公开(公告)号：US4273842A

公开(公告)日：1981-06-16

申请号：US895372

申请日：1978-04-11

申请人： Saburo Nonogaki ,  Hajime Morishita ,  Michiaki Hashimoto ,  Toshikatsu Manabe ,  Yoshifumi Tomita ,  Masahiro Nishizawa

发明人： Saburo Nonogaki ,  Hajime Morishita ,  Michiaki Hashimoto ,  Toshikatsu Manabe ,  Yoshifumi Tomita ,  Masahiro Nishizawa

IPC分类号： G03F7/016 ,  G03F7/28 ,  H01J9/227 ,  H01J29/22 ,  H01J29/32 ,  G03C5/00

CPC分类号： H01J29/327 ,  G03F7/016 ,  G03F7/28 ,  H01J29/225 ,  H01J9/2271 ,  H01J9/2278

摘要： A patternwise coated powder layer can be formed by a process comprising the steps of coating a photosensitive composition, which contains an aromatic diazonium salt as a photosensitive component and becomes sticky by exposure, onto the surface of a substrate to form a thin layer, subjecting the thin layer to patternwise exposure with actinic radiation to produce stickiness at the exposed area, and then contacting powder particles with the thin layer after exposure to make the thin layer to accept the powder particles according to the powder acceptability of the thin layer. According to this process, for example, the phosphor screen of a color picture tube can simply be produced.LIST OF PRIOR ART (37 CFR 1.56 (a))The following reference is cited to show the state of the art:Japanese Patent Laid-Open Publication No. 47-7266 (1972)

摘要翻译： 图案化涂层粉末层可以通过以下步骤形成，该方法包括以下步骤：将含有芳香族重氮盐作为感光性成分的感光性组合物涂布在基材表面上，形成薄层， 薄膜以光化辐射进行图案曝光以在曝光区域产生粘性，然后在曝光后使粉末颗粒与薄层接触，以使薄层根据薄层的粉末可接受性接受粉末颗粒。 根据该处理，例如可以简单地制造彩色显像管的荧光屏。

公开(公告)号：US4276363A

公开(公告)日：1981-06-30

申请号：US86445

申请日：1979-10-19

申请人： Toshikatsu Manabe ,  Saburo Nonogaki ,  Hajime Morishita ,  Shoichi Uchino ,  Yoshifumi Tomita ,  Masahiro Nishizawa ,  Hiroshi Yokomizo ,  Susumu Ohmatoi

发明人： Toshikatsu Manabe ,  Saburo Nonogaki ,  Hajime Morishita ,  Shoichi Uchino ,  Yoshifumi Tomita ,  Masahiro Nishizawa ,  Hiroshi Yokomizo ,  Susumu Ohmatoi

IPC分类号： C09K11/02 ,  C09K11/08 ,  H01J9/227 ,  H01J29/22 ,  G03C5/00 ,  B05D5/06

CPC分类号： H01J9/2271 ,  C09K11/025

摘要： A process for forming a phosphor screen of a color picture tube comprising forming a thin layer using a photosensitive composition which contains an aromatic diazonium salt as a photosensitive component and produces tackiness by exposure to actinic light on the surface of the substrate and contacting the tackified thin layer after exposure to light with phosphor particles to form each phosphor layer for emitting color is improved by using as the phosphor particles those coated with at least one surface coating material selected from the group consisting of Zn(OH).sub.2, Zn.sub.3 (PO.sub.4).sub.2 and AlPO.sub.4 in shortening the contact time between the thin layer and the phosphor particles.

