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公开(公告)号：US4430198A
公开(公告)日：1984-02-07
申请号：US425846
申请日：1982-09-28
摘要： An improved hydrotreating catalyst, and a process for using thereof, comprises a conventional Group VIA and Group VIIIA metal metal oxide or metal sulfide, deposited on an inorganic refractory support and about 0.1% by weight to about 7% by weight of the catalyst of a promoter comprising a halogenated metal selected from the Group consisting of halogenated metals of Group IB, IIB, IIIB, titanium and tin. The presence of the promoter results in greater degree of desulfurization and in CCR reduction of hydrocarbon feedstocks, especially highly aromatic petroleum residua and synthetically-derived hydrocarbons, e.g., coal liquids.
摘要翻译： 改进的加氢处理催化剂及其使用方法包括沉积在无机耐火载体上的常规的VIA族和VIIIA族金属氧化物或金属硫化物，和约0.1重量％至约7重量％的催化剂 促进剂，其包含选自组IB，IIB，IIIB，钛和锡的卤化金属的卤代金属。 促进剂的存在导致更大程度的脱硫和在烃原料，特别是高度芳族的石油残渣和合成衍生的烃例如煤液中的CCR还原。
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公开(公告)号：US4442023A
公开(公告)日：1984-04-10
申请号：US467573
申请日：1983-02-17
摘要： An improved hydrotreating catalyst, and a process for using thereof, comprises a conventional Group VIA and Group VIIIA metal oxide or metal sulfide, deposited on an inorganic refractory support and about 0.1% by weight to about 7% by weight of the catalyst of a promoter comprising a halogenated metal selected from the Group consisting of halogenated metals of Group IB, IIB, IIIB, titanium and tin. The presence of the promoter results in greater degree of desulfurization and in CCR reduction of hydrocarbon feedstocks, especially highly aromatic petroleum residue and synthetically-derived hydrocarbons, e.g., coal liquids.
摘要翻译： 一种改进的加氢处理催化剂及其使用方法包括沉积在无机耐火载体上的常规的VIA族和VIIIA族金属氧化物或金属硫化物，和约0.1重量％至约7重量％的促进剂催化剂 其包含选自组IB，IIB，IIIB，钛和锡的卤化金属的卤化金属。 促进剂的存在导致更大程度的脱硫和在烃原料，特别是高度芳族的石油残余物和合成衍生的烃例如煤液中的CCR还原。
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公开(公告)号：US4267033A
公开(公告)日：1981-05-12
申请号：US86876
申请日：1979-10-22
CPC分类号： C10G45/08 , B01J23/85 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061
摘要： Desulfurization, denitrogenation, deoxygenation and CCR reduction of highly aromatic petroleum and coal derived liquids are conducted with hydrogen and with a refractory base catalyst incorporating at least one Group VIA metal and at least one Group VIII metal. The catalyst has a surface area of between about 100 and 300 m.sup.2 /g and a total pore volume of between about 0.3 and 1.0 cc/g and is further characterized as follows:______________________________________ Pore Volume Distribution, Volume % in Pores of ______________________________________ 0-150 Angstroms diameter 20-40 150-200 Angstroms diameter 40-60 200+ Angstroms diameter 10-30 ______________________________________
摘要翻译： 使用氢气和掺入至少一种VIA族金属和至少一种第Ⅷ族金属的耐火碱催化剂进行高度芳香族石油和煤衍生液体的脱硫，脱氮，脱氧和降低CCR。 催化剂的表面积为约100至300m2 / g，总孔体积为约0.3至1.0cc / g，并进一步表征如下： - 孔体积分布， - 0- 150埃直径20-40-150-200埃直径40-60 -200+埃直径10-30 -
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公开(公告)号：US4357263A
公开(公告)日：1982-11-02
申请号：US216896
申请日：1980-12-16
CPC分类号： B01J23/85 , B01J35/10 , C10G45/08 , B01J35/1019 , B01J35/1042 , B01J35/1061
摘要： Desulfurization, denitrogenation, deoxygenation and CCR reduction of highly aromatic petroleum and coal derived liquids are conducted with hydrogen and with a refractory base catalyst incorporating at least one Group VIA metal and at least one Group VIII metal. The catalyst has a surface area of between about 100 and 300 m.sup.2 /g and a total pore volume of between about 0.3 and 1.0 cc/g and is further characterized as follows:______________________________________Pore Volume Distribution,Volume % in Pores of______________________________________0-150 Angstroms diameter 20-40150-200 Angstroms diameter 40-60200+ Angstroms diameter 10-30______________________________________
