公开(公告)号：US08536285B2

公开(公告)日：2013-09-17

申请号：US13133026

申请日：2009-11-25

申请人： Reinhard Dorfner ,  Klaus Lorenz ,  Petra Wagner ,  Christian Scholz

发明人： Reinhard Dorfner ,  Klaus Lorenz ,  Petra Wagner ,  Christian Scholz

IPC分类号： C08F216/14 ,  C08F2/10 ,  C08F224/00 ,  C04B16/04

CPC分类号： C08F290/00 ,  C08F265/00 ,  C08F267/00 ,  C08F283/06 ,  C08F290/062 ,  C08F290/142 ,  C08L51/003 ,  C08L2666/02

摘要： A process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus including a polymerization reactor connected to a metering device, acid monomer being initially taken in the metering device and polyether macromonomer and water in the polymerization reactor, acid monomer being metered from the metering device via an acid monomer metering line into the polymerization reactor, a portion of the copolymer-containing aqueous medium being passed continuously during the free radical polymerization from the polymerization reactor via a reaction mixture line which is connected via a mixing device to the acid monomer metering line, the discharged copolymer-containing aqueous medium being mixed with the acid monomer in the mixing device during the metering of the acid monomer and being recycled to the polymerization reactor after the mixing via the acid monomer metering line.

摘要翻译： 一种在包括连接到计量装置的聚合反应器的聚合装置中的半连续操作中制备共聚物的方法，初始计量装置中的酸单体和聚合反应器中的聚醚大分子单体和水，酸单体从 计量装置通过酸性单体计量管线进入聚合反应器，一部分含共聚物的水性介质在自由基聚合期间通过经由混合装置连接到酸单体的反应混合物线从聚合反应器中连续通过 计量管线，在计量酸性单体期间将含有共聚物的含水介质与酸性单体混合在混合装置中，并通过酸性单体计量管道在混合后再循环到聚合反应器中。

公开(公告)号：US20120035300A1

公开(公告)日：2012-02-09

申请号：US13133026

申请日：2009-11-25

申请人： Reinhard Dorfner ,  Klaus Lorenz ,  Petra Wagner ,  Christian Scholz

发明人： Reinhard Dorfner ,  Klaus Lorenz ,  Petra Wagner ,  Christian Scholz

IPC分类号： C04B16/04 ,  C08F216/14 ,  C08F2/10

CPC分类号： C08F290/00 ,  C08F265/00 ,  C08F267/00 ,  C08F283/06 ,  C08F290/062 ,  C08F290/142 ,  C08L51/003 ,  C08L2666/02

摘要： The present invention relates to a process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus, comprising a polymerization reactor connected to a metering device, in each case acid monomer being initially taken in the metering device and polyether macromonomer and water in the polymerization reactor, acid monomer being metered from the metering device via an acid monomer metering line into the polymerization reactor, free radical polymerization initiator being passed into the polymerization reactor before and/or during the metering of the acid monomer into the polymerization reactor so that an aqueous medium in which acid monomer and polyether macromonomer are reacted with formation of the copolymer by free radical polymerization forms in the polymerization reactor, a portion of the copolymer-containing aqueous medium being passed continuously during the free radical polymerization from the polymerization reactor via a reaction mixture line which is connected via a mixing device to the acid monomer metering line, the discharged copolymer-containing aqueous medium being mixed with the acid monomer in the mixing device during the metering of the acid monomer and being recycled to the polymerization reactor after the mixing via the acid monomer metering line.

摘要翻译： 本发明涉及一种在聚合设备中半连续操作中制备共聚物的方法，包括连接到计量装置的聚合反应器，在各种情况下，酸性单体最初被摄入计量装置中，聚醚大分子单体和水在 聚合反应器，酸性单体通过酸单体计量管线从计量装置计量到聚合反应器中，自由基聚合引发剂在酸单体计量之前和/或期间进入聚合反应器中，使得自由基聚合引发剂 其中酸性单体和聚醚大分子单体与在聚合反应器中通过自由基聚合形式形成共聚物的水性介质反应，一部分含共聚物的水性介质在自由基聚合过程中通过反应从聚合反应器中连续通过 混合线 ch通过混合装置连接到酸性单体计量管线，在计量酸性单体期间，将排出的含共聚物的水性介质与酸性单体混合在混合装置中，并在经过混合之后再循环到聚合反应器中 酸性单体计量线。

