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1.发明申请Regeneration of ionic liquid catalyst using a metal in the absence of added hydrogen 有权在没有加入氢气的情况下使用金属对离子液体催化剂进行再生公开(公告)号：US20070249485A1
公开(公告)日：2007-10-25
申请号：US11408336
申请日：2006-04-21
申请人： Saleh Elomari , Thomas Harris , Hye Timken , Steven Trumbull
发明人： Saleh Elomari , Thomas Harris , Hye Timken , Steven Trumbull
IPC分类号： B01J38/00
CPC分类号： B01J38/48 , B01J31/0284 , B01J31/0298 , B01J31/4092
摘要： A process for regenerating a used acidic ionic liquid catalyst comprising contacting the used ionic liquid catalyst with at least one metal in a regeneration zone in the absence of added hydrogen under regeneration conditions for a time sufficient to increase the activity of the ionic liquid catalyst is described. In one embodiment, regeneration is conducted in the presence of a hydrocarbon solvent.
摘要翻译： 一种用于再生所用酸性离子液体催化剂的方法，包括在再生条件下在不存在加入氢气的条件下使所用离子液体催化剂与再生区中的至少一种金属接触足够增加离子液体催化剂活性的时间 。 在一个实施方案中，在烃溶剂存在下进行再生。
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2.发明申请Regeneration of ionic liquid catalyst by hydrogenation using a supported catalyst 有权使用负载催化剂通过氢化再生离子液体催化剂公开(公告)号：US20070142215A1
公开(公告)日：2007-06-21
申请号：US11316450
申请日：2005-12-20
申请人： Thomas Harris , Saleh Elomari
发明人： Thomas Harris , Saleh Elomari
IPC分类号： B01J27/125 , B01J27/06 , B01J31/00
CPC分类号： B01J27/125 , B01J27/32 , B01J31/0239 , B01J31/0268 , B01J31/0284 , B01J31/0288 , B01J31/1616 , B01J31/26 , B01J31/40 , B01J38/10 , B01J2231/64 , C07C2/862 , Y02P20/584
摘要： A process for regenerating a used acidic ionic liquid catalyst comprising the steps of contacting the used ionic liquid catalyst and hydrogen with a supported hydrogenation catalyst comprising a hydrogenation component on a support in a reaction zone under hydrogenation conditions for a time sufficient to increase the activity of the used catalyst is disclosed.
摘要翻译： 一种用于再生所用酸性离子液体催化剂的方法，包括以下步骤：使氢离子液体催化剂和氢气在氢化条件下在反应区中的载体上在支持体上包含氢化组分的载体氢化催化剂接触足以增加活性的时间 公开了所用的催化剂。
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3.发明申请公开(公告)号：US20070142684A1
公开(公告)日：2007-06-21
申请号：US11316154
申请日：2005-12-20
申请人： Saleh Elomari , Russell Krug , Thomas Harris , Michael Driver
发明人： Saleh Elomari , Russell Krug , Thomas Harris , Michael Driver
CPC分类号： C10M127/02 , C10G2300/1081 , C10G2300/1088 , C10G2400/10 , C10M105/04 , C10M109/02 , C10M177/00 , C10M2205/0285 , C10N2220/022 , C10N2220/023 , C10N2230/02 , C10N2270/00 , C10M2203/0206
摘要： A process and method for making a superior lubricant or distillate fuel component by the oligomerization of a mixture comprising olefins to form an oligomer and the alkylation of the oligomer with isoparaffins to produce an alkylated (“capped”) olefin oligomer preferably using an acidic chloroaluminate ionic liquid catalyst system. Preferably the ionic liquid catalyst system comprises a Brönsted acid.
摘要翻译： 通过包含烯烃的混合物的低聚制备优异的润滑剂或馏出燃料成分的方法和方法，以形成低聚物，并用异链烷烃烷基化低聚物以产生烷基化（“封端”）烯烃低聚物，优选使用酸性氯铝酸盐离子 液体催化剂体系。 优选地，离子液体催化剂体系包含布朗斯台德酸。
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公开(公告)号：US20070142676A1
公开(公告)日：2007-06-21
申请号：US11315750
申请日：2005-12-20
申请人： Saleh Elomari , Thomas Harris
发明人： Saleh Elomari , Thomas Harris
IPC分类号： B01J27/132 , B01J27/135 , B01J27/138 , B01J27/06 , B01J31/00 , C07C45/46 , C07C15/46
CPC分类号： C07D213/20 , B01J27/125 , B01J27/32 , B01J31/0278 , B01J31/0284 , B01J31/0288 , B01J31/40 , C07C2/62 , C07C2531/02 , Y02P20/584 , C07C9/16
摘要： A process for producing acidic ionic liquid catalyst having enhanced activity comprising combining fresh acidic ionic liquid catalyst, a metal and a Broensted acid in a reaction zone for a time sufficient to increase the activity of the ionic liquid catalyst is disclosed. A process for producing acidic ionic liquid catalyst having enhanced activity comprising the steps of combining fresh ionic liquid catalyst, a metal and HCl in a reaction zone for a time sufficient to increase the activity of the fresh ionic liquid catalyst; removing reaction product from the reaction zone and recovering at least a portion of the treated ionic liquid catalyst is also disclosed.
