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    Free Radical Polymerisation Process for Making Macromonomers
    1.
    发明申请
    Free Radical Polymerisation Process for Making Macromonomers 审中-公开
    制备大分子单体的自由基聚合方法

    公开(公告)号：US20070219328A1

    公开(公告)日：2007-09-20

    申请号：US11587402

    申请日：2005-04-25

    申请人： Saskia Van Der Slot ,  Tijs Nabuurs ,  Alfred Jean Buckmann ,  Gerardus Overbeek

    发明人： Saskia Van Der Slot ,  Tijs Nabuurs ,  Alfred Jean Buckmann ,  Gerardus Overbeek

    IPC分类号： C08F4/06

    CPC分类号： C08F4/26 ,  C08F2/22 ,  C08F2/38 ,  C08F220/14 ,  C08F265/06 ,  C08F290/062 ,  C09D151/00 ,  C09J151/00 ,  C08F2220/1825 ,  C08F220/06 ,  C08F220/58

    摘要： Process for preparing a macromonomer using free radical-initiated aqueous emulsion polymerisation in a polymerisation reactor of at least one olefinically unsaturated monomer, which process employs a hydrophobic Co chelate complex as a CTA, a stabilising substance(s) for the emulsion polymerisation process and a monomer feed stage MF; wherein an aqueous pre-emulsified mixture A, comprising at least part of the Co chelate(s) employed, at least part of the stabilising substance(s) employed, and (i) a non-polymerisable organic solvent(s) and/or (ii) a polymerisable monomer(s) in unpolymerised or at least partially polymerised form, is contacted in the reactor with monomer(s) of feed stage MF at the beginning of and/or during the course of feed stage MF; and wherein in mixture A the weight ratio of (i) and/or (ii) to the stabilising substance(s) is in the range of from 10/1 to 1/10.

    摘要翻译： 在至少一种烯属不饱和单体的聚合反应器中使用自由基引发的水性乳液聚合制备大分子单体的方法，该方法使用疏水性Co螯合物络合物作为CTA，用于乳液聚合方法的稳定物质和 单体进料级MF; 其中包含至少部分所述Co螯合物的至少一部分所用稳定物质的水性预乳化混合物A和（i）不可聚合的有机溶剂和/或 （ii）未聚合或至少部分聚合形式的可聚合单体在反应器中在进料阶段MF的开始和/或期间在进料阶段MF的单体接触; 并且其中在混合物A中，（i）和/或（ii）与稳定物质的重量比在10/1至1/10的范围内。

    Aqueous crosslinkable coating compositions based on vinyl fluoropolymer
    3.
    发明申请
    Aqueous crosslinkable coating compositions based on vinyl fluoropolymer 失效
    基于乙烯基含氟聚合物的水性交联涂料组合物

    公开(公告)号：US20050004300A1

    公开(公告)日：2005-01-06

    申请号：US10485572

    申请日：2002-07-22

    申请人： Gerardus Overbeek ,  Jurgen Scheerder ,  Tijs Nabuurs

    发明人： Gerardus Overbeek ,  Jurgen Scheerder ,  Tijs Nabuurs

    IPC分类号： C08G18/48 ,  C08G18/62 ,  C08G18/70 ,  C08L61/20 ,  C09D133/16 ,  C09D175/04 ,  C08L1/00 ,  B05D1/00

    CPC分类号： C09D175/04 ,  C08G18/4833 ,  C08G18/6279 ,  C08G18/706 ,  C08L61/20 ,  C09D133/16 ,  C08L2666/14

    摘要： Aqueous crosslinkable coating composition suitable for anti-graffiti and heavy duty applications comprising: (A) an aqueous polymer emulsion comprising at least one vinyl fluoropolymer which comprises as a polymerised constituent monomer thereof (i) a fluoromonomer(s) having the formula (1) wherein R1 is CH3 or H, R2 is a per-fluorinated C1-5 alkyl group and n is 1, 2, 3 or 4, (ii) a hydroxyl functional monomer(s) and (iii) a carboxylic acid-functional monomer(s) where the vinyl fluoropolymer has a glass transition temperature Tg within the range of from −50 to 90° C. and (B) at least one hydroxyl-reactive crosslinker material.

