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    Polymer bound multidentate complexes
    5.
    发明授权
    Polymer bound multidentate complexes 失效
    聚合物结合的多齿络合物

    公开(公告)号：US4330642A

    公开(公告)日：1982-05-18

    申请号：US245578

    申请日：1981-03-20

    申请人： John H. Gaul, Jr. ,  Russell S. Drago

    发明人： John H. Gaul, Jr. ,  Russell S. Drago

    IPC分类号： C08F8/28 ,  C08F8/32 ,  C08F8/42 ,  C08F8/30 ,  C08F8/04

    CPC分类号： C08F8/28 ,  C08F2810/20

    摘要： Polymer bound multidentate complexes are prepared by reacting pendant benzyl chloride and benzyl iodide groups on a variety of polymer supports, including crosslinked polystyrene, with 3,3'-iminodiproprionitrile and reducing the nitrile groups by treatment with, for example, a boron hydride-tetrahydrofuran complex to form the amine. The amine is a precursor for other ligand systems; for example, the primary amine groups formed condense with an aldehyde or ketone to yield five coordinate Schiff base ligands. The polydentate amine ligand systems are useful for synthesis of chelating agents for sequestering metal ions from solution for purification or concentration purposes. Metal complexes of these ligands with manganese, iron, cobalt, nickel, copper, and zinc can be prepared which are useful as heterogeneous oxidation catalysts.

    摘要翻译： 通过使各种聚合物载体（包括交联聚苯乙烯）与3,3'-亚氨基二丙腈反应，将苄基氯和苄基碘基团反应，通过用例如硼氢化物 - 四氢呋喃处理来还原腈基来制备聚合物结合的多齿络合物 复合以形成胺。 胺是其他配体体系的前体; 例如，伯胺基团与醛或酮缩合以产生五配位席夫碱配体。 多齿胺配体体系可用于合成螯合剂，用于从溶液中螯合金属离子用于纯化或浓缩。 可以制备这些配体与锰，铁，钴，镍，铜和锌的金属络合物，其可用作非均相氧化催化剂。

    Zeolite containing entrapped anionic material
    8.
    发明授权
    Zeolite containing entrapped anionic material 失效
    含有截留阴离子材料的沸石

    公开(公告)号：US4830999A

    公开(公告)日：1989-05-16

    申请号：US16737

    申请日：1987-02-20

    申请人： Russell S. Drago ,  Iwona Bresinska

    发明人： Russell S. Drago ,  Iwona Bresinska

    IPC分类号： B01J29/08 ,  B01J29/70

    CPC分类号： B01J29/082 ,  B01J29/084 ,  B01J29/7003

    摘要： A composition comprising a crystalline aluminosilicate zeolite having entrapped therein as an ion pair an anionic material having the formula ML.sub.n.sup.-n+m, wherein M is a metal, L is an anionic ligand, which coordinates more strongly to M than to the surface of said zeolite, n is the number of ligands bound to the metal ion and is an integer from 1 to 6, and m is the oxidation state of the metal.

    摘要翻译： 一种组合物，其包含作为离子对截留的结晶铝硅酸盐沸石，其具有式MLn-n + m的阴离子材料，其中M是金属，L是阴离子配体，其比M的表面比M 沸石，n是与金属离子结合的配体的数量，为1〜6的整数，m为金属的氧化态。

    Heterogeneous anionic transition metal catalysts
    9.
    发明授权
    Heterogeneous anionic transition metal catalysts 失效
    非均相阴离子过渡金属催化剂

    公开(公告)号：US4417077A

    公开(公告)日：1983-11-22

    申请号：US342689

    申请日：1982-01-26

    申请人： Russell S. Drago ,  Anton El A'mma

    发明人： Russell S. Drago ,  Anton El A'mma

    IPC分类号： B01J31/08 ,  B01J31/16 ,  B01J31/20 ,  C07C45/50 ,  C07C51/12

    CPC分类号： B01J31/165 ,  B01J31/08 ,  B01J31/20 ,  C07C45/50 ,  C07C51/12 ,  B01J2231/321 ,  B01J2531/822

    摘要： Novel heterogeneous catalysts consist essentially of an anion exchange resin to which is bound ionically an anionic metal carbonyl species having the general formula M.sub.n (CO).sub.m (X).sub.p.sup.z- where M is a transition metal such as for example rhodium, cobalt, ruthenium, osmium, iridium, or iron; X is an anion, for example halide, hydride, or alkyl; n ranges from 1 to 12; m ranges from 1 to 34; p ranges from 0 to 2n+1; and z is an integer charge ranging from 1 to 5. The catalyst in which M is rhodium, m=2, p=2, n=1,and z=1 is highly effective for the carbonylation of alcohols to acids and esters. Many of these anionic species have utility in the hydroformylation of olefins.

    摘要翻译： 新型非均相催化剂基本上由阴离子交换树脂组成，其中离子性地结合具有通式Mn（CO）m（X）pz-的阴离子金属羰基物质，其中M是过渡金属，例如铑，钴，钌， 锇，铱或铁; X是阴离子，例如卤化物，氢化物或烷基; n范围从1到12; m范围从1到34; p范围从0到2n + 1; 并且z是1至5的整数.M是铑，m = 2，p = 2，n = 1和z = 1的催化剂对于将醇羰基化成酸和酯是非常有效的。 许多这些阴离子物质在烯烃的加氢甲酰化中具有效用。