摘要翻译： 公开了一种生产具有增强活性的酸性离子液体催化剂的方法，其包括在反应区中将新鲜的酸性离子液体催化剂，金属和布朗斯台德酸组合足以提高离子液体催化剂活性的时间。 一种生产具有增强活性的酸性离子液体催化剂的方法，包括以下步骤：将新鲜离子液体催化剂，金属和HCl在反应区中混合足以增加新鲜离子液体催化剂活性的时间; 从反应区除去反应产物并回收至少一部分经处理的离子液体催化剂。
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5.发明申请Catalyst and process for selective hydroconversion of normal paraffins to normal paraffin-rich lighter products 审中-公开将正构烷烃选择性加氢转化为正常富石蜡的轻质产物的催化剂和方法公开(公告)号：US20070032692A1
公开(公告)日：2007-02-08
申请号：US11501087
申请日：2006-08-07
申请人： Dennis O'Rear , Saleh Elomari , Thomas Harris , Cong-Yan Chen
发明人： Dennis O'Rear , Saleh Elomari , Thomas Harris , Cong-Yan Chen
摘要： A process and catalyst are suitable for hydroconverting heavy normal paraffins into lighter normal paraffin products with minimal formation of isoparaffins. The process and catalyst can be used on any feed that contains heavy normal paraffins such as waxy lubricant fractions, slack wax or Fischer Tropsch products. By selectively forming a normal paraffin rich product from heavy normal paraffins, the need for normal paraffin separation and purification processes can be reduced or eliminated.
摘要翻译： 一种方法和催化剂适用于将重质正链烷烃加氢转化成较轻质正链烷烃产物，同时形成异链烷烃。 该方法和催化剂可用于含有重质正链烷烃（如蜡状润滑剂部分，松散蜡或费托产品）的任何进料。 通过从重质正链烷烃选择性地形成正链烷烃富集产物，可以减少或消除对正链烷烃分离和纯化方法的需要。
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6.发明申请公开(公告)号：US20070142217A1
公开(公告)日：2007-06-21
申请号：US11316629
申请日：2005-12-20
申请人： Saleh Elomari , Thomas Harris
发明人： Saleh Elomari , Thomas Harris
IPC分类号： B01J27/125 , B01J27/06 , B01J31/00
CPC分类号： B01J27/32 , B01J27/125 , B01J31/0278 , B01J31/0284 , B01J31/0287 , B01J31/0288 , B01J31/40 , C07C2/862 , Y02P20/584
摘要： A process for regenerating a used acidic ionic liquid catalyst which has been deactivated by conjunct polymers comprising combining the used catalyst, a metal and a Broensted acid which acts a source of hydrogen in a reaction zone under hydrogenation conditions for a time sufficient to hydrogenate at least a portion of the conjunct polymer is disclosed. An embodiment of a process for regenerating a used acidic ionic liquid catalyst which has been deactivated by conjunct polymers comprising the steps of combining the used ionic liquid catalyst, a metal and HCl in a reaction zone under hydrogenation conditions for a time sufficient to hydrogenate at least a portion of the conjunct polymer; removing reaction product from the reaction zone; mixing the removed reaction product with a hydrocarbon solvent in which the hydrogenated conjunct polymers are soluble; allowing the mixture to separate into two phases, a lighter phase which contains the hydrogenated conjunct polymers and a heavier phase which contains a regenerated ionic liquid catalyst; and recovering at least a portion of the heavier phase is also disclosed.
摘要翻译： 一种再生使用的酸性离子液体催化剂的方法，其已经通过结合聚合物失活，包括将氢化条件下的反应区中使用的催化剂，金属和作为氢源的布朗斯台德酸组合至少足以氢化至少 公开了一部分结合聚合物。 用于再生已使用的结合聚合物失活的酸性离子液体催化剂的方法的一个实施方案包括以下步骤：在氢化条件下将反应区中使用的离子液体催化剂，金属和HCl组合至少足以氢化至少 结合聚合物的一部分; 从反应区除去反应产物; 将除去的反应产物与其中氢化结合聚合物可溶的烃溶剂混合; 允许混合物分离成两相，其中较轻的相含有氢化结合聚合物和较重相，其含有再生离子液体催化剂; 并且还公开了至少一部分较重相的回收。
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7.发明申请公开(公告)号：US20070142218A1
公开(公告)日：2007-06-21
申请号：US11316630
申请日：2005-12-20
申请人： Thomas Harris , Saleh Elomari
发明人： Thomas Harris , Saleh Elomari
IPC分类号： B01J27/125 , B01J27/06 , B01J31/00
CPC分类号： B01J31/0284 , B01J27/125 , B01J27/32 , B01J31/0239 , B01J31/0288 , B01J31/40 , B01J38/10 , B01J2231/4205 , C07C2/862 , Y02P20/584
摘要： A process for regenerating a used acidic ionic liquid catalyst comprising the steps of contacting the used ionic liquid catalyst and hydrogen with a homogeneous hydrogenation catalyst in a reaction zone under hydrogenation conditions for a time sufficient to increase the activity of the used catalyst is disclosed.