摘要翻译： 一种用于形成彩色显像管的荧光屏的方法，包括使用包含芳族重氮盐作为感光组分的感光组合物形成薄层，并通过在基材表面上暴露于光化合物并且使增粘的薄片 通过使用涂覆有选自Zn（OH）2，Zn 3（PO 4）2）中的至少一种表面涂层材料的荧光体颗粒，改善了用荧光体颗粒暴露于光以形成用于发射颜色的每个荧光体层之间的层 和AlPO 4，以缩短薄层和荧光体颗粒之间的接触时间。

公开(公告)号：US4815821A

公开(公告)日：1989-03-28

申请号：US87259

申请日：1987-08-20

申请人： Saburo Nonogaki ,  Hajime Morishita ,  Nobuaki Hayashi ,  Shoichi Uchino ,  Yoshifumi Tomita ,  Masahiro Nishizawa ,  Kiyoshi Miura

发明人： Saburo Nonogaki ,  Hajime Morishita ,  Nobuaki Hayashi ,  Shoichi Uchino ,  Yoshifumi Tomita ,  Masahiro Nishizawa ,  Kiyoshi Miura

IPC分类号： H01J29/22 ,  G02B1/10 ,  H01J29/24 ,  H01J29/32 ,  H01J29/89 ,  H04N9/16

CPC分类号： G02B1/10 ,  H01J29/896 ,  H01J2229/8916 ,  H01J2229/8918

摘要： A light-transmitting layer is formed on a transparent glass panel, the light-transmitting layer having a larger refractive index than that of the glass panel, and a light-absorbing layer having a light-transmitting region is formed on the light-transmitting layer. The light reflected from the interface of the glass panel and the light-absorbing layer is effectively attenuated by the light-transmitting layer, so that it is possible to obtain an excellent image having a considerably strong contrast.

摘要翻译： 透光层形成在透明玻璃面板上，透光层的折射率比玻璃面板的折射率大，在透光层上形成具有透光区域的光吸收层 。 从玻璃面板和光吸收层的界面反射的光被透光层有效地衰减，从而可以获得具有相当强的对比度的优异图像。

公开(公告)号：US4735880A

公开(公告)日：1988-04-05

申请号：US852750

申请日：1986-04-16

申请人： Hajime Morishita ,  Saburo Nonogaki ,  Nobuaki Hayashi ,  Shoichi Uchino ,  Masahiro Nishizawa ,  Kiyoshi Miura ,  Osamu Sasaya ,  Yoshifumi Tomita

发明人： Hajime Morishita ,  Saburo Nonogaki ,  Nobuaki Hayashi ,  Shoichi Uchino ,  Masahiro Nishizawa ,  Kiyoshi Miura ,  Osamu Sasaya ,  Yoshifumi Tomita

IPC分类号： G03F7/038 ,  G03C1/08 ,  G03C1/60 ,  G03C5/18 ,  G03F7/28 ,  H01J9/227 ,  G03C5/34 ,  G03F7/08 ,  G03F7/26

CPC分类号： G03C1/60 ,  G03F7/28

摘要： A photosensitive composition comprising (1) at least one diazonium compound selected from among salts and double salts of diazonium ions represented by the general formulas: ##STR1## wherein A stands for a substituent selected from among ##STR2## wherein R.sub.1 and R.sub.2 each stand for an alkyl or benzyl group with the proviso that the total number of carbon atoms of R.sub.1 and R.sub.2 is 8 to 16, and (2) at least one nitrate selected from the group consisting of calcium nitrate and magnesium nitrate and a pattern forming process using such a composition.This composition gets sticky upon exposure to light.

摘要翻译： 一种光敏组合物，其包含（1）至少一种选自以下通式表示的重氮盐的盐和复盐中的重氮化合物：其中A代表选自下述的取代基：[II] 其中R1和R2各自代表烷基或苄基，条件是R1和R2的碳原子总数为8-16，和（2）至少一种硝酸盐，其选自硝酸钙和 硝酸镁和使用这种组合物的图案形成方法。 这种组合物在曝光时变得粘稠。

公开(公告)号：US5024920A

公开(公告)日：1991-06-18

申请号：US355635

申请日：1989-05-23

申请人： Hajime Morishita ,  Nobuaki Hayashi ,  Saburo Nonogaki ,  Michiaki Hashimoto ,  Masato Ito ,  Masahiro Nishizawa ,  Kiyoshi Miura ,  Yoshiyuki Odaka

发明人： Hajime Morishita ,  Nobuaki Hayashi ,  Saburo Nonogaki ,  Michiaki Hashimoto ,  Masato Ito ,  Masahiro Nishizawa ,  Kiyoshi Miura ,  Yoshiyuki Odaka

IPC分类号： G02B5/20 ,  G03F7/00 ,  G03F7/012 ,  G03F7/26

CPC分类号： G03F7/012

摘要： This invention relates to a process for forming a pattern using a photosensitive composition comprising a polymeric azide and a high-molecular weight copolymer or polymer. The photosensitive composition comprises a copolymer containing at least a water-soluble non-photosensitive monomeric unit having an electrolytic functional group, a monomeric unit having an azido group and an electrolytic functional group and a high-soluble high molecular weight copolymer or polymer which exhibits reciprocity law failure characteristic.

