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    Process for reducing losses of mercury in alkali metal chloride electrolysis
    1.
    发明授权
    Process for reducing losses of mercury in alkali metal chloride electrolysis 失效
    降低碱金属氯化物电解汞损失的方法

    公开(公告)号：US4212715A

    公开(公告)日：1980-07-15

    申请号：US20086

    申请日：1979-03-13

    申请人： Siegfried Benninger ,  Adolf Schmidt

    发明人： Siegfried Benninger ,  Adolf Schmidt

    IPC分类号： C25B1/36 ,  C25B15/08

    CPC分类号： C25B15/08 ,  C25B1/36

    摘要： Brine (an aqueous solution of alkali metal chlorine) which is electrolyzed according to the amalgamation process, generally contains small amounts of mercury. It has been found that these traces of mercury are entrained with the evaporated water in a considerable amount when applying evaporation cooling to the brine. In order to keep these losses as low as possible, a pH of from 7 to 9.0 and a redox potential more than 1391-6.66(pH)-5.94(pH).sup.2 but not more than 1100 mV (based on the potential of the hydrogen electrode) is adjusted by adding chlorine or alkali metal hypochlorite and optionally alkali metal hydroxide to the brine.

    摘要翻译： 根据合并方法电解的盐水（碱金属氯的水溶液）通常含有少量的汞。 已经发现，当向盐水施加蒸发冷却时，这些痕量的汞被大量的蒸发的水夹带。 为了保持这些损失尽可能低，pH为7至9.0，氧化还原电位大于1391-6.66（pH）-5.94（pH）2但不大于1100mV（基于氢的电位 电极）通过向盐水中加入氯或碱金属次氯酸盐和任选的碱金属氢氧化物来调节。

    Process for preparing 2,2'-dimethyl-1,1'binaphthyl and 2,7'-dimethyl-1,1'-binaphthyl
    3.
    发明授权
    Process for preparing 2,2'-dimethyl-1,1'binaphthyl and 2,7'-dimethyl-1,1'-binaphthyl 失效
    制备2,2'-二甲基-1,1'-联萘和2,7'-二甲基-1,1'-联萘的方法

    公开(公告)号：US5767333A

    公开(公告)日：1998-06-16

    申请号：US351609

    申请日：1994-12-08

    申请人： Hans Millauer ,  Adolf Schmidt

    发明人： Hans Millauer ,  Adolf Schmidt

    IPC分类号： C07C2/80 ,  C07C15/24 ,  C25B3/10 ,  C25B3/12 ,  C07C2/02

    CPC分类号： C25B3/10 ,  C07C15/24

    摘要： 2,7'-Dimethyl-1,1'-binaphthyl and a process for preparing 2,2'-dimethyl-1,1'-binaphthyl and 2,7'-dimethyl-1,1'-binaphthyl by electrochemically oxidatively dimerizing 2-methylnaphthalene in the presence of acetonitrile/water/electrolyte salt mixtures which additionally contain at least one further component which, is immiscible or only partially miscible with water, and rectifying the reaction mixture obtained under reduced pressure.

    摘要翻译： 2,7'-二甲基-1,1'-联萘和通过电化学氧化二聚制备2,2'-二甲基-1,1'-联萘和2,7'-二甲基-1,1'-联萘的方法2 - 甲基萘在乙腈/水/电解质盐混合物的存在下，另外含有至少一种与水不混溶或仅部分混溶的另外的组分，并对减压下获得的反应混合物进行精馏。

    ABS type thermoplastic moulding compounds
    4.
    发明授权
    ABS type thermoplastic moulding compounds 失效
    ABS型热塑性成型料

