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1.发明授权Resid hydrotreating process using lanthana-alumina-aluminum phosphate catalyst 失效使用镧 - 氧化铝 - 磷酸铝催化剂的残余加氢处理工艺
公开(公告)号：US4810361A
公开(公告)日：1989-03-07
申请号：US50446
申请日：1987-05-18
CPC分类号： B01J27/1804 , B01J35/0026 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , C10G2300/107
摘要： This invention relates to a new and useful improvement in a process for upgrading petroleum residua. The process comprises contacting a vacuum or atmospheric resid feed with a metal-containing lanthana-alumina-aluminum phosphate catalyst whereby the resid feedstock is simultaneously demetallized and desulfurized.
摘要翻译： 本发明涉及一种用于升级石油渣的方法的新的和有用的改进。 该方法包括使真空或常压残留物与含金属的氧化镧 - 铝 - 磷酸铝催化剂接触，由此将残留物同时脱金属脱硫。
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公开(公告)号：US4873216A
公开(公告)日：1989-10-10
申请号：US283778
申请日：1988-12-13
CPC分类号： B01J27/1804 , B01J35/0026 , B01J35/1019 , B01J35/1042 , B01J35/108 , C10G2300/107
摘要： This invention relates to a new catalyst composition. The catalyst composition comprises a catalytic component and a support comprising an amorphous combination of lanthana, alumina and aluminum phosphate, and may be characterized after calcination by a pore size distribution including about 5 to 20 vol. % within the pore size diameter range of 50 to 100 Angstroms, about 10 to 35 vol. % within the pore size diameter range of 100 to 150 Angstroms, about 15 to 50 vol. % within the pore size diameter range of 150 to 200 Angstroms and about 10 to 50 vol. % within the pore size diameter range of 200 to 400 Angstroms.
摘要翻译： 本发明涉及新的催化剂组合物。 催化剂组合物包含催化组分和包含镧，氧化铝和磷酸铝的无定形组合的载体，并且可通过包括约5至20体积％的孔径分布煅烧来表征。 孔径范围为50至100埃，约10至35体积％。 孔径范围为100至150埃，约15至50体积％。 孔径范围为150至200埃和约10至50体积％。 孔径范围为200至400埃的％。
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3.发明授权
公开(公告)号：US4781817A
公开(公告)日：1988-11-01
申请号：US938084
申请日：1986-12-04
摘要： The present invention relates to resid hydrotreating with hydrogen bronze catalyst which unexpectedly achieve superior demetallization compared to large pore CoMo/Al.sub.2 O.sub.3 catalyst.
摘要翻译： 本发明涉及与氢青铜催化剂的渣油加氢处理，其与大孔CoMo / Al 2 O 3催化剂相比意外地实现了优异的脱金属化。
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公开(公告)号：US4910181A
公开(公告)日：1990-03-20
申请号：US263295
申请日：1988-10-27
摘要： The catalyst composition comprises a layered metal oxide and/or sulfide of a metal selected from the group consisting of Group VB and VIB metals and containing inserted atomic hydrogen therein, with no chemical bond between said atomic hydrogen and anionic oxygen or anionic sulfur of the oxide or sulfide. It is useful for demetallizing resids.
摘要翻译： 催化剂组合物包含选自组VB和VIB金属并且在其中含有插入的原子氢的金属的层状金属氧化物和/或硫化物，所述原子氢与阴离子氧或氧化物的阴离子硫之间没有化学键 或硫化物。 它对残留物进行去金属化是有用的。
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5.发明授权Octane improvement in catalytic cracking and cracking catalyst composition therefor 失效辛烷值改善催化裂化和裂化催化剂组成
公开(公告)号：US4983276A
公开(公告)日：1991-01-08
申请号：US471994
申请日：1990-01-29
IPC分类号： B01J29/08 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/80 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , C07C2/12 , C10G11/05 , C10G35/095
CPC分类号： B01J29/04 , B01J29/80 , C07C2/12 , C10G11/05 , B01J29/088 , B01J29/40 , C07C2529/70
摘要： The catalytic cracking of a hydrocarbon oil to provide a product of increased octane number and increased C.sub.5 + gasoline content is carried out employing a cracking catalyst composition containing both a large pore crystalline zeolite component and an MCM-22 zeolite component.
摘要翻译： 使用含有大孔结晶沸石组分和MCM-22沸石组分的裂化催化剂组合物进行烃油的催化裂化以提供增加的辛烷值和增加的C5 +汽油含量的产物。
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公开(公告)号：US4834869A
公开(公告)日：1989-05-30
申请号：US161693
申请日：1988-02-29
IPC分类号： B01J27/18 , B01J27/16 , B01J27/185 , B01J32/00 , B01J35/10 , B01J37/03 , C10G45/04 , C10G47/10
CPC分类号： B01J37/03 , B01J29/84 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/108
摘要： This invention relates to a method of preparing a metal-containing amorphous magnesia-alumina-aluminum phosphate catalyst support involving the admixture of an organic cation having a size equal to or greater than 2 Angstroms, the organic cation preferably being a tertiary or a tetraalkylammonium or phosphonium cation. The method permits recovery of a catalyst support having a controlled pore size distribution. The invention also relates to an improved catalytic support as well as an improved petroleum residua upgrading process comprising hydrotreating residua in the presence of the improved catalyst support.
