公开(公告)号：US20140011926A1

公开(公告)日：2014-01-09

申请号：US14010959

申请日：2013-08-27

申请人： Scott Michael Fisher ,  Qiwei Lu ,  William Eugene Pecak ,  Michael J. O'Brien

发明人： Scott Michael Fisher ,  Qiwei Lu ,  William Eugene Pecak ,  Michael J. O'Brien

IPC分类号： C08L71/12 ,  C08K5/523 ,  C08K5/01

CPC分类号： C08K5/01 ,  C04B24/26 ,  C04B28/02 ,  C08K3/04 ,  C08K5/523 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L25/06 ,  C08L71/12 ,  C08L91/00 ,  C08L7/00

摘要： A rubber composition with disperse phase particles containing poly(phenylene ether) can be formed by a method that includes melt blending an uncured rubber with a poly(phenylene ether) composition containing a poly(phenylene ether) and an oil to form an uncured rubber composition, then curing the uncured rubber composition. Before being blended with the rubber, the poly(phenylene ether) composition exhibits a glass transition temperature of about 40 to about 140° C., and during blending with the rubber, the oil component of poly(phenylene ether) composition migrates from the poly(phenylene ether) composition to the rubber, leaving a poly(phenylene ether)-containing disperse phase that gives rise to a second hysteresis peak temperature of about 160 to about 220° C. as measured by dynamic mechanical analysis of the cured rubber composition. Also described are the poly(phenylene ether) composition used in the method, a cured rubber composition formed by the method, and a tire containing the cured rubber composition.

摘要翻译： 含有聚（苯醚）的分散相颗粒的橡胶组合物可以通过包括将未固化的橡胶与含有聚（苯醚）和油的聚（苯醚）组合物熔融共混以形成未固化的橡胶组合物的方法形成 ，然后固化未固化的橡胶组合物。 在与橡胶混合之前，聚（苯醚）组合物的玻璃化转变温度为约40至约140℃，并且在与橡胶共混期间，聚（苯醚）组合物的油组分从聚 （亚苯基醚）组合物与橡胶反应，留下含聚亚苯基醚的分散相，其通过固化的橡胶组合物的动态机械分析测量，产生约160至约220℃的第二滞后峰值温度。 还描述了该方法中使用的聚（苯醚）组合物，通过该方法形成的固化橡胶组合物和含有固化橡胶组合物的轮胎。

公开(公告)号：US08557937B1

公开(公告)日：2013-10-15

申请号：US13488701

申请日：2012-06-05

申请人： Scott Michael Fisher ,  Qiwei Lu ,  William Eugene Pecak ,  Michael J. O'Brien

发明人： Scott Michael Fisher ,  Qiwei Lu ,  William Eugene Pecak ,  Michael J. O'Brien

IPC分类号： C08F2/00 ,  C04B28/02 ,  C04B24/26 ,  B60R13/08 ,  C08K5/00

CPC分类号： C08K5/01 ,  C04B24/26 ,  C04B28/02 ,  C08K3/04 ,  C08K5/523 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L25/06 ,  C08L71/12 ,  C08L91/00 ,  C08L7/00

摘要： A rubber composition with disperse phase particles containing poly(phenylene ether) can be formed by a method that includes melt blending an uncured rubber with a poly(phenylene ether) composition containing a poly(phenylene ether) and an oil to form an uncured rubber composition, then curing the uncured rubber composition. Before being blended with the rubber, the poly(phenylene ether) composition exhibits a glass transition temperature of about 40 to about 140° C., and during blending with the rubber, the oil component of poly(phenylene ether) composition migrates from the poly(phenylene ether) composition to the rubber, leaving a poly(phenylene ether)-containing disperse phase that gives rise to a second hysteresis peak temperature of about 160 to about 220° C. as measured by dynamic mechanical analysis of the cured rubber composition. Also described are the poly(phenylene ether) composition used in the method, a cured rubber composition formed by the method, and a tire containing the cured rubber composition.

摘要翻译： 含有聚（苯醚）的分散相颗粒的橡胶组合物可以通过包括将未固化的橡胶与含有聚（苯醚）和油的聚（苯醚）组合物熔融共混以形成未固化的橡胶组合物的方法形成 ，然后固化未固化的橡胶组合物。 在与橡胶混合之前，聚（苯醚）组合物的玻璃化转变温度为约40至约140℃，并且在与橡胶共混期间，聚（苯醚）组合物的油组分从聚 （亚苯基醚）组合物与橡胶反应，留下含聚亚苯基醚的分散相，其通过固化的橡胶组合物的动态机械分析测量，产生约160至约220℃的第二滞后峰值温度。 还描述了该方法中使用的聚（苯醚）组合物，通过该方法形成的固化橡胶组合物和含有固化橡胶组合物的轮胎。

公开(公告)号：US08674004B2

公开(公告)日：2014-03-18

申请号：US14010959

申请日：2013-08-27

申请人： Scott Michael Fisher ,  Qiwei Lu ,  William Eugene Pecak ,  Michael Joseph O'Brien

发明人： Scott Michael Fisher ,  Qiwei Lu ,  William Eugene Pecak ,  Michael Joseph O'Brien

