公开(公告)号：US08445703B2

公开(公告)日：2013-05-21

申请号：US13262985

申请日：2010-04-07

申请人： Scott D. Allen ,  Ronald R. Valente ,  Han Lee ,  Anna E. Cherian ,  Donald L. Bunning ,  Nye A. Clinton ,  Olan Stanley Fruchey ,  Bernard Duane Dombek

发明人： Scott D. Allen ,  Ronald R. Valente ,  Han Lee ,  Anna E. Cherian ,  Donald L. Bunning ,  Nye A. Clinton ,  Olan Stanley Fruchey ,  Bernard Duane Dombek

IPC分类号： C07D305/12

CPC分类号： C07C51/377 ,  C07C51/09 ,  C07C67/30 ,  C07C67/317 ,  C07C231/14 ,  C07D305/12 ,  C07D307/60 ,  C08G63/08 ,  Y02P20/584

摘要： The present application provides a method for producing an beta-lactone product. The method includes the steps of: reacting an epoxide, a solvent with a carbonylation catalyst and carbon monoxide to produce a reaction stream comprising a beta-lactone then separating a portion of the beta-lactone in the reaction stream from the solvent and carbonylation catalyst to produce: i) a beta-lactone stream with the beta-lactone, and ii) a catalyst recycling stream including the carbonylation catalyst and the high boiling solvent; and adding the catalyst recycling stream to the feed stream.

公开(公告)号：US20120123137A1

公开(公告)日：2012-05-17

申请号：US13262985

申请日：2010-04-07

申请人： Scott D. Allen ,  Ronald R. Valente ,  Han Lee ,  Anna E. Cherian ,  Donald L. Bunning ,  Nye A. Clinton ,  Olan Stanley Fruchey ,  Bernard Duane Dombek

发明人： Scott D. Allen ,  Ronald R. Valente ,  Han Lee ,  Anna E. Cherian ,  Donald L. Bunning ,  Nye A. Clinton ,  Olan Stanley Fruchey ,  Bernard Duane Dombek

IPC分类号： C07D305/12

CPC分类号： C07C51/377 ,  C07C51/09 ,  C07C67/30 ,  C07C67/317 ,  C07C231/14 ,  C07D305/12 ,  C07D307/60 ,  C08G63/08 ,  Y02P20/584

摘要： The present application provides a method for producing an beta-lactone product. The method includes the steps of: reacting an epoxide, a solvent with a carbonylation catalyst and carbon monoxide to produce a reaction stream comprising a beta-lactone then separating a portion of the beta-lactone in the reaction stream from the solvent and carbonylation catalyst to produce: i) a beta-lactone stream with the beta-lactone, and ii) a catalyst recycling stream including the carbonylation catalyst and the high boiling solvent; and adding the catalyst recycling stream to the feed stream.

摘要翻译： 本申请提供了生产β-内酯产物的方法。 该方法包括以下步骤：使环氧化物，溶剂与羰基化催化剂和一氧化碳反应，以产生包含β-内酯的反应物流，然后将反应物流中的一部分β-内酯与溶剂和羰基化催化剂分离成 产生：i）具有β-内酯的β-内酯流，和ii）包含羰基化催化剂和高沸点溶剂的催化剂再循环流; 并将催化剂再循环流加入进料流中。

公开(公告)号：US4593127A

公开(公告)日：1986-06-03

申请号：US690912

申请日：1985-01-11

申请人： Donald L. Bunning ,  Michael A. Blessing

发明人： Donald L. Bunning ,  Michael A. Blessing

IPC分类号： C07C47/00 ,  B01J31/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/00

CPC分类号： C07C45/50

摘要： In a primary process for hydroformylating olefins to form aldehydes in which a liquid or gas recycle step is conducted and a gaseous effluent is vented, the improvement which comprises employing the effluent as a reactant feed for a decoupled secondary liquid-or gas recycle hydroformylation process conducted conjointly therewith.