摘要翻译： 本发明涉及一种制备含金属的无定形氧化镁 - 氧化铝 - 磷酸铝催化剂载体的方法，该催化剂载体包括大小等于或大于2埃的有机阳离子的混合物，有机阳离子优选为叔烷基铵或四烷基铵或 鏻阳离子。 该方法允许回收具有可控孔径分布的催化剂载体。 本发明还涉及改进的催化剂载体以及改进的石油渣油改质方法，其包括在改进的催化剂载体存在下加氢处理残余物。
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7.发明授权Method for preparing a zeolite catalyst bound with a refractory oxide of low acidity 失效制备与低酸度的难熔氧化物结合的沸石催化剂的方法
公开(公告)号：US5053374A
公开(公告)日：1991-10-01
申请号：US431002
申请日：1989-11-02
申请人： Robert P. L. Absil , Philip J. Angevine , Joseph A. Herbst , Donald J. Klocke , John P. McWilliams , Scott Han , David S. Shihabi
发明人： Robert P. L. Absil , Philip J. Angevine , Joseph A. Herbst , Donald J. Klocke , John P. McWilliams , Scott Han , David S. Shihabi
CPC分类号： B01J37/0009 , B01J29/084 , B01J29/7007
摘要： Low acidity refractory oxide-bound zeolite catalysts, for example, silica-bound ultrastable Y zeolite, possessing physical properties, e.g., crush strength, similar to those of their alumina-bound counterparts are described. Since low acidity refractory oxide-bound catalysts are inherently less active than alumina-bound zeolite catalysts, the former are particularly useful in hydrocarbon conversion processes in which reduced coke make increases catalyst cycle length. Due to their stability in acid environments, the low acidity refractory oxide-bound zeolite extrudate herein can be acid treated without unduly compromising its structural integrity.
摘要翻译： 描述了具有类似于其氧化铝结合的对应物的物理性能，例如粉碎强度的低酸度难熔氧化物结合的沸石催化剂，例如二氧化硅结合的超稳定Y沸石。 由于低酸度难熔氧化物结合的催化剂固有地比氧化铝结合的沸石催化剂具有更低的活性，因此前者在烃转化方法中特别有用，其中减少的焦炭使催化剂循环长度增加。 由于其在酸性环境中的稳定性，本文中低酸度难熔氧化物结合的沸石挤出物可以进行酸处理，而不会不利地损害其结构完整性。
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8.发明授权Magnesia-alumina-aluminum phosphate catalyst and catalyst product thereof 失效氧化镁 - 铝 - 磷酸铝催化剂及其催化剂产物
公开(公告)号：US4743572A
公开(公告)日：1988-05-10
申请号：US938476
申请日：1986-12-05
IPC分类号： B01J27/18 , B01J27/16 , B01J27/185 , B01J32/00 , B01J35/10 , B01J37/03 , C10G45/04 , C10G47/10 , B01J29/06 , B01J27/14
CPC分类号： B01J37/03 , B01J29/84 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/108
摘要： This invention relates to a method of preparing a metal-containing amorphous magnesia-alumina-aluminum phosphate catalyst support involving the admixture of an organic cation having a size equal to or greater than 2 Angstroms, the organic cation preferably being a tertiary or a tetraalkylammonium or phosphonium cation, the method permits recovery of a catalyst support having a controlled pore size distribution. The invention also relates to an improved catalytic support as well as an improved petroleum residua upgrading process comprising hydrotreating residua in the presence of the improved catalyst support.
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公开(公告)号：US5039640A
公开(公告)日：1991-08-13
申请号：US567488
申请日：1990-08-14
申请人： Robert P. L. Absil , Philip J. Angevine , Robert G. Bundens , Joseph A. Herbst , Sadi Mizrahi , Mae K. Rubin
发明人： Robert P. L. Absil , Philip J. Angevine , Robert G. Bundens , Joseph A. Herbst , Sadi Mizrahi , Mae K. Rubin
CPC分类号： C07C2/12 , B01J29/04 , B01J29/80 , B01J29/088 , B01J29/40 , C07C2529/70
摘要： A novel catalyst composition is provided for catalytic cracking of a hydrocarbon oil to provide a product of increased octane number and increased C.sub.5 + gasoline content. The catalyst composition contains a large pore crystalline molecular sieve component and an MCM-22 zeolite component.
摘要翻译： 提供了新的催化剂组合物用于烃油的催化裂化，以提供增加的辛烷值和增加的C5 +汽油含量的产物。 催化剂组合物含有大孔结晶分子筛组分和MCM-22沸石组分。
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公开(公告)号：US20100084313A1
公开(公告)日：2010-04-08
申请号：US12287079
申请日：2008-10-06
申请人： Terry E. Helton , William J. Tracy, III , Michael T. Grove , Dennis H. Hoskin , Philip J. Angevine , David A. Pappal
发明人： Terry E. Helton , William J. Tracy, III , Michael T. Grove , Dennis H. Hoskin , Philip J. Angevine , David A. Pappal
IPC分类号： C10G69/02
CPC分类号： C10G3/00 , B01J29/74 , C10G45/04 , C10G47/18 , C10G65/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/1051 , C10G2300/301 , C10G2300/4018 , C10G2400/08 , C10L1/04 , Y02P30/20
摘要： This invention relates to a process for improving the yield and properties of jet fuel from a kerosene feed. More particularly, a kerosene feedstock is hydrotreated and dewaxed using a ZSM-48 catalyst to produce a jet fuel in improved yield and having improved properties.
摘要翻译： 本发明涉及一种提高煤油进料的喷气燃料的产率和性能的方法。 更具体地，使用ZSM-48催化剂对煤油原料进行加氢处理和脱蜡以产生具有改进的性能的喷射燃料。
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