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    Branched polyesters with sulfonate groups
    3.
    发明授权
    Branched polyesters with sulfonate groups 有权
    具有磺酸基团的支化聚酯

    公开(公告)号：US08901066B2

    公开(公告)日：2014-12-02

    申请号：US13495512

    申请日：2012-06-13

    申请人： Monika Haberecht ,  Juergen Detering ,  Bernd Bruchmann ,  Helmut Witteler ,  Heike Weber ,  Karl Kolter

    发明人： Monika Haberecht ,  Juergen Detering ,  Bernd Bruchmann ,  Helmut Witteler ,  Heike Weber ,  Karl Kolter

    IPC分类号： C11D3/37 ,  C11D1/00 ,  B08B3/04 ,  C08G63/91 ,  C02F5/10 ,  C08G63/688

    CPC分类号： C02F5/10 ,  C08G63/6884 ,  C08G63/918 ,  C11D3/378

    摘要： Branched polyesters with sulfonate groups can be obtained by reacting components A, B, optionally C, and optionally D to yield branched polyesters, then reacting these branched polyesters with hydrogen sulfite. Component A is at least one α,β-olefinically unsaturated dicarboxylic acid, component B is at least one di- or higher-functional alcohol, optional component C is at least one di- or higher-functional carboxylic acid or hydroxycarboxylic acid without an α,β-olefinically unsaturated bond, and optional component D is at least one compound of formula CH3(—O—CH2—CH2)n—OH. In reacting the branched polyesters with hydrogen sulfite, a molar amount of hydrogen sulfite is at most 95 mol %, based on an amount of α,β-olefinically unsaturated dicarboxylic acid.

    摘要翻译： 具有磺酸盐基团的支链聚酯可以通过使组分A，B，任选地C和任选的D反应得到支链聚酯，然后使这些支化聚酯与亚硫酸氢钠反应而获得。 组分A是至少一种α，β-烯属不饱和二羧酸，组分B是至少一种二官能或更高官能的醇，任选的组分C是至少一种二官能或更高官能的羧酸或羟基羧酸，没有 α，β-烯属不饱和键，任选的组分D是至少一种式CH3（-O-CH2-CH2）n-OH的化合物。 在使支化聚酯与亚硫酸氢钠反应时，基于α，α-烯属不饱和二羧酸的量，亚硫酸氢的摩尔量为至多95摩尔％。

    Alkoxylated Hyperbranched Polycarbonates for Solubilizing Poorly Soluble Active Ingredients
    4.
    发明申请
    Alkoxylated Hyperbranched Polycarbonates for Solubilizing Poorly Soluble Active Ingredients 有权
    用于溶解不良溶解活性成分的烷氧基化超支化聚碳酸酯

    公开(公告)号：US20120309629A1

    公开(公告)日：2012-12-06

    申请号：US13514332

    申请日：2010-12-03

    申请人： Holger Türk ,  Monika Haberecht ,  Bernd Bruchmann ,  Andreas Kunst ,  Daniel Schönfelder ,  Michael Ishaque

    发明人： Holger Türk ,  Monika Haberecht ,  Bernd Bruchmann ,  Andreas Kunst ,  Daniel Schönfelder ,  Michael Ishaque

    IPC分类号： A01N25/02 ,  A61K8/85 ,  A01P13/00 ,  C07C69/96 ,  A01P3/00 ,  A01P7/04 ,  A01P7/02 ,  A61K47/34 ,  A01P21/00

    CPC分类号： A01N25/30 ,  C08G64/0216 ,  A01N47/24

    摘要： The present invention provides a composition comprising an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, and an amphiphile comprising an alkoxylated hyperbranched polycarbonate, wherein the polycarbonate comprises an alcohol which is a trifunctional or higher polyfunctional polyetherol based on a C3-C12 alkylene oxide and an alcohol which has at least three OH groups. Likewise provided is an amphiphile comprising the polycarbonate, and a process for preparing the amphiphile. The invention further relates to the use of the amphiphile for solubilizing an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, in aqueous solutions, and a method of controlling phytopathogenic fungi and/or unwanted plant growth and/or unwanted insect or mite infestation and/or of regulating the growth of plants.

    摘要翻译： 本发明提供一种组合物，其包含其在20℃下在水中的溶解度不超过10g / L的活性成分和包含烷氧基化超支化聚碳酸酯的两亲物，其中所述聚碳酸酯包含三官能或更高官能度的醇 基于C3-C12环氧烷的聚醚类和具有至少三个OH基的醇。 同样提供包含聚碳酸酯的两亲物和制备两亲物的方法。 本发明还涉及两亲物在水溶液中溶解在20℃下在水中的溶解度不超过10g / L的活性成分的用途，以及控制植物病原真菌和/或不需要的植物生长的方法 和/或不期望的昆虫或螨虫侵袭和/或调节植物的生长。

    Highly branched polymers as cross-linking agents in microcapsule wall
    7.
    发明授权
    Highly branched polymers as cross-linking agents in microcapsule wall 有权
    高分支聚合物作为微胶囊壁中的交联剂

    公开(公告)号：US09056302B2

    公开(公告)日：2015-06-16

    申请号：US13376226

    申请日：2010-06-11

    申请人： Marc Rudolf Jung ,  Francisco Javier Lopez Villanueva ,  Tina Schroeder-Grimonpont ,  Monika Haberecht ,  Bernd Bruchmann

    发明人： Marc Rudolf Jung ,  Francisco Javier Lopez Villanueva ,  Tina Schroeder-Grimonpont ,  Monika Haberecht ,  Bernd Bruchmann

    IPC分类号： B01J13/14 ,  A61K8/11 ,  A61K8/81 ,  C09B67/02 ,  F28D20/02

    CPC分类号： B01J13/14 ,  A61K8/11 ,  A61K8/8147 ,  A61K2800/412 ,  C09B67/0097 ,  F28D20/023 ,  Y02E60/145 ,  Y10T428/2989

    摘要： The present invention relates to microcapsules comprising a capsule core and a capsule wall, obtainable by a process comprising the free-radical polymerization of an oil-in-water emulsion which comprises the following constituents: 30 to 90% by weight based on the total weight of the monomers of one or more monomers (monomers I) from the group comprising C1-C24-alkyl esters of acrylic acid and/or methacrylic acid, acrylic acid, methacrylic acid, maleic acid, fumaric acid and itaconic acid 10 to 70% by weight based on the total weight of the monomers of one or more ethylenically unsaturated crosslinkers (monomers II), where at least 10% by weight, based on the total weight of the monomers I, II and III, is a highly branched polymeric crosslinker, 0 to 30% by weight based on the total weight of the monomers of one or more monounsaturated monomers (monomer III), which are different from the monomers I, and a hydrophobic core material, to a process for their preparation and to their use.

    摘要翻译： 本发明涉及包含胶囊核心和胶囊壁的微胶囊，其通过包括以下组分的水包油乳液的自由基聚合的方法获得：基于总重量为30至90重量％ 的单体（单体I）来自包含丙烯酸和/或甲基丙烯酸的C 1 -C 24烷基酯，丙烯酸，甲基丙烯酸，马来酸，富马酸和衣康酸的单体（单体I）10至70％ 基于一种或多种烯键式不饱和交联剂（单体II）的单体的总重量，其中至少10重量％，基于单体I，II和III的总重量是高度支化的聚合物交联剂， 0〜30重量％，其与单体I不同的一种或多种单不饱和单体（单体III）和疏水性核心材料的单体的总重量相对于其制备方法及其用途。