摘要翻译： 使用氢气和掺入至少一种VIA族金属和至少一种第Ⅷ族金属的耐火碱催化剂进行高度芳香族石油和煤衍生液体的脱硫，脱氮，脱氧和降低CCR。 催化剂的表面积为约100-300m2 / g，总孔体积为约0.3至1.0cc / g，并进一步表征如下： - 孔体积分布，-0- 150埃直径20-40-150-200埃直径40-60 -200+埃直径10-30 -
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公开(公告)号：US09719034B2
公开(公告)日：2017-08-01
申请号：US14546565
申请日：2014-11-18
申请人： Stuart S. Shih , Gary P. Schleicher , Michael B. Carroll , Timothy L. Hilbert , Stephen J. McCarthy , William J. Novak
发明人： Stuart S. Shih , Gary P. Schleicher , Michael B. Carroll , Timothy L. Hilbert , Stephen J. McCarthy , William J. Novak
IPC分类号： C10G45/64 , C10G69/02 , C10M103/06 , B01J35/10 , C10G65/04 , C10G65/12 , B01J23/883 , B01J23/888 , B01J29/78
CPC分类号： C10G69/02 , B01J23/883 , B01J23/888 , B01J29/78 , B01J29/7846 , B01J29/7861 , B01J29/7884 , B01J29/7892 , B01J35/1014 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C10G65/043 , C10G65/12 , C10G2300/1048 , C10G2300/203 , C10G2300/301 , C10G2300/302 , C10G2300/307 , C10G2400/04 , C10G2400/10 , C10M103/06
摘要： Methods are provided for processing a gas oil boiling range feedstock, such as a vacuum gas oil, in a single reaction stage and/or without performing intermediate separations. The methods are suitable for forming lubricants and distillate fuels while reducing or minimizing the production of lower boiling products such as naphtha and light ends. The methods can provide desirable yields of distillate fuels and lubricant base oils without requiring separate catalyst beds or stages for dewaxing and hydrocracking. The methods are based in part on use of a dewaxing catalyst that is tolerant of sour processing environments while still providing desirable levels of activity for both feed conversion and feed isomerization.
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6.发明授权公开(公告)号：US09487714B2
公开(公告)日：2016-11-08
申请号：US14011061
申请日：2013-08-27
CPC分类号： C10G65/10 , C10G47/18 , C10G49/04 , C10G65/12 , C10G2300/1074 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/307 , C10G2300/4018 , C10G2300/4025 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.
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公开(公告)号：US20150275106A1
公开(公告)日：2015-10-01
申请号：US14629997
申请日：2015-02-24
申请人： Nicole D. Vaughn , Teck-Mui Hoo , Michael B. Carroll , Stuart S. Shih , Eric D. Joseck , William J. Novak
发明人： Nicole D. Vaughn , Teck-Mui Hoo , Michael B. Carroll , Stuart S. Shih , Eric D. Joseck , William J. Novak
IPC分类号： C10G67/02 , C10M101/02
CPC分类号： C10G67/02 , C10G65/043 , C10G65/12 , C10G2300/1096 , C10G2300/301 , C10G2400/10 , C10M101/02
摘要： Methods are provided for producing Group II/III lubricant base oil products where at least a portion of the feedstock for forming the lubricant base oil product is a solvent extract fraction from a Group I lubricant production facility. This can increase the overall volume of feedstock available for production of Group II/III lubricant base oils by using a lower value stream (Group I solvent extract) as a portion of the feedstock. The solvent extract fraction can be added to a full range lubricant feedstock or to a portion of a lubricant feedstock, such as adding an extract fraction to a higher viscosity portion (such as a heavy neutral portion) of a feedstock for lubricant production, while a lower viscosity portion (such as a light neutral portion) is processed without addition of an extract fraction.
