Resins with unsaturated carbonyl and hydroxyl groups
    4.
    发明授权
    Resins with unsaturated carbonyl and hydroxyl groups 失效
    具有不饱和羰基和羟基的树脂

    公开(公告)号:US5216094A

    公开(公告)日:1993-06-01

    申请号:US884881

    申请日:1992-05-18

    IPC分类号: C08F8/44

    CPC分类号: C08F8/44

    摘要: The present invention provides a curable resin coating composition consisting essentially of:(i) a resin (A) containing .alpha.,.beta.-unsaturated carbonyl group and primary and/or secondary hydroxyl group, or(ii) a mixture of a resin (B) containing .alpha.,.beta.-unsaturated carbonyl group and a resin (C) containing primary and/or secondary hydroxyl group, and(iii) at least one curing catalyst selected from the group consisting of alkali metal alkoxides, metal hydroxides, organic acid salts of metals, quaternary ammonium hydroxides, quaternary phosphonium hydroxides, tertiary sulfonium hydroxides and organic acid salts of these onium hydroxides.

    摘要翻译: 本发明提供一种可固化树脂涂料组合物,其基本上由以下组成:(i)含有α,β-不饱和羰基和伯和/或仲羟基的树脂(A),或(ii)树脂(B) 含有α,β-不饱和羰基和含有伯和/或仲羟基的树脂(C),和(iii)至少一种选自碱金属醇盐,金属氢氧化物,金属有机酸盐的固化催化剂 ,季铵氢氧化物,季铵氢氧化物,叔锍氢氧化物和这些氢氧化镧的有机酸盐。

    Coating compositions and methods for preventing adhesion of organisms
    5.
    发明授权
    Coating compositions and methods for preventing adhesion of organisms 失效
    用于防止生物粘附的涂料组合物和方法

    公开(公告)号:US5015472A

    公开(公告)日:1991-05-14

    申请号:US527465

    申请日:1990-05-23

    IPC分类号: C09D5/16

    CPC分类号: C09D5/1668

    摘要: Disclosed are a coating composition (A) for preventing adhesion of organisms which comprises as its vehicle component a homopolymer or a copolymer, the homopolymer being one prepared by homopolymerizing a phenol-modified unsaturated monomer obtained by reacting (a) an unsaturated monomer containing epoxy group and/or hydroxyl group with (b) an addition reaction product of a phenolic compound with a compound having one carboxylic anhydride group per molecule, and the copolymer being one prepared by copolymerizing said phenol-modified unsaturated monomer and a radically polymerizable unsaturated monomer, and also a coating composition (B) for preventing adhesion of organisms which comprises as its vehicle component a phenol-modified resin prepared by reacting (c) a resin containing epoxy group and/or hydroxyl group with (b) and addition reaction product of a phenolic compound with a compound having one carboxylic anhyhdride group per molecule.Also disclosed is a method for preventing adhesion of organisms, characterized by coating a substrate with the coating composition (A) or (B).

    Coating compositions for preventing adhesion of organisms
    6.
    发明授权
    Coating compositions for preventing adhesion of organisms 失效
    用于防止生物附着的涂料组合物

    公开(公告)号:US4973477A

    公开(公告)日:1990-11-27

    申请号:US317501

    申请日:1989-03-01

    IPC分类号: C09D5/16

    CPC分类号: C09D5/1668

    摘要: Disclosed are a coating composition (A) for preventing adhesion of organisms which comprises as its vehicle component a homopolymer or a copolymer, the homopolymer being one prepared by homopolymerizing a phenol-modified unsaturated monomer obtained by reacting (a) an unsaturated monomer containing epoxy group and/or hydroxyl group with (b) an addition reaction product of a phenolic compound with a compound having one carboxylic anhydride group per molecule, and the copolymer being one prepared by copolymerizing said phenol-modified unsaturated monomer and a radically polymerizable unsaturated monomer, and also a coating composition (B) for preventing adhesion of organisms which comprises as its vehicle component a phenol-modified resin prepared by reacting (c) a resin containing epoxy group and/or hydroxyl group with (b) an addition reaction product of a phenolic compound with a compound having one carboxylic anhydride group per molecule.Also disclosed is a method for preventing adhesion of organisms, characterized by coating a substrate with the coating composition (A) or (B).

    Method of forming a cured coating film
    7.
    发明授权
    Method of forming a cured coating film 失效
    形成固化涂膜的方法

    公开(公告)号:US5093223A

    公开(公告)日:1992-03-03

    申请号:US278505

    申请日:1988-12-01

    摘要: The invention provides a method of forming a cured coating film which comprises exposing a coating composition consisting of, or containing as a main component, a resin containing polymerizable unsaturated group and aprotic onium-containing group of the formula ##STR1## wherein R.sub.1 means a hydrogen atom or a hydrocarbon group of 1 to 8 carbon atoms which may optionally be substituted by a hydroxyl, alkoxy or ester group or a halogen atom; ##STR2## where Z means a nitrogen atom or phosphorus atom and Y means a sulfur atom; R.sub.2, R.sub.3 and R.sub.4 are the same or different and respectively mean an organic group of 1 to 14 carbon atoms, provided that R.sub.2 and R.sub.3, or R.sub.2, R.sub.3 and R.sub.4 may jointly form a heterocyclic group taken together with the adjacent nitrogen, phosphorus or sulfur atom, to actinic radiation or electron beams to thereby induce a crosslinking reaction and, then, subjecting the composition to heat treatment at a temperature not less than 80.degree. C.

    摘要翻译: 本发明提供一种形成固化涂膜的方法,该方法包括使包含可聚合不饱和基团的树脂和式(Ⅰ)所示的非质子含鎓基团组成或包含作为主要成分的涂料组合物,其中R 1 是指氢原子或可任选被羟基,烷氧基或酯基或卤素原子取代的1至8个碳原子的烃基; 其中Z表示氮原子或磷原子,Y表示硫原子; R 2,R 3和R 4相同或不同,分别表示1至14个碳原子的有机基团,条件是R 2和R 3或R 2,R 3和R 4可以与相邻的氮,磷或磷一起形成杂环基 硫原子,光化辐射或电子束,从而引起交联反应,然后使组合物在不低于80℃的温度下进行热处理。

    Curable resin and resin composition curable at low temperature
    10.
    发明授权
    Curable resin and resin composition curable at low temperature 失效
    可固化树脂和树脂组合物在低温下可固化

    公开(公告)号:US4923930A

    公开(公告)日:1990-05-08

    申请号:US272959

    申请日:1988-11-18

    摘要: This invention provides a curable resin obtained by polymerizing at least one of an alkoxysiloxane-containing vinyl monomer and a polysiloxane macromonomer with an oxirane-containing vinyl monomer in the presence of a polymerization initiator and a resin having in the molecule a carboxyl group and/or an alicyclic hydrocarbon ring having one or two hydrogen atoms bonded to at least one carbon atom forming the alicyclic hydrocarbon ring; and a resin composition curable at a low temperature comprising the curable resin as defined above and a chelate compound.

    摘要翻译: 本发明提供一种固化树脂,其通过在聚合引发剂和分子内具有羧基和/或其分子的树脂的存在下将含烷氧基硅氧烷的乙烯基单体和聚硅氧烷大分子单体中的至少一种与含环氧乙烷的乙烯基单体聚合而获得, 具有一个或两个氢原子与形成脂环烃环的至少一个碳原子键合的脂环烃环; 以及包含上述固化性树脂的低温可固化的树脂组合物和螯合化合物。