    摘要翻译： 适用于防涂鸦和重载应用的水性可交联涂料组合物包括：（A）包含至少一种乙烯基含氟聚合物的含水聚合物乳液，其包含作为其聚合的构成单体（i）具有式（1）的含氟单体， 其中R 1是CH 3或H，R 2是全氟化的C 1-5烷基，n是1,2,3或4，（ii）羟基官能单体和（iii）a 羧酸官能单体，其中乙烯基含氟聚合物的玻璃化转变温度Tg在-50至90℃的范围内，和（B）至少一种羟基反应性交联剂材料。

    AQUEOUS DISPERSIONS CONTAINING CRYSTALLISABLE BLOCK COPOLYMERS
    5.
    发明申请
    AQUEOUS DISPERSIONS CONTAINING CRYSTALLISABLE BLOCK COPOLYMERS 审中-公开
    含有可溶性嵌段共聚物的水性分散体

    公开(公告)号：US20110207871A1

    公开(公告)日：2011-08-25

    申请号：US12671887

    申请日：2008-07-31

    申请人： John Geurts ,  Michael Arnoldus Jacobus Schellekens ,  Tijs Nabuurs ,  Gerardus Comelis Overbeek

    发明人： John Geurts ,  Michael Arnoldus Jacobus Schellekens ,  Tijs Nabuurs ,  Gerardus Comelis Overbeek

    IPC分类号： C08F2/22 ,  C08L53/00

    CPC分类号： C08F2/18 ,  C08F2/38 ,  C08F293/005 ,  C08F2438/03 ,  C08L53/00 ,  C09D153/00 ,  C08L2666/02

    摘要： An aqueous dispersion comprising a crystallisable vinyl block copolymer-polymer which comprises: i) a vinyl block copolymer comprising at least blocks [A]x [B]y , wherein at least a crystallisable block [A] is obtained by a controlled radical polymerisation of at least one vinyl monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism in solution, in the presence of a control agent and a source of free radicals; and wherein the vinyl block copolymer comprises 2 to 50 wt % of vinyl monomers bearing at least a crystallisable side chain by weight of the vinyl block copolymer-polymer; wherein crystallisable block [A] has an average degree of polymerisation x, wherein x is an integer in the range of from 3 to 80; wherein block [B] has an average degree of polymerisation y, wherein y is an integer ≦3; and ii) a vinyl polymer [P] obtained by the free radical emulsion polymerisation of one or more vinyl monomers in the presence of the vinyl block copolymer; and wherein the block copolymer:polymer weight ratio is in the range of from 10:90 to 70:30.

    摘要翻译： 包含可结晶乙烯基嵌段共聚物 - 聚合物的水分散体，其包含：i）至少包含嵌段[A] x [B] y的乙烯基嵌段共聚物，其中至少可结晶嵌段[A]通过受控自由基聚合 至少一种乙烯基单体通过溶解中的可逆加成 - 断裂链转移（RAFT）机理，在控制剂和自由基源的存在下进行; 并且其中所述乙烯基嵌段共聚物包含2-50重量％的至少具有乙烯基嵌段共聚物 - 聚合物重量的可结晶侧链的乙烯基单体; 其中可结晶嵌段[A]具有平均聚合度x，其中x是3至80的整数; 其中嵌段[B]具有平均聚合度y，其中y是整数nlE; 3; 和ii）在乙烯基嵌段共聚物存在下通过一种或多种乙烯基单体的自由基乳液聚合获得的乙烯基聚合物[P]; 并且其中所述嵌段共聚物：聚合物重量比在10:90至70:30的范围内。

    Aqueous crosslinkable coating compositions
    8.
    发明授权
    Aqueous crosslinkable coating compositions 失效
    水性交联涂料组合物

    公开(公告)号：US06395827B1

    公开(公告)日：2002-05-28

    申请号：US09402586

    申请日：1999-11-22

    申请人： David Alan Pears ,  Erik Hendrik Colstee ,  Gerardus Cornelis Overbeek ,  John Christopher Padget ,  Tijs Nabuurs