    公开(公告)号：US5719232A

    公开(公告)日：1998-02-17

    申请号：US424656

    申请日：1995-04-19

    申请人： Adolf Schmidt ,  Herbert Eichenauer ,  Ulrich Jansen

    发明人： Adolf Schmidt ,  Herbert Eichenauer ,  Ulrich Jansen

    IPC分类号： C08F2/22 ,  C08L55/02

    CPC分类号： C08L55/02 ,  Y10S525/902

    摘要： ABS type thermoplastic moulding compounds obtainable by A) producing a rubber latex with an average particle diameter d.sub.50 of 30 to 160 nm and a gel content of 75 to 100 wt. % B) emulsion polymerization of an amount of butadiene and optionally up to 50 wt. % (with reference to the total amount of monomer in stage B) of a comonomer in the presence of the rubber obtained in stage A, such that a rubber latex (B) with an average particle diameter d.sub.50 =220 to 330 nm and a gel content of 25 to 70 wt. % is produced, C) emulsion polymerization of 40 to 95 parts by wt. of a mixture of styrene and acrylonitrile, which optionally contains up to 50 wt. % (with reference to the total amount of monomers used in stage C) of one or more comonomers, in the presence of 5 to 60 parts by wt. (with reference to the solids) of the rubber obtained in stage B by introducing the monomer in such a way that 55 to 90 wt. % of the monomers are added within the first half of the total monomer introduction time, and D) mixing the polymer obtained in stage C, preferably after first converting it into a powder, with at least one thermoplastic vinyl resin.

    摘要翻译： ABS型热塑性成型化合物，其可通过以下方法得到：A）制备平均粒径d50为30〜160nm，凝胶含量为75〜100重量％的橡胶胶乳。 B）一定量的丁二烯的乳液聚合和任选的至多50wt。 在阶段A中获得的橡胶存在下，共聚单体的％（相对于阶段B中的单体的总量），使得平均粒径d 50 = 220〜330nm的橡胶胶乳（B）和凝胶 含量为25〜70wt。 产生％，C）乳液聚合40〜95重量份。 的苯乙烯和丙烯腈的混合物，其任选地含有至多50重量％ 在5至60重量份存在下，一种或多种共聚单体的％（相对于阶段C中使用的单体的总量）。 （相对于固体），通过以55〜90重量％的比例引入单体，得到阶段B中得到的橡胶。 在全部单体引入时间的前半部分内加入％的单体，和D）将在阶段C中获得的聚合物，优选在首先将其转化为粉末之后，与至少一种热塑性乙烯基树脂混合。

    Copolymer dispersions
    5.
    发明授权
    Copolymer dispersions 失效
    共聚物分散体

    公开(公告)号：US4321175A

    公开(公告)日：1982-03-23

    申请号：US100418

    申请日：1979-12-05

    申请人： Adolf Schmidt ,  Werner Clarenz

    发明人： Adolf Schmidt ,  Werner Clarenz

    IPC分类号： C08F2/00 ,  C08F2/22 ,  C08F2/26 ,  C08F220/00 ,  C08F220/04 ,  C08F220/10 ,  C08F220/18 ,  C09D133/06 ,  C08F220/06

    CPC分类号： C09D133/064 ,  C08F220/18 ,  Y10T428/31692 ,  Y10T428/31989

    摘要： 40-50% by weight finely divided, stable, aqueous dispersions (particle size 0.1-0.15.mu.) of copolymers of copolymerized units of20-48% by weight of acrylonitrile which may be partially substituted by styrene,47,5-70,5% by weight of n-butyl acrylate,3,5-4,5% by weight of methacrylic acid, which may be substituted up to 50% by acrylic acid and0-5% by weight of N-methoxymethyl metharylamide.The dispersions are prepared by a special process characterized by a critical combination of known process steps. The dispersions are eminently suitable for use as binders in unpigmented or pigmented aqueous dispersion paints for metal, wood, plastics and mineral substrates.

    摘要翻译： 40-50重量％的细分散，稳定的水分散体（粒度0.1-0.15μm）共聚单元的共聚物，其中20-48重量％的可以被苯乙烯部分取代的丙烯腈，47,5-70,5 重量％的丙烯酸正丁酯，3,5-4.5重量％的甲基丙烯酸，其可以被丙烯酸取代至多50％，和0-5重量％的N-甲氧基甲基甲基丙烯酰胺。 分散体通过特征在于以已知方法步骤的关键组合为特征的方法制备。 分散体特别适合用作金属，木材，塑料和矿物基材的未着色或着色的水性分散体涂料中的粘合剂。

    Azo-di-isobutyric acid-(N,N-hydroxyalkyl)-amidines
    6.
    发明授权
    Azo-di-isobutyric acid-(N,N-hydroxyalkyl)-amidines 失效
    偶氮二异丁酸 - （N，N-羟烷基） - 脒

