公开(公告)号：US07459263B2

公开(公告)日：2008-12-02

申请号：US10944580

申请日：2004-09-17

申请人： Samir Y. Farid ,  Douglas R. Robello ,  Joseph P. Dinnocenzo ,  Paul B. Merkel ,  Lorraine Ferrar ,  Yeonsuk Roh ,  Mark R. Mis

发明人： Samir Y. Farid ,  Douglas R. Robello ,  Joseph P. Dinnocenzo ,  Paul B. Merkel ,  Lorraine Ferrar ,  Yeonsuk Roh ,  Mark R. Mis

IPC分类号： G11B7/24

CPC分类号： G11B7/24044 ,  G11B7/245 ,  G11B2007/0009 ,  Y10S430/146

摘要： The invention relates to an optical recording material comprising: a polymeric matrix; a dewarbenzene derivative reactant capable of undergoing isomerization to a benzene product upon triplet excitation, thereby causing a change in optical properties; and a sensitizer capable of absorbing actinic radiation to cause triplet energy transfer to said reactant, wherein the algebraic sum of the excitation energy of said sensitizer and its reduction potential is at least 0.05 eV less than the oxidation potential of said reactant, thereby precluding one-electron oxidation of said reactant. The invention further relates to an optical device comprising regional variations in concentrations of reactants and products produced by triplet chain isomerization, thereby providing a pattern of intelligence.

摘要翻译： 本发明涉及一种光学记录材料，包括：聚合物基体; 能够在三重激发时进行苯产物异构化的杜烷苯衍生物反应物，从而引起光学性能的变化; 以及能够吸收光化辐射以使三重态能量转移到所述反应物的敏化剂，其中所述敏化剂的激发能和其还原电位的代数之和小于所述反应物的氧化电位至少0.05eV， 所述反应物的电子氧化。 本发明还涉及一种光学装置，其包括通过三线态异构化产生的反应物和产物的浓度的区域变化，从而提供智力模式。

公开(公告)号：US07022392B2

公开(公告)日：2006-04-04

申请号：US10700873

申请日：2003-11-04

申请人： Joseph P. Dinnocenzo ,  Douglas R. Robello ,  Samir Y. Farid ,  Mark R. Mis ,  Lorraine Ferrar ,  Aaron S. Peer ,  Thomas G. Brown

发明人： Joseph P. Dinnocenzo ,  Douglas R. Robello ,  Samir Y. Farid ,  Mark R. Mis ,  Lorraine Ferrar ,  Aaron S. Peer ,  Thomas G. Brown

IPC分类号： B32B3/02

CPC分类号： G11B7/0065 ,  B82Y10/00 ,  G11B7/24044 ,  G11B7/245 ,  Y10T428/21

摘要： An optically recorded article comprising a pattern of isomerized material in two isomeric forms in a matrix, wherein one of the isomeric forms is capable of being converted to the other form by one-electron oxidation and wherein said matrix was polymerized in-situ.

摘要翻译： 一种光学记录的制品，其包含在基质中具有两种异构体形式的异构化材料的图案，其中异构体形式之一能够通过单电子氧化转化为其它形式，并且其中所述基质原位聚合。

公开(公告)号：US06969578B2

公开(公告)日：2005-11-29

申请号：US10223238

申请日：2002-08-19

申请人： Douglas R. Robello ,  Samir Y. Farid ,  Joseph P. Dinnocenzo ,  Jason G. Gillmore

发明人： Douglas R. Robello ,  Samir Y. Farid ,  Joseph P. Dinnocenzo ,  Jason G. Gillmore

IPC分类号： G03C1/72 ,  G03F7/00 ,  G03F7/038 ,  G03G9/08 ,  G03H1/02 ,  G11B7/244 ,  G11B7/245 ,  G11B7/24

CPC分类号： G03F7/0388 ,  G03F7/001 ,  G03G9/0821 ,  G11B7/244 ,  G11B7/245

摘要： An optical recording material which when exposed to actinic radiation produces a change in optical properties in the exposed regions, thereby providing a pattern of intelligence for storing and retrieving information, the recording material having: a) a polymer containing a covalently bound reactant moiety which is capable of undergoing a chemical transformation upon a one electron oxidation, thus causing the change in optical properties in the exposed regions; and b) a sensitizer capable of absorbing actinic radiation to cause an initial one electron oxidation of the reactant.

