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公开(公告)号：US07244292B2
公开(公告)日：2007-07-17
申请号：US11120049
申请日：2005-05-02
IPC分类号： B03C3/28
CPC分类号： B01D39/1623 , Y10S55/33 , Y10S55/35 , Y10S55/39 , Y10T442/2189 , Y10T442/2238
摘要： An electret article that includes a polymeric material that has electric charge imparted thereto, that has one or more heteroatoms, that has a fluorosaturation ratio of less than 200, and that has an atomic percent fluorine of greater than about 40%. The inventive electret article is resistant to charge degradation upon exposure to high temperatures for prolonged time periods.
摘要翻译： 一种驻极体制品，其包含具有赋予电荷的聚合材料，其具有一个或多个杂原子，其具有小于200的氟碳饱和比，并且具有大于约40％的原子百分比的氟。 本发明的驻极体制品在长时间暴露于高温下可抵抗电荷降解。
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公开(公告)号：US07244291B2
公开(公告)日：2007-07-17
申请号：US11119877
申请日：2005-05-02
申请人： Gerald R. Spartz , Seth M. Kirk , Marvin E. Jones , Hyacinth L. Cabibil , Alan D. Rousseau , Steven J. Pachuta
发明人： Gerald R. Spartz , Seth M. Kirk , Marvin E. Jones , Hyacinth L. Cabibil , Alan D. Rousseau , Steven J. Pachuta
IPC分类号： B03C3/28
CPC分类号： B01D39/1623 , H01G7/023 , Y10S55/33 , Y10S55/35 , Y10S55/39 , Y10T442/2189 , Y10T442/2238
摘要： An electret article that includes a polymeric material that has electric charge imparted thereto, that has a CF3:CF2 ratio of at least 0.15 and that has a fluorosaturation ratio greater than about 200. The electret article may be in the form of a porous web of polymeric fibers suitable for use as a filter. The inventive electret article is resistant to charge degradation upon exposure to high temperatures for prolonged time periods.
摘要翻译： 一种驻极体制品，其包含具有赋予电荷的聚合物材料，其具有至少0.15的CF 3/3 CF 2 - 比率，并且其含氟比例大于 约200个。驻极体制品可以是适合用作过滤器的聚合物纤维的多孔网的形式。 本发明的驻极体制品在长时间暴露于高温下可抵抗电荷降解。
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公开(公告)号：US20100252047A1
公开(公告)日：2010-10-07
申请号：US12418290
申请日：2009-04-03
申请人： Seth M. Kirk , Marvin E. Jones , Steven J. Pachuta , Andrew W. Chen , William P. Klinzing , Patrick J. Sager
发明人： Seth M. Kirk , Marvin E. Jones , Steven J. Pachuta , Andrew W. Chen , William P. Klinzing , Patrick J. Sager
CPC分类号： B01D39/1623 , B01D46/0032 , B01D2239/025 , B01D2239/0414 , B01D2239/0435 , B01D2239/0622 , B01D2239/0627 , B01D2239/10 , B03C3/28 , B03C3/30 , B03C3/64 , B03C7/006 , B03C2201/26 , C23C16/50 , D06M10/025 , D06M10/06 , D06M2200/00 , Y10T442/2008 , Y10T442/2475 , Y10T442/608 , Y10T442/68
摘要： A method of making a fluorinated fibrous web, which method includes providing a nonwoven web 22 that contains polymeric fibers, creating a plasma that contains fluorine atoms at a first location 14, and contacting the nonwoven web with products from the plasma at a second location 26 remote from the first location 14. The method avoids exposure of the web to the plasma and hence expands the manufacturing processing window. Webs so fluorinated have a different C3F4H+ to C2F5+ ratio when compared to locally fluorinated webs having similar levels of surface fluorination. The remote fluorinated webs can be subsequently charged electrically to provide a good performing electret filter 40 suitable for use in an air purifying respirator 30. Webs fluorinated in accordance with this invention also may exhibit good performance even after being “aged” at high temperatures.
