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    Alkoxyalkylaminotriazine trans-etherification products
    1.
    发明授权
    Alkoxyalkylaminotriazine trans-etherification products 失效
    烷氧基烷基氨基三嗪反醚化产物

    公开(公告)号：US4393207A

    公开(公告)日：1983-07-12

    申请号：US279586

    申请日：1981-07-01

    申请人： Rainer Hummerich ,  Wolfram Weiss ,  Franz Merger ,  Guenther Immel ,  Hans-Joachim Kraus ,  Karl-Clemens Peters

    发明人： Rainer Hummerich ,  Wolfram Weiss ,  Franz Merger ,  Guenther Immel ,  Hans-Joachim Kraus ,  Karl-Clemens Peters

    IPC分类号： C07D251/18 ,  C07D251/64 ,  C08G12/42 ,  C09D161/32 ,  C07D251/70

    CPC分类号： C09D161/32 ,  C07D251/18 ,  C07D251/64 ,  C08G12/425

    摘要： Alkoxyalkylaminotriazine trans-etherification products are obtained by reacting an alkoxyalkylaminotriazine of the general formula ##STR1## where X is hydrogen, alkyl, phenyl, alkylphenyl or ##STR2## A and B are hydrogen, alkyl, alkenyl or ##STR3## and R and R' are hydrogen or alkyl, with from 0.1 to 6 moles, per mole of alkoxyalkylaminotriazine, of a .beta.-hydroxyaldehyde of the general formula ##STR4## where R", R"' and R"" are identical or different and each is hydrogen or alkyl or R"' and R"" together with the .alpha.-carbon atom form a cyclopentane or cyclohexane ring, and R"' and/or R"" can also be hydroxyalkyl and R"" can also be phenyl, in the presence of an acidic catalyst, and removing the alcohol resulting from the trans-etherification. The alkoxyalkylaminotriazine trans-etherification products may be used in baking finishes and acid-hardening surface coatings.

    摘要翻译： 烷氧基烷基氨基三嗪反醚化产物是通过使通式（I）的烷氧基​​烷基氨基三嗪（X）为氢，烷基，苯基，烷基苯基或者A，B为氢，烷基，链烯基或者R 和R'是氢或烷基，每摩尔烷氧基烷基氨基三嗪具有0.1至6摩尔的通式为“IMAGE”的β-羟基醛，其中R“，R”和R“”相同或 不同的是氢或烷基或R“和R”与α-碳原子一起形成环戊烷或环己烷环，R“和/或R”'也可以是羟烷基和 在酸性催化剂的存在下，R“也可以是苯基，并除去由反式醚化产生的醇。 烷氧基烷基氨基三嗪反醚化产物可用于烘烤整理剂和酸硬化表面涂料。

    Preparation of aminoplast resins
    2.
    发明授权
    Preparation of aminoplast resins 失效
    氨基塑料树脂的制备

    公开(公告)号：US4387212A

    公开(公告)日：1983-06-07

    申请号：US420318

    申请日：1982-09-20

    申请人： Rainer Hummerich ,  Herbert Hahn ,  Wolfram Weiss ,  Guenther Immel ,  Hans-Joachim Krause ,  Karl-Clemens Peters

    发明人： Rainer Hummerich ,  Herbert Hahn ,  Wolfram Weiss ,  Guenther Immel ,  Hans-Joachim Krause ,  Karl-Clemens Peters

    IPC分类号： C08G12/30 ,  C08G12/32 ,  C08G12/42 ,  C08G4/00 ,  C08G12/00

    CPC分类号： C08G12/30 ,  C08G12/32 ,  C08G12/425

    摘要： A process for the preparation of etherified or non-etherified aminoplast resins, wherein an aminotriazine of the general formula (I) ##STR1## where X is hydrogen, alkyl, phenyl, alkylphenyl or --NH.sub.2, is reacted with a .beta.-hydroxyaldehyde of the general formula (II) ##STR2## where R', R" and R'" are identical or different and each is hydrogen or alkyl, or R" and R'", together with the .alpha.-carbon atom, are a cyclopentane or cyclohexane ring, and R" and/or R'" can be hydroxyalkyl and R" can be phenyl, the reaction being carried out in the presence of not less than one alcohol and an acid catalyst for the preparation of etherified aminoplast resins and in the presence or absence of an acid catalyst for the preparation of non-etherified aminoplast resins. The aminoplast resins prepared according to the invention can be used as surface-coatings raw materials.

