公开(公告)号：US09083051B2

公开(公告)日：2015-07-14

申请号：US13577843

申请日：2011-02-09

申请人： Kunchan Lee ,  Ryoko Konta ,  Masaki Horikita ,  Chunfu Yu ,  Yasuaki Wakizaka ,  Kenichiro Ota ,  Ryuji Monden ,  Kazunori Ichioka ,  Takashi Sato ,  Takuya Imai

发明人： Kunchan Lee ,  Ryoko Konta ,  Masaki Horikita ,  Chunfu Yu ,  Yasuaki Wakizaka ,  Kenichiro Ota ,  Ryuji Monden ,  Kazunori Ichioka ,  Takashi Sato ,  Takuya Imai

IPC分类号： H01M4/04 ,  H01M4/90 ,  B01J23/74 ,  B01J23/75 ,  B01J37/00 ,  B01J37/08 ,  B01J37/18 ,  C01B21/082 ,  H01M4/88 ,  H01M8/10

摘要： Provided is a process for producing a fuel cell electrode catalyst having high catalytic activity which uses a transition metal, e.g., titanium, which process comprises thermal treatment at relatively low temperature, i.e., not including thermal treatment at high temperature (calcining) step. The process for producing a fuel cell electrode catalyst comprises a step (1) of mixing at least a transition metal-containing compound, a nitrogen-containing organic compound and a solvent to provide a catalyst precursor solution; a step (2) of removing the solvent from the catalyst precursor solution; and a step (3) of thermally treating a solid residue obtained in the step (2) at a temperature of 500 to 1100° C. to provide an electrode catalyst; wherein the transition metal-containing compound is partly or wholly a compound comprising at least one transition metal element (M1) selected from the group 4 and 5 elements of the periodic table as a transition metal element.

公开(公告)号：US20120315568A1

公开(公告)日：2012-12-13

申请号：US13577843

申请日：2011-02-09

申请人： Kunchan Lee ,  Ryoko Konta ,  Masaki Horikita ,  Chunfu Yu ,  Yasuaki Wakizaka ,  Kenichiro Ota ,  Ryuji Monden ,  Kazunori Ichioka ,  Takashi Sato ,  Takuya Imai

发明人： Kunchan Lee ,  Ryoko Konta ,  Masaki Horikita ,  Chunfu Yu ,  Yasuaki Wakizaka ,  Kenichiro Ota ,  Ryuji Monden ,  Kazunori Ichioka ,  Takashi Sato ,  Takuya Imai

IPC分类号： H01M4/90 ,  C01B21/082 ,  B01J27/24 ,  H01M4/96 ,  H01M8/10

CPC分类号： H01M4/9016 ,  C01B21/0828 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/8896 ,  H01M8/1004 ,  Y02E60/521

摘要： Provided is a process for producing a fuel cell electrode catalyst having high catalytic activity which uses a transition metal, e.g., titanium, which process comprises thermal treatment at relatively low temperature, i.e., not including thermal treatment at high temperature (calcining) step. The process for producing a fuel cell electrode catalyst comprises a step (1) of mixing at least a transition metal-containing compound, a nitrogen-containing organic compound and a solvent to provide a catalyst precursor solution; a step (2) of removing the solvent from the catalyst precursor solution; and a step (3) of thermally treating a solid residue obtained in the step (2) at a temperature of 500 to 1100° C. to provide an electrode catalyst; wherein the transition metal-containing compound is partly or wholly a compound comprising at least one transition metal element (M1) selected from the group 4 and 5 elements of the periodic table as a transition metal element.

摘要翻译： 提供了一种使用过渡金属（例如钛）具有高催化活性的燃料电池电极催化剂的方法，该方法包括在较低温度下的热处理，即不包括在高温（煅烧）步骤的热处理。 制造燃料电池电极催化剂的方法包括将至少含过渡金属的化合物，含氮有机化合物和溶剂混合以提供催化剂前体溶液的步骤（1） 从催化剂前体溶液中除去溶剂的步骤（2）; 以及在500〜1100℃的温度下热处理步骤（2）中得到的固体残渣以提供电极催化剂的步骤（3）; 其中所述含过渡金属的化合物部分或全部为包含至少一种选自周期表第4族和第5族元素的过渡金属元素（M1）作为过渡金属元素的化合物。

公开(公告)号：US20130295483A1

公开(公告)日：2013-11-07

申请号：US13979305

申请日：2011-08-09

申请人： Ryuji Monden ,  Takuya Imai ,  Yasuaki Wakizaka ,  Kunchan Lee ,  Takashi Sato