摘要翻译： 提供用于生产组II / III润滑剂基础油产品的方法，其中用于形成润滑剂基础油产品的原料的至少一部分是来自第I组润滑剂生产设备的溶剂提取物部分。 这可以通过使用较低价值的流（I类溶剂提取物）作为原料的一部分来增加可用于生产II / III族润滑油基础油的原料的总体积。 可以将溶剂萃取馏分加入到全润滑油原料中或一部分润滑剂原料中，例如将提取物馏分加入用于润滑剂生产的原料的较高粘度部分（例如重中性部分），而 低粘度部分（如轻中性部分）被加工而不添加萃取部分。
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公开(公告)号：US08852425B2
公开(公告)日：2014-10-07
申请号：US12946353
申请日：2010-11-15
申请人： Benjamin S. Umansky , Berne K. Stober , Carlos N. Lopez , Stuart S. Shih , Timothy L. Hilbert , Andre T. Sims , William J. Tracy, III , Akira Murata , Paul W. Kamienski
发明人： Benjamin S. Umansky , Berne K. Stober , Carlos N. Lopez , Stuart S. Shih , Timothy L. Hilbert , Andre T. Sims , William J. Tracy, III , Akira Murata , Paul W. Kamienski
CPC分类号： C10G45/02 , B01D3/141 , C10G7/00 , C10G47/00 , C10G65/043 , C10G65/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/202 , C10G2300/304 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/04 , Y02P30/20
摘要： A divided wall column allows for fractionation of multiple streams while maintaining separate product qualities. Effluents from multiple stages of a reaction system can be processed in a single divided wall column. The divided wall column can produce multiple cuts from each separated area, as well as at least one output from a common area.
摘要翻译： 分隔壁柱允许分离多个流，同时保持单独的产品质量。 来自反应体系的多个阶段的流出物可以在单个分隔壁塔中进行处理。 分隔壁柱可以从每个分离的区域产生多个切割，以及从公共区域产生至少一个输出。
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9.发明授权Hydrocracking process selective for improved distillate and improved lube yield and properties 有权加氢裂化过程选择性改善馏出物和改善润滑油产量和性能公开(公告)号：US08557106B2
公开(公告)日：2013-10-15
申请号：US13237361
申请日：2011-09-20
CPC分类号： C10G65/10 , C10G47/18 , C10G49/04 , C10G65/12 , C10G2300/1074 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/307 , C10G2300/4018 , C10G2300/4025 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.
摘要翻译： 本发明涉及一种包含进料流加氢裂化的方法，其中转化馏分可表现出相对较高的馏出物产物产率和维持或改善的馏出物燃料性质，而未转化的馏分可表现出在润滑剂区域特别有用的改进的性能。 在该加氢裂化过程中，相对于转化的馏出物燃料和未转化的润滑剂，可以有利于减少或最小化汽油燃料应用的转化/未转化产物的产率。 可以选择催化剂和条件以帮助实现或优化所需的产物产率和/或性能。
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公开(公告)号：US20120000817A1
公开(公告)日：2012-01-05
申请号：US13169170
申请日：2011-06-27
申请人： Stuart S. Shih
发明人： Stuart S. Shih
IPC分类号： C10G49/00
CPC分类号： C10G65/04 , C10G45/10 , C10G45/12 , C10G2300/1048 , C10G2300/202 , C10G2300/301 , C10G2300/304 , C10G2300/4006 , C10G2300/4018 , C10G2400/04 , C10G2400/08
摘要： In a process for producing a low color diesel and/or kerosene fuel, a middle distillate feed can be supplied to a reactor having at least one first catalyst bed containing a first desulfurization and/or isomerization catalyst and at least one second catalyst bed containing a decolorization catalyst downstream from the first catalyst bed(s). The feed can be reacted with the hydrogen in the presence of the first catalyst at a temperature from about 290° C. to about 430° C. to produce a first liquid effluent, which can be cooled by about 10° C. to about 40° C. with a quench medium and cascaded to the at least one second catalyst bed. The cooled first liquid effluent can then be reacted with hydrogen in the presence of the decolorization catalyst at a temperature from about 280° C. to about 415° C. to produce a second effluent having an ASTM color less than 2.5.
摘要翻译： 在生产低色柴油和/或煤油燃料的方法中，中间馏分料可以供给至具有至少一个含有第一脱硫和/或异构化催化剂的第一催化剂床和至少一个含有 脱色催化剂从第一催化剂床下游。 在约290℃至约430℃的温度下，进料可以在第一催化剂存在下与氢反应，以产生第一液体流出物，其可被冷却约10℃至约40℃ ℃，并与骤冷介质并级联至至少一个第二催化剂床。 然后在约280℃至约415℃的温度下，将冷却的第一液体流出物在脱色催化剂存在下与氢气反应，以产生ASTM颜色小于2.5的第二流出物。
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