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    Catalyst containing phosphorous and a process hydrotreatment of petroleum feeds using the catalyst
    1.
    发明授权
    Catalyst containing phosphorous and a process hydrotreatment of petroleum feeds using the catalyst 有权
    含有磷的催化剂和使用催化剂的石油进料的工艺加氢处理

    公开(公告)号：US06332976B1

    公开(公告)日：2001-12-25

    申请号：US09310105

    申请日：1999-05-12

    申请人： Samuel Mignard ,  Nathalie George-Marchal ,  Virginie Harle ,  Slavik Kasztelan

    发明人： Samuel Mignard ,  Nathalie George-Marchal ,  Virginie Harle ,  Slavik Kasztelan

    IPC分类号： C10G4508

    CPC分类号： B01J27/188 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/108 ,  C10G45/08 ,  C10G49/04

    摘要： The invention concerns an alumina based catalyst containing, expressed as the oxide content by weight, 2-10% by weight of cobalt oxide CoO, 10-30% by weight of molybdenum oxide MoO3 and 4-10% of phosphorous oxide P2O5, with a BET surface area in the range 100-300 m2/g, a crushing strength CSH of more than 1.4 MPa, and an average pore diameter in the range 8-11 nm, the pore volume of pores with diameter of more than 14 nm being less than 0.08 ml/g, or less than 22% of total pore volume, the volume of pores with a diameter of less than 8 nm being at most 0.05 ml/g, or less than 10% of total pore volume, the volume of pores with diameter less than 10 nm being in the range of 20%-70%, the volume of pores with diameter between 10 nm and 13 nm being in the range of 20%-60%, and the volume of pores with a diameter which is in the range 8 to 14 nm being in the range 0.20 ml/g to 0.8 ml/g. The invention also concerns a hydrotreatment process using the catalyst, in particular hydrodesulphuration.

    摘要翻译： 本发明涉及一种氧化铝基催化剂，其含有氧化物含量为2-10重量％的氧化钴CoO，10-30重量％的氧化钼MoO 3和4-10重量％的氧化磷P2O5，其中a BET表面积在100-300m2 / g范围内，抗碎强度CSH大于1.4MPa，平均孔径在8-11nm范围内，孔径大于14nm的孔体积较小 直径小于8nm的孔的体积至少为0.05ml / g，或小于总孔体积的10％，孔的体积小于0.08ml / g，或小于总细孔容积的22％ 直径小于10nm的范围在20％-70％的范围内，直径在10nm和13nm之间的孔的体积在20％-60％的范围内，直径的孔的体积是 在8至14nm的范围内在0.20ml / g至0.8ml / g的范围内。本发明还涉及使用该催化剂，特别是加氢脱硫的加氢处理方法。

    Catalyst and process for hydrocracking fractions that contain hydrocarbon
    4.
    发明授权
    Catalyst and process for hydrocracking fractions that contain hydrocarbon 有权
    含有烃的加氢裂化馏分的催化剂和方法

    公开(公告)号：US06174429B1

    公开(公告)日：2001-01-16

    申请号：US09175468

    申请日：1998-10-20

    申请人： Nathalie George-Marchal ,  Samuel Mignard ,  Slavik Kasztelan

    发明人： Nathalie George-Marchal ,  Samuel Mignard ,  Slavik Kasztelan

    IPC分类号： C10G4700

    CPC分类号： C10G47/20 ,  B01J29/166 ,  B01J35/108 ,  B01J2229/42

    摘要： The invention relates to a hydrocracking catalyst that contains at least one metal of group VIB, and/or at least one metal of group VIII of the periodic table, an alumina matrix, phosphorus, optionally at least one element from group VIIA (fluorine), and a zeolite Y that is not fully dealuminificated, with a crystalline parameter that is greater than 2,438 nm, an overall SiO2/Al2O3 ratio that is less than 8, and a framework SiO2/Al2O3 ratio that is less than 21 and greater than the overall SiO2/Al2O3 ratio. The invention also relates to a process for hydrocracking with this catalyst, in particular at low pressure of 7.5 to 11 MPa.

