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公开(公告)号：US5280124A
公开(公告)日：1994-01-18
申请号：US828291
申请日：1992-02-05
申请人： Roland A. E. Winter , Volker H. von Ahn , Tyler A. Stevenson , Mark S. Holt , Ramanathan Ravichandran
发明人： Roland A. E. Winter , Volker H. von Ahn , Tyler A. Stevenson , Mark S. Holt , Ramanathan Ravichandran
IPC分类号： C07D249/20 , C07F7/18 , C07F9/6518 , C08F220/38 , C08K5/3472 , C08K5/3475 , C08K5/41 , C08L33/14 , C09D5/00 , C09D7/12 , C09K3/00
CPC分类号： C07F9/65188 , C07D249/20 , C07F7/1896 , C08F220/38 , C08K5/41 , C09D7/1241 , C08K5/3475
摘要： 2-(2-Hydroxyphenyl)-2H-benzotriazole UV-absorbers substituted at the 5-position of the benzo ring by a sulfoxide or sulfone group exhibit enhanced absorption in the near visible range (over 350 nm) allowing said compounds to be particularly effective in protecting polymer systems which are prone to degradation caused by actinic irradiation with wavelengths over 350 nm.
摘要翻译： 2-（2-羟基苯基）-2H-苯并三唑通过亚砜或砜基在苯环的5-位取代的紫外线吸收剂在近似可见的范围（超过350nm）表现出增强的吸收，使所述化合物特别有效 在保护由波长超过350nm的光化辐射引起的易于降解的聚合物体系中。
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2.发明授权Compositions stabilized with 5-thio-substituted benzotriazole UV-absorbers 失效用5-硫代取代的苯并三唑紫外线吸收剂稳定的组合物
公开(公告)号：US5516914A
公开(公告)日：1996-05-14
申请号：US146331
申请日：1993-11-01
申请人： Roland A. E. Winter , Volker H. von Ahn , Tyler A. Stevenson , Mark S. Holt , Ramanathan Ravichandran
发明人： Roland A. E. Winter , Volker H. von Ahn , Tyler A. Stevenson , Mark S. Holt , Ramanathan Ravichandran
IPC分类号： C07D249/20 , C07F7/18 , C07F9/6518 , C08F220/38 , C08G65/32 , C08K5/3472 , C08K5/3475 , C08K5/378 , C09K3/00 , C07D249/16 , C08K5/34
CPC分类号： C08K5/378 , C07D249/20 , C07F9/65188 , C08F220/38 , C08K5/3475
摘要： 2-(2-Hydroxyphenyl)-2H-benzotriazole UV-absorbers substituted at the 5-position of the benzo ring by a thioether group exhibit enhanced absorption in the near visible range (over 350 nm) allowing said compounds to be particularly effective in protecting polymer systems which are prone to degradation caused by actinic irradiation with wavelengths over 350 nm.
摘要翻译： 2-（2-羟基苯基）-2H-苯并三唑通过硫醚基在苯环的5-位取代的紫外线吸收剂在近似可见的范围（超过350nm）表现出增强的吸收，使所述化合物在保护中特别有效 由波长超过350nm的光化辐射引起的易于降解的聚合物体系。
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公开(公告)号：US5278314A
公开(公告)日：1994-01-11
申请号：US828290
申请日：1992-02-05
申请人： Roland A. E. Winter , Volker H. von Ahn , Tyler A. Stevenson , Mark S. Holt , Ramanathan Ravichandran
发明人： Roland A. E. Winter , Volker H. von Ahn , Tyler A. Stevenson , Mark S. Holt , Ramanathan Ravichandran
IPC分类号： C07D249/20 , C07F7/18 , C07F9/6518 , C08F220/38 , C08G65/32 , C08K5/3472 , C08K5/3475 , C08K5/378 , C09K3/00
CPC分类号： C08K5/378 , C07D249/20 , C07F9/65188 , C08F220/38 , C08K5/3475
摘要： 2-(2-Hydroxyphenyl)-2H-benzotriazole UV-absorbers substituted at the 5-position of the benzo ring by a thioether group exhibit enhanced absorption in the near visible range (over 350 nm) allowing said compounds to be particularly effective in protecting polymer systems which are prone to degradation caused by actinic irradiation with wavelengths over 350 nm.