IPC分类号： C04B28/02 ,  C04B24/26 ,  B60R13/08 ,  C08K5/00 ,  C08F2/00

CPC分类号： C08K5/01 ,  C04B24/26 ,  C04B28/02 ,  C08K3/04 ,  C08K5/523 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L25/06 ,  C08L71/12 ,  C08L91/00 ,  C08L7/00

摘要： A rubber composition with disperse phase particles containing poly(phenylene ether) can be formed by a method that includes melt blending an uncured rubber with a poly(phenylene ether) composition containing a poly(phenylene ether) and an oil to form an uncured rubber composition, then curing the uncured rubber composition. Before being blended with the rubber, the poly(phenylene ether) composition exhibits a glass transition temperature of about 40 to about 140° C., and during blending with the rubber, the oil component of poly(phenylene ether) composition migrates from the poly(phenylene ether) composition to the rubber, leaving a poly(phenylene ether)-containing disperse phase that gives rise to a second hysteresis peak temperature of about 160 to about 220° C. as measured by dynamic mechanical analysis of the cured rubber composition. Also described are the poly(phenylene ether) composition used in the method, a cured rubber composition formed by the method, and a tire containing the cured rubber composition.

公开(公告)号：US3962126A

公开(公告)日：1976-06-08

申请号：US527139

申请日：1974-11-25

申请人： William Eugene Pecak

发明人： William Eugene Pecak

IPC分类号： B01J21/10 ,  B01J21/20 ,  B01J23/92 ,  B01J38/12 ,  C07B61/00 ,  C07C27/00 ,  C07C37/16 ,  C07C67/00 ,  B01J31/06

CPC分类号： B01J21/20 ,  B01J23/92 ,  C07C37/16 ,  Y02P20/584

摘要： A improved method of reactivating a magnesium oxide catalyst is disclosed which comprises contacting the catalyst with water after heating the catalyst.

公开(公告)号：US06908964B2

公开(公告)日：2005-06-21

申请号：US10617849

申请日：2003-07-10

申请人： Adeyinka Adedeji ,  John C. Haylock ,  Robert Hossan ,  William Eugene Pecak ,  Mark Victor Vendon

发明人： Adeyinka Adedeji ,  John C. Haylock ,  Robert Hossan ,  William Eugene Pecak ,  Mark Victor Vendon

IPC分类号： B29B7/42 ,  C08K7/14 ,  C08L23/00 ,  C08L23/10 ,  C08L23/16 ,  C08L25/00 ,  C08L51/04 ,  C08L53/00 ,  C08L53/02 ,  C08L71/12

CPC分类号： C08L23/10 ,  B29B7/421 ,  B29C47/6025 ,  B29C47/6031 ,  B29C47/6056 ,  C08L23/16 ,  C08L25/06 ,  C08L51/06 ,  C08L53/00 ,  C08L53/02 ,  C08L71/12 ,  C08L71/123 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/22 ,  C08L2666/24

摘要： A poly(arylene ether)-polyolefin composition is prepared by melt-blending a poly(arylene ether), a poly(alkenyl aromatic) resin, a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, and an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene to form a first blend, and melt-blending the first blend and a polyolefin and additional hydrogenated block copolymer to form a second blend. A reinforcing filler and/or an ethylene/alpha-olefin elastomeric copolymer may, optionally, be added during formation of the second blend or in an additional step. Multiple mixing elements, low throughput, and high extruder rotations per minute may be used to achieve high energy mixing of the first and second blends. Compositions prepared by the method exhibit an improved balance of impact strength, stiffness, and heat resistance, as well as reduced variability of physical properties.

摘要翻译： 聚（亚芳基醚） - 聚烯烃组合物通过熔融共混聚（亚芳基醚），聚（烯基芳族）树脂，链烯基芳族化合物和共轭二烯的氢化嵌段共聚物和未氢化嵌段共聚物 烯基芳族化合物和共轭二烯以形成第一共混物，并将第一共混物和聚烯烃和另外的氢化嵌段共聚物熔融共混以形成第二共混物。 任选地，在形成第二共混物期间或在另外的步骤中加入增强填料和/或乙烯/α-烯烃弹性体共聚物。 可以使用多个混合元件，低通量和每分钟高的挤出机旋转以实现第一和第二共混物的高能量混合。 通过该方法制备的组合物表现出改善的冲击强度，刚度和耐热性的平衡，以及物理性能的变化性降低。

公开(公告)号：US20080114102A1

公开(公告)日：2008-05-15

申请号：US11559032

申请日：2006-11-13

申请人： Kim G. Balfour ,  Vijay Mhetar ,  William Eugene Pecak ,  Vijay Rajamani

发明人： Kim G. Balfour ,  Vijay Mhetar ,  William Eugene Pecak ,  Vijay Rajamani

IPC分类号： C08K5/3477 ,  C08L53/00 ,  C08L51/00

CPC分类号： C08L23/10 ,  C08L51/04 ,  C08L53/02 ,  C08L71/12 ,  C08L71/123 ,  C08L79/02 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/04

摘要： A thermoplastic composition includes the product of melt kneading a composition including a poly(arylene ether), a polyolefin, an acid-functionalized hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, and a polyamine compound. The composition exhibits substantially improved chemical resistance compared to a corresponding composition lacking the polyamine compound. Methods of preparing the composition and articles prepared for the composition are also described. The composition is particularly useful for fabricating halogen-free tubes for sheathing automotive wiring harnesses.