    摘要翻译： 本发明涉及加氢裂化催化剂，其含有至少一种VIB族金属和/或至少一种周期表第VIII族金属，氧化铝基质，磷，任选地至少一种来自VIIA族（氟）的元素， 和未完全脱沥青的沸石Y，其结晶参数大于2,438nm，SiO 2 / Al 2 O 3的总体比小于8，骨架SiO 2 / Al 2 O 3比小于21且大于总体 SiO2 / Al2O3比例。 本发明还涉及一种用该催化剂进行加氢裂化的方法，特别是在7.5至11MPa的低压下。

    Catalyst comprising a zeolite Y globally non-dealuminated and containing boron and/or silicon
    6.
    发明授权
    Catalyst comprising a zeolite Y globally non-dealuminated and containing boron and/or silicon 有权
    催化剂包含全部非脱铝并含有硼和/或硅的沸石Y

    公开(公告)号：US06420296B2

    公开(公告)日：2002-07-16

    申请号：US09305296

    申请日：1999-05-05

    申请人： Samuel Mignard ,  Nathalie George-Marchal ,  Slavik Kasztelan

    发明人： Samuel Mignard ,  Nathalie George-Marchal ,  Slavik Kasztelan

    IPC分类号： B01J2910

    CPC分类号： C10G47/20 ,  B01J29/166

    摘要： A catalyst comprising 0.1-99.7% by weight of at least one alumina matrix; 0.1-80% by weight of at least one globally non dealuminated Y zeolite with a lattice parameter of more than 2.438 nm, a global SiO2/Al2O3 mole ratio of less than 8, and a framework SiO2/Al2O3 mole ratio of less than 21 and more than the global SiO2/Al2O3 mole ratio; 0.1-30% by weight of at least one group VIII metal and/or 1-40% by weight of at least one group VIB metal (% oxide); 0.1-20% by weight of at least one promoter element selected from the group formed by boron and silicon (% oxide); 0-20% by weight of at least one group VIIA element; 0-20% by weight of phosphorous (% oxide); 0.1-20% by weight of at least one group VIIB element, useful for hydrocracking processes, especially at low pressures of 7.5 to 11 MPa.

    摘要翻译： 包含0.1-99.7重量％的至少一种氧化铝基质的催化剂; 0.1-80重量％的至少一种全球非脱铝Y沸石，其晶格参数大于2.438nm，全球SiO 2 / Al 2 O 3摩尔比小于8，框架SiO 2 / Al 2 O 3摩尔比小于21， 超过全球SiO2 / Al2O3摩尔比; 0.1-30重量％的至少一种VIII族金属和/或1-40重量％的至少一种VIB族金属（％氧化物）; 至少一种选自硼和硅（％氧化物）形成的基团的至少一种助催化剂元素; 0-20重量％的至少一种VIIA族元素; 0-20重量％的磷（氧化物％）; 0.1-20重量％的至少一种VIIB族元素，可用于加氢裂化过程，特别是在7.5至11MPa的低压下。

    Catalyst comprising a zeolite Y globally non-dealuminated and containing boron and/or silicon
    8.
    发明授权
    Catalyst comprising a zeolite Y globally non-dealuminated and containing boron and/or silicon 有权
    催化剂包含全部非脱铝并含有硼和/或硅的沸石Y

