ,  C04B2111/0081 ,  C04B2111/00844 ,  F01N3/2828 ,  F01N2260/18 ,  Y10S55/30 ,  Y10T428/24149 ,  C04B41/502 ,  C04B41/4539 ,  C04B41/457 ,  C04B41/50 ,  C04B38/0006

摘要： A process for coating, with a suspension, a ceramic honeycomb body which has a cylindrical shape with two flat end-faces and one jacket, and through which channels parallel to the axis, formed by channel walls, run from one flat end-face to the other, the honeycomb body being coated by suitable processes. The honeycomb body is partially wetted and then coated.

摘要翻译： 一种用悬浮液涂覆陶瓷蜂窝体的方法，陶瓷蜂窝体具有两个平坦的端面和一个护套的圆柱形形状，并且通过通道壁形成的平行于轴线的通道通过该通道从一个平坦的端面延伸到 另一方面，蜂窝体被适当的工艺涂覆。 蜂窝体被部分润湿然后涂覆。

公开(公告)号：US06338831B1

公开(公告)日：2002-01-15

申请号：US09276903

申请日：1999-03-26

申请人： Wolfgang Strehlau ,  Ulrich Göbel ,  Rainer Domesle ,  Egbert Lox ,  Thomas Kreuzer

发明人： Wolfgang Strehlau ,  Ulrich Göbel ,  Rainer Domesle ,  Egbert Lox ,  Thomas Kreuzer

IPC分类号： B01D5350

CPC分类号： B01J20/08 ,  B01D53/508 ,  B01D53/94 ,  B01J20/041 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236

摘要： A sulfur oxide storage material contains a magnesium-aluminum spinel (MgO.Al2O3) and can be used as a so-called “sulfur trap” to remove sulfur oxides from oxygen-containing exhaust gases of industrial processes. In particular, it can be used for the catalytic purification of exhaust gas from internal-combustion engines to remove the sulfur oxides from the exhaust gas in order to protect the exhaust gas catalysts from sulfur poisoning. The material displays a molar ratio of magnesium oxide to aluminum oxide in the range of over 1.1:1, and the magnesium oxide present in stoichiometric excess is homogeneously distributed in a highly disperse form in the storage material.

摘要翻译： 硫氧化物储存材料含有镁 - 铝尖晶石（MgO·Al 2 O 3），并且可以用作所谓的“硫阱”，以从工业过程的含氧废气中除去硫氧化物。 特别地，其可以用于从内燃机排出的废气的催化净化，以从废气中除去硫氧化物，以保护废气催化剂免受硫中毒。 该材料显示氧化铝与氧化铝的摩尔比在1.1:1以上，以化学计量过量存在的氧化镁以高分散形式均匀地分布在储存材料中。

公开(公告)号：US06220022B1

公开(公告)日：2001-04-24

申请号：US09180112

申请日：1999-08-04

申请人： Wilfried Müller ,  Jürgen Leyrer ,  Rainer Domesle ,  Klaus Ostgathe ,  Egbert Lox ,  Thomas Kreuzer

发明人： Wilfried Müller ,  Jürgen Leyrer ,  Rainer Domesle ,  Klaus Ostgathe ,  Egbert Lox ,  Thomas Kreuzer

IPC分类号： F01N310

CPC分类号： B01D53/9454 ,  Y02T10/22

摘要： A catalyst system for the treatment of exhaust gases from a diesel engine includes a first and a second catalyst reducing catalyst arranged in series in an exhaust gas treatment system. The first catalyst is located near the engine in a region of the exhaust gas treatment system in which the exhaust gas temperature reaches temperatures of more than 200° C. under full engine load. The second catalyst is located further from the engine in a region of the exhaust gas treatment system in which the exhaust gas temperature reaches a maximum of 500° C. under full engine load. The maximum nitrogen oxides reduction in the first catalyst takes place at a lower temperature than the maximum nitrogen oxides reduction in the second catalyst.

摘要翻译： 用于处理来自柴油发动机的废气的催化剂系统包括在废气处理系统中串联布置的第一和第二催化剂还原催化剂。 第一催化剂位于排气处理系统的区域内的发动机附近，其中在全发动机负荷下，废气温度达到超过200℃的温度。 第二催化剂在排气处理系统的一个区域内比发动机更远，其中在全发动机负荷下废气温度达到最大值500℃。 第一催化剂中的最大氮氧化物还原在比第二催化剂中的最大氮氧化物还原更低的温度下进行。

公开(公告)号：US07811969B2

公开(公告)日：2010-10-12

申请号：US10535589

申请日：2003-11-04

申请人： Rainer Domesle ,  Thomas Kreuzer ,  Egbert Lox

发明人： Rainer Domesle ,  Thomas Kreuzer ,  Egbert Lox

IPC分类号： B01J21/04

CPC分类号： B01J37/0018 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/06 ,  B01J37/0217 ,  F01N2250/02 ,  F01N2330/10

摘要： The invention relates to a process for the coating of a catalyst support with a catalytically active coat using a coating dispersion, the catalyst support containing at least two partial structures which differ in their absorptivity for the coating dispersion. The process is characterized in that the absorptivity of the partial structures is modified relative to one another by precoating of the catalyst support with a material which can be burnt out or with liquid, and the catalytic coat is then applied to the filter body in a known manner, dried and/or calcined.

摘要翻译： 本发明涉及一种使用涂料分散体涂覆具有催化活性涂层的催化剂载体的方法，所述催化剂载体含有至少两种对于涂料分散体的吸收率不同的部分结构。 该方法的特征在于，部分结构的吸收率相对于彼此通过用可燃烧或用液体的材料预涂覆催化剂载体而改变，然后将催化涂层以已知的方式施加到过滤器体上 方式，干燥和/或煅烧。

公开(公告)号：US5928981A

公开(公告)日：1999-07-27

申请号：US838846

申请日：1997-04-11

申请人： Jurgen Leyrer ,  Dieter Lindner ,  Egbert Lox ,  Thomas Kreuzer ,  Wilfried Muller ,  Rainer Domesle

发明人： Jurgen Leyrer ,  Dieter Lindner ,  Egbert Lox ,  Thomas Kreuzer ,  Wilfried Muller ,  Rainer Domesle

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J29/03 ,  B01J29/068 ,  B01J29/08 ,  B01J29/40 ,  B01J29/44 ,  B01J29/80 ,  B01J29/06 ,  B01J8/00 ,  B01J29/22

CPC分类号： B01D53/945 ,  B01J29/068 ,  B01J29/80 ,  B01J2229/16 ,  B01J29/084 ,  B01J29/40 ,  Y02T10/22

摘要： A catalyst for purifying the exhaust gases from diesel engines. The catalyst contains a zeolite mixture of several zeolites with different moduli and platinum group metals as well as further metal oxides from the group aluminum silicate, aluminum oxide and titanium oxide, wherein the aluminum silicate has a ratio by weight of silicon dioxide to aluminum oxide of 0.005 to 1 and the platinum group metals are deposited on only the further metal oxides.

摘要翻译： 用于净化柴油发动机废气的催化剂。 催化剂含有具有不同模量和铂族金属的几种沸石以及来自硅酸铝，氧化铝和氧化钛的其它金属氧化物的沸石混合物，其中硅酸铝的二氧化硅与氧化铝的重量比 0.005至1，并且铂族金属仅沉积在另外的金属氧化物上。