摘要翻译： 2-（2-羟基苯基）-2H-苯并三唑通过硫醚基在苯环的5-位取代的紫外线吸收剂在近似可见的范围（超过350nm）表现出增强的吸收，使所述化合物在保护中特别有效 由波长超过350nm的光化辐射引起的易于降解的聚合物体系。
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4.发明授权Compositions stabilized with 5-sulfonyl-substituted benotriazole UV-absorbers 失效组合物用5-磺酰基取代的苯并三唑紫外线吸收剂稳定
公开(公告)号：US5436349A
公开(公告)日：1995-07-25
申请号：US146338
申请日：1993-11-01
申请人： Roland A. E. Winter , Volker H. von Ahn , Tyler A. Stevenson , Mark S. Holt , Ramanathan Ravichandran
发明人： Roland A. E. Winter , Volker H. von Ahn , Tyler A. Stevenson , Mark S. Holt , Ramanathan Ravichandran
IPC分类号： C07D249/20 , C07F7/18 , C07F9/6518 , C08F220/38 , C08K5/3472 , C08K5/3475 , C08K5/41 , C08L33/14 , C09D5/00 , C09D7/12 , C09K3/00 , C07D249/16 , C07D249/18 , C08F232/08 , C08F120/36
CPC分类号： C07F9/65188 , C07D249/20 , C07F7/1896 , C08F220/38 , C08K5/41 , C09D7/1241 , C08K5/3475
摘要： 2-(2-Hydroxyphenyl)-2H-benzotriazole UV-absorbers substituted at the 5-position of the benzo ring by a sulfoxide or sulfone group exhibit enhanced absorption in the near visible range (over 350 nm) allowing said compounds to be particularly effective in protecting polymer systems which are prone to degradation caused by actinic irradiation with wavelengths over 350 nm.
摘要翻译： 2-（2-羟基苯基）-2H-苯并三唑通过亚砜或砜基在苯环的5-位取代的紫外线吸收剂在近似可见的范围（超过350nm）表现出增强的吸收，使所述化合物特别有效 在保护由波长超过350nm的光化辐射引起的易于降解的聚合物体系中。
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5.发明授权Crystalline form of 2-(2-hydroxy-3-.alpha.-cumyl-5-tert-octylphenyl)-2H-benzotriazole 失效2-（2-羟基-3-α-枯烯基-5-叔辛基苯基）-2H-苯并三唑的结晶形式
公开(公告)号：US5574166A
公开(公告)日：1996-11-12
申请号：US424843
申请日：1995-04-19
申请人： Roland A. E. Winter , Ramanathan Ravichandran , Mark S. Holt , Volker H. von Ahn , Joseph E. Babiarz , David G. Leppard
发明人： Roland A. E. Winter , Ramanathan Ravichandran , Mark S. Holt , Volker H. von Ahn , Joseph E. Babiarz , David G. Leppard
IPC分类号： B41J2/01 , B05D1/36 , B05D7/14 , B05D7/24 , B32B15/08 , B41M5/382 , B41M5/46 , B41M5/50 , B41M5/52 , C07D249/20 , C08K5/34 , C08K5/3472 , C08K5/3475 , C08L23/02 , C09D7/12 , C09D11/00 , C09D133/04 , C09D133/06 , C09D161/20 , C09D161/28 , C09D175/00 , C09D175/04 , G03C1/815 , G03C8/08 , G03F7/031
CPC分类号： G03F7/031 , B41M5/46 , B41M5/5227 , C07D249/20 , C08K5/3475 , C09D11/38 , G03C1/815 , G03C1/8155
摘要： Soluble and thermally stable benzotriazole UV absorbers typified by those of formula I ##STR1## where R.sub.1 is hydrogen or chloro, R.sub.2 is alkyl or --CH.sub.2 CH.sub.2 COOR.sub.4 where R.sub.4 is hydrogen, alkyl or alkyl substituted with hydroxyl, and R.sub.3 is .alpha.-cumyl, provide excellent light stability protection to electro coat, base coat or clear coat finishes. The new soluble, crystalline form of 2-(2-hydroxy-3-.alpha.-cumyl-5-tert-octylphenyl)-2H-benzotriazole is particularly effective.