摘要翻译： 本发明涉及使用包含聚合叠氮化物和高分子量共聚物或聚合物的光敏组合物形成图案的方法。 光敏组合物包含至少含有具有电解官能团的水溶性非感光单体单元，具有叠氮基的单体单元和电解官能团的共聚物以及表现出互易性的高溶解性高分子量共聚物或聚合物 法律失效特征。

公开(公告)号：US4269918A

公开(公告)日：1981-05-26

申请号：US63474

申请日：1979-08-03

申请人： Saburo Nonogaki ,  Hajime Morishita ,  Shoichi Uchino ,  Toshikatsu Manabe

发明人： Saburo Nonogaki ,  Hajime Morishita ,  Shoichi Uchino ,  Toshikatsu Manabe

IPC分类号： B05D5/06 ,  G03C5/18 ,  G03F7/28 ,  H01J9/227 ,  H01J29/22 ,  G03C5/34

CPC分类号： G03F7/28 ,  G03C5/18 ,  H01J9/2271

摘要： A strongly fixed patternwise coated powder layer is formed on a substrate by subjecting a thin layer of photo-sensitive composition containing an aromatic diazonium salt as a photo-sensitive component capable of becoming sticky due to the formation of a photolytic reaction product of the salt by a patternwise light exposure, thereby making the light-exposed part of the thin layer sticky, bringing the thin layer in contact with powdery grains, thereby forming a powder-containing coating layer, and contacting the powder-containing coating layer with a powdery material that reacts with the photolytic product, thereby forming a water-insoluble or slightly water-soluble solid material to fix the powdery grains to the substrate.

摘要翻译： 通过使含有芳香族重氮盐的感光性组合物的薄层作为能够变粘的光敏性成分由于盐的光解反应产物而形成，从而在基材上形成牢固固定的图案化涂层粉末层 从而使薄层的光暴露部分粘着，使薄层与粉末状颗粒接触，从而形成含粉末的涂层，并使含粉末涂层与粉末状材料接触， 与光解产物反应，从而形成水不溶性或微溶于水的固体材料，以将粉末颗粒固定在基材上。

公开(公告)号：US5081394A

公开(公告)日：1992-01-14

申请号：US238497

申请日：1988-08-31

申请人： Hajime Morishita ,  Nobuaki Hayashi ,  Saburo Nonogaki ,  Masahiro Nishizawa ,  Kiyoshi Miura ,  Teruki Suzuki

发明人： Hajime Morishita ,  Nobuaki Hayashi ,  Saburo Nonogaki ,  Masahiro Nishizawa ,  Kiyoshi Miura ,  Teruki Suzuki

IPC分类号： C03C8/08 ,  C03C17/34 ,  H01J9/227 ,  H01J29/24 ,  H01J29/32

CPC分类号： H01J29/327 ,  C03C17/3411 ,  C03C8/08 ,  H01J29/24 ,  H01J9/2271 ,  H01J9/2278 ,  C03C2217/42

摘要： A black matrix color picture tube has a phosphor layer and black matrix layer formed on the inner surface of the faceplate. A layer of glass having a low softening point is provided between the phosphor layer and the inner surface of the faceplate and between the black matrix layer and the inner surface of the faceplate. The softening point of the glass is below the temperature at which the tube is subjected during a frit baking step employed in the fabrication of the tube. For example, a borophosphate glass is used as the layer of glass having a low softening point.