公开(公告)号：US08541518B2

公开(公告)日：2013-09-24

申请号：US12920143

申请日：2009-02-10

申请人： Gerhard Albrecht ,  Klaus Lorenz ,  Christian Scholz ,  Petra Wagner

发明人： Gerhard Albrecht ,  Klaus Lorenz ,  Christian Scholz ,  Petra Wagner

IPC分类号： C08F2/04 ,  C08F224/00 ,  C08F2/10 ,  C04B28/28

CPC分类号： C08F220/04 ,  C08F220/26

摘要： A process for the preparation of a copolymer in a semicontinuous mode of operation in a polymerization apparatus containing a polymerization reactor connected to a metering device, in each case acid monomer being initially introduced into the metering device and polyether macromonomer and water into the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, the metering of the acid monomer into the polymerization reactor being effected in such a way that first a polymerization pH is established in the aqueous medium and then, until the conversion of 70 mol % of the polyether macromonomer initially introduced into the polymerization reactor, acid monomer is passed into the polymerization reactor in an amount per unit time such that the pH in the aqueous medium deviates by not more than ±0.3 from the initially established polymerization pH.

摘要翻译： 在含有连接到计量装置的聚合反应器的聚合装置中制备半连续操作模式的共聚物的方法，每种情况下，酸性单体最初引入计量装置和聚醚大分子单体和水进入聚合反应器， 酸性单体从计量装置计量到聚合反应器中，酸性单体计量到聚合反应器中的方式是首先在水性介质中建立聚合pH，然后直到70mol％ 的最初引入聚合反应器的聚醚大分子单体，酸单体以每单位时间的量进入聚合反应器，使得水介质中的pH从最初建立的聚合pH偏离不大于±0.3。

公开(公告)号：US08536251B2

公开(公告)日：2013-09-17

申请号：US13132990

申请日：2009-11-25

申请人： Silke Flakus ,  Klaus Lorenz ,  Helmut Mack ,  Christian Scholz ,  Petra Wagner ,  Barbara Wimmer ,  Angelika Hartl ,  Martin Winklbauer ,  Manfred Bichler

发明人： Silke Flakus ,  Klaus Lorenz ,  Helmut Mack ,  Christian Scholz ,  Petra Wagner ,  Barbara Wimmer ,  Angelika Hartl ,  Martin Winklbauer ,  Manfred Bichler

IPC分类号： C04B24/26 ,  C08L53/00 ,  C08L39/04 ,  C08L27/04 ,  C08L29/00 ,  C08K5/00 ,  C08F16/12 ,  C08F220/12 ,  C08F12/30 ,  C08F30/02

CPC分类号： C08F216/1416 ,  C04B24/2605 ,  C04B24/2647 ,  C04B24/267 ,  C04B28/02 ,  C04B28/04 ,  C04B2103/30 ,  C04B2103/408 ,  C08F220/06 ,  C04B14/06

摘要： The invention relates to a copolymer comprising i) 3 to 40 mol % of an isoprenolpolyether derivative structural unit α ii) 3 to 40 mol % of a vinyloxypolyether derivative structural unit β and iii) 35 to 93 mol % of an acid structural unit γ, the structural units of the copolymer which belong to the vinyloxypolyether derivative structural unit β having longer side chains than the structural units which belong to the isoprenolpolyether derivative structural unit α.

摘要翻译： 本发明涉及一种共聚物，其包含i）3至40mol％的异戊二烯聚醚衍生物结构单元αii）3至40mol％的乙烯氧基聚醚衍生物结构单元β和iii）35至93mol％的酸性结构单元γ， 属于乙烯氧基聚醚醚衍生物结构单元β的共聚物的结构单元具有比属于异戊二烯聚醚衍生物结构单元α的结构单元更长的侧链。

公开(公告)号：US20060247402A1

公开(公告)日：2006-11-02

申请号：US10551268

申请日：2004-03-05

申请人： Toshimi Matsumoto ,  Sven Asmus ,  Gerhard Albrecht ,  Klaus Lorenz ,  Petra Wagner ,  Christian Scholz

发明人： Toshimi Matsumoto ,  Sven Asmus ,  Gerhard Albrecht ,  Klaus Lorenz ,  Petra Wagner ,  Christian Scholz

IPC分类号： C08F224/00

CPC分类号： C04B24/2647 ,  C04B24/267 ,  C04B24/2688 ,  C04B40/0039 ,  C04B2111/34 ,  C04B24/06 ,  C04B24/121 ,  C04B24/122 ,  C04B24/18 ,  C04B24/32 ,  C04B24/38 ,  C04B38/10 ,  C04B2103/10 ,  C04B2103/20 ,  C04B2103/304 ,  C04B2103/44 ,  C04B2103/50 ,  C04B2103/61