摘要翻译： 一种制造氟化纤维网的方法，该方法包括提供含有聚合物纤维的非织造纤维网22，在第一位置14产生含有氟原子的等离子体，并使第二位置26处的来自等离子体的产物接触非织造纤维网 远离第一位置14.该方法避免了将幅材暴露于等离子体，并因此扩展了制造处理窗口。 当与具有相似水平的表面氟化的局部氟化网相比时，如此氟化的网具有不同的C3F4H +至C2F5 +比。 远程氟化纤维网随后可以电连接以提供适合用于空气净化呼吸器30的性能优异的驻极体过滤器40.根据本发明氟化的网络即使在高温下“老化”之后也可能表现出良好的性能。
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公开(公告)号：US20110162653A1
公开(公告)日：2011-07-07
申请号：US13049051
申请日：2011-03-16
申请人： Seth M. Kirk , Marvin E. Jones , Steven J. Pachuta , Andrew W. Chen , William P. Klinzing , Patrick J. Sager
发明人： Seth M. Kirk , Marvin E. Jones , Steven J. Pachuta , Andrew W. Chen , William P. Klinzing , Patrick J. Sager
CPC分类号： B01D39/1623 , B01D46/0032 , B01D2239/025 , B01D2239/0414 , B01D2239/0435 , B01D2239/0622 , B01D2239/0627 , B01D2239/10 , B03C3/28 , B03C3/30 , B03C3/64 , B03C7/006 , B03C2201/26 , C23C16/50 , D06M10/025 , D06M10/06 , D06M2200/00 , Y10T442/2008 , Y10T442/2475 , Y10T442/608 , Y10T442/68
摘要： A method of making a fluorinated fibrous web, which method includes providing a nonwoven web 22 that contains polymeric fibers, creating a plasma that contains fluorine atoms at a first location 14, and contacting the nonwoven web with products from the plasma at a second location 26 remote from the first location 14. The method avoids exposure of the web to the plasma and hence expands the manufacturing processing window. Webs so fluorinated have a different C3F4H+ to C2F5+ ratio when compared to locally fluorinated webs having similar levels of surface fluorination. The remote fluorinated webs can be subsequently charged electrically to provide a good performing electret filter 40 suitable for use in an air purifying respirator 30. Webs fluorinated in accordance with this invention also may exhibit good performance even after being “aged” at high temperatures.
摘要翻译： 一种制造氟化纤维网的方法，该方法包括提供含有聚合物纤维的非织造纤维网22，在第一位置14产生含有氟原子的等离子体，并使第二位置26处的来自等离子体的产物接触非织造纤维网 远离第一位置14.该方法避免了将幅材暴露于等离子体，并因此扩展了制造处理窗口。 当与具有相似水平的表面氟化的局部氟化网相比时，如此氟化的网具有不同的C3F4H +至C2F5 +比。 远程氟化纤维网随后可以电连接以提供适合用于空气净化呼吸器30的性能优异的驻极体过滤器40.根据本发明氟化的网络即使在高温下“老化”之后也可能表现出良好的性能。
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公开(公告)号：US10035909B2
公开(公告)日：2018-07-31
申请号：US13502836
申请日：2009-12-17
申请人： William J. Schultz , Mary I. Buckett , Peter D. Condo , Douglas P. Goetz , Chad A. Haraldson , Mark McCormick , Wendy L. Thompson , Steven J. Pachuta
发明人： William J. Schultz , Mary I. Buckett , Peter D. Condo , Douglas P. Goetz , Chad A. Haraldson , Mark McCormick , Wendy L. Thompson , Steven J. Pachuta
CPC分类号： C08L63/00 , C08K3/26 , C08K5/42 , C08K9/04 , C08K2003/265
摘要： Compositions comprising surface-modified calcite nanoparticles dispersed in a curable resin and to coatings and fibrous composites incorporating such compositions are described. The nanocalcite particles have a high magnesium to calcium surface concentration ratio. The surface-modifying agents include a binding group ionically associated with the nanoparticles, and a compatiblizing segment compatible with the curable resin. The surface-modifying agent may also include a reactive group capable of reacting with the curable resin. Methods of preparing nanocalcite composites, and coatings and fibrous composites prepared from such nanocalcite composites are also described.
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公开(公告)号：US20120245253A1
公开(公告)日：2012-09-27
申请号：US13502836
申请日：2009-12-17
申请人： William J. Schultz , Mary I. Buckett , Peter D. Condo , Douglas P. Goetz , Chad A. Haraldson , Mark McCormick , Wendy L. Thompson , Steven J. Pachuta
发明人： William J. Schultz , Mary I. Buckett , Peter D. Condo , Douglas P. Goetz , Chad A. Haraldson , Mark McCormick , Wendy L. Thompson , Steven J. Pachuta
IPC分类号： C09D163/00 , B05D3/00
摘要： Compositions comprising surface-modified calcite nanoparticles dispersed in a curable resin and to coatings and fibrous composites incorporating such compositions are described. The nanocalcite particles have a high magnesium to calcium surface concentration ratio. The surface-modifying agents include a binding group ionically associated with the nanoparticles, and a compatiblizing segment compatible with the curable resin. The surface-modifying agent may also include a reactive group capable of reacting with the curable resin. Methods of preparing nanocalcite composites, and coatings and fibrous composites prepared from such nanocalcite composites are also described.
摘要翻译： 描述了包含分散在可固化树脂中的表面改性方解石纳米颗粒的组合物和包含这种组合物的涂层和纤维复合材料。 纳米碳酸钙颗粒具有高镁/钙表面浓度比。 表面改性剂包括与纳米颗粒离子键合的结合基团和与可固化树脂相容的相容片段。 表面改性剂也可以包括能够与可固化树脂反应的反应性基团。 还描述了制备纳米碳酸钙复合材料的方法，以及由这种纳米碳酸钙复合材料制备的涂层和纤维复合材料。
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