    公开(公告)号：US4256636A

    公开(公告)日：1981-03-17

    申请号：US76235

    申请日：1979-09-17

    申请人： Ernst Roos ,  Herbert Bartl ,  Klaus Schuster ,  Adolf Schmidt

    发明人： Ernst Roos ,  Herbert Bartl ,  Klaus Schuster ,  Adolf Schmidt

    IPC分类号： C07C257/14 ,  C08F4/04 ,  C07C123/00

    CPC分类号： C07C257/14 ,  C08F4/04

    摘要： An azo di-isobutyric acid-(N,N'-hydroxyalkyl)-amidine corresponding to the formula (I): ##STR1## in which R and R', which may be the same or different, represent linear or branched alkylene radicals containing from 2 to 4 carbon atoms, andX represents R'-OH or H.They may be produced by reacting an azo-di-isobutyric acid iminoalkyl ether containing from 1 to 4 carbon atoms in the alkyl group with at least one mono-alkanolamine containing from 2 to 4 carbon atoms or with a mixture of at least one monoalkanolamine and at least one dialkanolamine each containing from 2 to 4 carbon atoms in an alkanol radical, the molar ratio of monoalkanolamines to dialkanolamines in the mixture amounting to substantially 1:1, in substantially equivalent quantitative ratios at a temperature in the range of from 0.degree. to 50.degree. C. The amidines may be used as polymerization initiators, as cross-linking agents and as blowing agents in the production of foams.

    摘要翻译： 对应于式（I）的偶氮二异丁酸 - （N，N'-羟基烷基） - 脒：其中R和R'可以相同或不同，表示直链或支链 含有2至4个碳原子的亚烷基，X代表R'-OH或H.

    Continuous bulk polymerization process
    7.
    发明授权
    Continuous bulk polymerization process 失效
    连续本体聚合工艺

    公开(公告)号：US4141934A

    公开(公告)日：1979-02-27

    申请号：US668984

    申请日：1976-03-22

    申请人： Frank Wingler ,  Adolf Schmidt ,  Lothar Liebig ,  Gerd Wassmuth

    发明人： Frank Wingler ,  Adolf Schmidt ,  Lothar Liebig ,  Gerd Wassmuth

    IPC分类号： C08F2/00 ,  C08F2/02 ,  C08F212/10 ,  C08F220/00 ,  C08F220/42 ,  C08F257/02

    CPC分类号： C08F212/10

    摘要： Copolymers ofA 22 to 96 mol-% of styrene and/or .alpha.-methyl styrene,B 0 to 78 mol-% of at least one monoolefinically unsaturated monomer containing nitrile groups, andC 0 to 50 mol-% of at least one monoolefinically unsaturated monomer different from A or B are obtained by continuous bulk polymerization in a homogeneous liquid phase, in several process stages, in one or more different temperature ranges and in the presence of one or more initiators with different dissociation times in each temperature range and under pressures of from 1 to 20 bars.In first stage the monomers are copolymerized with backmixing up to a conversion of from 10 - 60 mol-% in an ideally mixed tank reactor and then after optionally additional addition of further parts of monomers copolymerization is continued with backmixing in a completely flooded, self-cleaning polymerization kneader up to a residual monomer content of from 10-50 mol-%.Residual monomers are continuously removed from the copolymer up to a content of less than 0.5% by weight based on the copolymer.The process according to the invention provides uniform, compatible, homogeneous products which are free from gel-like particles and which combine improved transparency with greater dimensional stability under heat and better mechanical properties together with improved processibility.