摘要： The present invention concerns a cement additive containing copolymers comprising one or more constitutional units represented by formula A: (A) R1 is hydrogen, an alkyl group having 1 to 4 carbon atoms, an alkenyl group having 1 to 4 carbon atoms or an aryl group having 6 to 9 carbon atoms; R2 is hydrogen or an alkyl group having 1 to 9 carbon atoms, an alkenyl group having 1 to 9 carbon atoms or an aryl group having 6 to 9 carbon atoms; T is alkylene (including straight-chain and branched alkylene) having 1 to 4 carbon atoms or arylene having 6 to 9 carbon atoms; n is 0 or 1; S1 and S2 are, independently of one another, —OCkH2k— or —OCH2CHR3—, with the proviso that k is 2 or 3, R3 is an alkyl group having 1 to 9 carbon atoms, an aryl group having 6 to 9 carbon atoms; and 6

摘要翻译： 本发明涉及包含一种或多种由式A表示的结构单元的共聚物的水泥添加剂：（A）R 1是氢，具有1至4个碳原子的烷基，具有1个 至4个碳原子或具有6至9个碳原子的芳基; R2是氢或碳原子数1〜9的烷基，碳原子数1〜9的烯基或碳原子数6〜9的芳基。 T是具有1至4个碳原子的亚烷基（包括直链和支链亚烷基）或具有6至9个碳原子的亚芳基; n为0或1; S 1和S 2 2彼此独立地是-OC 2 k H 2 - 或-OCH 3， 其中k为2或3，R3为碳原子数1〜9的烷基，碳原子数为6〜9的芳基。 和6 <_M 1 + m 2 <_ 25。

公开(公告)号：US08461232B2

公开(公告)日：2013-06-11

申请号：US13132971

申请日：2009-11-25

申请人： Mario Vierle ,  Klaus Lorenz ,  Silke Flakus ,  Petra Wagner ,  Christian Scholz ,  Barbara Wimmer ,  Manfred Bichler ,  Angelika Hartl ,  Martin Winklbauer

发明人： Mario Vierle ,  Klaus Lorenz ,  Silke Flakus ,  Petra Wagner ,  Christian Scholz ,  Barbara Wimmer ,  Manfred Bichler ,  Angelika Hartl ,  Martin Winklbauer

IPC分类号： C04B28/02 ,  C08J3/02 ,  C08K3/20 ,  C08L39/04 ,  C08L33/14

CPC分类号： C04B24/2694 ,  C04B24/2647 ,  C04B24/267 ,  C04B2103/30 ,  C04B2103/40 ,  C04B2103/52 ,  C08L29/10 ,  C08L33/02 ,  C08L35/08 ,  C08L2205/02 ,  C08L2666/04

摘要： The invention relates to a polymer composition containing 3 to 90% by weight of a copolymer H and 3 to 90% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, at least 60 mol % of the polyether macromonomer structural units of the copolymer H being represented by the isoprenol polyether derivative structural units and at least 60 mol % of the polyether macromonomer structural units of the copolymer K being represented by the vinyloxy polyether derivative structural units.

摘要翻译： 本发明涉及含有3〜90重量％共聚物H和3〜90重量％共聚物K的聚合物组合物，共聚物H和K各自具有聚醚大分子单体结构单元和酸单体结构单元，其存在 在共聚物H和K中的摩尔比为1:20至1:1的共聚物中，和共聚物H的所有结构单元的至少20摩尔％和共聚物K的所有结构单元的至少25摩尔％ 在各种情况下以酸性单体结构单元的形式存在，共聚物H的至少60摩尔％的聚醚大分子单体结构单元由异戊二烯醇聚醚衍生物结构单元表示，并且至少60摩尔％的聚醚大分子单体结构单元 的共聚物K由乙烯基氧基聚醚衍生物结构单元表示。

公开(公告)号：US20090163622A1

公开(公告)日：2009-06-25

申请号：US12084665

申请日：2006-12-20

申请人： Gerhard Albrecht ,  Klaus Lorenz ,  Christian Scholz ,  Petra Wagner

发明人： Gerhard Albrecht ,  Klaus Lorenz ,  Christian Scholz ,  Petra Wagner

IPC分类号： C08F220/00 ,  C08F222/04 ,  C08F216/12 ,  C08K3/00 ,  C08K3/30

CPC分类号： C04B24/2605 ,  C04B24/2647 ,  C04B24/267 ,  C04B24/2694 ,  C04B2103/30 ,  C04B2103/408 ,  C08F216/1416 ,  C08F220/06 ,  C08F222/06

