摘要:
Microcapsules containing a color-forming material and a solvent therefor, the solvent being a mixture of certain oligomeric isomers of benzylcumene and its higher homologues and a mixture of isomers of bis(isopropylphenyl) phenylmethane.
摘要:
A process for separating dichlorotoluene isomers from a mixture containing at least two dichlorotoluene isomers comprising(a) passing said mixture containing dichlorotoluene isomers through a mordenite having the following composition; in molar ratios:a H.sub.2 O: b M.sub.2/n O: Al.sub.2 O.sub.3 : (10-400 SiO.sub.2) in which M is hydrogen or at least one cation selected from an alkali metal or an alkaline-earth metal with the exception of cesium and rubidium, n is the valence of M, 0.7.ltoreq.a+b.ltoreq.1.1, and 0.ltoreq.b.ltoreq.0.2,(b) separating the non-adsorbed dichlorotoluenes from said mordenite,(c) contacting said mordenite containing the adsorbed isomers with a desorbent capable of separating said isomers from said mordenite, and(d) separating the desorbed isomers from the desorbent.
摘要翻译:一种从含有至少两种二氯甲苯异构体的混合物中分离二氯甲苯异构体的方法,包括:(a)使含有二氯甲苯异构体的混合物通过具有以下组成的丝光沸石; 摩尔比:H 2 O:b M2 / nO:Al 2 O 3:(10-400SiO 2)其中M是氢或至少一种选自碱金属或碱土金属的阳离子,铯和铷除外,n 是M的化合价,0.7≤a+ b = 1.1,0≤b≤0.2,(b)从所述丝光沸石中分离未吸附的二氯甲苯,(c)使含有 具有能够从所述丝光沸石分离所述异构体的解吸剂的吸附异构体,和(d)从解吸剂中分离解吸的异构体。
摘要:
Polyarylalkane oligomer compositions consisting essentially of a mixture of isomers of xylyl-xylene and of higher homologues and a mixture of isomers of bis(dimethylphenyl)xylylene and of higher homologues; the method of making such compositions by first reacting toluene, xylene, or a mixture of toluene and xylene with chlorine in the presence of a radical generator, removing the unreacted toluene, and then subjecting the reaction product to the action of an inorganic halide or inorganic acid in the presence of xylene, and microcapsules containing color-forming material wherein the compositions are used as solvents for the color-forming material.
摘要:
Polyarylalkane oligomer compositions containing essentially of a mixture of isomers of benzylcumene and its higher homologues and a mixture of isomers of bis(isopropylphenyl)phenylmethane; the method of making such compositions by first reacting chlorine with toluene, xylene, or a mixture of toluene and xylene in the presence of a radical generator, removing the unreacted toluene and/or xylene, and then subjecting the reaction product to the action of an inorganic halide or of an inorganic acid in the presence of a benzene-related compound; and microcapsules containing color-forming material wherein the compositions are used as solvents for the color-forming material.
摘要:
The process for the separation of isomeric dichlorotoluenes, comprising the steps of:(a) passing a mixture containing isomeric dichlorotoluenes over a zeolite of the ZSM5 type having the composition (expressed in molar ratios) of (0.9+0.2) M.sub.2/n O:Al.sub.2 O.sub.3 : (10-100) SiO.sub.2 : z H.sub.2 O in which M is at least one cation selected from H, an alkali metal, an alkaline earth metal or a tetraalkylammonium cation; n is the valency of M; and z is between 0 and 40:(b) separating the non-adsorbed dichlorotoluenes;(c) contacting the zeolite containing the adsorbed isomers with an eluent; and(d) separating the isomers from the eluent.
摘要:
Halogenated organic species, e.g., chlorinated or brominated dioxins or dibenzofurans, PCBs, and the like, are consumed by contacting such species, at a temperature of greater than 220.degree. C., with a stoichiometric excess, relative to the halogen content thereof, of at least one alkali metal alcoholate.
摘要:
Polyarylalkane oligomer compositions comprising a mixture of two oligomers A and B, wherein oligomer A is a mixture of isomers of formula: ##STR1## with n1 and n2=0, 1 and 2, given that n1+n2.ltoreq.3; and oligomer B is a mixture of isomers of formula: ##STR2## with n'1, n"1 and n4=0, 1 and 2, n'2, n"2, n3, n'3 and n5=0 and 1, given that n'1+n"1+n'2+n"2+n3+n'3+n4+n5.ltoreq.2.The invention also comprises the process for the preparation of said oligomer compositions by the action of a halide or inorganic acid on a product of free-radical chlorination of toluene.
摘要:
In a process for the purification by distillation of chlorinated aromatic hydrocarbons originating from the chlorination of aromatic hydrocarbons in the presence of FeCl.sub.3, the crude reaction product is first partially degassed and then directly subjected to distillation in the presence of said FeCl.sub.3.
摘要:
The invention relates to a process for the synthesis of 1,1-bis(chlorophenyl)-2,2,2-trichloroethanol in (dicofol) from chlorol and chlorobenzene, in which process the acid by-products formed during the condensation reaction of the chloral and the chlorobenzene are used as reaction medium in the final step for synthesis of dicofol.
摘要:
Dielectric liquids are prepared by (a) Friedel-Crafts condensing at least one aromatic halide with at least one aromatic compound in the presence of a catalytically effective amount of ferric chloride, and thereafter deliberately avoiding any downstream destruction/neutralization and/or washing of such ferric chloride catalyst, (b) optionally, removing unreacted reactants from the medium of reaction, and (c) recovering from such medium of reaction a purified dielectric liquid; the subject process is thus environmentally improved by avoiding the generation of aqueous solutions containing contaminating amounts of objectionable organic compounds.