    公开(公告)号：US06719895B2

    公开(公告)日：2004-04-13

    申请号：US09965804

    申请日：2001-10-01

    申请人： Samuel Mignard ,  Nathalie George-Marchal ,  Slavik Kasztelan

    发明人： Samuel Mignard ,  Nathalie George-Marchal ,  Slavik Kasztelan

    IPC分类号： C10G4716

    CPC分类号： C10G47/20 ,  B01J29/166

    摘要： The present invention relates to a hydrocracking process including contacting a hydrocarbon feed with a catalyst which is carried out at a pressure of at least 2 MPa, a temperature of at least 230° C., using a quantity of hydrogen of at least 100 Nl hydrogen/l of feed and with an hourly space velocity of 0.1-10 h−1. The catalyst includes 0.1-99.7% by weight of at least one alumina matrix; 0.1-80% by weight of at least one globally non dealuminated Y zeolite with a lattice parameter of more than 2.438 nm, a global SiO2/Al2O3 mole ratio of less than 8, and a framework SiO2/Al2O3 mole ratio of less than 21 and more than the global SiO2/Al2O3 mole ratio; 0.1-30% by weight of at least one group VIII metal and/or 1-40% by weight of at least one group VIB metal (% oxide); 0.1-20% by weight of at least one promoter element selected from the group formed by boron and silicon (% oxide); 0-20% by weight of at least one group VIIA element; 0-20% by weight of phosphorous (% oxide); and 0.1-20% by weight of at least one group VIIB element.

    摘要翻译： 本发明涉及一种加氢裂化方法，包括使烃进料与催化剂接触，所述催化剂在至少2MPa的压力，至少230℃的温度下使用至少100N氢气的氢气进行 / l的饲料，每小时空速为0.1-10小时-1。 催化剂包含0.1-99.7重量％的至少一个氧化铝基质; 0.1-80重量％的至少一种全部非脱铝Y沸石，其晶格参数大于2.438nm，全体SiO 2 / Al 2 O 3摩尔比 小于8，并且SiO 2 / Al 2 O 3的骨架比小于21且大于全局SiO 2 / Al 2 O 3摩尔比; 0.1-30重量％的至少一种VIII族金属和/或1-40重量％ 至少一种VIB族金属（％氧化物）; 0.1-20％重量的选自硼和硅（氧化物％）的至少一种助催化剂元素; 0-20％重量的至少一种VIIA族元素 ; 0-20重量％的磷（％氧化物）; 和0.1-20重量％的至少一种VIIB族元素。

    Process for activation of catalysts with a nitrogenous compound and excess thionic compound the catalysts that is obtained and it use in hydroconversion
    9.
    发明授权
    Process for activation of catalysts with a nitrogenous compound and excess thionic compound the catalysts that is obtained and it use in hydroconversion 有权
    用含氮化合物和过量的硫辛酸化合物活化催化剂的方法，所得催化剂及其在加氢转化中的应用

    公开(公告)号：US06187708B1

    公开(公告)日：2001-02-13

    申请号：US09305285

    申请日：1999-05-05

    申请人： Samuel Mignard ,  Virginie Harle ,  Slavik Kasztelan ,  Nathalie Marchal-George

    发明人： Samuel Mignard ,  Virginie Harle ,  Slavik Kasztelan ,  Nathalie Marchal-George

    IPC分类号： B01J3720

    CPC分类号： B01J37/20 ,  C10G47/12

    摘要： The invention relates to a process for the sulfurization of hydroconversion catalysts, whereby said catalyst contains at least one element of group VIII of the periodic table and optionally an element of group VI, whereby said metal is present in the oxide state. Said process comprises at least one stage that is carried out in a hydrotreatment zone in the presence of at least one thionic compound and at least one nitrogenous compound. This process is carried out in such a way that before the final sulfurization temperature is reached, at least 130% of the stoichiometric amount of sulfur that is necessary for complete sulfurization of the catalyst is injected in said catalyst.

    摘要翻译： 本发明涉及一种加氢转化催化剂硫化方法，其中所述催化剂含有至少一种元素周期表第Ⅷ族元素和任选的第Ⅵ族元素，其中所述金属以氧化态存在。 所述方法包括在至少一种硫辛酸化合物和至少一种含氮化合物的存在下在加氢处理区中进行的至少一个阶段。 该方法是在达到最终硫化温度之前进行的，在催化剂中注入催化剂完全硫化所需的化学计量量的至少130％的硫。