摘要翻译： 一种光学记录材料，当暴露于光化辐射时，在暴露区域中产生光学特性的变化，从而提供用于存储和检索信息的智能模式，所述记录材料具有：a）含有共价结合的反应物部分的聚合物， 能够在一电子氧化下进行化学转化，从而导致曝光区域的光学特性的变化; 和b）能够吸收光化辐射以引起反应物的初始一次电子氧化的敏化剂。

公开(公告)号：US06569600B2

公开(公告)日：2003-05-27

申请号：US09822057

申请日：2001-03-30

申请人： Joseph P. Dinnocenzo ,  Samir Y. Farid ,  Douglas R. Robello ,  Turan Erdogan

发明人： Joseph P. Dinnocenzo ,  Samir Y. Farid ,  Douglas R. Robello ,  Turan Erdogan

IPC分类号： G11B724

CPC分类号： G11B7/244 ,  G11B7/0065 ,  G11B2007/0009 ,  Y10S430/146 ,  Y10T428/21

摘要： An optical recording material which when exposed to actinic radiation produces a change in optical properties in the exposed regions, thereby providing a pattern of intelligence for storing and retrieving information, the recording material comprising: a) a binder; b) a reactant which is capable of undergoing a chemical transformation upon a one electron oxidation, thus causing the change in optical properties in the exposed regions; and c) a sensitizer capable of absorbing actinic radiation to cause an initial one electron oxidation of the reactant.

摘要翻译： 一种光学记录材料，当暴露于光化辐射时，在曝光区域中产生光学特性的改变，从而提供用于存储和检索信息的智能模式，所述记录材料包括：a）粘合剂; b） 在一次电子氧化下进行化学转化，从而导致曝光区域的光学特性的变化; 和c）能够吸收光化辐射以引起反应物的初始一次电子氧化的敏化剂。

公开(公告)号：US6153371A

公开(公告)日：2000-11-28

申请号：US118552

申请日：1998-07-17

申请人： Samir Y. Farid ,  Ian R. Gould ,  Stephen A. Godleski ,  Jerome R. Lenhard ,  Annabel A. Muenter ,  Paul A. Zielinski

发明人： Samir Y. Farid ,  Ian R. Gould ,  Stephen A. Godleski ,  Jerome R. Lenhard ,  Annabel A. Muenter ,  Paul A. Zielinski

IPC分类号： G03C1/10 ,  G03C1/12 ,  G03C1/29

CPC分类号： G03C1/12 ,  G03C1/10 ,  G03C1/29 ,  G03C2200/24

摘要： This invention comprises a photographic element comprising a support and at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula:Q-XYwherein Q represents the atoms necessary to form a chromophore comprising an amidinium-ion, a carboxyl-ion or dipolar-amidic chromophoric system when conjugated with XY, and XY is a fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein:1) XY has an oxidation potential between 0 and about 1.4 V;2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment of the invention, the radical X.cndot. has an oxidation potential

摘要翻译： 本发明包括一种照相元件，其包括载体和至少一个卤化银乳剂层，其中卤化银用下式化合物敏化：Q-XY，其中Q表示形成包含脒鎓离子的发色团所需的原子， 羧基离子或偶极 - 酰胺发色体系，XY为可裂解的电子给体部分，其中X为电子给体基团，Y为氢以外的离去基团，其中：1）XY具有氧化电位 介于0和约1.4 V之间; 2）XY的氧化形式经历键断裂反应，得到基团X.和离去片段Y.在本发明的优选实施方案中，基团X的氧化势<-0.7V。

公开(公告)号：US4743530A

公开(公告)日：1988-05-10

申请号：US933660

申请日：1986-11-21

申请人： Samir Y. Farid ,  Neil F. Haley ,  Roger E. Moody ,  Donald P. Specht

发明人： Samir Y. Farid ,  Neil F. Haley ,  Roger E. Moody ,  Donald P. Specht

IPC分类号： C08F2/50 ,  G03F7/031 ,  G03C1/76

CPC分类号： G03F7/031 ,  Y10S430/115 ,  Y10S430/121

摘要： A negative working photoresist is disclosed responsive to imaging radiation of a wavelength longer than 550 nm comprised of an organic film forming component containing ethylenic unsaturation and capable of selective immobilization by addition at the site of ethylenic unsaturation and activator and photosensitizer coinitiators for ethylenic addition. The activator is an azinium salt activator, and the photosensitizer is a dye having its principal absorption peak at a wavelength longer than 550 nm and having a reduction potential which in relation to that of said azinium salt activator is at most 0.1 volt more positive.

摘要翻译： 公开了一种负光致抗蚀剂，其响应于包含含有烯属不饱和键的有机成膜组分的波长超过550nm的成像辐射，并且能够通过在烯属不饱和位置加入而选择性地固定，并且用于乙烯添加的活化剂和光敏剂共引发剂。 活化剂是吖嗪盐活化剂，并且光敏剂是其波长比550nm长的主要吸收峰并且具有与所述氮鎓盐活化剂相关的还原电位至多为0.1伏更多正电荷的还原电位的染料。

公开(公告)号：US4422972A

公开(公告)日：1983-12-27

申请号：US260434

申请日：1981-05-04

申请人： Robert C. Daly ,  Danny R. Thompson ,  Samir Y. Farid

发明人： Robert C. Daly ,  Danny R. Thompson ,  Samir Y. Farid

IPC分类号： G03F7/031 ,  C07C49/72

CPC分类号： G03F7/031

摘要： There are disclosed light-sensitive compounds and a composition comprising (a) such compounds and (b) a compound having at least one reactive site capable of stepwise photoreaction with the light-sensitive compounds. The light-sensitive compounds have the structural formula, ##STR1## wherein Z.sup.1 and Z.sup.2 are each independently the number of non-metallic atoms necessary to complete 1, 2, 3, or 4 unsaturated carbocyclic or heterocyclic rings of from 6 to 18 nuclear atoms;Z.sup.3 is either a carbon-to-carbon bond or vinylene;and X is a linking group.The composition can be applied to a variety of supports and photoreacted by exposure to activating radiation.