摘要翻译： 黑矩阵彩色显象管具有在面板的内表面上形成的荧光体层和黑矩阵层。 在荧光体层和面板的内表面之间以及黑矩阵层和面板的内表面之间设置具有低软化点的玻璃层。 玻璃的软化点低于在制造管中所用的玻璃料烘烤步骤期间管子经受的温度。 例如，使用硼磷酸盐玻璃作为低软化点的玻璃层。

公开(公告)号：US5173382A

公开(公告)日：1992-12-22

申请号：US462589

申请日：1990-01-09

申请人： Hajime Morishita ,  Nobuaki Hayashi ,  Saburo Nonogaki ,  Masato Ito ,  Masahiro Nishizawa ,  Kiyoshi Miura

发明人： Hajime Morishita ,  Nobuaki Hayashi ,  Saburo Nonogaki ,  Masato Ito ,  Masahiro Nishizawa ,  Kiyoshi Miura

IPC分类号： G03F7/016 ,  G03F7/04 ,  H01J9/227

CPC分类号： G03F7/016 ,  Y10S430/11 ,  Y10S430/163

摘要： A photosensitive composition comprising a water-soluble polymer, a dichromate and at least one aromatic diazonium salt selected from aromatic diazonium sulfates, sulfonates and chromates has high sensitivity, and a pattern having high resolution can be formed therefrom with a shortened exposure time.

摘要翻译： 包含选自芳族重氮硫酸盐，磺酸盐和铬酸盐的水溶性聚合物，重铬酸盐和至少一种芳族重氮盐的光敏组合物具有高灵敏度，并且可以缩短曝光时间从而形成具有高分辨率的图案。

公开(公告)号：US4520094A

公开(公告)日：1985-05-28

申请号：US435272

申请日：1982-10-19

申请人： Hajime Morishita ,  Motoo Akagi ,  Nobuaki Hayashi ,  Saburo Nonogaki ,  Shoichi Uchino ,  Takahiro Kohashi

发明人： Hajime Morishita ,  Motoo Akagi ,  Nobuaki Hayashi ,  Saburo Nonogaki ,  Shoichi Uchino ,  Takahiro Kohashi

IPC分类号： C08K5/00 ,  C08K5/22 ,  C08K5/23 ,  C08L33/00 ,  C08L33/02 ,  G03C1/52 ,  G03F7/038 ,  G03F7/28 ,  H01J29/22 ,  G03C5/34 ,  G03C5/18

CPC分类号： H01J29/225 ,  G03F7/28

摘要： A photosensitive composition turning shicky by light exposure, which comprises a salt or p-aminobenzenediazonium compound and at least one of salts of o- and m-aminobenzenediazonium compounds, has a distinguished effect in forming a phosphor screen of a color picture tube.

摘要翻译： 包含盐或对氨基苯二氮化合物和邻氨基苯并二氮化合物的盐中的至少一种的光曝光感光组合物在形成彩色显像管的荧光屏方面具有显着的效果。

公开(公告)号：US4564572A

公开(公告)日：1986-01-14

申请号：US694237

申请日：1985-01-24

申请人： Hajime Morishita ,  Kiyoshi Miura ,  Osamu Sasaya ,  Saburo Nonogaki

发明人： Hajime Morishita ,  Kiyoshi Miura ,  Osamu Sasaya ,  Saburo Nonogaki

IPC分类号： C09K11/02 ,  G03F7/016 ,  H01J9/227 ,  H01J29/20 ,  B05D3/06

CPC分类号： G03F7/016 ,  H01J9/2271

摘要： A process for forming a pattern on the interior side of a face plate of a color picture tube by using a photosensitive composition comprising p-diazo-N,N-dimethylaniline chloride-zinc chloride double salt and a p-diazo-bromophenol chloride-zinc chloride double salt and conducting imagewise exposure of coated film of the photosensitive composition to light and contacting with powder particles at least one time gives higher sensitivity compared with a conventional process.

摘要翻译： 通过使用包含对重氮-N，N-二甲基苯胺氯化物 - 氯化锌复盐和对 - 重氮 - 溴苯酚氯化物 - 锌的光敏组合物在彩色显像管的面板的内侧上形成图案的方法 氯化物双盐，并将感光性组合物的涂膜进行成像曝光，并与粉末颗粒接触至少一次，与常规方法相比具有更高的灵敏度。