发明人： Ryuji Monden ,  Takuya Imai ,  Yasuaki Wakizaka ,  Kunchan Lee ,  Takashi Sato

IPC分类号： H01M4/90

CPC分类号： H01M4/9008 ,  B01J31/1658 ,  B01J31/1815 ,  B01J2231/324 ,  B01J2231/4205 ,  B01J2231/46 ,  B01J2231/70 ,  B01J2531/821 ,  B01J2531/827 ,  H01M4/88 ,  H01M4/9041 ,  H01M4/9083 ,  Y02E60/50

摘要： A method for producing a fuel cell electrode catalyst including a metal element selected from aluminum, chromium, manganese, iron, cobalt, nickel, copper, strontium, yttrium, tin, tungsten, and cerium and having high catalytic activity through heat treatment at comparatively low temperature. The method including: a step (1) of mixing at least a certain metal compound (1), a nitrogen-containing organic compound (2), and a solvent to obtain a catalyst precursor solution, a step (2) of removing the solvent from the catalyst precursor solution, and a step (3) of heat-treating a solid residue, obtained in the step (2), at a temperature of 500 to 1100° C. to obtain an electrode catalyst; a portion or the entirety of the metal compound (1) being a compound containing, as the metal element, a metal element M1 selected from aluminum, chromium, manganese, iron, cobalt, nickel, copper, strontium, yttrium, tin, tungsten, and cerium.

摘要翻译： 一种生产包括选自铝，铬，锰，铁，钴，镍，铜，锶，钇，锡，钨和铈的金属元素的燃料电池电极催化剂的方法，并且通过相对较低的热处理具有高催化活性 温度。 该方法包括：将至少一种金属化合物（1），含氮有机化合物（2）和溶剂混合以获得催化剂前体溶液的步骤（1），除去溶剂的步骤（2） 和催化剂前体溶液的步骤（3）和步骤（2）中获得的固体残渣热处理步骤（3），在500〜1100℃的温度下进行，得到电极催化剂; 金属化合物（1）的一部分或全部是含有选自铝，铬，锰，铁，钴，镍，铜，锶，钇，锡，钨中的金属元素M1作为金属元素的化合物， 和铈。

公开(公告)号：US09350025B2

公开(公告)日：2016-05-24

申请号：US13979305

申请日：2011-08-09

申请人： Ryuji Monden ,  Takuya Imai ,  Yasuaki Wakizaka ,  Kunchan Lee ,  Takashi Sato

发明人： Ryuji Monden ,  Takuya Imai ,  Yasuaki Wakizaka ,  Kunchan Lee ,  Takashi Sato

IPC分类号： H01M4/90 ,  H01M4/88 ,  B01J31/16 ,  B01J31/18

CPC分类号： H01M4/9008 ,  B01J31/1658 ,  B01J31/1815 ,  B01J2231/324 ,  B01J2231/4205 ,  B01J2231/46 ,  B01J2231/70 ,  B01J2531/821 ,  B01J2531/827 ,  H01M4/88 ,  H01M4/9041 ,  H01M4/9083 ,  Y02E60/50

摘要： A method for producing a fuel cell electrode catalyst including a metal element selected from aluminum, chromium, manganese, iron, cobalt, nickel, copper, strontium, yttrium, tin, tungsten, and cerium and having high catalytic activity through heat treatment at comparatively low temperature. The method including: a step (1) of mixing at least a certain metal compound (1), a nitrogen-containing organic compound (2), and a solvent to obtain a catalyst precursor solution, a step (2) of removing the solvent from the catalyst precursor solution, and a step (3) of heat-treating a solid residue, obtained in the step (2), at a temperature of 500 to 1100° C. to obtain an electrode catalyst; a portion or the entirety of the metal compound (1) being a compound containing, as the metal element, a metal element M1 selected from aluminum, chromium, manganese, iron, cobalt, nickel, copper, strontium, yttrium, tin, tungsten, and cerium.