    摘要翻译： 用于制备醚化或非醚化的氨基塑料树脂的方法，其中X为氢，烷基，苯基，烷基苯基或-NH 2的通式（I）的氨基三嗪与β - 通式（II）的羟醛通式（II）其中R'，R“和R”'相同或不同，各自为氢或烷基，或R“和R”'连同 α-碳原子是环戊烷或环己烷环，R“和/或R”可以是羟烷基，R“可以是苯基，该反应在不少于一个醇和 用于制备醚化氨基塑料树脂的酸催化剂和用于制备非醚化氨基塑料树脂的酸催化剂存在或不存在。 根据本发明制备的氨基塑料树脂可用作表面涂料原料。

    Aqueous formulations suitable as sealing compounds of adhesives for ceramic tiles
    5.
    发明授权
    Aqueous formulations suitable as sealing compounds of adhesives for ceramic tiles 失效
    适用于陶瓷胶粘剂密封化合物的水性配方

    公开(公告)号：US5100948A

    公开(公告)日：1992-03-31

    申请号：US545118

    申请日：1990-06-27

    申请人： Oral Aydin ,  Rainer Hummerich ,  Joachim Krobb ,  Michael Portugall ,  Falko Ramsteiner ,  Albrecht Zosel

    发明人： Oral Aydin ,  Rainer Hummerich ,  Joachim Krobb ,  Michael Portugall ,  Falko Ramsteiner ,  Albrecht Zosel

    IPC分类号： C08J3/03 ,  C08F2/24 ,  C09J11/00 ,  C09J11/06 ,  C09J133/06 ,  C09J143/04 ,  C09J157/00 ,  C09J201/00 ,  C09K3/10

    CPC分类号： C09J143/04 ,  C09J133/06

    摘要： Aqueous formulations suitable as sealing compounds or adhesives for ceramic tiles essentially containA) from 3 to 30% by weight of plastics particles which consist ofa) from 0.1 to 4% by weight of one or more mercaptosilanes of the general formula I ##STR1## where n is from 1 to 8, R.sup.1 and R.sup.2 are hydrogen and/or C.sub.1 -C.sub.4 -alkyl, R.sup.3, R.sup.4 and R.sup.5 are C.sub.1 -C.sub.6 -alkyl and/or C.sub.1 -C.sub.6 -alkoxy, with the proviso that one or more of the radicals R.sup.3 to R.sup.5 is alkoxy, andb) ethylenically unsaturated monomers capable of undergoing free radical polymerization, as the residual amount, the polymer having a glass transition temperature of from -60 to +40.degree. C.,B) from 40 to 90% by weight of an inorganic filler,C) an effective amount of an emulsifier,D) from 0 to 15% by weight external plasticizer andE) from 5 to 40% by weight of water.

    摘要翻译： 适合用作陶瓷砖的密封化合物或粘合剂的水性制剂基本上含有A）3至30重量％的塑料颗粒，其由以下组成：a）0.1至4重量％的一种或多种通式I的巯基硅烷， 其中n为1至8，R 1和R 2为氢和/或C 1 -C 4烷基，R 3，R 4和R 5为C 1 -C 6 - 烷基和/或C 1 -C 6 - 烷氧基，条件是一个或多个 的基团R 3至R 5为烷氧基，b）能够进行自由基聚合的烯属不饱和单体作为剩余量，聚合物的玻璃化转变温度为-60至+ 40℃，B）为40至 无机填料的90重量％，C）有效量的乳化剂，D）0〜15重量％的外用增塑剂，E）5〜40重量％的水。

    Polyurethane adhesive mixtures
    6.
    发明授权
    Polyurethane adhesive mixtures 失效
    聚氨酯胶粘剂混合物