摘要翻译： 可溶性和热稳定性的苯并三唑UV吸收剂，其中R 1为氢或氯，R 2为烷基或-CH 2 CH 2 COOR 4，其中R 4为氢，烷基或被羟基取代的烷基，R 3为α-枯烯基 为电涂，底漆或透明涂层提供优异的光稳定性保护。 2-（2-羟基-3-甲基 - 枯基-5-叔辛基苯基）-2H-苯并三唑的新的可溶性晶体形式是特别有效的。
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6.发明授权2-(2-hydroxy-3-.alpha.-cumyl-5-nonylor 5-dodecylphenyl)-2H-benzotriazole 失效2-（2-羟基-3-甲基 - 辛基-5-壬基酮-5-十二烷基苯基）-2H-苯并三唑
公开(公告)号：US5554760A
公开(公告)日：1996-09-10
申请号：US466851
申请日：1995-06-06
申请人： Roland A. E. Winter , Ramanathan Ravichandran , Mark S. Holt , Volker H. von Ahn , Joseph E. Babiarz , David G. Leppard
发明人： Roland A. E. Winter , Ramanathan Ravichandran , Mark S. Holt , Volker H. von Ahn , Joseph E. Babiarz , David G. Leppard
IPC分类号： B41J2/01 , B05D1/36 , B05D7/14 , B05D7/24 , B32B15/08 , B41M5/382 , B41M5/46 , B41M5/50 , B41M5/52 , C07D249/20 , C08K5/34 , C08K5/3472 , C08K5/3475 , C08L23/02 , C09D7/12 , C09D11/00 , C09D133/04 , C09D133/06 , C09D161/20 , C09D161/28 , C09D175/00 , C09D175/04 , G03C1/815 , G03C8/08 , G03F7/031
CPC分类号： G03F7/031 , B41M5/46 , B41M5/5227 , C07D249/20 , C08K5/3475 , C09D11/38 , G03C1/815 , G03C1/8155
摘要： Soluble and thermally stable benzotriazole UV absorbers typified by those of formula I ##STR1## where R.sub.1 is hydrogen or chloro, R.sub.2 is alkyl or --CH.sub.2 CH.sub.2 COOR.sub.4 where R.sub.4 is hydrogen, alkyl or alkyl substituted with hydroxyl, and R.sub.3 is .alpha.-cumyl, provide excellent light stability protection to electro coat, base coat or clear coat finishes. The new soluble, crystalline form of 2-(2-hydroxy-3-.alpha.-cumyl-5-tert-octylphenyl)-2H-benzotriazole is particularly effective.
摘要翻译： 可溶性和热稳定性的苯并三唑UV吸收剂，其中R 1为氢或氯，R 2为烷基或-CH 2 CH 2 COOR 4，其中R 4为氢，烷基或被羟基取代的烷基，R 3为α-枯烯基 为电涂，底漆或透明涂层提供优异的光稳定性保护。 2-（2-羟基-3-甲基 - 枯基-5-叔辛基苯基）-2H-苯并三唑的新的可溶性晶体形式是特别有效的。
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7.发明授权Electro coat/base coat/clear coat finishes stabilized with soluble and thermally stable benzotriazole UV absorbers 失效用可溶性和热稳定性的苯并三唑UV吸收剂稳定电涂/底涂/透明涂层
公开(公告)号：US5563242A
公开(公告)日：1996-10-08
申请号：US466850
申请日：1995-06-06
申请人： Roland A. E. Winter , Ramanathan Ravichandran , Mark S. Holt , Volker H. von Ahn , Joseph E. Babiarz , David G. Leppard
发明人： Roland A. E. Winter , Ramanathan Ravichandran , Mark S. Holt , Volker H. von Ahn , Joseph E. Babiarz , David G. Leppard
IPC分类号： B41J2/01 , B05D1/36 , B05D7/14 , B05D7/24 , B32B15/08 , B41M5/382 , B41M5/46 , B41M5/50 , B41M5/52 , C07D249/20 , C08K5/34 , C08K5/3472 , C08K5/3475 , C08L23/02 , C09D7/12 , C09D11/00 , C09D133/04 , C09D133/06 , C09D161/20 , C09D161/28 , C09D175/00 , C09D175/04 , G03C1/815 , G03C8/08 , G03F7/031 , C08K5/3492
CPC分类号： G03F7/031 , B41M5/46 , B41M5/5227 , C07D249/20 , C08K5/3475 , C09D11/38 , G03C1/815 , G03C1/8155
摘要： Soluble and thermally stable benzotriazole UV absorbers typified by those of formula I ##STR1## where R.sub.1 is hydrogen or chloro, R.sub.2 is alkyl or --CH.sub.2 CH.sub.2 COOR.sub.4 where R.sub.4 is hydrogen, alkyl or alkyl substituted with hydroxyl, and R.sub.3 is .alpha.-cumyl, provide excellent light stability protection to electro coat, base coat or clear coat finishes. The new soluble, crystalline form of 2-(2-hydroxy-3-.alpha.-cumyl-5-tert-octylphenyl)-2H-benzotriazole is particularly effective.