摘要翻译： 热塑性组合物包括熔融捏合包含聚（亚芳基醚），聚烯烃，链烯基芳族化合物的酸官能化氢化嵌段共聚物和共轭二烯的组合物和多胺化合物的产物。 与不含多胺化合物的相应组合物相比，该组合物显示出显着改善的耐化学性。 还描述了制备组合物的方法和为组合物制备的制品。 该组合物特别适用于制造用于护套汽车线束的无卤管。

公开(公告)号：US07253227B2

公开(公告)日：2007-08-07

申请号：US10248125

申请日：2002-12-19

申请人： Vijay R. Mhetar ,  Robert John Hossan ,  William Eugene Pecak

发明人： Vijay R. Mhetar ,  Robert John Hossan ,  William Eugene Pecak

IPC分类号： C08F290/04

CPC分类号： C08L71/123 ,  C08L25/04 ,  C08L2666/04

摘要： A composition comprises poly(arylene ether), a rubber modified poly(alkenyle aromatic) resin, and an unsaturated impact modifier. The composition may further comprise an encapsulated fluoropolymer. The melt strength of the composition, measured as the hang time of an extruded tube, is especially suited for blow molding methods. The composition exhibits good melt strength, surface quality and/or sandability and is particularly useful in blow molding applications.

摘要翻译： 组合物包含聚（亚芳基醚），橡胶改性聚（烯烃芳族）树脂和不饱和抗冲改性剂。 组合物还可包含封装的含氟聚合物。 以挤出管的悬挂时间测量的组合物的熔体强度特别适用于吹塑成型方法。 该组合物表现出良好的熔体强度，表面质量和/或砂性，并且特别适用于吹塑应用。

公开(公告)号：US20080113138A1

公开(公告)日：2008-05-15

申请号：US11559008

申请日：2006-11-13

申请人： William Eugene Pecak ,  Vijay Rajamani

发明人： William Eugene Pecak ,  Vijay Rajamani

IPC分类号： B32B1/08 ,  C08K3/32 ,  C08L9/06

CPC分类号： C08L23/12 ,  C08K3/32 ,  C08L23/06 ,  C08L53/025 ,  C08L71/00 ,  C08L71/123 ,  Y10T428/139 ,  C08L2666/24 ,  C08L2666/06 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14

摘要： A thermoplastic composition includes the product of melt kneading a composition including a poly(arylene ether), a polyolefin, and a high molecular weight hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene. The composition exhibits substantially improved chemical resistance compared to a corresponding composition prepared with a lower molecular weight hydrogenated block copolymer. Methods of preparing the composition and articles prepared for the composition are also described. The composition is particularly useful for fabricating halogen-free tubes for sheathing automotive wiring harnesses.

摘要翻译： 热塑性组合物包括熔融捏合包含聚（亚芳基醚），聚烯烃和链烯基芳族化合物和共轭二烯的高分子量氢化嵌段共聚物的组合物的产物。 与用较低分子量氢化嵌段共聚物制备的相应组合物相比，该组合物显示出显着改善的耐化学性。 还描述了制备组合物的方法和为组合物制备的制品。 该组合物特别适用于制造用于护套汽车线束的无卤管。

公开(公告)号：US07718721B2

公开(公告)日：2010-05-18

申请号：US11559032

申请日：2006-11-13

申请人： Kim G. Balfour ,  Vijay Mhetar ,  William Eugene Pecak ,  Vijay Rajamani

发明人： Kim G. Balfour ,  Vijay Mhetar ,  William Eugene Pecak ,  Vijay Rajamani

IPC分类号： C08K5/3492 ,  C08K5/52 ,  C08K3/10 ,  C08L51/00 ,  C08L53/00

CPC分类号： C08L23/10 ,  C08L51/04 ,  C08L53/02 ,  C08L71/12 ,  C08L71/123 ,  C08L79/02 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/04

摘要： A thermoplastic composition includes the product of melt kneading a composition including a poly(arylene ether), a polyolefin, an acid-functionalized hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, and a polyamine compound. The composition exhibits substantially improved chemical resistance compared to a corresponding composition lacking the polyamine compound. Methods of preparing the composition and articles prepared for the composition are also described. The composition is particularly useful for fabricating halogen-free tubes for sheathing automotive wiring harnesses.

摘要翻译： 热塑性组合物包括熔融捏合包含聚（亚芳基醚），聚烯烃，链烯基芳族化合物的酸官能化氢化嵌段共聚物和共轭二烯的组合物和多胺化合物的产物。 与不含多胺化合物的相应组合物相比，该组合物显示出显着改善的耐化学性。 还描述了制备组合物的方法和为组合物制备的制品。 该组合物特别适用于制造用于护套汽车线束的无卤管。