    公开(公告)号：US4731410A

    公开(公告)日：1988-03-15

    申请号：US881244

    申请日：1986-07-02

    申请人： Uwe Bueltjer ,  Rainer Hummerich ,  Michael Kerber

    发明人： Uwe Bueltjer ,  Rainer Hummerich ,  Michael Kerber

    IPC分类号： C08G18/76 ,  C09J175/06 ,  C08G18/66 ,  C08L75/06

    CPC分类号： C08G18/7671 ,  C09J175/06 ,  C08G2170/20

    摘要： Polyurethane adhesive mixtures or polyurethane adhesive solutions contain(a) a polyurethane elastomer which advantageously has a mean molecular weight of not less than 30,000 and which is prepared by reacting(i) one or more essentially linear polyesterpolyols and(ii) one or more chain extenders with(iii) a mixture of 4,4'- and 2,4'-diphenylmethane diisocyanate isomers in a weight ratio of from 60:40 to 40:60 and(b) if appropriate, additives and/or organic solvents.

    摘要翻译： 聚氨酯粘合剂混合物或聚氨酯粘合剂溶液包含（a）有利地具有不小于30,000的平均分子量的聚氨酯弹性体，其通过（i）一种或多种基本上线性的聚酯多元醇和（ii）一种或多种扩链剂 与（iii）重量比为60:40至40:60的4,4'-和2,4'-二苯基甲烷二异氰酸酯异构体的混合物和（b）如果合适的话，添加剂和/或有机溶剂。

    Formaldehyde-free binding, impregnating or coating compositions for fibrous sheet materials
    8.
    发明授权
    Formaldehyde-free binding, impregnating or coating compositions for fibrous sheet materials 失效
    用于纤维片材的无甲醛结合，浸渍或涂料组合物

    公开(公告)号：US5536766A

    公开(公告)日：1996-07-16

    申请号：US404578

    申请日：1995-03-15

    申请人： Hermann Seyffer ,  Robert Rupaner ,  Erhard Gunther ,  Rainer Hummerich

    发明人： Hermann Seyffer ,  Robert Rupaner ,  Erhard Gunther ,  Rainer Hummerich

    IPC分类号： C08L33/00 ,  C08G65/333 ,  C08K5/04 ,  C08L33/02 ,  C08L35/00 ,  D04H1/4209 ,  D04H1/4218 ,  D04H1/435 ,  D04H1/587 ,  D04H1/645 ,  D06M13/148 ,  D06M13/152 ,  D06M13/358 ,  D06M15/263 ,  D06N3/04 ,  D06N5/00 ,  H01M2/16 ,  C08K5/34

    CPC分类号： D04H1/645 ,  C08G65/33317 ,  C08K5/04 ,  D04H1/4209 ,  D04H1/4218 ,  D04H1/435 ,  D04H1/587 ,  D06M13/148 ,  D06M13/152 ,  D06M13/358 ,  D06M15/263 ,  D06N3/04 ,  D06N3/042

    摘要： A formaldehyde-free binding, impregnating or coating composition comprisesA) a polymer constituted to from 2 to 100% by weight of an ethylenically unsaturated acid or anhydride as comonomer, andB) at least one polyol selected froma triazine of the formula ##STR1## where R.sup.1 to R.sup.3 are each independently of the others a radical X[(C.sub.m H.sub.2m O).sub.n H] or N[(C.sub.m H.sub.2m O).sub.n H].sub.2 where X is NH, O or S, m is from 2 to 5 and n is from 1 to 10,a triazinetrione of the formula ##STR2## where R.sup.4 to R.sup.6 are each independently of the others a radical [(C.sub.m H.sub.2m O).sub.n H] where m is from 2 to 5 and n is from 1 to 10,a benzene or cyclohexyl derivative of the formula ##STR3## where R.sup.7 to R.sup.9 are each independently of the others a radical [X(C.sub.m H.sub.2m O).sub.n H], a radical N[C.sub.m H.sub.2m O).sub.n H].sub.2, a radical [Y(C.sub.m H.sub.2m O).sub.n H] or a radical [(C.sub.m H.sub.2m O).sub.n H] where X is NH, O or S, Y is bivalent C.sub.1 -C.sub.6 -alkyl or acyl, m is from 2 to 5 and n is from 1 to 10, anda compound of the formula ##STR4## where R.sup.10 to R.sup.12 are each independently of the others a linear or branched, aliphatic or aromatic radical which has a total of from 1 to 12 carbon atoms and which may also contain ether groups and carries at least one hydroxyl group, and Z is N, PO.sub.3, BO.sub.3, PO.sub.4 or C--R.sup.13, where R.sup.13 is a linear or branched, substituted or unsubstituted alkyl or aryl radical having up to 10 carbon atoms.