摘要翻译： 可溶性和热稳定性的苯并三唑UV吸收剂，其中R 1为氢或氯，R 2为烷基或-CH 2 CH 2 COOR 4，其中R 4为氢，烷基或被羟基取代的烷基，R 3为α-枯烯基 为电涂，底漆或透明涂层提供优异的光稳定性保护。 2-（2-羟基-3-甲基 - 枯基-5-叔辛基苯基）-2H-苯并三唑的新的可溶性晶体形式是特别有效的。
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8.发明授权2-(2-hydroxy-3-.alpha. cumyl-5-tert nonyl or dodecyl phenyl)-2H- Benzotriazole UV Absorbers 失效2-（2-羟基-3-异丙基-5-叔壬基或十二烷基苯基）-2H-苯并三唑UV吸收剂
公开(公告)号：US5607987A
公开(公告)日：1997-03-04
申请号：US628433
申请日：1996-04-05
申请人： Roland A. E. Winter , Ramanathan Ravichandran , Mark S. Holt , Volker H. von Ahn , Joseph E. Babiarz , David G. Leppard
发明人： Roland A. E. Winter , Ramanathan Ravichandran , Mark S. Holt , Volker H. von Ahn , Joseph E. Babiarz , David G. Leppard
IPC分类号： B41J2/01 , B05D1/36 , B05D7/14 , B05D7/24 , B32B15/08 , B41M5/382 , B41M5/46 , B41M5/50 , B41M5/52 , C07D249/20 , C08K5/34 , C08K5/3472 , C08K5/3475 , C08L23/02 , C09D7/12 , C09D11/00 , C09D133/04 , C09D133/06 , C09D161/20 , C09D161/28 , C09D175/00 , C09D175/04 , G03C1/815 , G03C8/08 , G03F7/031
CPC分类号： G03F7/031 , B41M5/46 , B41M5/5227 , C07D249/20 , C08K5/3475 , C09D11/38 , G03C1/815 , G03C1/8155
摘要： Soluble and thermally stable benzotriazole UV absorbers typified by those of formula I ##STR1## where R.sub.1 is hydrogen or chloro, R.sub.2 is alkyl or --CH.sub.2 CH.sub.2 COOR.sub.4 where R.sub.4 is hydrogen, alkyl or alkyl substituted with hydroxyl, and R.sub.3 is .alpha.-cumyl, provide excellent light stability protection to electro coat, base coat or clear coat finishes. The new soluble, crystalline form of 2-(2-hydroxy-3-.alpha.-cumyl-5-tert-octylphenyl)-2H-benzotriazole is particularly effective.
摘要翻译： 可溶性和热稳定性的苯并三唑UV吸收剂，其中R 1为氢或氯，R 2为烷基或-CH 2 CH 2 COOR 4，其中R 4为氢，烷基或被羟基取代的烷基，R 3为α-枯烯基 为电涂，底漆或透明涂层提供优异的光稳定性保护。 2-（2-羟基-3-甲基 - 枯基-5-叔辛基苯基）-2H-苯并三唑的新的可溶性晶体形式是特别有效的。
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公开(公告)号：US5545786A
公开(公告)日：1996-08-13
申请号：US383279
申请日：1995-02-03
IPC分类号： C07B63/04 , C07C7/04 , C07C7/20 , C07C15/44 , C07C303/42 , C07C309/29 , C07C5/10
摘要： Nitroxyl inhibitors in combination with some oxygen reduce the premature polymerization of vinyl aromatic monomers during the manufacturing processes for such monomers. Even small quantities of air used in combination with the nitroxyl inhibitors result in vastly prolonged inhibition times for said monomers.
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10.发明授权
公开(公告)号：US5583247A
公开(公告)日：1996-12-10
申请号：US422285
申请日：1995-04-14
IPC分类号： C07D295/16 , C07B63/04 , C07C7/20 , C07C15/46 , C07C45/51 , C07C49/603 , C07C49/647 , C07C49/683 , C07C49/747 , C07C49/753 , C07C49/798 , C07C59/80 , C07C59/82 , C07C67/62 , C07C69/007 , C07C69/145 , C07C69/24 , C07C69/54 , C07C69/738 , C07C69/78 , C07C205/45 , C07C235/78 , C07C255/31 , C07C255/40 , C07F9/38 , C07F9/40 , C08F2/38 , C08F2/40 , C08K5/00 , C09K15/08 , C09K15/24 , C09K15/32 , C07D64/00
CPC分类号： C07C59/80 , C07B63/04 , C07C205/45 , C07C255/31 , C07C45/512 , C07C49/647 , C07C49/683 , C07C49/747 , C07C49/753 , C07C69/007 , C07C69/738 , C07C7/20 , C07F9/3826 , C07F9/4015 , C07C2101/14
摘要： Ethylenically unsaturated monomers are protected from premature polymerization during manufacture and storage by the incorporation therein of an effective stabilizing amount of a 7-substituted quinone methide compound.
摘要翻译： 乙烯基不饱和单体通过在其中加入有效稳定量的7-取代醌甲基化合物而在制备和储存过程中避免过早聚合。
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