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公开(公告)号：US3986991A
公开(公告)日：1976-10-19
申请号：US584743
申请日：1975-06-09
CPC分类号： C08G18/092 , Y10S264/13 , Y10S521/902
摘要： A novel catalyst combination for the trimerization of polyisocyanates to polyisocyanurates is disclosed. The catalyst combination comprises (i) a tertiary amine trimerization catalyst containing a dimethylamino moiety, (ii) an alkali metal salt of an N-(2-hydroxyphenyl)methyl glycine, and (iii) a monomeric epoxide. The use of these catalysts in the preparation of polyisocyanurate foams results in facile machine preparation of bun stock foam without incurring the processing problems that arise from the prior art method. The polyisocyanurate foams produced using the novel catalyst combination of the invention are characterized by a reduced level of smoke generated on combustion.
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公开(公告)号：US4039487A
公开(公告)日：1977-08-02
申请号：US650453
申请日：1976-01-19
CPC分类号： C08G18/161 , C08G18/4244 , C08G18/425 , C08G18/4252 , C08G18/7664 , C08G2105/02 , Y10S521/902 , Y10S521/903
摘要： Polyisocyanurate foams are disclosed which are characterized by low Flame Spread Ratings and low smoke generation values, as determined by the Underwriter's Laboratory Tunnel Test in accordance with the ASTM E-84 test procedure. The smoke and flame resistant properties are achieved, not through the use of flame retardants or additives, but rather by the use of a minor amount of a hydroxyl terminated aromatic polyester having a hydroxyl equivalent weight from about 150 to about 500 and which is the product of the reaction of an excess of a polyethyleneglycol having an equivalent weight from about 75 to about 225, with an aromatic polycarboxylic compound.
摘要翻译： 公开了聚异氰脲酸酯泡沫，其特征在于根据ASTM E-84测试程序，由Underwriter's Laboratory Tunnel Test确定的低火焰蔓延等级和低烟雾产生值。 烟气和阻燃性能不是通过使用阻燃剂或添加剂而是通过使用少量羟基当量重量为约150至约500的羟基封端的芳族聚酯而得到的，并且是产物 过量的当量为约75至约225的聚乙二醇与芳族多元羧酸化合物的反应。
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公开(公告)号：US3991252A
公开(公告)日：1976-11-09
申请号：US572719
申请日：1975-04-29
CPC分类号： E04B1/941 , B32B13/12 , Y10S428/921 , Y10T428/249965 , Y10T428/249985
摘要： Novel fire resistant insulating structural building elements are provided which are comprised of unitized structures such as walls, roofs, ceilings, and floors in combination with a layer of plastic foam insulation to which is in turn bonded a coating of gypsum plaster by a layer of bonding agent. The novel elements of the invention find particular utility in the rapid and economic construction of thermally insulated and fire resistant buildings. Additionally, a method is disclosed for a facile and economic way of providing thermal barrier protection for exposed plastic foam insulation in existing buildings by the application of a bonding agent and a plaster coat on said foam.
摘要翻译： 提供了新型的耐火绝缘结构建筑构件，其由诸如墙壁，屋顶，天花板和地板的组合结构组合，并与一层塑料泡沫绝缘体结合，通过一层粘合剂将石膏涂层 代理商 本发明的新颖元件在隔热和耐火建筑物的快速和经济建造中具有实用价值。 此外，公开了一种通过在所述泡沫上施加粘合剂和石膏涂层来为现有建筑物中暴露的塑料泡沫隔离物提供热障保护的便利且经济的方法。
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公开(公告)号：US4003859A
公开(公告)日：1977-01-18
申请号：US578428
申请日：1975-05-19
CPC分类号： C08G18/092 , Y10S521/902
摘要： A novel catalyst combination for the trimerization of polyisocyanates to polyisocyanurates is disclosed. The catalyst combination comprises (i) a tertiary amine trimerization catalyst, (ii) an alkali metal salt of an N-substituted amide, and (iii) a dibutyl tin di(alkanoate) compound. The use of this catalyst combination in the preparation of polyisocyanurate spray foams enables the systems to be sprayed in either a 1:1 or 2:1 by volume ratio, or ratios between these limits interchangably with no alterations being required in reactant formulations. The polyisocyanurate foams produced using the novel catalyst combination of the invention are characterized by having high resistance to flame and heat distortion.