    摘要翻译： 无甲醛结合，浸渍或涂料组合物包含A）构成2至100重量％的作为共聚单体的烯属不饱和酸或酸酐的聚合物，和B）至少一种选自下式的三嗪的多元醇 >其中R1至R3各自独立地为基团X [（CmH2mO）nH]或N [（CmH2mO）nH] 2，其中X为NH，O或S，m为2至5，n为1 式（10）表示的化合物，其中R 4至R 6各自独立地为基团[（C m H 2 m O）n H]，其中m为2至5且n为1至10的三嗪三酮，苯或环己基衍生物 式[X（C m H 2 m O）n H]，基团N [C m H 2 m O] n H] 2，基团[Y（C m H 2 m O）n H]或基团[（C m H 2 m O）n H] ，O或S中，Y为二价C 1 -C 6 - 烷基或酰基，m为2至5，n为1至10，并且其中R 10至R 12各自独立地为其中的化合物 直链或支链，脂族或 总共具有1至12个碳原子并且还可以含有醚基并带有至少一个羟基的芳基，Z是N，PO 3，BO 3，PO 4或C-R 13，其中R 13是直链或支链 具有至多10个碳原子的取代或未取代的烷基或芳基。

    Aqueous polyurethane adhesive dispersions
    9.
    发明授权
    Aqueous polyurethane adhesive dispersions 失效
    水性聚氨酯胶粘剂分散体

    公开(公告)号：US4861826A

    公开(公告)日：1989-08-29

    申请号：US133378

    申请日：1987-12-15

    申请人： Rainer Hummerich ,  Michael Kerber ,  Lothar Maempel ,  Peter Weyland

    发明人： Rainer Hummerich ,  Michael Kerber ,  Lothar Maempel ,  Peter Weyland

    IPC分类号： C08G18/66 ,  C08G18/00 ,  C08G18/08 ,  C08G18/28 ,  C08G18/65 ,  C08L75/04 ,  C09J175/00 ,  C09J175/04

    CPC分类号： C08G18/283 ,  C08G18/0804 ,  C09J175/04 ,  C08G2170/80 ,  C08G2170/90

    摘要： Aqueous dispersions of polyurethanes consisting of(a) organic polyisocyanates,(b) polyesterpolyols having a molecular weight of from 500 to 5,000,(c) organic hydroxy compounds having a molecular weight of from 62 to 400 and two terminal groups which are reactive to isocyanate groups, as chain extenders, and(d) compounds containing ionic groups or groups which can be converted to ionic groups and one or more isocyanate groups or a hydroxyl or amino group which is reactive to isocyanate groups,which contain from 0.05 to 2 meq of ionic groups incorporated into the polyurethane via (d) per g of polyurethane are particularly suitable for adhesives when the chain extenders (c) are incorporated in an amount of from 1.5 to 8 moles per mole of polyols, and a minor amount of (a) can be replaced with monoisocyanates, and a minor amount of (b) with polyetherpolyols.

    摘要翻译： 由（a）有机多异氰酸酯，（b）分子量为500〜5000的聚酯多元醇组成的聚氨酯的水分散体，（c）分子量为62〜400的有机羟基化合物和与异氰酸酯反应的两个端基 基团，作为扩链剂，和（d）可以转化为离子基团和一个或多个异氰酸酯基团或与异氰酸酯基团反应的羟基或氨基的离子基团或基团的化合物，其含有0.05至2meq 通过（d）每g聚氨酯掺入聚氨酯中的离子基团特别适用于粘合剂，当增链剂（c）以每摩尔多元醇1.5至8摩尔的量加入时，少量的（a） 可以用单异氰酸酯代替，和少量的（b）与聚醚多元醇。