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公开(公告)号：US20220204424A1
公开(公告)日：2022-06-30
申请号：US17623756
申请日：2020-07-06
摘要： In the method of the present invention, 1,3-butadiene is produced by vaporizing an ethanol feedstock in a vaporizer (104), feeding the resulting into two or more parallel first reactors (108) to convert the ethanol to acetaldehyde in the presence of a first catalyst, supplying the resulting intermediate gas to a second reactor (110) to convert the ethanol and acetaldehyde to 1,3-butadiene in the presence of a second catalyst, purifying the resulting crude gas containing 1,3-butadiene by a gas-liquid separator (112), a first distillation column (114), a fourth reactor (116), a second distillation column (118), and mixing one of both of a part of the ethanol-containing gas and an acetaldehyde-containing gas obtained in the second distillation column (118) are mixed with the intermediate gas, thereby adjusting an ethanol/acetaldehyde molar ratio in the intermediate gas to 1 to 100.
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公开(公告)号：US20220288562A1
公开(公告)日：2022-09-15
申请号：US17621848
申请日：2020-06-24
摘要： A catalyst includes at least one element X selected from the group consisting of Groups 3 to 6 of the Periodic Table, and at least one element Z selected from the group consisting of Group 14 elements. At least one diffraction peak is observed in a low angle range of θ=6° or less in an X-ray diffraction profile observed using X-ray diffraction. The at least one diffraction peak has a ratio (I/H) of a peak intensity I to a half width at half maximum H of the diffraction peak of 5000 or more.
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公开(公告)号：US20220161235A1
公开(公告)日：2022-05-26
申请号：US17666980
申请日：2022-02-08
摘要： The present invention provides a catalyst comprising at least one first metal selected from the group consisting of Groups 3 to 6 of the periodic table, wherein an amount of Bronsted acid sites of the catalyst is 1.8 μmol/g or less.
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公开(公告)号：US20230146921A1
公开(公告)日：2023-05-11
申请号：US17913605
申请日：2021-03-03
摘要： A reducing agent for use in production of a product gas containing carbon monoxide, the reducing agent being brought into contact with a raw material gas containing carbon dioxide to reduce the carbon dioxide to produce the product gas; the reducing agent containing an oxygen carrier having oxygen ionic conductivity, and a basic oxide supported on the oxygen carrier. In addition, the basic oxide preferably contains at least one selected from the group consisting of lithium (Li), sodium (Na), potassium (K), magnesium (Mg), manganese (Mn), cobalt (Co), strontium (Sr), and rubidium (Rb). The reducing agent has a high conversion efficiency of carbon dioxide to carbon monoxide, and can be used, for example, in a chemical looping method, and a method for producing a gas using such a reducing agent.
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5.发明申请公开(公告)号：US20210170364A1
公开(公告)日：2021-06-10
申请号：US16770743
申请日：2019-01-10
摘要： The present invention relates to a catalyst including: a porous carrier including at least one element X selected from the group consisting of elements belonging to Groups 13 and 14 of the periodic table; an oxide of at least one metal element A selected from the group consisting of elements belonging to Groups 3 to 6 of the periodic table; and at least one oxide of a metal element B selected from the group consisting of elements belonging to Group 2 and Groups 7 to 12 of the periodic table, wherein at least a part of the oxide of the metal element A is bonded to the porous carrier.
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6.发明申请公开(公告)号：US20200276562A1
公开(公告)日：2020-09-03
申请号：US16763653
申请日：2018-12-27
IPC分类号： B01J23/30 , B01J23/06 , B01J23/22 , B01J23/20 , B01J35/10 , B01J37/03 , B01J37/08 , C07C1/20
摘要： The present invention relates to a catalyst which is a composite oxide including at least one element X selected from the group consisting of elements belonging to Groups 3 to 6 of the periodic table, and at least one element Z selected from the group consisting of elements belonging to Group 14 of the periodic table, wherein the catalyst has mesopores.
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公开(公告)号：US20240141088A1
公开(公告)日：2024-05-02
申请号：US18387137
申请日：2023-11-06
IPC分类号： C08F236/10 , C07C1/24 , C07C29/80 , C07C31/08 , C07C67/08 , C08C19/00 , C08J3/20 , C10J3/72 , C10K1/00 , C10L1/02 , C12N1/20 , C12P7/06 , C12P7/08
CPC分类号： C08F236/10 , C07C1/24 , C07C29/80 , C07C31/08 , C07C67/08 , C08C19/00 , C08J3/203 , C10J3/72 , C10K1/005 , C10L1/02 , C12N1/20 , C12P7/06 , C12P7/065 , C12P7/08 , B60C1/0016
摘要： The present disclosure provides a novel and practical alcohol and derivatives thereof which have more industrial value than existing petrochemical raw materials. The present disclosure further provides ethanol, characterized in that a peak in gas chromatography measured by gas chromatograph mass spectrometry (GC/MS) has at least one peak with a retention time selected from (A) a peak of 5 minutes 25 seconds to 5 minutes 35 seconds and two peaks of 2 minutes 55 seconds to 3 minutes 5 seconds; (B) a peak of 12 minutes 30 seconds to 12 minutes 40 seconds; (C) a peak of 6 minutes 36 seconds to 6 minutes 45 seconds; and (D) a peak of 15 minutes 00 seconds to 15 minutes 15 seconds.
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公开(公告)号：US20220259120A1
公开(公告)日：2022-08-18
申请号：US17623077
申请日：2020-07-06
摘要： The method of the present invention for producing 1,3-butadiene includes: vaporizing an ethanol feedstock in a vaporizer (104), supplying the feedstock to two or more parallel first reactors (108) to convert ethanol into acetaldehyde in the presence of a first catalyst; supplying a resulting intermediate gas to a second reactor (110) to convert ethanol and acetaldehyde into 1,3-butadiene in the presence of a second catalyst; purifying a resulting crude gas containing 1,3-butadiene by a gas-liquid separator (112), a first distillation column (114), a fourth reactor (116), and a second distillation column (118); and supplying an oxygen-containing gas to at least one of the two or more parallel first reactors (108) under specific conditions, while discharging a carbon dioxide-containing gas from the first reactor (108), to thereby regenerate the first catalyst, while continuing the conversion reaction.
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公开(公告)号：US20210339226A1
公开(公告)日：2021-11-04
申请号：US17270254
申请日：2019-09-24
摘要： The present invention provides a catalyst comprising at least one first metal selected from the group consisting of Groups 3 to 6 of the periodic table, wherein an amount of Bronsted acid sites of the catalyst is 1.8 μmol/g or less.
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公开(公告)号：US20230330635A1
公开(公告)日：2023-10-19
申请号：US17914042
申请日：2021-03-03
IPC分类号： B01J23/10 , C01B32/40 , B01J23/745 , B01J23/92 , B01J38/10
CPC分类号： B01J23/10 , C01B32/40 , B01J23/745 , B01J23/92 , B01J38/10
摘要： A reducing agent for use in production of a product gas containing carbon monoxide, the reducing agent being brought into contact with a raw material gas containing carbon dioxide to reduce the carbon dioxide to produce the product gas; the reducing agent containing a composite metal oxide represented by Ce1-x(M)xOy, where M is a metal element with an ionic radius smaller than an ionic radius of Ce with an identical valence number and an identical coordination number, x represents a positive real number, and y represents a real number from 1 to 4. The reducing agent that has a high conversion efficiency of carbon dioxide to carbon monoxide, and can be used, for example, in a chemical looping method, and a method for producing a gas using such a reducing agent.
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