摘要翻译： 公开了一种用于将多异氰酸酯三聚化为聚异氰脲酸酯的新型催化剂组合。 催化剂组合包括（i）叔胺三聚催化剂，（ii）N-取代酰胺的碱金属盐和（iii）二丁基锡二（链烷酸酯）化合物。 在制备聚异氰脲酸酯喷雾泡沫中使用该催化剂组合使得系统能够以1:1或2:1体积比喷射，或者这些极限之间的比例可互换地进行喷射，而在反应物制剂中不需要改变。 使用本发明的新型催化剂组合制备的聚异氰脲酸酯泡沫的特征在于具有高的耐火焰和热变形性。
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公开(公告)号：US4101465A
公开(公告)日：1978-07-18
申请号：US729899
申请日：1976-10-06
CPC分类号： C08G18/1875 , C08G18/163 , C08G18/225 , C08G2105/02 , Y10S521/902 , Y10T428/31547
摘要： A novel cocatalyst combination for the trimerization of polyisocyanates to polyisocyanurates is disclosed. The catalyst combination comprises: (a) alkali metal glycine salts, (b) hydroxyalkyltrialkylammonium carboxylate salts, and (c) alkali metal salts selected from the group consisting of (i) alkali metal salts of N-phenyl aliphatic amides, and (ii) alkali metal salts of aliphatic carboxylic acids. The use of the cocatalyst combination provides for the facile formation of polyisocyanurate foam laminate boardstock which is characterized by good fire resistance and good physical properties.
摘要翻译： 公开了一种用于将多异氰酸酯三聚化成聚异氰脲酸酯的新型助催化剂组合物。 催化剂组合包括：（a）碱金属甘氨酸盐，（b）羟烷基三烷基铵羧酸盐，和（c）选自（i）N-苯基脂族酰胺的碱金属盐和（ii） 脂肪族羧酸的碱金属盐。 助催化剂组合的使用提供了容易形成聚异氰脲酸酯泡沫层压板材，其特征在于具有良好的耐火性和良好的物理性能。
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公开(公告)号：US4011180A
公开(公告)日：1977-03-08
申请号：US573908
申请日：1975-05-02
CPC分类号： C08G18/022 , B32B5/20 , C08G12/02 , Y10S521/902 , Y10T428/249984
摘要： A novel catalyst combination for the trimerization of polyisocyanates to polyisocyanurates is disclosed. The catalyst combination comprises (i) an alkali metal salt of an N-substituted amide, (ii) an alkali metal salt of an N-(2-hydroxyphenyl)methyl glycine, and optionally a tertiary amine trimerization catalyst. The use of these catalyst combinations in the preparation of polyisocyanurate foams results in the facile continuous formation of laminate board stock. The polyisocyanurate foams produced using the novel catalyst combinations of the invention are characterized by having high resistance to heat distortion and volume change.
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7.发明授权Process for preparing particle board and polyisocyanate-phosphorus compound release agent composition therefor 失效制备刨花板和多异氰酸酯 - 磷化合物脱模剂组合物的方法
公开(公告)号：US4257995A
公开(公告)日：1981-03-24
申请号：US134315
申请日：1980-03-26
IPC分类号： B27N3/02 , C07C67/00 , C07C241/00 , C07C265/14 , C08G18/00 , C08G18/30 , C08G18/70 , C08K5/52 , C08L75/00 , C08L75/04 , C08L97/02 , B29J5/02 , C08G18/28 , C08L1/02
CPC分类号： C08G18/706 , C08G18/302 , C08G18/70 , C08L97/02 , C08G2125/00 , C08L2205/06 , C08L75/04
摘要： The use of polyisocyanates as binders in the preparation of particle boards is subject to the drawback that the boards exhibit a tendency to adhere to the face of the platens used in their formation. This problem is minimized by incorporating minor amounts of a mixture of certain mono- and di- (saturated or unsaturated aliphatic) acid phosphates or the corresponding pyrophosphates, into the polyisocyanate to be used as binder. The polyisocyanates and the acid phosphates and or pyrophosphates, are applied to the particles separately, or after preblending one with the other. Whether the components are applied separately or in combination one with the other, they can each be applied either neat or in the form of an emulsion or emulsions.