    摘要翻译： A 22至96摩尔％的苯乙烯和/或α-甲基苯乙烯的共聚物，B 0至78摩尔％的至少一种含有腈基的单烯属不饱和单体和C 0至50摩尔％的至少一种单烯烃 不同于A或B的不饱和单体通过在均相液相中，在几个工艺阶段中，在一个或多个不同温度范围内并且在一个或多个在每个温度范围和下面具有不同解离时间的引发剂的存在下连续本体聚合获得 压力为1至20巴。

    Elastic-thermoplastic graft polymers with improved properties
    8.
    发明授权
    Elastic-thermoplastic graft polymers with improved properties 失效
    具有改进性能的弹性 - 热塑性接枝聚合物

    公开(公告)号：US5723540A

    公开(公告)日：1998-03-03

    申请号：US834755

    申请日：1997-04-03

    申请人： Herbert Eichenauer ,  Martin Bohnenpoll ,  Adolf Schmidt ,  Heinrich Alberts

    发明人： Herbert Eichenauer ,  Martin Bohnenpoll ,  Adolf Schmidt ,  Heinrich Alberts

    IPC分类号： C08F2/22 ,  C08F4/34 ,  C08F279/02 ,  C08L25/12 ,  C08L27/12 ,  C08L51/04 ,  C08F291/02

    CPC分类号： C08F279/02 ,  C08F4/34 ,  C08L25/12 ,  C08L27/12 ,  C08L51/04

    摘要： Elastic-thermoplastic graft polymers manufactured by radical emulsion polymerization of resin-forming vinyl monomers in the presence of rubber present in latex form with the use of a combination of a peroxide of formula (I) ##STR1## where R.sup.1 signifies alkyl, cycloalkyl and aryl groups with 4 to 20 carbon atoms, X the groups --COOH and --SO.sub.3 H as well as their alkali, alkaline-earth or ammonium salts, n an integer in the range from 1 to 6, A alkylene, cycloalkylene and arylene groups with 6 to 40 carbon atoms and a reducing agent as initiator system, a method for their manufacture and their use as moulding compositions.

    摘要翻译： 弹性 - 热塑性接枝聚合物是通过在胶乳形式的橡胶存在下，通过使用式（I）的过氧化物（I）的组合使树脂形成乙烯基单体进行自由基乳液聚合而制备的，其中R 1表示烷基， 具有4至20个碳原子的环烷基和芳基，X是-COOH和-SO 3 H基团，以及它们的碱金属，碱土金属或铵盐，n为1至6的整数，亚烷基，亚环烷基和亚芳基 具有6至40个碳原子和还原剂作为引发剂体系，其制备方法及其作为模塑组合物的用途。

    Elastic-thermoplastic graft polymers with improved properties
    9.
    发明授权
    Elastic-thermoplastic graft polymers with improved properties 失效
    具有改进性能的弹性 - 热塑性接枝聚合物

    公开(公告)号：US5668218A

    公开(公告)日：1997-09-16

    申请号：US644133

    申请日：1996-05-10

    申请人： Herbert Eichenauer ,  Martin Bohnenpoll ,  Adolf Schmidt ,  Heinrich Alberts

    发明人： Herbert Eichenauer ,  Martin Bohnenpoll ,  Adolf Schmidt ,  Heinrich Alberts

    IPC分类号： C08F2/22 ,  C08F4/34 ,  C08F279/02 ,  C08L25/12 ,  C08L27/12 ,  C08L51/04

    CPC分类号： C08F279/02 ,  C08F4/34 ,  C08L25/12 ,  C08L27/12 ,  C08L51/04

    摘要： Elastic-thermoplastic graft polymers manufactured by radical emulsion polymerisation of resin-forming vinyl monomers in the presence of rubber present in latex form with the use of a combination of a peroxide of formula (I) ##STR1## where R.sup.1 signifies alkyl, cycloalkyl and aryl groups with 4 to 20 carbon atoms,X the groups --COOH and --SO.sub.3 H as well as their alkali, alkaline-earth or ammonium salts,n an integer in the range from 1 to 6,A alkylene, cycloalkylene and arylene groups with 6 to 40 carbon atomsand a reducing agent as initiator system, a method for their manufacture and their use as moulding compositions.

    摘要翻译： 弹性 - 热塑性接枝聚合物是通过在胶乳形式的橡胶存在下，通过使用式（I）的过氧化物（I）的组合使树脂形成乙烯基单体进行自由基乳液聚合制备的，其中R 1表示烷基， 具有4至20个碳原子的环烷基和芳基，X是-COOH和-SO 3 H基团，以及它们的碱金属，碱土金属或铵盐，n为1至6的整数，亚烷基，亚环烷基和亚芳基 具有6至40个碳原子和还原剂作为引发剂体系，其制备方法及其作为模塑组合物的用途。