摘要翻译： 一种生产包括选自铝，铬，锰，铁，钴，镍，铜，锶，钇，锡，钨和铈的金属元素的燃料电池电极催化剂的方法，并且通过相对较低的热处理具有高催化活性 温度。 该方法包括：将至少一种金属化合物（1），含氮有机化合物（2）和溶剂混合以获得催化剂前体溶液的步骤（1），除去溶剂的步骤（2） 和催化剂前体溶液的步骤（3）和步骤（2）中获得的固体残渣热处理步骤（3），在500〜1100℃的温度下进行，得到电极催化剂; 金属化合物（1）的一部分或全部是含有选自铝，铬，锰，铁，钴，镍，铜，锶，钇，锡，钨中的金属元素M1作为金属元素的化合物， 和铈。

公开(公告)号：US09136541B2

公开(公告)日：2015-09-15

申请号：US13577843

申请日：2011-02-09

申请人： Kunchan Lee ,  Ryoko Konta ,  Masaki Horikita ,  Chunfu Yu ,  Yasuaki Wakizaka ,  Kenichiro Ota ,  Ryuji Monden ,  Kazunori Ichioka ,  Takashi Sato ,  Takuya Imai

发明人： Kunchan Lee ,  Ryoko Konta ,  Masaki Horikita ,  Chunfu Yu ,  Yasuaki Wakizaka ,  Kenichiro Ota ,  Ryuji Monden ,  Kazunori Ichioka ,  Takashi Sato ,  Takuya Imai

IPC分类号： H01M4/04 ,  H01M4/90 ,  B01J23/74 ,  B01J23/75 ,  B01J37/00 ,  B01J37/08 ,  B01J37/18 ,  C01B21/082 ,  H01M4/88 ,  H01M8/10

CPC分类号： H01M4/9016 ,  C01B21/0828 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/8896 ,  H01M8/1004 ,  Y02E60/521

摘要： Provided is a process for producing a fuel cell electrode catalyst having high catalytic activity which uses a transition metal, e.g., titanium, which process comprises thermal treatment at relatively low temperature, i.e., not including thermal treatment at high temperature (calcining) step. The process for producing a fuel cell electrode catalyst comprises a step (1) of mixing at least a transition metal-containing compound, a nitrogen-containing organic compound and a solvent to provide a catalyst precursor solution; a step (2) of removing the solvent from the catalyst precursor solution; and a step (3) of thermally treating a solid residue obtained in the step (2) at a temperature of 500 to 1100° C. to provide an electrode catalyst; wherein the transition metal-containing compound is partly or wholly a compound comprising at least one transition metal element (M1) selected from the group 4 and 5 elements of the periodic table as a transition metal element.

摘要翻译： 提供了一种使用过渡金属（例如钛）具有高催化活性的燃料电池电极催化剂的方法，该方法包括在较低温度下的热处理，即不包括在高温（煅烧）步骤的热处理。 制造燃料电池电极催化剂的方法包括将至少含过渡金属的化合物，含氮有机化合物和溶剂混合以提供催化剂前体溶液的步骤（1） 从催化剂前体溶液中除去溶剂的步骤（2）; 以及在500〜1100℃的温度下热处理步骤（2）中得到的固体残渣以提供电极催化剂的步骤（3）; 其中所述含过渡金属的化合物部分或全部为包含至少一种选自周期表第4族和第5族元素的过渡金属元素（M1）作为过渡金属元素的化合物。

公开(公告)号：US09118083B2

公开(公告)日：2015-08-25

申请号：US13979333

申请日：2011-08-09

申请人： Ryuji Monden ,  Takuya Imai ,  Yasuaki Wakizaka ,  Kunchan Lee ,  Takashi Sato

发明人： Ryuji Monden ,  Takuya Imai ,  Yasuaki Wakizaka ,  Kunchan Lee ,  Takashi Sato

IPC分类号： H01M4/90 ,  H01M4/88 ,  B01J31/02 ,  B01J31/22 ,  B01J37/04 ,  B01J37/08

CPC分类号： H01M4/9008 ,  B01J31/0232 ,  B01J31/223 ,  B01J31/2239 ,  B01J2531/42 ,  B01J2531/57 ,  B01J2531/58 ,  B01J2531/62 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  B01J2540/42 ,  H01M4/88 ,  H01M4/9041 ,  Y02E60/50

摘要： A method for producing a fuel cell electrode catalyst, including: a step (1) of mixing at least a metal compound (1), a nitrogen-containing organic compound (2), a compound (3) containing fluorine and at least one element A selected from the group consisting of boron, phosphorus, and sulfur, and a solvent to obtain a catalyst precursor solution, a step (2) of removing the solvent from the catalyst precursor solution, and a step (3) of heat-treating a solid residue, obtained in the step (2), at a temperature of 500 to 1100° C. to obtain an electrode catalyst; a portion or the entirety of the metal compound (1) being a compound containing, as a metal element, at least one transition metal element M1 selected from the elements of group 4 and group 5 of the periodic table; and at least one of the compounds (1), (2), and (3) having an oxygen atom.