摘要翻译： 在制备刨花板时使用多异氰酸酯作为粘合剂具有这样的缺点：板表现出粘附在其形成中使用的压板的表面的倾向。 通过将少量的某些单和二（饱和或不饱和脂肪酸）磷酸酯或相应的焦磷酸酯的混合物掺入到用作粘合剂的多异氰酸酯中来最小化该问题。 将多异氰酸酯和酸式磷酸盐和/或焦磷酸盐分别施加到颗粒上，或在与另一种预混合之后。 组分是单独使用还是与另一种组合使用，它们各自可以整齐地或以乳液或乳液的形式施用。
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8.发明授权Concrete preparation with aqueous solution of product from polyether with polymethylene polyphenyl polyisocyanate 失效具有由聚醚与聚亚甲基多苯基多异氰酸酯制成的产品水溶液的混凝土制备
公开(公告)号：US4228053A
公开(公告)日：1980-10-14
申请号：US7588
申请日：1979-01-29
CPC分类号： C08G18/4833 , C04B24/282 , C04B28/02
摘要： The structural strength properties of concrete and its resistance to sealing are improved by incorporating into the concrete-forming mixture an aqueous solution obtained by admixing polymethylene polyphenyl polyisocyanates with less than a stoichiometric amount of a polyethylene glycol (MW 600 to 3000) or polypropylene glycol tipped with 15 to 85 percent ethylene oxide (MW 1000 to 3500) and, within a short time of completing the admixture but during the period where said mixture is completely soluble in water, dissolving said mixture in water. Optionally, a difunctional extender is added to the solution so obtained in an amount less than that required to react with all the excess isocyanate groups.
摘要翻译： 混凝土的结构强度特性及其耐密封性通过将混合多亚甲基多苯基多异氰酸酯与少于化学计量量的聚乙二醇（MW 600至3000）或聚丙二醇封端得到的水溶液 具有15至85％的环氧乙烷（MW 1000至3500），并且在完成混合物的短时间内，但在所述混合物完全溶于水的期间，将所述混合物溶解在水中。 任选地，向如此获得的溶液中加入少量与所有过量异氰酸酯基团反应所需的量的双官能增量剂。
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公开(公告)号：US4143014A
公开(公告)日：1979-03-06
申请号：US849859
申请日：1977-11-09
CPC分类号： C08G18/7664 , C08G18/10 , C08G18/4833 , C08G18/4841 , Y10T428/249992 , Y10T428/31591
摘要： Storage stable aqueous solutions derived from polymethylene polyphenyl polyisocyanates are described, which solutions are useful as sealant coating compositions for wood and other substrates and, in the form of emulsions with polyisocyanates, as improved particle board binders. The storage stable aqueous solutions are obtained by admixing polymethylene polyphenyl polyisocyanates with less than a stoichiometric amount of a polyethylene glycol (MW 600 to 3000) or polypropylene glycol tipped with 15 to 85 percent ethylene oxide (MW 1000 to 3500) and, within a short time of completing the admixture but during the period where said mixture is completely soluble in water, dissolving said mixture in water. Optionally, a difunctional extender is added to the resulting solution in amount less than that required to react with all the isocyanate groups.
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公开(公告)号：US4126742A
公开(公告)日：1978-11-21
申请号：US905653
申请日：1978-05-15
CPC分类号： C08G18/4841 , C08G18/6674 , C08G2105/02 , C08G2120/00 , Y10S264/83 , Y10S528/905 , Y10S528/906 , Y10T428/31547
摘要： Novel solid polyisocyanurate polymers are disclosed which comprises the reaction product of an organic polyisocyanate, a trimerization catalyst and a polyol combination comprising from about 0.025 to about 0.15 equivalent and about 0.05 to about 0.25 equivalent, per equivalent of polyisocyanate, respectively of an ethylene oxide capped polypropyleneoxy glycol having an equivalent weight of from about 750 to about 1500 and either 1,4-butanediol or diethylene glycol.Although containing a higher proportion of polyurethane linkages than those polyisocyanurates containing the polypropyleneoxy glycol alone, the polymers of the invention are characterized by superior high temperature resistance and are particularly useful in the preparation of high modulus molded parts using reaction injection molding (RIM) techniques.
摘要翻译： 公开了新的固体聚异氰脲酸酯聚合物，其包含有机多异氰酸酯，三聚催化剂和多元醇组合的反应产物，其中每个多异氰酸酯分别包含约0.025至约0.15当量和约0.05至约0.25当量的环氧乙烷封端 当量为约750至约1500的聚丙烯氧基二醇和1,4-丁二醇或二甘醇。
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