摘要翻译： 一种用于再生所用酸性离子液体催化剂的方法，包括以下步骤：使氢离子液体催化剂和氢与均相氢化催化剂在氢化条件下在反应区中接触足以提高所用催化剂活性的时间。
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8.发明申请Regeneration of ionic liquid catalyst by hydrogenation using a metal or metal alloy catalyst 有权使用金属或金属合金催化剂通过氢化再生离子液体催化剂公开(公告)号：US20070142214A1
公开(公告)日：2007-06-21
申请号：US11316107
申请日：2005-12-20
申请人： Saleh Elomari , Thomas Harris
发明人： Saleh Elomari , Thomas Harris
CPC分类号： B01J31/0288 , B01J27/125 , B01J27/32 , B01J31/0239 , B01J31/0284 , B01J31/40 , B01J38/10 , B01J2231/4205 , B01J2231/64 , C07C2/861 , Y02P20/584
摘要： A process for regenerating a used acidic ionic liquid catalyst which has, been deactivated comprising the steps of contacting the used chloroaluminate ionic liquid catalyst and hydrogen with a metal hydrogenation catalyst in a reaction zone under hydrogenation conditions for a time sufficient to increase the activity of the ionic liquid catalyst is described. In one embodiment, hydrogenation is conducted in the presence of a hydrocarbon solvent.
摘要翻译： 一种使已使用的酸性离子液体催化剂再生的方法，其被去活化，包括以下步骤：在氢化条件下在反应区中使所用的氯铝酸盐离子液体催化剂和氢与金属氢化催化剂接触足够时间以提高活性 离子液体催化剂。 在一个实施方案中，在烃溶剂的存在下进行氢化。
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公开(公告)号：US20070142213A1
公开(公告)日：2007-06-21
申请号：US11315749
申请日：2005-12-20
申请人： Saleh Elomari , Thomas Harris
发明人： Saleh Elomari , Thomas Harris
IPC分类号： B01J31/00
CPC分类号： B01J31/4092 , B01J27/30 , B01J27/32 , B01J31/0284 , B01J31/0288 , B01J31/0298 , B01J35/12 , B01J38/50 , B01J38/54 , B01J2231/12 , B01J2231/20 , B01J2231/4205 , B01J2231/44 , B01J2531/31 , C01B17/905 , C07D213/20 , Y02P20/584
摘要： A process for regenerating a used acidic catalyst which has been deactivated by conjunct polymers by removing the conjunct polymers so as to increase the activity of the catalyst is disclosed. Methods for removing the conjunct polymers include hydrogenation, addition of a basic reagent and alkylation. The methods are applicable to all acidic catalysts and are described with reference to certain ionic liquid catalysts.
摘要翻译： 公开了一种通过除去结合聚合物以使催化剂的活性提高而使被结合的聚合物失活的酸性催化剂再生的方法。 去除结合聚合物的方法包括氢化，加入碱性试剂和烷基化。 该方法适用于所有酸性催化剂，并参照某些离子液体催化剂进行了描述。
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10.发明申请Regeneration of ionic liquid catalyst using a regeneration metal in the presence of added hydrogen 有权在加入氢气存在下使用再生金属再生离子液体催化剂公开(公告)号：US20070249486A1
公开(公告)日：2007-10-25
申请号：US11408335
申请日：2006-04-21
申请人： Saleh Elomari , Thomas Harris
发明人： Saleh Elomari , Thomas Harris
IPC分类号： B01J38/10
CPC分类号： B01J38/10 , B01J31/0239 , B01J31/0284 , B01J31/0288 , B01J31/40 , B01J38/58 , B01J2231/4205
摘要： A process for regenerating a used acidic ionic liquid catalyst comprising contacting the used ionic liquid catalyst with at least one ‘regeneration’ metal in a regeneration zone in the presence of added hydrogen under regeneration conditions for a time sufficient to increase the activity of the ionic liquid catalyst is described. In one embodiment, regeneration is conducted in the presence of a hydrocarbon solvent.
摘要翻译： 一种用于再生所用酸性离子液体催化剂的方法，包括在再生条件下，在加入的氢气存在下，将所用离子液体催化剂与再生区中的至少一种“再生”金属接触足以增加离子液体的活性的时间 催化剂。 在一个实施方案中，在烃溶剂存在下进行再生。
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