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公开(公告)号：US5324817A
公开(公告)日：1994-06-28
申请号：US63396
申请日：1993-05-18
CPC分类号： C08F8/26
摘要： The present invention relates to a process for dehydrochlorinating polyvinylchloride polymers to remove about 30 wt % chlorine therefrom by heating the starting materials PVC and deoxygenated liquid water, preferably neutral liquid water at temperatures from about 200.degree. C. up to the critical temperature of water at autogenous pressure to maintain the water as a liquid phase. The process has utility in recycling by enabling PVC to be dechlorinated specifically by a means that does not release chlorine gas.
摘要翻译： 本发明涉及通过将起始材料PVC和脱氧液体水（优选中性液体水）在约200℃至约临界温度的温度下加热来除去约30重量％氯的氯乙烯聚合物脱氯化氢的方法 自发压力保持水为液相。 该方法可以通过使PVC不特别地通过不释放氯气的方式脱氯来实现再循环。
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公开(公告)号：US5312898A
公开(公告)日：1994-05-17
申请号：US812250
申请日：1991-12-20
CPC分类号： C08F8/50
摘要： The present invention relates to a process for depolymerizing polyacrylonitrile into water soluble by-products, including ammonia and lower molecular weight carbonaceous materials by contacting the starting materials, polyacrylonitrile, and neutral, hot liquid water at a temperature from about 200.degree. C. up to the critical temperature of water at autogenous pressure. The present invention has utility as a means for degrading polyacrylonitrile without producing toxic hydrogen cyanide as a by-product.
摘要翻译： 本发明涉及通过使原料，聚丙烯腈和中性热液体水在约200℃至约200℃的温度下接触将聚丙烯腈解聚为水溶性副产物，包括氨和低分子量碳质材料的方法， 自生压力下水的临界温度。 本发明作为用于降解聚丙烯腈而不产生有毒的氰化氢作为副产物的方法是有用的。
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公开(公告)号：US5403964A
公开(公告)日：1995-04-04
申请号：US187672
申请日：1994-01-27
摘要： The present invention relates to enhanced process for converting certain ethers, such as sec-butyl ether and isopropyl ether to their corresponding reaction products in the presence of water. This may be accomplished by adding a rate enhancing surfactant, such as an anionic or cationic surfactant to a mixture of the ether and water, preferably least about 10.sup.-5 molar surfactant. Under those conditions the reaction shows an increase in reaction rate over the rate of the process wherein surfactant is not used.
摘要翻译： 本发明涉及在水存在下将某些醚如仲丁醚和异丙醚转化成其相应的反应产物的增强方法。 这可以通过将速率增强表面活性剂例如阴离子或阳离子表面活性剂加入到醚和水的混合物中，优选至少约10-5摩尔表面活性剂来实现。 在这些条件下，该反应显示反应速率相对于不使用表面活性剂的方法的速率增加。
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4.发明授权Process for depolymerization of butyl rubbers and halobutyl rubbers using hot liquid water 失效使用热液体水解丁基橡胶和卤代丁基橡胶的方法
公开(公告)号：US5283318A
公开(公告)日：1994-02-01
申请号：US812175
申请日：1991-12-20
申请人： Ramzi Y. Saleh , Michael Siskin , George Knudsen
发明人： Ramzi Y. Saleh , Michael Siskin , George Knudsen
摘要： The present invention relates to a process for depolymerizing and dehalogenating rubber materials by heating the rubber materials with neutral liquid water at temperatures from about 200.degree. C. up to the critical temperature of water at autogenous pressure. The process has utility in degrading rubber materials, and further does not release hydrogen halogen into a gas phase.
摘要翻译： 本发明涉及一种通过在约200℃至约自然压力的水临界温度的温度下用中性液体水加热橡胶材料来解聚和脱卤橡胶材料的方法。 该方法可用于降解橡胶材料，并且不会将氢卤素释放到气相中。
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公开(公告)号：US5453561A
公开(公告)日：1995-09-26
申请号：US187673
申请日：1994-01-27
摘要： The invention concerns a method for reactive separation of mixtures containing hydrocarbons and oxygenated hydrocarbons, by contacting a mixture of hydrocarbons such as C.sub.2 to C.sub.26 hydrocarbons and mixtures thereof and oxygenated hydrocarbons, such as C.sub.2 to C.sub.40 oxygenated hydrocarbons and mixtures thereof to form a mixture of hydrocarbons and lower molecular weight oxygenated hydrocarbons and heating the mixture in water at temperature typically from about and pressure sufficient to cleave the oxygenated hydrocarbons to lower molecular weight products to form a liquid layer containing water soluble reaction products and an organic layer containing primarily hydrocarbons.
摘要翻译： 本发明涉及通过使烃类混合物例如C 2至C 26烃及其混合物和含氧烃如C2至C40含氧烃及其混合物的混合物与烃和氧化烃的混合物进行反应分离的方法，以形成混合物 碳氢化合物和较低分子量的氧化烃，并将混合物在水中加热，其温度通常为足以将氧化烃切割成较低分子量产物的温度，形成含有水溶性反应产物和主要含有烃的有机层的液体层。
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公开(公告)号：US5043486A
公开(公告)日：1991-08-27
申请号：US572485
申请日：1990-08-23
CPC分类号： C07C29/10
摘要： The present invention provides for a simplified process for converting ethers into their corresponding alcohols comprising forming an aqueous mixture of the ether and at least about 50% by weight water and heating the mixture under autogeneous pressure at a temperature of from about 250.degree. to 450.degree. C., more preferably from about 250.degree. C. up to the critical temperature of water which is about 374.degree. C. Heating is continued for a period of time sufficient to convert at least about 20% by weight of the ether, usually from about 5 up to about 120 minutes, depending on temperature and the amount of water present, and the identity of the starting ether feedstock.The process may be characterized as an aquathermolysis reaction wherein the reaction proceeds in water primarily through ionic routes rather than through free radical routes. Accordingly, relatively high conversion rates and good yields of alcohol and other reaction by-products may be obtained without the necessity of using a catalyst in the process.