摘要翻译： 一种燃料电池用电极催化剂的制造方法，其特征在于，包括：将至少含有金属化合物（1），含氮有机化合物（2），含氟化合物（3）和至少一种元素 选自硼，磷和硫的A和选自催化剂前体溶液的溶剂，从催化剂前体溶液中除去溶剂的步骤（2）以及热处理步骤 在步骤（2）中获得的固体残余物在500至1100℃的温度下进行，以获得电极催化剂; 金属化合物（1）的一部分或全部是含有选自周期表的第4族和第5族的元素的至少一种过渡金属元素作为金属元素的化合物; 和具有氧原子的化合物（1），（2）和（3）中的至少一种。

公开(公告)号：US20130288154A1

公开(公告)日：2013-10-31

申请号：US13979333

申请日：2011-08-09

申请人： Ryuji Monden ,  Takuya Imai ,  Yasuaki Wakizaka ,  Kunchan Lee ,  Takashi Sato

发明人： Ryuji Monden ,  Takuya Imai ,  Yasuaki Wakizaka ,  Kunchan Lee ,  Takashi Sato

IPC分类号： H01M4/90

CPC分类号： H01M4/9008 ,  B01J31/0232 ,  B01J31/223 ,  B01J31/2239 ,  B01J2531/42 ,  B01J2531/57 ,  B01J2531/58 ,  B01J2531/62 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  B01J2540/42 ,  H01M4/88 ,  H01M4/9041 ,  Y02E60/50

摘要： A method for producing a fuel cell electrode catalyst, including: a step (1) of mixing at least a metal compound (1), a nitrogen-containing organic compound (2), a compound (3) containing fluorine and at least one element A selected from the group consisting of boron, phosphorus, and sulfur, and a solvent to obtain a catalyst precursor solution, a step (2) of removing the solvent from the catalyst precursor solution, and a step (3) of heat-treating a solid residue, obtained in the step (2), at a temperature of 500 to 1100° C. to obtain an electrode catalyst; a portion or the entirety of the metal compound (1) being a compound containing, as a metal element, at least one transition metal element M1 selected from the elements of group 4 and group 5 of the periodic table; and at least one of the compounds (1), (2), and (3) having an oxygen atom.

摘要翻译： 一种燃料电池用电极催化剂的制造方法，其特征在于，包括：将至少含有金属化合物（1），含氮有机化合物（2），含氟化合物（3）和至少一种元素 选自硼，磷和硫的A和选自催化剂前体溶液的溶剂，从催化剂前体溶液中除去溶剂的步骤（2）以及热处理步骤 在步骤（2）中获得的固体残余物在500至1100℃的温度下进行，以获得电极催化剂; 金属化合物（1）的一部分或全部是含有选自周期表的第4族和第5族的元素的至少一种过渡金属元素作为金属元素的化合物; 和具有氧原子的化合物（1），（2）和（3）中的至少一种。

公开(公告)号：US20140193739A1

公开(公告)日：2014-07-10

申请号：US14232409

申请日：2012-04-13

申请人： Akira Takahashi ,  Takuya Imai ,  Ryuji Monden ,  Yasuaki Wakizaka ,  Takashi Sato

发明人： Akira Takahashi ,  Takuya Imai ,  Ryuji Monden ,  Yasuaki Wakizaka ,  Takashi Sato

IPC分类号： H01M4/86 ,  H01M8/10 ,  H01M4/90

CPC分类号： H01M4/8652 ,  H01M4/9016 ,  H01M4/9091 ,  H01M2004/8689 ,  H01M2008/1095

摘要： It is an object of the present invention to provide an oxygen reducing catalyst having high catalytic activity and high durability using a transition metal (such as titanium); and a method for producing a fuel cell electrode catalyst using the oxygen reducing catalyst. The present invention provides the oxygen reduction catalyst including titanium, carbon, nitrogen, and oxygen as constituent elements at a specific ratio, wherein in XRD measurement using a Cu—Kα ray, peaks are each present in at least regions A and B among regions A to D which occupy 2θ ranges of 42° to 43°, B: 36.5° to 37°, 25° to 26°, and 27° to 28°, respectively; and each of maximum peak intensities IA, IB, IC, and ID in the regions A to D satisfies both relationships of IA>IB and 0.3≦(IA/(IA+IC+ID))≦1.