摘要： Copolymers based on unsaturated mono- or dicarboxylic acid derivatives, oxyalkylene glycol alkenyl ethers and optionally vinylic polyalkylene glycol or ester compounds are described and also their use as additives for aqueous suspensions based on mineral or bituminous binders, in particular cement, gypsum, lime, anhydrite, or other calcium sulphate-based binders, and based on pulverulent dispersion binders. The copolymers according to the invention impart to the aqueous binder suspensions a very good dispersing and liquefying action with, at the same time, simultaneous excellent processing properties. Moreover, the oxyalkylene glycol alkenyl ethers according to the invention are industrially relatively simple and inexpensive to prepare and need comparatively low initiator concentrations in the copolymerization.

摘要翻译： 描述了基于不饱和单羧酸或二羧酸衍生物，氧亚烷基二醇烯基醚和任选的乙烯基聚亚烷基二醇或酯化合物的共聚物，也用作基于矿物或沥青粘合剂，特别是水泥，石膏，石灰，无水石膏 ，或其它基于硫酸钙的粘合剂，并且基于粉末分散粘合剂。 根据本发明的共聚物赋予水性粘合剂悬浮液非常好的分散和液化作用，同时具有同时优异的加工性能。 此外，根据本发明的氧亚烷基二醇烯基醚在工业上相对简单且制备成本低，并且在共聚中需要相对较低的引发剂浓度。

公开(公告)号：US08907016B2

公开(公告)日：2014-12-09

申请号：US13133022

申请日：2009-11-25

申请人： Mario Vierle ,  Klaus Lorenz ,  Gerhard Albrecht ,  Christian Scholz ,  Petra Wagner ,  Barbara Wimmer

发明人： Mario Vierle ,  Klaus Lorenz ,  Gerhard Albrecht ,  Christian Scholz ,  Petra Wagner ,  Barbara Wimmer

IPC分类号： C04B24/26 ,  C08L29/10 ,  C08L33/02 ,  C08L35/08 ,  C04B103/40

CPC分类号： C04B24/2694 ,  C04B24/2647 ,  C04B2103/408 ,  C08L29/10 ,  C08L33/02 ,  C08L35/08 ,  C08L2205/02 ,  C08L2666/04

摘要： The invention relates to a polymer composition containing 5 to 95% by weight of a copolymer H and 2 to 60% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, the polyether macromonomer structural units of the copolymer H having side chains containing in each case at least 5 ether oxygen atoms, the number of ether oxygen atoms per side chain of the polyether macromonomer structural units of the copolymer H varying in such a way that the corresponding frequency distribution diagram, in which the number of ether oxygen atoms per side chain of a polyether macromonomer structural unit is plotted along the abscissa and the associated frequency for the copolymer H is plotted along the ordinate, contains at least 2 maxima.

摘要翻译： 本发明涉及一种聚合物组合物，其含有5〜95重量％的共聚物H和2〜60重量％的共聚物K，共聚物H和K各自具有聚醚大分子单体结构单元和酸单体结构单元，其存在 在共聚物H和K中的摩尔比为1:20至1:1的共聚物中，和共聚物H的所有结构单元的至少20摩尔％和共聚物K的所有结构单元的至少25摩尔％ 在各种情况下以酸性单体结构单元的形式存在，共聚物H的聚醚大分子单体结构单元具有侧链含有至少5个醚氧原子，每个侧链上的醚氧原子的数量为聚醚大分子单体 共聚物H的结构单元以这样的方式变化，其中相应的频率分布图，其中聚醚大分子单体结构单元的每个侧链的醚氧原子的数量沿着横坐标绘制， 共聚物H的相关频率沿纵坐标绘制，含有至少2个最大值。

公开(公告)号：US08772377B2

公开(公告)日：2014-07-08

申请号：US13133043

申请日：2009-11-25

申请人： Klaus Lorenz ,  Mario Vierle ,  Gerhard Albrecht ,  Barbara Wimmer ,  Petra Wagner ,  Christian Scholz

发明人： Klaus Lorenz ,  Mario Vierle ,  Gerhard Albrecht ,  Barbara Wimmer ,  Petra Wagner ,  Christian Scholz

IPC分类号： C04B28/02 ,  C08J3/02 ,  C08L39/04 ,  C08L33/14 ,  C04B24/26 ,  C08L33/26 ,  C08L43/02 ,  C04B40/00 ,  C04B28/00 ,  C08J3/00 ,  C08L39/00 ,  C08L33/00 ,  C04B103/40 ,  C04B103/32