    发明人： David Alan Pears ,  Erik Hendrik Colstee ,  Gerardus Cornelis Overbeek ,  John Christopher Padget ,  Tijs Nabuurs

    IPC分类号： C08F800

    CPC分类号： C08G18/6254

    摘要： An aqueous crosslinkable coating composition suitable for the provision of thick coatings without incurring carbon dioxide bubble formation comprising: (A) an aqueous dispersion of at least one hydroxyl- and acid-functional vinyl polymer having a hydroxyl value of 8 to 250 mg KOH/g of polymer and an acid value of 2 to 55 mg KOH/g of polymer, where the contribution of at least 30% of the acid value results from a monocarboxylic acid(s) of formula: CH2—CR1—Q—CO2H  (1) where R1 is H or lower alkyl of 1 to 5 carbon atoms and Q is a spacer group of formula: [—C(═O)—X—(CH2)m—]k  (2) where X is —O— or —NH—, m is at least 1, preferably 2 or 3, and k is at least 1, preferably 2, 3, 4 or 5; and (B) at least one organic polyisocyanate. The acid of formula (1) preferably comprises &bgr;-carboxyethyl acrylate.

    摘要翻译： 适用于提供厚涂层而不引起二氧化碳气泡形成的水性可交联涂料组合物，其包含：（A）羟基值为8至250mg KOH / g的至少一种羟基和酸官能的乙烯基聚合物的水分散体 的聚合物，酸值为2至55mg KOH / g聚合物，其中至少30％酸值的贡献来自下式的单羧酸：其中R 1为H或低级烷基为1至 5个碳原子，Q是下式的间隔基：其中X是-O-或-NH-，m是至少1，优选2或3，k是至少1，优选2,3,4或5; 和（B）至少一种有机多异氰酸酯。 式（1）的酸优选包含丙烯酸β-羧乙酯。

    AQUEOUS EMULSION
    10.
    发明申请
    AQUEOUS EMULSION 有权
    水乳液

    公开(公告)号：US20130065070A1

    公开(公告)日：2013-03-14

    申请号：US13516452

    申请日：2010-12-17

    申请人： Tijs Nabuurs ,  Gerardus Cornelis Overbeek ,  Jeffrey Stubbs

    发明人： Tijs Nabuurs ,  Gerardus Cornelis Overbeek ,  Jeffrey Stubbs

    IPC分类号： C09D135/02

    CPC分类号： C09D135/02 ,  C08F212/08 ,  C08F220/18 ,  C08F222/14 ,  C08F265/04 ,  C08F267/06 ,  C08F2220/1808 ,  C08F2220/1825 ,  C08F2220/1833 ,  C08L35/02 ,  Y10T428/31935 ,  C08L2666/04 ,  C08L2666/02

    摘要： The invention relates to an aqueous emulsion comprising at least a vinyl polymer, said vinyl polymer comprising: a) 45 to 99 wt % of itaconate ester monomers having formula (I), wherein R and R′ are independently an alkyl or an aryl group; b) 0.1 to 15 wt % of ionic or potentially ionic unsaturated monomers; c) 0 to 54 wt % of unsaturated monomers, different from a) and b); and 0.9 to 54.9 wt % by weight of total monomers of a chaser monomer composition added subsequently and polymerised after the polymerisation of monomers a), b) and c); wherein a)+b)+c) and the chaser monomer composition add up to 100%; and wherein the aqueous emulsion contains less than 0.5 wt % free itaconate ester monomers of formula I based on the total weight of the aqueous emulsion.

    摘要翻译： 本发明涉及包含至少一种乙烯基聚合物的水乳液，所述乙烯基聚合物包含：a）45至99重量％的具有式（I）的衣康酸酯单体，其中R和R'独立地为烷基或芳基; b）0.1至15重量％的离子或潜在的不饱和单体; c）0至54重量％的不饱和单体，不同于a）和b）; 和0.9至54.9重量％的随后加入的追踪单体组合物的单体的总量，并且在单体a），b）和c）的聚合之后聚合。 其中a）+ b）+ c）和所述追踪单体组合物总计高达100％; 并且其中基于所述水性乳液的总重量，所述水性乳液含有小于0.5重量％的式I的游离的衣康酸酯单体。