摘要翻译： 本发明提供了将醚转化成其相应的醇的简化方法，包括形成醚的水性混合物和至少约50重量％的水，并在约250-450℃的温度下在自主压力下加热混合物 更优选约250℃至约374℃的水的临界温度。继续加热足够的时间以使至少约20重量％的乙醚转化成通常为约 5至约120分钟，这取决于温度和存在的水的量以及起始醚原料的特性。 该方法可以表征为水解溶解反应，其中反应在水中主要通过离子路线而不是通过自由基途径进行。 因此，可以获得醇和其它反应副产物的相对高的转化率和良好的产率，而不需要在该方法中使用催化剂。
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公开(公告)号：US09707512B2
公开(公告)日：2017-07-18
申请号：US14085999
申请日：2013-11-21
申请人： Pavel Kortunov , Michael Siskin
发明人： Pavel Kortunov , Michael Siskin
CPC分类号： B01D53/62 , B01D53/1475 , B01D2252/20431 , B01D2252/602 , B01D2257/504 , C10L3/104 , C10L2290/541 , Y02C10/04 , Y02C10/06
摘要： Promoter amines are used to enhance CO2 uptake by sterically hindered or tertiary amines. The promoter amines can be cyclic amines, including aromatic cyclic amines or bridged cyclic amines. The combination of a promoter amine plus a sterically hindered or tertiary amines allows for improved uptake kinetics while reducing or minimizing the amount of formation of carbamate salts. The promoted sterically hindered or tertiary amines can be used as part of a CO2 capture and release system that involves a phase transition from a solution of amine-CO2 products to a slurry of amine-CO2 precipitate solids.
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公开(公告)号：US09458367B2
公开(公告)日：2016-10-04
申请号：US13793298
申请日：2013-03-11
CPC分类号： C09K3/00 , B01D53/1468 , B01D53/1493 , B01D2252/103 , B01D2252/2023 , B01D2252/2025 , B01D2252/204 , B01D2252/504 , B01D2252/60 , Y10T137/0391
摘要： A liquid aminoether acid gas absorbent which is subject to freezing in a cold climatic zone though which the aminoether is to be shipped is rendered freeze-resistant by mixing the aminoether with water prior to transport through the cold climatic zone; the aminoether/water mixture typically contains 10 to 40 weight percent water, based on the weight of the aminoether. The aminoether/water mixture can also be stored in the cold climatic zone without being externally maintained at a temperature above the inherent freezing point of the aminoether.
摘要翻译： 在运输氨基醚的寒冷气候区域内要冷冻的液体氨基醚酸吸收剂在通过冷气候区域运输之前通过混合氨基醚与水而变成抗冻性; 基于氨基醚的重量，氨基醚/水混合物通常含有10至40重量％的水。 氨基醚/水混合物也可以储存在寒冷气候区，而不会外部保持在高于氨基醚固有凝固点的温度。
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9.发明授权公开(公告)号：US09186618B2
公开(公告)日：2015-11-17
申请号：US13228734
申请日：2011-09-09
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： Ionic liquids are capable of acting as solvents for amine CO2 absorbent compounds in CO2 separation processes and when so used enhance the sorption of the CO2 by the amine. A cyclic sorption process for separating CO2 from a gas stream, such as flue gas or natural gas, brings the gas stream into contact with an absorbent solution of an amine CO2 sorbent in an ionic liquid solvent followed by desorbing the CO2 to regenerate the amine.
摘要翻译： 离子液体能够作为二氧化碳分离过程中胺二氧化碳吸收剂化合物的溶剂，当这样使用时，胺可以增强二氧化碳的吸附。 用于从气流（例如废气或天然气）中分离CO 2的循环吸附方法使气流与胺CO 2吸附剂在离子液体溶剂中的吸收剂溶液接触，然后解吸CO 2以再生胺。
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公开(公告)号：US20140255250A1
公开(公告)日：2014-09-11
申请号：US14285686
申请日：2014-05-23
IPC分类号： C23F11/14
CPC分类号： C23F11/146 , C23F11/141 , F22B1/00 , F22B37/025
摘要： Aminoethers are used as corrosion inhibitors in boiler systems in which a working fluid comprising water with an aminoether corrosion inhibitor is circulated from a heater to a utilization site at which the working fluid gives up energy and decreases in temperature. A preferred class of aminoethers are the alkoxytriethyleneglycol-tert-alkylamines such as methoxy triethyleneglycol-tert-butylamine
摘要翻译： 氨基醚用作锅炉系统中的腐蚀抑制剂，其中包含水与氨基醚腐蚀抑制剂的工作流体从加热器循环到工作流体释放能量并降低温度的使用场所。 优选的氨基醚类是烷氧基三乙二醇 - 叔烷基胺，例如甲氧基三乙二醇 - 叔丁胺
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