CPC分类号： C04B24/2647 ,  C04B24/2658 ,  C04B24/267 ,  C04B40/0039 ,  C04B2103/32 ,  C04B2103/408 ,  C08G65/2609 ,  C08L29/10 ,  C08L33/02 ,  C08L33/066 ,  C08L33/14 ,  C08L33/26 ,  C08L35/08 ,  C08L43/02 ,  C08L71/02 ,  C08L2205/02 ,  C08L2666/04 ,  C08L2666/22

摘要： The invention relates to a polymer composition containing 3 to 95% by weight of a copolymer H and 3 to 95% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, the polyether macromonomer structural units of the copolymers H and K having side chains containing in each case at least 5 ether oxygen atoms, the number of ether oxygen atoms per side chain of the polyether macromonomer structural units of the copolymers H and K varying in each case in such a way that the corresponding frequency distribution diagrams, in which the number of ether oxygen atoms per side chain of a polyether macromonomer structural unit is plotted in each case along the abscissae and the respectively associated frequencies for the copolymers H or K are plotted in each case along the ordinates, contain in each case at least 2 maxima whose abscissa values differ in each case by more than 7 ether oxygen atoms from one another, the frequency distribution diagrams of the copolymers H and K differing from one another in that the abscissa value of at least one maximum of the copolymer H differs in each case by more than 5 ether oxygen atoms from the abscissa values of all maxima of the copolymer K and/or that the arithmetic means of the ether oxygen atoms of the polyether macromonomer structural units of the copolymers H and K differ from one another by more than 5 ether oxygen atoms.

摘要翻译： 本发明涉及含有3〜95重量％共聚物H和3〜95重量％共聚物K的聚合物组合物，共聚物H和K各自具有聚醚大分子单体结构单元和酸单体结构单元，其存在 在共聚物H和K中的摩尔比为1:20至1:1的共聚物中，和共聚物H的所有结构单元的至少20摩尔％和共聚物K的所有结构单元的至少25摩尔％ 在各种情况下以酸单体结构单元的形式存在，共聚物H和K的聚醚大分子单体结构单元具有侧链，每种情况下含有至少5个醚氧原子，每个侧链的醚氧原子数 共聚物H和K的聚醚大分子单体结构单元在每种情况下变化，使得相应的频率分布图，其中聚醚大分子单体结构单元每侧链的醚氧原子数为pl 在每个情况下沿着横坐标分别表示，并且在每种情况下沿着纵坐标绘制共聚物H或K的分别相关联的频率，每种情况下包含至少2个最大值，其横坐标值在每种情况下不同于7个以上的醚氧原子 另一方面，共聚物H和K的频率分布图彼此不同，因为共聚物H的至少一个最大值的横坐标值在每种情况下都不同于5个以上的醚氧原子，从所有最大值的横坐标值 共聚物K和/或共聚物H和K的聚醚大分子单体结构单元的醚氧原子的算术手段彼此间隔超过5个醚氧原子。

公开(公告)号：US08519030B2

公开(公告)日：2013-08-27

申请号：US12866998

申请日：2009-01-12

申请人： Klaus Lorenz ,  Gerhard Albrecht ,  Silke Flakus ,  Alexander Kraus ,  Helmut Mack ,  Petra Wagner ,  Christian Scholz ,  Barbara Wimmer ,  Angelika Hartl ,  Martin Winklbauer

发明人： Klaus Lorenz ,  Gerhard Albrecht ,  Silke Flakus ,  Alexander Kraus ,  Helmut Mack ,  Petra Wagner ,  Christian Scholz ,  Barbara Wimmer ,  Angelika Hartl ,  Martin Winklbauer

IPC分类号： C08F220/06 ,  C08L31/02 ,  C04B16/04

CPC分类号： C08F290/062 ,  C04B24/2647 ,  C04B2103/408

摘要： The invention relates to a copolymer which is suitable as a superplasticizer for hydraulic binders and comprises 5 to 55 mol % of an isoprenol polyether derivative structural unit, 2 to 90 mol % of an acrylic acid derivative structural unit and 2 to 90 mol % of a hydroxyalkyl acrylate structural unit.

摘要翻译： 本发明涉及一种适用作水硬性粘合剂的超增塑剂的共聚物，它包括5至55摩尔％的异戊二烯醇聚醚衍生物结构单元，2至90摩尔％的丙烯酸衍生物结构单元和2至90摩尔％的 丙烯酸羟烷基酯结构单元。