摘要翻译： 本发明的目的是提供一种使用过渡金属（例如钛）具有高催化活性和高耐久性的氧还原催化剂; 以及使用该氧还原催化剂制造燃料电池用电极催化剂的方法。 本发明提供了以特定比例含有钛，碳，氮，氧作为构成元素的氧还原催化剂，其中，在使用Cu-Kα射线的XRD测定中，各区域A和B各自存在峰 到D，占据2个; 范围为42°至43°，B：36.5°至37°，25°至26°，27°至28°; 并且区域A至D中的每个最大峰值强度IA，IB，IC和ID满足IA> IB和0.3＆amp; NlE的两个关系;（IA /（IA + IC + ID））＆nlE; 1。

公开(公告)号：US10044045B2

公开(公告)日：2018-08-07

申请号：US14236814

申请日：2012-04-13

申请人： Ryuji Monden ,  Takuya Imai ,  Yuji Ito ,  Kunchan Lee ,  Takashi Sato

发明人： Ryuji Monden ,  Takuya Imai ,  Yuji Ito ,  Kunchan Lee ,  Takashi Sato

IPC分类号： B01J31/00 ,  H01M4/90 ,  H01M4/88 ,  B01J31/02 ,  B01J31/22 ,  H01M4/86 ,  B01J31/18 ,  H01M8/1007

摘要： Provided is a process for producing a fuel cell electrode catalyst with high catalytic activity that is alternative to a noble metal catalyst, through a heat treatment at a relatively low temperature. A process for producing a fuel cell electrode catalyst includes a step (I) of obtaining a catalyst precursor, including a step (Ia) of mixing at least a metal compound (1), a nitrogen-containing organic compound (2), and a fluorine-containing compound (3), and a step (II) of heat-treating the catalyst precursor at a temperature of 500 to 1300° C. to obtain an electrode catalyst, a portion or the entirety of the metal compound (1) being a compound containing an atom of a metal element M1 selected from the group consisting of iron, cobalt, chromium, nickel, copper, zinc, titanium, niobium and zirconium, and at least one of the compounds (1), (2) and (3) containing an oxygen atom.

公开(公告)号：US20140170528A1

公开(公告)日：2014-06-19

申请号：US14236814

申请日：2012-04-13

申请人： Ryuji Monden ,  Takuya Imai ,  Yuji Ito ,  Kunchan Lee ,  Takashi Sato

发明人： Ryuji Monden ,  Takuya Imai ,  Yuji Ito ,  Kunchan Lee ,  Takashi Sato

IPC分类号： H01M4/90

CPC分类号： H01M4/9075 ,  B01J31/0202 ,  B01J31/0232 ,  B01J31/1815 ,  B01J31/2217 ,  B01J31/2234 ,  B01J31/2239 ,  B01J2231/20 ,  B01J2531/16 ,  B01J2531/26 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/57 ,  B01J2531/72 ,  B01J2531/821 ,  B01J2531/842 ,  B01J2531/845 ,  H01M4/86 ,  H01M4/88 ,  H01M4/9083 ,  H01M8/1007

摘要： Provided is a process for producing a fuel cell electrode catalyst with high catalytic activity that is alternative to a noble metal catalyst, through a heat treatment at a relatively low temperature. A process for producing a fuel cell electrode catalyst includes a step (I) of obtaining a catalyst precursor, including a step (Ia) of mixing at least a metal compound (1), a nitrogen-containing organic compound (2), and a fluorine-containing compound (3), and a step (II) of heat-treating the catalyst precursor at a temperature of 500 to 1300° C. to obtain an electrode catalyst, a portion or the entirety of the metal compound (1) being a compound containing an atom of a metal element M1 selected from the group consisting of iron, cobalt, chromium, nickel, copper, zinc, titanium, niobium and zirconium, and at least one of the compounds (1), (2) and (3) containing an oxygen atom.

摘要翻译： 提供了通过在较低温度下的热处理来制造具有高贵催化活性的燃料电池用电极催化剂的方法，该催化剂催化剂替代贵金属催化剂。 制备燃料电池电极催化剂的方法包括获得催化剂前体的步骤（I），包括将至少一种金属化合物（1），含氮有机化合物（2）和 含氟化合物（3）和在500〜1300℃的温度下对催化剂前体进行热处理以获得电极催化剂的步骤（II），所述金属化合物（1）的一部分或全部为 包含选自铁，钴，铬，镍，铜，锌，钛，铌和锆的金属元素M1的原子的化合物，以及至少一种化合物（1），（2）和（ 3）含有氧原子。