摘要翻译： 公开了光敏化合物和包含（a）这种化合物的组合物和（b）具有至少一个能够与光敏化合物分步光反应的反应位点的化合物。 光敏化合物具有结构式，其中Z1和Z2各自独立地是完成1,2,3或4个6至18个核原子的不饱和碳环或杂环所必需的非金属原子的数目 ; Z3是碳 - 碳键或亚乙烯基; X是连接基团。 组合物可以应用于多种载体并通过暴露于活化辐射而被光反应。

公开(公告)号：US4859572A

公开(公告)日：1989-08-22

申请号：US189002

申请日：1988-05-02

申请人： Samir Y. Farid ,  Roger E. Moody

发明人： Samir Y. Farid ,  Roger E. Moody

IPC分类号： G03F7/028 ,  C08F2/46 ,  C08F2/48 ,  G03F7/031

CPC分类号： G03F7/031 ,  Y10S430/115 ,  Y10S430/116 ,  Y10S430/117

摘要： A photographic imaging system is disclosed comprised of a hardenable organic component containing ethylenic unsaturation sites and an initiator system for ethylenic addition. The initiator system is comprised of an electron acceptor activator, an electron donor activator, and, acting as a photosensitizer, a dye capable of absorbing imaging radiation. The dye has a reduction potential related to that of the electron acceptor activator and an oxidation potential related to that of the electron donor activator to permit each to release a free radical upon excitation of the photosensitizer by exposure to actinic radiation.

公开(公告)号：US4743531A

公开(公告)日：1988-05-10

申请号：US933712

申请日：1986-11-21

申请人： Samir Y. Farid ,  Neil F. Haley ,  Roger E. Moody ,  Donald P. Specht

发明人： Samir Y. Farid ,  Neil F. Haley ,  Roger E. Moody ,  Donald P. Specht

IPC分类号： G03C1/00 ,  C08F2/50 ,  G03F7/00 ,  G03F7/031 ,  G03C1/72

CPC分类号： G03F7/031 ,  G03F7/002 ,  Y10S430/12 ,  Y10S430/121

摘要： A photographic imaging system is disclosed comprised of an imaging dye or a precursor thereof, a hardenable organic component containing ethylenic unsaturation sites and capable of imagewise modulating mobility of the dye or dye precursor as a function of addition at the sites of ethylenic unsaturation, and coinitiators for ethylenic addition. The coinitiators include an azinium salt activator and a photosensitizer which is a dye exhibiting a reduction potential which in relation to that of said ionized azinium salt activator is at most 0.1 volt more positive, with the further proviso that, when the photosensitizer is a keto dye having its principal absorption peak at a wavelength shorter than 550 nm, it exhibits when excited by imaging radiation an intersystem crossing efficiency to a triplet state of less than 10 percent.

摘要翻译： 公开了一种摄影成像系统，其包括成像染料或其前体，含有烯属不饱和位点的可硬化有机组分，并且能够成像地调节染料或染料前体的迁移率，作为在烯属不饱和位点处的添加和共引发剂 用于乙烯加成。 共引发剂包括吖嗪盐活化剂和作为显示还原电位的染料的光敏剂，其与所述电离的氮鎓盐活化剂的相对于0.1至更高的正电位为止，其进一步的条件是当光敏剂是酮基染料时 在波长短于550nm处具有主要的吸收峰，当通过成像辐射激发系统交叉效率达到小于10％的三线态时，它表现出来。

公开(公告)号：US4341852A

公开(公告)日：1982-07-27

申请号：US193062

申请日：1980-10-02

申请人： Susan L. Mattes ,  Samir Y. Farid

发明人： Susan L. Mattes ,  Samir Y. Farid

IPC分类号： G03G5/06 ,  G03G5/09 ,  C07C121/64

CPC分类号： G03G5/0614 ,  G03G5/0612 ,  Y10S430/10

摘要： Polycyanoanthracenes containing three or more cyano groups, and in particular the novel compound 2,6,9,10-tetracyanoanthracene, are sensitizers for organic photoconductors.

摘要翻译： 含有三个或更多氰基的聚氰基蒽，特别是新化合物2,6,9,10-四氰基蒽是有机光电导体的敏化剂。