Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom
    3.
    发明授权
    Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom 失效
    包括羟基或静止反应性官能团的膨胀的阴离子化合物及其催化剂活化剂

    公开(公告)号:US06627573B2

    公开(公告)日:2003-09-30

    申请号:US09904422

    申请日:2001-07-12

    IPC分类号: B01J3000

    摘要: A compound useful as a cocatalyst or cocatalyst component, especially for use as an addition polymerization catalyst compound, corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, said A* having a charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.

    摘要翻译: 用作助催化剂或助催化剂组分的化合物,特别是用作加成聚合催化剂化合物,其对应于下式:其中:A *是不计氢原子的1至80个,优选1至60个原子的阳离子,所述化合物 A *具有电荷+ a,Z *是1至50个,优选1至30个原子的阴离子基团,不计算氢原子,进一步含有两个或更多个路易斯碱基位点; J *各自独立地为路易斯酸 1至80个,优选1至60个原子,不计数氢原子,与Z *的至少一个路易斯碱碱基位点配位,并且任选地两个或多个这样的J *基团可以连接在具有多个路易斯酸官能团的部分中, j是2至12的数字,a,b,c和d是1至3的整数,条件是axb等于cxd,进一步提供A *,Z *或J *中的一个或多个包括 羟基或含有静止反应性官能团的极性基团。