Sulfonated and non-sulfonated, thiol, and hydroxy functional
polyurethanes and graft copolymers made therewith
    4.
    发明授权
    Sulfonated and non-sulfonated, thiol, and hydroxy functional polyurethanes and graft copolymers made therewith 失效
    磺化和非磺化,硫醇和羟基官能的聚氨酯和由其制备的接枝共聚物

    公开(公告)号:US5218072A

    公开(公告)日:1993-06-08

    申请号:US917461

    申请日:1992-07-21

    摘要: The invention relates to a sulfonated, thiol, and hydroxy-functional polyurethane polymer which comprises: (i) a polyurethane backbone; (ii) at least one SO.sub.3 M group pendant from the polyurethane backbone, wherein the polyurethane backbone has an SO.sub.3 M equivalent weight of from about 2,000 to about 100,000, and wherein M is selected from the group consisting of H.sup.+, NR.sub.4.sup.+ wherein R can be H.sup.+ or an alkyl group, Li.sup.+, Na.sup.+, K.sup.+, and mixtures thereof; (iii) at least two crosslinkable hydroxy groups pendant from the polyurethane backbone, wherein the polyurethane backbone has a hydroxy equivalent weight of from about 500 to about 50,000; and (iv) at least one --SD group pendant from the polyurethane backbone. The invention also relates to vinyl/polyurethane copolymers made therewith which are particularly useful as binders in magnetic recording media and a method of making the copolymers. The invention also relates to certain nonsulfonated thiol and hydroxy functional polyurethane graft copolymers and dispersions made therewith.

    摘要翻译: 本发明涉及磺化,硫醇和羟基官能的聚氨酯聚合物,其包括:(i)聚氨酯主链; (ii)来自聚氨酯主链的至少一个SO 3 M基团,其中聚氨酯主链具有约2,000至约100,000的SO 3 M当量,并且其中M选自H +,NR4 +,其中R可以是H +或 烷基,Li +,Na +,K +及其混合物; (iii)从聚氨酯主链悬挂的至少两个可交联羟基,其中聚氨酯主链具有约500至约50,000的羟基当量; 和(iv)来自聚氨酯主链的至少一个-SD基团侧基。 本发明还涉及由其制备的乙烯基/聚氨酯共聚物,其特别用作磁记录介质中的粘合剂和制备该共聚物的方法。 本发明还涉及某些非磺化硫醇和羟基官能聚氨酯接枝共聚物和由其制成的分散体。

    Water-based release coating containing fluorochemical
    5.
    发明授权
    Water-based release coating containing fluorochemical 有权
    含氟化合物的水性防粘涂层

    公开(公告)号:US07411020B2

    公开(公告)日:2008-08-12

    申请号:US11027606

    申请日:2004-12-28

    IPC分类号: C09D133/00 B32B33/00

    摘要: In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.

    摘要翻译: 一方面,本发明提供了一种水性防粘涂料组合物,其包含以下混合物:A.从0.1至约5wt%的氟(甲基)丙烯酸酯(共)聚合物或含有至少一个氟化基团的含氟氨基甲酸酯化合物 具有式 - (CF 2)n CF 3,其中n为1至3的整数; B.约5至约99.9重量%的包含a的反应产物的共聚物。 约40至约70重量%的(甲基)丙烯酸烷基酯,其中烷基含有16至22个碳原子,b。 约3至约20重量%的(甲基)丙烯酸,c。 约20至约40重量%的丙烯腈,以及d。 0至约15重量%的乙烯基单体,除了丙烯腈,其中a。 通过d。 等于100%; 和C.0至约94.9重量%的增量聚合物,其中A.,B.和C.的总和为100%,wt%基于组合物中固体的总量。

    FLUOROACRYLATE-MULTIFUNCTIONAL ACRYLATE COPOLYMER COMPOSITIONS
    10.
    发明申请
    FLUOROACRYLATE-MULTIFUNCTIONAL ACRYLATE COPOLYMER COMPOSITIONS 有权
    氟代丙烯酸酯多官能丙烯酸酯共聚物组合物

    公开(公告)号:US20080132132A1

    公开(公告)日:2008-06-05

    申请号:US12028589

    申请日:2008-02-08

    IPC分类号: C08F14/18 B32B27/00 B32B27/04

    摘要: A composition comprises a copolymer comprising repeating units derived from at least one co-reactant comprising two or more acrylate groups and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion; wherein the composition is coatable.

    摘要翻译: 组合物包含共聚物,其包含衍生自至少一种包含两个或更多个丙烯酸酯基团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元,所述重复单元包含以下反应产物:(a)至少一种由下式表示的含氟醇: in-line-formula description =“In-line Formulas”end =“lead”?> C 3 -X-OH <?in-line-formula description 其中:R =氢或1至4个碳原子的烷基,m = 2至8,R f = C 1, n = 2〜1,n = 1〜5,y = 0〜6,q = 1〜8; (b)至少一种非支化对称二异氰酸酯; 和(c)至少一种羟基封端的(甲基)丙烯酸烷基酯或其亚烷基部分具有2-30个碳原子的2-氟丙烯酸酯单体; 其中所述组合物是可涂覆的。