摘要翻译： 在用于加氢甲酰化烯烃以形成其中进行液体或气体再循环步骤并排出气态流出物的主要方法中，包括采用流出物作为反应物进料进行去耦合的二次液体或气体循环加氢甲酰化方法的改进 与此同时。

公开(公告)号：US20100298610A1

公开(公告)日：2010-11-25

申请号：US12565446

申请日：2009-09-23

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas ,  Jeffrey S. Kanel

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas ,  Jeffrey S. Kanel

IPC分类号： C07C47/02

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。

公开(公告)号：US20100126060A1

公开(公告)日：2010-05-27

申请号：US12523184

申请日：2008-01-23

申请人： Thomas A. Maliszewski ,  Donald L. Bunning ,  David J. Schreck ,  Louis A. Kapicak ,  Norman L. Balmer

发明人： Thomas A. Maliszewski ,  Donald L. Bunning ,  David J. Schreck ,  Louis A. Kapicak ,  Norman L. Balmer

IPC分类号： C10L1/19 ,  B01J8/00

CPC分类号： C10L1/026 ,  C10G2300/1011 ,  Y02E50/13 ,  Y02P30/20

摘要： Waste water emissions from a biodiesel production facility are substantially reduced by recovering water from a spent water stream used in a water washing step in the refining of crude biodiesel which water washing removes glycerin. The water is recovered from the spent water stream is concentrated to provide an aqueous fraction which can be recycled for the water washing. The concentration also provides a glycerin-containing fraction containing that can be blended with crude glycerin by-product generated by transesterification of glycerides to make the biodiesel.

摘要翻译： 生物柴油生产设备的废水排放通过从用于水洗涤去除甘油的粗生物柴油精制中的水洗步骤中使用的废水流中回收水而大大减少。 从废水流中回收的水被浓缩以提供可以循环用于水洗的含水部分。 该浓度还提供含甘油的级分，其可以与通过甘油酯的酯交换产生的粗甘油副产物混合以制备生物柴油。

公开(公告)号：US20090118548A1

公开(公告)日：2009-05-07

申请号：US12299853

申请日：2007-04-17

申请人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

发明人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

IPC分类号： C07C45/50

CPC分类号： C07C45/80 ,  C07C45/50 ,  C07C67/347 ,  Y02P20/584 ,  C07C69/738 ,  C07C69/716 ,  C07C47/02

摘要： A non-aqueous hydroformylation process with liquid catalyst recycle involving a hydroformylation step and one or more stages of phase separation to recover a high molecular weight aldehyde product with efficient recovery of rhodium catalyst. The process includes a hydroformylation step to prepare a non-aqueous hydroformylation reaction product composition comprising one or more aldehyde products, one or more conjugated polyolefins, a rhodium-organophosphorus ligand complex, free organophosphorus ligand, and an organic solubilizing agent for said complex and said free ligand, and thereafter one or more stages of phase separation using added water under a carbon monoxide gas, hydrogen gas, or a mixture thereof. The process requires a specific range of total pressure for the hydroformylation, a specific range of total pressure for at least one of the separation stages, and a minimum sum of the total pressure of the hydroformylation step and the total pressure of the separation stage containing said gas.

摘要翻译： 具有液体催化剂循环的非水羰基化方法，其涉及加氢甲酰化步骤和一个或多个相分离阶段以回收高分子量醛产物并有效回收铑催化剂。 该方法包括加氢甲酰化步骤，以制备包含一种或多种醛产物，一种或多种共轭聚烯烃，铑 - 有机磷配体络合物，游离有机磷配体和用于所述络合物的有机增溶剂的非水羰基化反应产物组合物和所述 游离配体，然后在一氧化碳气体，氢气或其混合物中使用加入的水进行一个或多个相分离阶段。 该方法需要加氢甲酰化的总压力的特定范围，至少一个分离阶段的总压力的特定范围，以及加氢甲酰化步骤的总压力和含有所述分离阶段的分离阶段的总压力的最小总和 加油站。

公开(公告)号：US4999452A

公开(公告)日：1991-03-12

申请号：US351479

申请日：1989-05-15

申请人： Donald L. Bunning ,  William G. Etzkorn ,  William M. Haydon ,  Gordon G. Harkreader ,  Jonathan J. Kurland ,  Wai C. Liu ,  Ernesto Vera-Castaneda

发明人： Donald L. Bunning ,  William G. Etzkorn ,  William M. Haydon ,  Gordon G. Harkreader ,  Jonathan J. Kurland ,  Wai C. Liu ,  Ernesto Vera-Castaneda

IPC分类号： C07C67/08 ,  C07B61/00 ,  C07C51/42 ,  C07C57/07 ,  C07C69/54

CPC分类号： C07C51/42 ,  C07C67/08

摘要： A process for producing acrylic ester by the catalytic esterification of a crude liquid stream of enriched acrylic acid recovered by the partial condensation of the reaction gas effluent from the catalytic oxidation of propylene and/or acrolein. The partial condensation allows a significant proportion of volatile aldehydes and water to pass through the first recovery stage to a second stage for conventional recovery, along with uncondensed acrylic acid vapors and the remainder of the uncondensed reaction gases.

公开(公告)号：US08124812B2

公开(公告)日：2012-02-28

申请号：US12565446

申请日：2009-09-23

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

IPC分类号： C07C47/02 ,  C07C45/50 ,  C07C29/14 ,  C07C59/147

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。

公开(公告)号：US07663002B2

公开(公告)日：2010-02-16

申请号：US12299853

申请日：2007-04-17

申请人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

发明人： Wei-Jun Peng ,  Kurt D. Olson ,  Donald L. Morrison ,  Brian M. Roesch ,  Donald L. Bunning ,  Jeffrey G. Hippler ,  Vincent J. Stricker

IPC分类号： C07C45/50

CPC分类号： C07C45/80 ,  C07C45/50 ,  C07C67/347 ,  Y02P20/584 ,  C07C69/738 ,  C07C69/716 ,  C07C47/02

摘要： A non-aqueous hydroformylation process with liquid catalyst recycle involving a hydroformylation step and one or more stages of phase separation to recover a high molecular weight aldehyde product with efficient recovery of rhodium catalyst. The process includes a hydroformylation step to prepare a non-aqueous hydroformylation reaction product composition comprising one or more aldehyde products, one or more conjugated polyolefins, a rhodium-organophosphorus ligand complex, free organophosphorus ligand, and an organic solubilizing agent for said complex and said free ligand, and thereafter one or more stages of phase separation using added water under a carbon monoxide gas, hydrogen gas, or a mixture thereof. The process requires a specific range of total pressure for the hydroformylation, a specific range of total pressure for at least one of the separation stages, and a minimum sum of the total pressure of the hydroformylation step and the total pressure of the separation stage containing said gas.

摘要翻译： 具有液体催化剂循环的非水羰基化方法，其涉及加氢甲酰化步骤和一个或多个相分离阶段以回收高分子量醛产物并有效回收铑催化剂。 该方法包括加氢甲酰化步骤，以制备包含一种或多种醛产物，一种或多种共轭聚烯烃，铑 - 有机磷配体络合物，游离有机磷配体和用于所述络合物的有机增溶剂的非水羰基化反应产物组合物和所述 游离配体，然后在一氧化碳气体，氢气或其混合物中使用加入的水进行一个或多个相分离阶段。 该方法需要加氢甲酰化的总压力的特定范围，至少一个分离阶段的总压力的特定范围，以及加氢甲酰化步骤的总压力和含有所述分离阶段的分离阶段的总压力的最小总和 加油站。

公开(公告)号：US07615658B2

公开(公告)日：2009-11-10

申请号：US10551854

申请日：2004-04-22

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

IPC分类号： C07C51/367 ,  C07C27/00

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxymethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foam.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或具有以下重量组成的脂肪酸酯的混合物：大于约10至小于约95％的一元醇（单（羟甲基）}， 大于约1至小于约65％的二醇{二（羟甲基）}，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯; 优选大于约3至小于约35％的饱和物; 并且优选小于约10％的不饱和物。 醇组合物可以转化为用于制造聚氨酯板坯柔性泡沫的低聚多元醇。